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51.
52.
Bivalves (Crassostrea rizhophorae, Isognomon alatus, Codakia orbicularis Linné, and Tellina fausta) and sediment samples collected from 12 locations along the Dominican Republic coastline were used to assess the degree of nearshore contamination by selected chlorinated hydrocarbons and heavy metals. Concentrations of total chlordanes, DDTs and PCBs ranged from 0.51 to 7.47 ng/g, < MDL to 30.9 ng/g and 11.3 to 82.3 ng/g, and from < MDL to 1.73 ng/g, 0.21 to 12.5 ng/g and 0.46 to 41.9 ng/g in bivalves and surface sediments, respectively. The concentration ranges of predominantly anthropogenic Cu, Pb and Zn were 3.08–866 μg/g, 0.08–1.46 μg/g and 22.9–4380 μg/g in bivalve soft parts and 1.01–111 mg/g, 0.420–134 μg/g and 1.96–277 μg/g in surface sediments, respectively. Mercury concentrations ranged from 0.290 to 7.02 μg/g and from 0.096 to 0.565 μg/g in both matrices. The relatively high Hg concentrations found in bivalves from two stations in Bahia Samana, near to a known source of past Hg contamination in the sediments, require a more in-depth survey of the area. In general the concentrations of selected chlorinated hydrocarbons and trace metals, compared with those reported for the same matrices in the Caribbean and west Atlantic coastal areas, show at present the existence of only very localized contamination problems in the Dominican Republic.  相似文献   
53.
Using differential emission measure tomography (DEMT) based on time series of EUV images, we carry out a quantitative comparative analysis of the three-dimensional (3D) structure of the electron density and temperature of the inner corona (\(r<1.25\,\mathrm{R}_{\odot}\)) between two specific rotations selected from the last two solar minima, namely Carrington Rotations (CR)1915 and CR-2081. The analysis places error bars on the results because of the systematic uncertainty of the sources. While the results for CR-2081 are characterized by a remarkable north–south symmetry, the southern hemisphere for CR-1915 exhibits higher densities and temperatures than the northern hemisphere. The core region of the streamer belt in both rotations is found to be populated by structures whose temperature decreases with height (called “down loops” in our previous articles). They are characterized by plasma \(\beta\gtrsim1\), and may be the result of the efficient dissipation of Alfvén waves at low coronal heights. The comparative analysis reveals that the low latitudes of the equatorial streamer belt of CR-1915 exhibit higher densities than for CR-2081. This cannot be explained by the systematic uncertainties. In addition, the southern hemisphere of the streamer belt of CR-1915 is characterized by higher temperatures and density scale heights than for CR-2081. On the other hand, the coronal hole region of CR-1915 shows lower temperatures than for CR-2081. The reported differences are in the range \({\approx}\,10\,\mbox{--}\,25\%\), depending on the specific physical quantity and region that is compared, as fully detailed in the analysis. For other regions and/or physical quantities, the uncertainties do not allow assessing the thermodynamical differences between the two rotations. Future investigation will involve a DEMT analysis of other Carrington rotations selected from both epochs, and also a comparison of their tomographic reconstructions with magnetohydrodynamical simulations of the inner corona.  相似文献   
54.
The paper presents an analysis of 17 long annual maximum series (AMS) of flood flows for Swiss Alpine basins, aimed at checking the presence of changes in the frequency regime of annual maxima. We apply Pettitt's change point test, the nonparametric sign test and Sen's test on trends. We also apply a parametric goodness‐of‐fit test for assessing the suitability of distributions estimated on the basis of annual maxima collected up to a certain year for describing the frequency regime of later observations. For a number of series the tests yield consistent indications for significant changes in the frequency regime of annual maxima and increasing trends in the intensity of annual maximum discharges. In most cases, these changes cannot be explained by anthropogenic causes only (e.g. streamflow regulation, construction of dams). Instead, we observe a statistically significant relationship between the year of change and the elevation of the catchment outlet. This evidence is consistent with the findings of recent studies that explain increasing discharges in alpine catchments with an increase in the temperature controlling the portion of mountain catchments above the freezing point. Finally, we analyse the differences in return periods (RPs) estimated for a given flood flow on the basis of recent and past observations. For a large number of the study AMS, we observe that, on average, the 100‐year flood for past observations corresponds to a RP of approximately 10 to 30 years on the basis of more recent observation. From a complementary perspective, we also notice that estimated RP‐year flood (i.e. flood quantile (FQ) associated with RP) increases on average by approximately 20% for the study area, irrespectively of the RP. Practical implications of the observed changes are illustrated and discussed in the paper. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
55.
This paper presents a statistical model to characterize the long-term extreme value distribution of significant wave height, conditioning to the duration of the storm and accounting for seasonality. A time-dependent version of the peak over threshold (POT) approach is used to build the model, which is then applied to specific reanalysis time series and NOAA buoy records. The model considers the annual and semiannual cycles which are parameterized in terms of harmonic functions. The inclusion of seasonal variabilities substantially reduces the residuals of the fitted model. The information obtained in this study can be useful to design maritime works, because (a) the model improves the understanding of the variability of extreme wave climate along a year and (b) the model accounts for the duration of the storm, which is a key parameter in several formulations for rubble mound breakwater design.  相似文献   
56.
The present paper assesses the use of the supralittoral amphipod Talitrus saltator as a bioindicator of the effects of human trampling on the supralittoral sandy band. Samplings in delimited areas were carried out at sites subjected to different human impact. The results showed a strong negative correlation between the number of swimmers and the sandhopper population density, while there was no clear relationship between sandhopper abundance and the other factors considered: granulometry, compactness and organic carbon content of the sand, and trace metal contents in the sand and sandhoppers. A field test of trampling conducted in a confined space showed its direct negative effect on sandhopper survival. However, trace metal analysis confirmed the ability of T. saltator to bioaccumulate some elements (Hg, Zn, Cu, Cd). Our study demonstrates that T. saltator is a good bioindicator of human impact in the supralittoral zone of sandy shores.  相似文献   
57.
We explore the evolution of the angular velocity of an elastic Earth model, within the Hamiltonian formalism. The evolution of the rotation state of the Earth is caused by the tidal deformation exerted by the Moon and the Sun. It can be demonstrated that the tidal perturbation to spin depends not only upon the instantaneous orientation of the Earth, but also upon its instantaneous angular velocity. Parameterizing the orientation of the Earth figure axis with the three Euler angles, and introducing the canonical momenta conjugated to these, one can then show that the tidal perturbation depends both upon the angles and the momenta. This circumstance complicates the integration of the rotational motion. Specifically, when the integration is carried out in terms of the canonical Andoyer variables (which are the rotational analogues to the orbital Delaunay variables), one should keep in mind the following subtlety: under the said kind of perturbations, the functional dependence of the angular velocity upon the Andoyer elements differs from the unperturbed dependence (Efroimsky in Proceedings of Journées 2004: Systèmes de référence spatio-temporels. l’Observatoire de Paris, pp 74–81, 2005; Efroimsky and Escapa in Celest. Mech. Dyn. Astron. 98:251–283, 2007). This happens because, under angular velocity dependent perturbations, the requirement for the Andoyer elements to be canonical comes into a contradiction with the requirement for these elements to be osculating, a situation that parallels a similar antinomy in orbital dynamics. Under the said perturbations, the expression for the angular velocity acquires an additional contribution, the so called convective term. Hence, the time variation induced on the angular velocity by the tidal deformation contains two parts. The first one comes from the direct terms, caused by the action of the elastic perturbation on the torque-free expressions of the angular velocity. The second one arises from the convective terms. We compute the variations of the angular velocity through the approach developed in Getino and Ferrándiz (Celest. Mech. Dyn. Astron. 61:117–180, 1995), but considering the contribution of the convective terms. Specifically, we derive analytical formulas that determine the elastic perturbations of the directional angles of the angular velocity with respect to a non-rotating reference system, and also of its Cartesian components relative to the Tisserand reference system of the Earth. The perturbation of the directional angles of the angular velocity turns out to be different from the evolution law found in Kubo (Celest. Mech. Dyn. Astron. 105:261–274, 2009), where it was stated that the evolution of the angular velocity vector mimics that of the figure axis. We investigate comprehensively the source of this discrepancy, concluding that the difference between our results and those obtained in Ibid. stems from an oversimplification made by Kubo when computing the direct terms. Namely, in his computations Kubo disregarded the motion of the tide raising bodies with respect to a non-rotating reference system when compared with the Earth rotational motion. We demonstrate that, from a numerical perspective, the convective part provides the principal contribution to the variation of the directional angles and of length of day. In the case of the x and y components in the Tisserand system, the convective contribution is of the same order of magnitude as the direct one. Finally, we show that the approximation employed in Kubo (Ibid.) leads to significant numerical differences at the level of a hundred micro-arcsecond.  相似文献   
58.
Abstract– Six large iron meteorites have been discovered in the Meridiani Planum region of Mars by the Mars Exploration Rover Opportunity in a nearly 25 km‐long traverse. Herein, we review and synthesize the available data to propose that the discovery and characteristics of the six meteorites could be explained as the result of their impact into a soft and wet surface, sometime during the Noachian or the Hesperian, subsequently to be exposed at the Martian surface through differential erosion. As recorded by its sediments and chemical deposits, Meridiani has been interpreted to have undergone a watery past, including a shallow sea, a playa, an environment of fluctuating ground water, and/or an icy landscape. Meteorites could have been encased upon impact and/or subsequently buried, and kept underground for a long time, shielded from the atmosphere. The meteorites apparently underwent significant chemical weathering due to aqueous alteration, as indicated by cavernous features that suggest differential acidic corrosion removing less resistant material and softer inclusions. During the Amazonian, the almost complete disappearance of surface water and desiccation of the landscape, followed by induration of the sediments and subsequent differential erosion and degradation of Meridiani sediments, including at least 10–80 m of deflation in the last 3–3.5 Gy, would have exposed the buried meteorites. We conclude that the iron meteorites support the hypothesis that Mars once had a denser atmosphere and considerable amounts of water and/or water ice at and/or near the surface.  相似文献   
59.
This work focuses on a rigorous analysis of the physical–chemical, compositional and textural relationships of amphibole stability and the development of new thermobarometric formulations for amphibole-bearing calc-alkaline products of subduction-related systems. Literature experimental results (550–1,120°C, <1,200 MPa, −1 ≤ ΔNNO ≤ +5), H2O–CO2 solubility models, a multitude of amphibole-bearing calc-alkaline products (whole-rocks and glasses, representing 38 volcanoes worldwide), crustal and high-P (1–3 GPa) mantle amphibole compositions have been used. Calcic amphiboles of basalt-rhyolite volcanic products display tschermakitic pargasite (37%), magnesiohastingsite (32%) and magnesiohornblende (31%) compositions with aluminium number (i.e. Al# = [6]Al/AlT) ≤ 0.21. A few volcanic amphiboles (~1%) show high Al# (>0.21) and are inferred to represent xenocrysts of crustal or mantle materials. Most experimental results on calc-alkaline suites have been found to be unsuitable for using in thermobarometric calibrations due to the high Al# (>0.21) of amphiboles and high Al2O3/SiO2 ratios of the coexisting melts. The pre-eruptive crystallization of consistent amphiboles is confined to relatively narrow physical–chemical ranges, next to their dehydration curves. The widespread occurrence of amphiboles with dehydration (breakdown) rims made of anhydrous phases and/or glass, related to sub-volcanic processes such as magma mixing and/or slow ascent during extrusion, confirms that crystal destabilization occurs with relatively low TP shifts. At the stability curves, the variance of the system decreases so that amphibole composition and physical–chemical conditions are strictly linked to each other. This allowed us to retrieve some empirical thermobarometric formulations which work independently with different compositional components (i.e. Si*, AlT, Mg*, [6]Al*) of a single phase (amphibole), and are therefore easily applicable to all types of calc-alkaline volcanic products (including hybrid andesites). The Si*-sensitive thermometer and the fO2–Mg* equation account for accuracies of ±22°C (σest) and 0.4 log units (maximum error), respectively. The uncertainties of the AlT-sensitive barometer increase with pressure and decrease with temperature. Near the PT stability curve, the error is <11% whereas for crystal-rich (porphyritic index i.e. PI > 35%) and lower-T magmas, the uncertainty increases up to 24%, consistent with depth uncertainties of 0.4 km, at 90 MPa (~3.4 km), and 7.9 km, at 800 MPa (~30 km), respectively. For magnesiohornblendes, the [6]Al*-sensitive hygrometer has an accuracy of 0.4 wt% (σest) whereas for magnesiohastingsite and tschermakitic pargasite species, H2Omelt uncertainties can be as high as 15% relative. The thermobarometric results obtained with the application of these equations to calc-alkaline amphibole-bearing products were finally, and successfully, crosschecked on several subduction-related volcanoes, through complementary methodologies such as pre-eruptive seismicity (volcano-tectonic earthquake locations and frequency), seismic tomography, Fe–Ti oxides, amphibole–plagioclase, plagioclase–liquid equilibria thermobarometry and melt inclusion studies. A user-friendly spreadsheet (i.e. AMP-TB.xls) to calculate the physical–chemical conditions of amphibole crystallization is also provided.  相似文献   
60.
Extracellular enzymatic hydrolysis of high-molecular weight organic matter is the initial step in sedimentary organic carbon degradation and is often regarded as the rate-limiting step. Temperature effects on enzyme activities may therefore exert an indirect control on carbon mineralization. We explored the temperature sensitivity of enzymatic hydrolysis and its connection to subsequent steps in anoxic organic carbon degradation in long-term incubations of sediments from the Arctic and the North Sea. These sediments were incubated under anaerobic conditions for 24 months at temperatures of 0, 10, and 20 °C. The short-term temperature response of the active microbial community was tested in temperature gradient block incubations. The temperature optimum of extracellular enzymatic hydrolysis, as measured with a polysaccharide (chondroitin sulfate), differed between Arctic and temperate habitats by about 8-13 °C in fresh sediments and in sediments incubated for 24 months. In both Arctic and temperate sediments, the temperature response of chondroitin sulfate hydrolysis was initially similar to that of sulfate reduction. After 24 months, however, hydrolysis outpaced sulfate reduction rates, as demonstrated by increased concentrations of dissolved organic carbon (DOC) and total dissolved carbohydrates. This effect was stronger at higher incubation temperatures, particularly in the Arctic sediments. In all experiments, concentrations of volatile fatty acids (VFA) were low, indicating tight coupling between VFA production and consumption. Together, these data indicate that long-term incubation at elevated temperatures led to increased decoupling of hydrolytic DOC production relative to fermentation. Temperature increases in marine sedimentary environments may thus significantly affect the downstream carbon mineralization and lead to the increased formation of refractory DOC.  相似文献   
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