Thallium removal through adsorption onto ionic liquid-impregnated solid support: influence of the impregnation conditions     

P. Negrea  A. Popa  L. Lupa  R. Voda 《International Journal of Environmental Science and Technology》2016,13(8):1873-1882

This article presents the use of ionic liquid in the removal process of thallium ions using solid–liquid extraction by impregnating ionic liquid (1-n-hexyl-3-methylimidazolium chloride) onto an inorganic solid support (Florisil). The influence of impregnation was studied in order to improve the adsorption capacity of the material obtained. Impregnation was realized with the help of a rotavapor. Stirring time and temperature used were varied. Ionic liquid-impregnated materials obtained at different conditions of impregnation were characterized using scanning electron microscopy, energy-dispersive X-ray analysis, and Fourier transform infrared spectroscopy. In order to determine the most efficient adsorbent material, the materials obtained were used in the removal process of thallium ions from aqueous solutions, varying the initial concentration of thallium ions and the stirring time used in the adsorption process. It was observed that for the improving the adsorption capacity of the obtained ionic liquid-impregnated material, it is not necessary to increase the stirring time of the impregnation process but to increase the temperature. The experimental data obtained in the adsorption process were fitted with the Langmuir isotherm. Adsorption of thallium ions onto Florisil impregnated with 1-n-hexyl-3-methylimidazolium chloride ionic liquid corresponds to a pseudo-second-order kinetic model.  相似文献   

Pressure-induced structural transition in Ln2Zr2O7 (Ln = Ce, Nd, Gd) pyrochlores     

S. Surblé  S. Heathman  P. E. Raison  D. Bouëxière  K. Popa  R. Caciuffo 《Physics and Chemistry of Minerals》2010,37(10):761-767

The structural behavior under pressure of three lanthanide pyrochlore zirconates Ln₂Zr₂O₇ (Ln³⁺ = Ce, Nd and Gd) has been investigated by X-ray diffraction up to 50 GPa. For all three compounds, a symmetry reduction from cubic to monoclinic is observed under increasing pressure dependant on a pressure value that increases with the ionic radius of the lanthanide ions, r _Ln. The cubic and monoclinic phases coexist over a wide pressure range which increases with r _Ln. The zero-pressure bulk modulus of the cubic phase, B ₀, and its pressure derivative, B ₀′, have been determined by fitting the experimental compressibility curves to the Birch–Murnaghan equation of state.  相似文献   

Note on the evolution of a Miocene composite volcano in an extensional setting, Zârand Basin (Apuseni Mts., Romania)     

Ioan Seghedi  Alexandru Szakács  Emilian Roşu  Zoltán Pécskay  Katalin Gméling 《Central European Journal of Geosciences》2010,2(3):321-328

Bontâu is a major eroded composite volcano filling the Miocene Zârand extensional basin, near the junction between the Codru-Moma and Highi?-Drocea Mountains, at the tectonic boundary between the South and North Apuseni Mountains. It is a quasi-symmetric structure (16–18 km in diameter) centered on an eroded vent area (9×4 km), buttressed to the south against Mesozoic ophiolites and sedimentary deposits of the South Apuseni Mountains. The volcano was built up in two sub-aerial phases (14–12.5 Ma and 11–10 Ma) from successive eruptions of andesite lava and pyroclastic rocks with a time-increasing volatile budget. The initial phase was dominated by emplacement of pyroxene andesite and resulted in scattered individual volcanic lava domes associated marginally with lava flows and/or pyroclastic block-and-ash flows. The second phase is characterized by amphibole-pyroxene andesite as a succession of pyroclastic eruptions (varying from strombolian to subplinian type) and extrusion of volcanic domes that resulted in the formation of a central vent area. Numerous debris flow deposits accumulated at the periphery of primary pyroclastic deposits. Several intrusive andesitic-dioritic bodies and associated hydrothermal and mineralization processes are known in the volcano vent complex area. Distal epiclastic deposits initially as gravity mass flows and then as alluvial volcaniclastic and terrestrial detritic and coal filled the basin around the volcano in its western and eastern part. Chemical analyses show that lavas are calc-alkaline andesites with SiO₂ ranging from 56–61%. The petrographical differences between the two stages are an increase in amphibole content at the expense of two pyroxenes (augite and hypersthene) in the second stage of eruption; CaO and MgO contents decrease with increasing SiO₂. In spite of a ～4 Ma evolution, the compositions of calc-alkaline lavas suggest similar fractionation processes. The extensional setting favored two pulses of short-lived magma chamber processes.  相似文献   

The urban heat island of Bucharest during the extreme high temperatures of July 2007     

Sorin Cheval  Alexandru Dumitrescu  Aurora Bell 《Theoretical and Applied Climatology》2009,97(3-4):391-401

This paper explores the characteristics of the air (T_air) and land surface temperature (LST) from the city of Bucharest (Romania) during the extreme high temperatures that affected the region in July 2007. The behavior of Bucharest’s Urban Heat Island (UHI) is quantitatively described following similar methodological approaches to previous studies. The analysis integrates thermal data supplied by the Moderate Resolution Imaging Spectroradiometer (MODIS) sensors aboard the NASA satellites and meteorological data provided by the ground-based weather stations. Based on the T_air, one may claim that during extreme high summer temperatures, the UHI preserves its spatial and temporal pattern regarding the differences between the central urban perimeter and the suburban area. The investigation of the LST from July 2007 reveals that the nocturnal changes refer mainly to the magnitude and the limits of the UHI, while the shape is not changed. However, the extreme temperatures induce significant modifications of the features of the diurnal UHI, obliterating and dissipating it in certain spots, enlarging it and creating shifted heat islands in some other spots. The main explanation is the outstanding duration and intensity of the hot mass of air impacting the area. The correlations between the T_air measured at the weather stations in Bucharest and the corresponding LST retrieved significant values both under “normal” conditions and extreme temperature persistence, and offer good premises for robust validation studies. The MODIS products performed like an extremely useful instrument for analyzing the UHI.  相似文献   

Paleolakes, paleofloods, and depressions in Aurorae and Ophir Plana, Mars: Connectivity of surface and subsurface hydrological systems     

Goro Komatsu  Gaetano Di Achille  Ciprian Popa  Stefano Di Lorenzo  Jose Alexis Palmero Rodriguez 《Icarus》2009,201(2):474-491

The plains of Aurorae and Ophir in the equatorial region of Mars display geomorphic evidence indicative of extensive but generally short-lived paleohydrological processes. Elaver Vallis in Aurorae Planum south of Ganges Chasma is an outflow channel system >180 km long, and here inferred to have formed by cataclysmic spillover flooding from a paleolake(s) contained in the Morella crater basin. Ganges Cavus is an enormous 5-km-deep depression of probable collapse origin located in the Morella basin. The fluid responsible for the infilling of the Morella basin likely emerged at least partially through Ganges Cavus or its incipient depression, and it may have been supplied also from small-scale springs in the basin. Similar paleohydrological processes are inferred also in Ophir Planum. It is reasonable to assume that water, sometimes sediment-laden and/or mixed with gases, was the responsible fluid for these phenomena although some of the observed features could be explained by non-aqueous processes such as volcanism. Water emergence may have occurred as consequences of ground ice melting or breaching of cryosphere to release water from the underlying hydrosphere. Dike intrusion is considered to be an important cause of formation for the cavi and smaller depressions in Aurorae and Ophir Plana, explaining also melting of ground ice or breaching of cryosphere. Alternatively, the depressions and crater basins may have been filled by regional groundwater table rising during the period(s) when cryosphere was absent or considerably thin. The large quantities of water necessary for explaining the paleohydrological processes in Aurorae and Ophir Plana could have been derived through crustal migration from the crust of higher plains in western Ophir Planum where water existed in confined aquifers or was produced by melting of ground ice due to magmatic heating or climatic shift, or from a paleolake in Candor Chasma further west.  相似文献   

Cs baseline levels in the Mediterranean and Black Sea: A cross-basin survey of the CIESM Mediterranean Mussel Watch programme     

Herv Thbault  Alessia M. Rodriguez y Baena  Bruno Andral  Delko Barisic  Jos Benedicto Albaladejo  Alexandru S. Bologa  Redouane Boudjenoun  Roberta Delfanti  Victor N. Egorov  Tahar El Khoukhi  Heleni Florou  Goran Kniewald  Abdelkader Noureddine  Vasile Patrascu  Mai Khanh Pham  Alfonso Scarpato  Nikolay A. Stokozov  Sayhan Topcuoglu  Michel Warnau 《Marine pollution bulletin》2008,57(6-12):801

The common mussel Mytilus galloprovincialis was selected as unique biomonitor species to implement a regional monitoring programme, the CIESM Mediterranean Mussel Watch (MMW), in the Mediterranean and Black Seas. As of today, and upon standardization of the methodological approach, the MMW Network has been able to quantify ¹³⁷Cs levels in mussels from 60 coastal stations and to produce the first distribution map of this artificial radionuclide at the scale of the entire Mediterranean and Black Seas. While measured ¹³⁷Cs levels were found to be very low (usually <1 Bq kg⁻¹ wet wt) ¹³⁷Cs activity concentrations in the Black Sea and North Aegean Sea were up to two orders of magnitude higher than those in the western Mediterranean Basin. Such effects, far from representing a threat to human populations or the environment, reflect a persistent signature of the Chernobyl fallout in this area.  相似文献   

Accuracy of CM-SAF solar irradiance incident on horizontal surface     

Viorel Badescu  Alexandru Dumitrescu 《Theoretical and Applied Climatology》2014,117(1-2):233-246

The Climate Monitoring Satellite Application Facility (CM-SAF) provides estimates of global solar irradiance incident on horizontal surface at Earth surface. Measurements performed in 2010 at five Romanian meteorological stations are used to test the accuracy of the CM-SAF irradiance data. The dataset contains null solar global irradiance values, which cannot be explained by very large values of the zenith angle neither by overcast sky conditions. Sub-databases have been created. The database Z85 consists of irradiance data, without filtering and processing. The database Z85SIS+ remove all null irradiance values. For a given database, the root mean square error (RMSE) with respect to the ground-based measurements is rather similar for all stations, i.e. around 35 % for Z85 and 24 % for Z85SIS+. On average, the database Z85SIS+ has smaller mean bias error (MBE) than the database Z85, independent of the degree of cloudiness. For the database Z85, MBE (RMSE) ranges, depending on station, between ?9.4 and ?1.2 % (35.3 and 39.1 %). For database Z85SIS+, the MBE (RMSE) ranges, depending on station, between ?4.0 and 0.1 % (23.0 and 29.1 %). On overcast sky, we found for some stations MBE?=??0.1 % and RMSE?=?46.4 % when the database Z85SIS+ has been considered. The accuracy of the database Z85 is lower; we found MBE?=??7.0 % and RMSE?=?58.8 % as extreme cases.  相似文献   

Recent climatic changes in Romania from observational data (1961–2013)     

Alexandru Dumitrescu  Roxana Bojariu  Marius-Victor Birsan  Lenuta Marin  Ancuta Manea 《Theoretical and Applied Climatology》2015,122(1-2):111-119

  相似文献   

Spatiotemporal distribution of aridity indices based on temperature and precipitation in the extra-Carpathian regions of Romania   总被引：2，自引：2，他引：0  

Adina-Eliza Croitoru  Adrian Piticar  Alexandru Mircea Imbroane  Doina Cristina Burada 《Theoretical and Applied Climatology》2013,112(3-4):597-607

In the last decades, droughts are a recurrent phenomena in many regions of the world, especially in the subtropics and mid-latitudes, affecting more and more the society. Aridity indices are often used to identify regions prone to that phenomenon. In this paper, we used data recorded in 30 locations in the extra-Carpathian areas of Romania over the period 1961–2007. The De Martonne aridity index (I _DM) and the Pinna combinative index (I _P) were employed in order to identify critical areas in the most important agricultural regions of the country. Monthly, seasonal, annual, and winter wheat and maize growing season datasets of I _DM and annual values of I _P were calculated. The trends were identified using the Mann–Kendall test and Sen’s slope, while ordinary Kriging technique was employed for interpolation. The main findings are that the most vulnerable to semi-aridity are the southeastern regions, especially during the warm period of the year, and that for Romania, the use of I _DM is more appropriate compared to I _P.  相似文献   

Risk-targeted maps for Romania     

Radu Vacareanu  Florin Pavel  Ionut Craciun  Veronica Coliba  Cristian Arion  Alexandru Aldea  Cristian Neagu 《Journal of Seismology》2018,22(2):407-417

Romania has one of the highest seismic hazard levels in Europe. The seismic hazard is due to a combination of local crustal seismic sources, situated mainly in the western part of the country and the Vrancea intermediate-depth seismic source, which can be found at the bend of the Carpathian Mountains. Recent seismic hazard studies have shown that there are consistent differences between the slopes of the seismic hazard curves for sites situated in the fore-arc and back-arc of the Carpathian Mountains. Consequently, in this study we extend this finding to the evaluation of the probability of collapse of buildings and finally to the development of uniform risk-targeted maps. The main advantage of uniform risk approach is that the target probability of collapse will be uniform throughout the country. Finally, the results obtained are discussed in the light of a recent study with the same focus performed at European level using the hazard data from SHARE project. The analyses performed in this study have pointed out to a dominant influence of the quantile of peak ground acceleration used for anchoring the fragility function. This parameter basically alters the shape of the risk-targeted maps shifting the areas which have higher collapse probabilities from eastern Romania to western Romania, as its exceedance probability increases. Consequently, a uniform procedure for deriving risk-targeted maps appears as more than necessary.  相似文献