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51.
Sediments are depositories of toxic substances such as organochlorine pesticides and there is a global need for their removal in contaminated environments. Studies that combine contaminated sediments and phytoremediation are relatively recent and their number has been increasing. This work aimed to investigate whether salt marsh plants (sea club-rush Scirpus maritimus, sea rush Juncus maritimus and sea purslane Halimione portulacoides) can favor DDT and metabolites remediation in estuarine environment. For this purpose the levels of DDT, DDE and DDD were compared in vegetated and non-vegetated sediments from an estuary in the North of Portugal (in-situ study) and from another in the South of Portugal (ex-situ study). Results obtained both in the in-situ study, involving S. maritimus and J. maritimus, and in the ex-situ study, involving H. portulacoides, indicated that these plants did not have a significant role in DDTs removal and/or degradation. Therefore, it seems that the tested plants cannot influence levels and distribution of DDTs in estuarine areas.  相似文献   
52.
ABSTRACT

This paper is the outcome of a community initiative to identify major unsolved scientific problems in hydrology motivated by a need for stronger harmonisation of research efforts. The procedure involved a public consultation through online media, followed by two workshops through which a large number of potential science questions were collated, prioritised, and synthesised. In spite of the diversity of the participants (230 scientists in total), the process revealed much about community priorities and the state of our science: a preference for continuity in research questions rather than radical departures or redirections from past and current work. Questions remain focused on the process-based understanding of hydrological variability and causality at all space and time scales. Increased attention to environmental change drives a new emphasis on understanding how change propagates across interfaces within the hydrological system and across disciplinary boundaries. In particular, the expansion of the human footprint raises a new set of questions related to human interactions with nature and water cycle feedbacks in the context of complex water management problems. We hope that this reflection and synthesis of the 23 unsolved problems in hydrology will help guide research efforts for some years to come.  相似文献   
53.
In this article, we present a study on the tidal bore dynamics based on the analysis of the database acquired in 2011 during two simultaneous field campaigns in the Seine and Garonne Rivers. We have shown that in the Garonne River, contrary to the common view, undular tidal bore can form for a large majority of tides, even sometimes at neap tide when the river discharge is low. We have identified, from surface elevation measurements, low-steepness, low-frequency undular tidal bores which are not visually observable. Such low-frequency tidal bores have been also identified and characterised for the first time in the Seine River. In this river, the first undulation wave height can be higher than 1 m. We have shown that the secondary wave steepness strongly increases when the Froude number exceeds the critical value Fc. The large-steepness tidal bore regime corresponds to what is commonly termed in French mascaret.  相似文献   
54.
This work investigates the behavior of the sunspot number and Southern Oscillation Index (SOI) signal recorded in the tree ring time series for three different locations in Brazil: Humaitá in Amaz?nia State, Porto Ferreira in S?o Paulo State, and Passo Fundo in Rio Grande do Sul State, using wavelet and cross-wavelet analysis techniques. The wavelet spectra of tree ring time series showed signs of 11 and 22?years, possibly related to the solar activity, and periods of 2–8?years, possibly related to El Ni?o events. The cross-wavelet spectra for all tree ring time series from Brazil present a significant response to the 11-year solar cycle in the time interval between 1921 to after 1981. These tree ring time series still have a response to the second harmonic of the solar cycle (5.5?years), but in different time intervals. The cross-wavelet maps also showed that the relationship between the SOI x tree ring time series is more intense, for oscillation in the range of 4–8?years.  相似文献   
55.
A toposequence of Holocene soils located between 1100–2400 m asl in the Italian Alps served as the basis for the following analyses: the weathering of limestone and dolomite, the calculation of mass balances, understanding the formation of pedogenic Fe and Al, the determination of soil mineral and clay mineral reactions and transformation and the measurement of accumulation and stabilisation mechanisms of soil organic matter. Leaching of carbonates is most intense at the lower elevations, although calcite and dolomite have a higher solubility at low temperatures. The pCO2 in the soil is higher at lower elevations and weathering is driven mainly by carbonic acids. At higher elevations, organic acids appear to determine the mineral transformations and weathering reactions to a greater extent. This suggests that two very different weathering regimes (carbonic and organic acid weathering) exist along the toposequence. The transformation of mica into vermiculite is the main process in both the clay and fine-earth fraction. Weathering of silicate minerals started even before the carbonates had been completely removed from the soils. The transformation mechanisms of silicate minerals in the A and O horizon at higher elevations was at least as intensive as that at the climatically warmer sites. The neoformation of pedogenetic clays at climatically cooler sites was slightly greater than that at the warmer sites. However, the formation rate of secondary Fe and Al phases was more pronounced at lower elevation, which means that this process seemed to be driven dominantly by carbonic acid (weathering of primary minerals). Soil organic matter (SOM) abundance in the mineral soil is nearly 15 kg/m2 at all sites and, surprisingly, no climate-driven effect could be detected. In general, the preservation and stabilisation of SOM was due to poorly crystalline Al and Fe phases and vermiculite, regardless of some variations in the composition of the parent material (varying calcite/dolomite ratio).  相似文献   
56.
Interactions between climate and soil remain ambiguous, particularly when silicate weathering and clay mineral formation and transformation rates are considered in relation to global climate changes. Recent studies suggest that climate affects weathering rates much less than previously thought. Here we show that the climate in the central European Alps has a significant, but indirect, influence on the weathering of soils through vegetation. The pattern of element leaching and mineral transformations is not only due to precipitation and temperature. Element leaching was greatest in subalpine forests near the timberline; weathering is lessened at higher and lower altitudes. Vegetation, therefore, contributes significantly to weathering processes. The highest accumulation of organic matter was found in climatically cooler sites (subalpine range) where the production of organic ligands, which enhance weathering, is greatest. Patterns of smectite formation and distribution had strong similarities to that of the elemental losses of Fe and Al (R = 0.69; P < 0.01) or base cations (R = 0.58; P < 0.05). Higher precipitation rates and the production of organic chelating compounds in the soil promoted the appearance of smectites. The relationship between climate, element leaching (Fe, Al, Ca, Mg, K, Na), and smectite formation is strongly nonlinear and driven by the podzolisation process, which is more pronounced near the timberline because of the bioclimatic constellation. Climate warming will probably, in the future, lead to a decrease in SOM stocks in the subalpine to alpine range because of more favourable conditions for biodegradation that would also affect weathering processes.  相似文献   
57.
58.
A joint analysis of down-hole (DH) and multichannel analysis of surface waves (MASW) measurements offers a complete evaluation of shear wave velocity profiles, especially for sites where a strong lateral variability is expected, such as archeological sites. In this complex stratigraphic setting, the high “subsoil anisotropy” (i.e., sharp lithological changes due to the presence of anthropogenic backfill deposits and/or buried man-made structures) implies a different role for DH and MASW tests. This paper discusses some results of a broad experimental program conducted on the Palatine Hill, one of the most ancient areas of the city of Rome (Italy). The experiments were part of a project on seismic microzoning and consisted of 20 MASW and 11 DH tests. The main objective of this study was to examine the difficulties related to the interpretation of the DH and MASW tests and the reliability limits inherent in the application of the noninvasive method in complex stratigraphic settings. As is well known, DH tests provide good determinations of shear wave velocities (Vs) for different lithologies and man-made materials, whereas MASW tests provide average values for the subsoil volume investigated. The data obtained from each method with blind tests were compared and were correlated to site-specific subsurface conditions, including lateral variability. Differences between punctual (DH) and global (MASW) Vs measurements are discussed, quantifying the errors by synthetic comparison and by site response analyses. This study demonstrates that, for archeological sites, VS profiles obtained from the DH and MASW methods differ by more than 15 %. However, the local site effect showed comparable results in terms of natural frequencies, whereas the resolution of the inverted shear wave velocity was influenced by the fundamental mode of propagation.  相似文献   
59.
60.
The present paper addresses the problem of factor of safety (FS) determination in 3D slope stability analysis. For that purpose, use is made of two numerical methods/techniques in three benchmark problems: numerical limit analysis (NLA) and elasto-plastic analysis (EPA). Finite elements are used in both techniques. The primary objective of the study is, by comparing the two techniques, to establish the feasibility of using NLA in the evaluation of 3D slope stability problems and to establish its practical applicability and competitiveness in relation to EPA. Because of their geometry or their boundary conditions, the problems cannot be analysed as plane strain state problems or using the 2D limit equilibrium technique. In both methods, an FS is determined for the slopes by reducing the strength parameters of the geological materials using a scalar factor, known as the strength reduction factor. From the comparison of the FSs and of the computational efforts required for the two numerical techniques, it was possible to establish NLA’s competiveness and viability for the analysis of real 3D slope stability problems when implemented in an efficient manner.  相似文献   
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