Effects of the peat acid digestion protocol on geochemically and morphologically diverse tephra deposits     

Alistair J. Monteath  Alex E. Teuten  Paul D. M. Hughes  Stefan Wastegrd 《第四纪科学杂志》2019,34(4-5):269-274

Tephra shards for electron probe microanalysis are most efficiently extracted from peat using acid digestion, which removes organic material that hinders density separation methods. However, strong acids are known to alter glass chemical compositions, and several studies have examined how acid digestion affects rhyolitic volcanic glass. The focus on rhyolitic tephra in these studies leaves considerable uncertainty, as the dissolution rates of natural glasses (including tephra) are determined by the chemical composition and surface area/volume ratio, both of which vary in tephra deposits. Here, we use duplicate samples of basaltic, trachydacitic and rhyolitic tephra to examine physical and geochemical alteration following acid digestion. Scanning electron microscope imagery reveals no discernible degradation of glass surfaces, and electron probe microanalysis results from duplicate samples are statistically indistinguishable. These findings suggest the acid digestion protocol for organic peats does not significantly alter glass geochemistry regardless of shard morphologies or geochemical compositions.  相似文献   

Stable carbon isotopes (δ<Superscript>13</Superscript>C) of total organic carbon and long-chain <Emphasis Type="Italic">n</Emphasis>-alkanes as proxies for climate and environmental change in a sediment core from Lake Petén-Itzá, Guatemala     

Jennifer L. Mays  Mark Brenner  Jason H. Curtis  Kathryn V. Curtis  David A. Hodell  Alex Correa-Metrio  Jaime Escobar  Andrea L. Dutton  Andrew R. Zimmerman  Thomas P. Guilderson 《Journal of Paleolimnology》2017,57(4):307-319

Sediment core PI-6 from Lake Petén Itzá, Guatemala, possesses an ~85-ka record of climate and environmental change from lowland Central America. Variations in sediment lithology suggest large and abrupt changes in precipitation during the last glacial and deglacial periods, and into the early Holocene. We measured stable carbon isotope ratios of total organic carbon and long-chain n-alkanes from the core, the latter representing a largely allochthonous (terrestrial) source of organic matter, to reveal past shifts in the relative proportion of C₃–C₄ terrestrial biomass. We sought to test whether stable carbon isotope results were consistent with other paleoclimate proxies measured in the PI-6 core, and if extraction and isotope analysis of n-alkanes is warranted. The largest δ¹³C variations are associated with Heinrich Events. Carbon isotope values in sediments deposited during the last glacial maximum indicate moderate precipitation with little fluctuation. The deglacial was a period of pronounced climate variability, e.g. a relatively warm and moist Bølling–Allerød, but a cool and dry Younger Dryas. Arid periods of the deglacial were inferred from samples with high δ¹³C values in total organic carbon, which reflect times of greater proportions of C₄ plants. These inferences are supported by stable isotope measurements on ostracod shells and relative abundance of grass pollen from the same depths in core PI-6. Similar trends in carbon stable isotopes measured on bulk organic carbon and n-alkanes suggest that carbon isotope measures on bulk organic carbon in sediments from this lake are sufficient to infer past climate-driven shifts in local vegetation.  相似文献   

Fractionation of grain size in terrestrial sediment routing systems          下载免费PDF全文

Philip A. Allen  Nikolaos A. Michael  Mitchall D’Arcy  Duna C. Roda‐Boluda  Alexander C. Whittaker  Robert A. Duller  John J. Armitage 《Basin Research》2017,29(2):180-202

Sediment is fractionated by size during its cascade from source to sink in sediment routing systems. It is anticipated, therefore, that the grain size distribution of sediment will undergo down‐system changes as a result of fluvial sorting processes and selective deposition. We assess this hypothesis by comparing grain size statistical properties of samples from within the erosional source region with those that have undergone different amounts of transport. A truncated Pareto distribution describes well the coarser half of the clast size distribution of regolith, coarse channel bed sediment and proximal debris flows (particularly their levees), as well as the coarser half of the clast size distribution of gravels that have undergone considerable amounts of transport in rivers. The Pareto shape parameter a evolves in response to mobilization, sediment transport and, importantly, the selective extraction of particles from the surface flow to build underlying stratigraphy. A goodness of fit statistic, the Kolmogorov–Smirnov vertical difference, illustrates the closeness of the observed clast size distributions to the Pareto, Weibull and log‐normal models as a function of distance from the depositional apex. The goodness of fit of the particle size distribution of regolith varies with bedrock geology. Bedload sediment at catchment outlets is fitted well by the log‐normal and truncated Pareto models, whereas the exponential Weibull model provides a less good fit. In the Eocene Escanilla palaeo‐sediment routing system of the south‐central Pyrenees, the log‐normal and truncated Pareto models provide excellent fits for distances of up to 80 km from the depositional apex, whereas the Weibull fit progressively worsens with increasing transport distance. A similar trend is found in the Miocene–Pliocene gravels of the Nebraskan Great Plains over a distance of >300 km. Despite the large fractionation in mean grain size and gravel percentage from source region to depositional sink, particle size distributions therefore appear to maintain log‐normality over a wide range of transport distance. Use of statistical models enables down‐system fractionation of sediment released from source regions to be better understood and predicted and is a potentially valuable tool in source‐to‐sink approaches to basin analysis.  相似文献   

Constructing economic geographies from corporate interviews: insights from a cross-country comparison of retailer–supplier relationships     

Alex Hughes 《Geoforum》1999,30(4):469

In the light of the significant role played by corporate interviews in the construction of contemporary economic geographies, this paper suggests that the practices of corporate interviewing in the research process demand critical reflection. These practices are reflected upon in the context of a comparative study of retailer–manufacturer power relations in the UK and USA. In particular, attention is paid to the ways in which corporate interviews actively construct knowledge of contrasting own-brand supply relationships in these national economies. To do this, the paper addresses the following issues: (i) the embeddedness of corporate interviews in a transforming economic geography; (ii) the processes of identifying, and gaining access to, own-brand supply networks in the UK and USA; (iii) the use of materials resulting from corporate interviews to produce nuanced understandings of own-brand supply relationships; (iv) the adoption of an appropriate textual strategy for writing such interview-based material into economic geography.  相似文献   

Intercomparison of multiple statistical downscaling methods: multi-criteria model selection for South Korea     

Hyung-Il?EumEmail author  Alex?J.?Cannon  Trevor?Q.?Murdock 《Stochastic Environmental Research and Risk Assessment (SERRA)》2017,31(3):683-703

A number of statistical downscaling methodologies have been introduced to bridge the gap in scale between outputs of climate models and climate information needed to assess potential impacts at local and regional scales. Four statistical downscaling methods [bias-correction/spatial disaggregation (BCSD), bias-correction/constructed analogue (BCCA), multivariate adaptive constructed analogs (MACA), and bias-correction/climate imprint (BCCI)] are applied to downscale the latest climate forecast system reanalysis (CFSR) data to stations for precipitation, maximum temperature, and minimum temperature over South Korea. All methods are calibrated with observational station data for 19 years from 1973 to 1991 and validated for the more recent 19-year period from 1992 to 2010. We construct a comprehensive suite of performance metrics to inter-compare methods, which is comprised of five criteria related to time-series, distribution, multi-day persistence, extremes, and spatial structure. Based on the performance metrics, we employ technique for order of preference by similarity to ideal solution (TOPSIS) and apply 10,000 different weighting combinations to the criteria of performance metrics to identify a robust statistical downscaling method and important criteria. The results show that MACA and BCSD have comparable skill in the time-series related criterion and BCSD outperforms other methods in distribution and extremes related criteria. In addition, MACA and BCCA, which incorporate spatial patterns, show higher skill in the multi-day persistence criterion for temperature, while BCSD shows the highest skill for precipitation. For the spatial structure related criterion, BCCA and MACA outperformed BCSD and BCCI. From the TOPSIS analysis, we found that MACA is the most robust method for all variables in South Korea, and BCCA and BCSD are the second for temperature and precipitation, respectively. We also found that the contribution of the multi-day persistence and spatial structure related criteria are crucial to ranking the skill of statistical downscaling methods.  相似文献   

Three-Dimensional Modeling of the Casing Effect in Onshore Controlled-Source Electromagnetic Surveys     

Vladimir Puzyrev  Eloi Vilamajo  Pilar Queralt  Juanjo Ledo  Alex Marcuello 《Surveys in Geophysics》2017,38(2):527-545

The presence of steel-cased wells and other infrastructure causes a significant change in the electromagnetic fields that has to be taken into consideration in modeling and interpretation of field data. A realistic and accurate simulation requires the borehole casing to be incorporated into the modeling scheme, which is numerically challenging. Due to the huge conductivity contrast between the casing and surrounding media, a spatial discretization that provides accurate results at different spatial scales ranging from millimeters to hundreds of meters is required. In this paper, we present a full 3D frequency-domain electromagnetic modeling based on a parallel finite-difference algorithm considering the casing effect and investigate its applicability on the borehole-to-surface configuration of the Hontomín CO₂ storage site. To guarantee a robust solution of linear systems with highly ill-conditioned matrices caused by huge conductivity contrasts and multiple spatial scales in the model, we employ direct sparse solvers. Different scenarios are simulated in order to study the influence of the source position, conductivity model, and the effect of the steel casing on the measured data. Several approximations of the real hollow casing that allow for a large reduction in the number of elements in the resulting meshes are studied. A good agreement between the modeled responses and the real field data demonstrates the feasibility of simulating casing effects in complex geological areas. The steel casing of the well greatly increases the amplitude of the surface electromagnetic fields and thus improves the signal-to-noise ratio and the sensitivity to deep targets.  相似文献   

Normal fault growth and linkage in the Gediz (Alaşehir) Graben,Western Turkey,revealed by transient river long‐profiles and slope‐break knickpoints          下载免费PDF全文

Emiko Kent  Sarah J. Boulton  Alexander C. Whittaker  Iain S. Stewart  M. Cihat Alçiçek 《地球表面变化过程与地形》2017,42(5):836-852

The Gediz (Ala?ehir) Graben is located in the highly tectonically active and seismogenic region of Western Turkey. The rivers upstream of the normal fault‐bounded graben each contain a non‐lithologic knickpoint, including those that drain through inferred fault segment boundaries. Knickpoint heights measured vertically from the fault scale with footwall relief and documented fault throw (vertical displacement). Consequently, we deduce these knickpoints were initiated by an increase in slip rate on the basin‐bounding fault, driven by linkage of the three main fault segments of the high‐angle graben bounding fault array. Fault interaction theory and ratios of channel steepness suggest that the slip rate enhancement factor on linkage was a factor of 3. We combine this information with geomorphic and structural constraints to estimate that linkage took place between 0.6 Ma and 1 Ma. Calculated pre‐ and post‐linkage throw rates are 0.6 and 2 mm/yr respectively. Maximum knickpoint retreat rates upstream of the faults range from 4.5 to 28 mm/yr, faster than for similar catchments upstream of normal faults in the Central Apennines and the Hatay Graben of Turkey, and implying a fluvial landscape response time of 1.6 to 2.7 Myr. We explore the relative controls of drainage area and precipitation on these retreat rates, and conclude that while climate variation and fault throw rate partially explain the variations seen, lithology remains a potentially important but poorly characterised variable. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Towards Real‐Time Geodemographics: Clustering Algorithm Performance for Large Multidimensional Spatial Databases     

Muhammad Adnan  Paul A Longley  Alex D Singleton  Chris Brunsdon 《Transactions in GIS》2010,14(3):283-297

Geodemographic classifications provide discrete indicators of the social, economic and demographic characteristics of people living within small geographic areas. They have hitherto been regarded as products, which are the final “best” outcome that can be achieved using available data and algorithms. However, reduction in computational cost, increased network bandwidths and increasingly accessible spatial data infrastructures have together created the potential for the creation of classifications in near real time within distributed online environments. Yet paramount to the creation of truly real time geodemographic classifications is the ability for software to process and efficiency cluster large multidimensional spatial databases within a timescale that is consistent with online user interaction. To this end, this article evaluates the computational efficiency of a number of clustering algorithms with a view to creating geodemographic classifications “on the fly” at a range of different geographic scales.  相似文献   

Tectonics,sedimentation and surface processes: from the erosional engine to basin deposition          下载免费PDF全文

Sébastien Castelltort  Alex Whittaker  Jaume Vergés 《地球表面变化过程与地形》2015,40(13):1839-1846

  相似文献   

An advanced numerical model of elastomeric seismic isolation bearings   总被引：1，自引：0，他引：1       下载免费PDF全文

Manish Kumar  Andrew S. Whittaker  Michael C. Constantinou 《地震工程与结构动力学》2014,43(13):1955-1974

The nuclear accident at Fukushima Daiichi in March 2011 has led the nuclear community to consider seismic isolation for new large light water and small modular reactors to withstand the effects of beyond design basis loadings, including extreme earthquakes. The United States Nuclear Regulatory Commission is sponsoring a research project that will quantify the response of low damping rubber (LDR) and lead rubber (LR) bearings under loadings associated with extreme earthquakes. Under design basis loadings, the response of an elastomeric bearing is not expected to deviate from well‐established numerical models, and bearings are not expected to experience net tension. However, under extended or beyond design basis shaking, elastomer shear strains may exceed 300% in regions of high seismic hazard, bearings may experience net tension, the compression and tension stiffness will be affected by isolator lateral displacement, and the properties of the lead core in LR bearings will degrade in the short‐term because of substantial energy dissipation. New mathematical models of LDR and LR bearings are presented for the analysis of base isolated structures under design and beyond design basis shaking, explicitly considering both the effects of lateral displacement and cyclic vertical and horizontal loading. These mathematical models extend the available formulations in shear and compression. Phenomenological models are presented to describe the behavior of elastomeric isolation bearings in tension, including the cavitation and post‐cavitation behavior. The elastic mechanical properties make use of the two‐spring model. Strength degradation of LR bearing under cyclic shear loading due to heating of lead core is incorporated. The bilinear area reduction method is used to include variation of critical buckling load capacity with lateral displacement. The numerical models are coded in OpenSees, and the results of numerical analysis are compared with test data. The effect of different parameters on the response is investigated through a series of analyses. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献