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1.
Abstract— Olivine in the angritic meteorite Lewis Cliff (LEW) 86010 contains abundant exsolution lamellae of kirschsteinite. Compositional gradients adjacent to the interface in both host and lamellae were formed by diffusion of chemical components into and out of the lamellae during cooling and growth. We have compared these gradients with compositional profiles calculated from diffusion and heat flow equations to estimate the cooling rate and burial depth of the sample. The resulting values for cooling rate and burial depth depend on which values are used for the diffusion rate of Ca in olivine, and how measured diffusivities are extrapolated to the lower temperatures at which the lamellae grew. If the highest diffusion coefficients are used, the cooling rates obtained from seven different lamellae range from 30 to 52 °C/year, with an average of 42 °C/year, and burial depths (assuming an overburden with a thermal diffusivity typical of solid rock) range from 14 to 17 m, with an average of 15 m. If the lowest reasonable diffusion coefficients are used, the cooling rates range from 1.4 to 2.2 °C/year, with an average of 1.7 °C/year, and the depths range from 68 to 83 m, with an average of 75 m. For the highest Ca diffusivities, details of the compositional profiles near the olivine/kirschsteinite interface suggest that continuous cooling was greatly accelerated at a temperature near 600–700 °C. The simplest physical explanation for such an acceleration is excavation of the sample from its original burial depth by an impact event. If Ca diffusivities are lower, a two-stage cooling history is not required.  相似文献   
2.
Fifteen rock reference samples "Igneous rock series" issued by the Geological Survey of Japan were analysed for up to 31 elements by neutron activation analysis (NAA); 14 MeV-NAA for Si and Al, fission track method for U, radiochemical and instrumental NAA for rare-earth elements, and instrumental NAA for the remaining elements, with reactor neutrons for the latter three. The present results are compared with published values.  相似文献   
3.
Abstract– Six large iron meteorites have been discovered in the Meridiani Planum region of Mars by the Mars Exploration Rover Opportunity in a nearly 25 km‐long traverse. Herein, we review and synthesize the available data to propose that the discovery and characteristics of the six meteorites could be explained as the result of their impact into a soft and wet surface, sometime during the Noachian or the Hesperian, subsequently to be exposed at the Martian surface through differential erosion. As recorded by its sediments and chemical deposits, Meridiani has been interpreted to have undergone a watery past, including a shallow sea, a playa, an environment of fluctuating ground water, and/or an icy landscape. Meteorites could have been encased upon impact and/or subsequently buried, and kept underground for a long time, shielded from the atmosphere. The meteorites apparently underwent significant chemical weathering due to aqueous alteration, as indicated by cavernous features that suggest differential acidic corrosion removing less resistant material and softer inclusions. During the Amazonian, the almost complete disappearance of surface water and desiccation of the landscape, followed by induration of the sediments and subsequent differential erosion and degradation of Meridiani sediments, including at least 10–80 m of deflation in the last 3–3.5 Gy, would have exposed the buried meteorites. We conclude that the iron meteorites support the hypothesis that Mars once had a denser atmosphere and considerable amounts of water and/or water ice at and/or near the surface.  相似文献   
4.
Abstract— Cooling rates of chondrules provide important constraints on the formation process of chondrite components at high temperatures. Although many dynamic crystallization experiments have been performed to obtain the cooling rate of chondrules, these only provide a possible range of cooling rates, rather than providing actual measured values from natural chondrules. We have developed a new model to calculate chondrule cooling rates by using the Fe‐Mg chemical zoning profile of olivine, considering diffusional modification of zoning profiles as crystals grow by fractional crystallization from a chondrule melt. The model was successfully verified by reproducing the Fe‐Mg zoning profiles obtained in dynamic crystallization experiments on analogs for type II chondrules in Semarkona. We applied the model to calculating cooling rates for olivine grains of type II porphyritic olivine chondrules in the Semarkona (LL3.00) ordinary chondrite. Calculated cooling rates show a wide range from 0.7 °C/h to 2400 °C/h and are broadly consistent with those obtained by dynamic crystallization experiments (10–1000 °C/h). Variations in cooling rates in individual chondrules can be attributed to the fact that we modeled grains with different core Fa compositions that are more Fe‐rich either because of sectioning effects or because of delayed nucleation. Variations in cooling rates among chondrules suggest that each chondrule formed in different conditions, for example in regions with varying gas density, and assembled in the Semarkona parent body after chondrule formation.  相似文献   
5.
Abstract– The Northwest Africa (NWA) 1500 meteorite is an olivine‐rich achondrite containing approximately 2–3 vol% augite, 1–2 vol% plagioclase, 1 vol% chromite, and minor orthopyroxene, Cl‐apatite, metal and sulfide. It was originally classified as a ureilite, but is currently ungrouped. We re‐examined the oxygen three‐isotope composition of NWA 1500. Results of ultra‐high precision (～0.03‰ for Δ17O) laser fluorination analyses of two bulk chips, and high precision (～0.3‰) secondary ion mass spectrometry (SIMS) analyses of olivine and plagioclase in a thin section, show that the oxygen isotope composition of NWA 1500 (Δ17O = ?0.22‰ from bulk samples and ?0.18 ± 0.06‰ from 16 mineral analyses) is within the range of brachinites. We compare petrologic and geochemical characteristics of NWA 1500 with those of brachinites and other olivine‐rich primitive achondrites, including new petrographic, mineral compositional and bulk compositional data for brachinites Hughes 026, Reid 013, NWA 5191, NWA 595, and Brachina. Modal mineral abundances, texture, olivine and pyroxene major and minor element compositions, plagioclase major element compositions, rare earth element abundances, and siderophile element abundances of NWA 1500 are within the range of those in brachinites and, in most cases, well distinguished from those of winonaites/IAB silicates, acapulcoites/lodranites, ureilites, and Divnoe. NWA 1500 shows evidence of internal reduction, in the form of reversely zoned olivine (Fo ～65–73 core to rim) and fine‐grained intergrowths of orthopyroxene + metal along olivine grain margins. The latter also occur in Reid 013, Hughes 026, NWA 5191, and NWA 595. We argue that reduction (olivine→enstatite + Fe0 + O2) is the best hypothesis for their origin in these samples as well. We suggest that NWA 1500 should be classified as a brachinite, which has implications for the petrogenesis of brachinites. Fe‐Mn‐Mg compositions of brachinite olivine provide evidence of redox processes among bulk samples. NWA 1500 provides evidence for redox processes on a smaller scale as well, which supports the interpretation that these processes occurred in a parent body setting. SIMS data for 26Al‐26Mg isotopes in plagioclase in NWA 1500 show no 26Mg excesses beyond analytical uncertainties (1–2‰). The calculated upper limit for the initial 26Al/27Al ratio of the plagioclase corresponds to an age younger than 7 Ma after CAI. Compared to 53Mn‐53Cr data for Brachina ( Wadhwa et al. 1998b ), this implies either a much younger formation age or a more protracted cooling history. However, Brachina is atypical and this comparison may not extend to other brachinites.  相似文献   
6.
Abstract— Amoeboid olivine aggregates (AOAs) from the reduced CV chondrites Efremovka, Leoville and Vigarano are irregularly‐shaped objects, up to 5 mm in size, composed of forsteritic olivine (Fa<10) and a refractory, Ca, Al‐rich component. The AOAs are depleted in moderately volatile elements (Mn, Cr, Na, K), Fe, Ni‐metal and sulfides and contain no low‐Ca pyroxene. The refractory component consists of fine‐grained calcium‐aluminum‐rich inclusions (CAIs) composed of Al‐diopside, anorthite (An100), and magnesium‐rich spinel (～1 wt% FeO) or fine‐grained intergrowths of these minerals; secondary nepheline and sodalite are very minor. This indicates that AOAs from the reduced CV chondrites are more pristine than those from the oxidized CV chondrites Allende and Mokoia. Although AOAs from the reduced CV chondrites show evidence for high‐temperature nebular annealing (e.g., forsterite grain boundaries form 120° triple junctions) and possibly a minor degree of melting of Al‐diopside‐anorthite materials, none of the AOAs studied appear to have experienced extensive (>50%) melting. We infer that AOAs are aggregates of high‐temperature nebular condensates, which formed in CAI‐forming regions, and that they were absent from chondrule‐forming regions at the time of chondrule formation. The absence of low‐Ca pyroxene and depletion in moderately volatile elements (Mn, Cr, Na, K) suggest that AOAs were either removed from CAI‐forming regions prior to condensation of these elements and low‐Ca pyroxene or gas‐solid condensation of low‐Ca‐pyroxene was kinetically inhibited.  相似文献   
7.
Nine rock reference samples "Sedimentary rock series" issued by the Geological Survey of Japan (GSJ) were analysed for up to 31 elements by neutron activation analysis (NAA); 14MeV-NAA for Si and Al, fission track method for U, radiochemical and instrumental NAA for rare-earth elements, and instrumental NAA for the remaining elements, with reactor neutrons for the latter three. The present results are compared with reported values.  相似文献   
8.
Abstract— The Nakhla meteorite, commonly accepted to have originated from Mars, is a cumulus clinopyroxenite with ～10 vol% of Fe‐rich olivine. Almost all olivine grains in Nakhla contain dark lamellar inclusions (less than 2–3 μm wide). High‐resolution scanning and transmission electron microscopy revealed that the inclusions are complex intergrowths of augite and magnetite. Such a symplectic intergrowth of augite and magnetite in olivine was known in some terrestrial rocks, lunar rocks, and a few meteorites. The inclusion in Nakhla olivine is the first symplectite found in a martian rock. Apparently, the presence of Fe3+ in olivine under an oxidizing condition on Mars caused symplectic exsolution at high temperature (>900 °C) during cooling.  相似文献   
9.
The paradigm of an ancient warm, wet, and dynamically active Mars, which transitioned into a cold, dry, and internally dead planet, has persisted up until recently despite published Viking-based geologic maps that indicate geologic and hydrologic activity extending into the Late Amazonian epoch. This paradigm is shifting to a water-enriched planet, which may still exhibit internal activity, based on a collection of geologic, hydrologic, topographic, chemical, and elemental evidences obtained by the Viking, Mars Global Surveyor (MGS), Mars Odyssey (MO), Mars Exploration Rovers (MER), and Mars Express (MEx) missions. The evidence includes: (1) stratigraphically young rock materials such as pristine lava flows with few, if any, superposed impact craters; (2) tectonic features that cut stratigraphically young materials; (3) features with possible aqueous origin such as structurally controlled channels that dissect stratigraphically young materials and anastomosing-patterned slope streaks on hillslopes; (4) spatially varying elemental abundances for such elements as hydrogen (H) and chlorine (Cl) recorded in rock materials up to 0.33 m depth; and (5) regions of elevated atmospheric methane. This evidence is pronounced in parts of Tharsis, Elysium, and the region that straddles the two volcanic provinces, collectively referred to here as the Tharsis/Elysium corridor. Based in part on field investigations of Solfatara Crater, Italy, recommended as a suitable terrestrial analog, the Tharsis/Elysium corridor should be considered a prime target for Mars Reconnaissance Orbiter (MRO) investigations and future science-driven exploration to investigate whether Mars is internally and hydrologically active at the present time, and whether the persistence of this activity has resulted in biologic activity.  相似文献   
10.
Abstract— We measured infrared diffuse reflectance spectra of several carbonaceous chondrites in order to obtain additional information on the surface materials of their presumed parent bodies, C-type asteroids. The presence and intensity of absorption bands near 3 μm in the reflectance spectra are due to the presence and abundance of hydrates and/or hydroxyl ions. The absorption features of the 3 μm hydration bands of carbonaceous chondrites were compared with those of asteroids 1 Ceres and 2 Pallas. They are commonly classified into separate subtypes, G- and B-type. The spectral shapes of Pallas and Renazzo (CR2 chondrite) around the 3 μm absorption band are an excellent match. This result may suggest that the amount of hydrous minerals in the surface material of Pallas is smaller than that in the CM2 or CI chondrites, and the hydrous minerals on the surface of Pallas may be similar to those found in Renazzo. The spectral features around the 3 μm band of Ceres are different from those of carbonaceous chondrites studied in this paper.  相似文献   
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