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Seismotectonics of the Cyprian Arc 总被引：1，自引：0，他引：1
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Nenad Grba Aleksandra Šajnović Ksenija Stojanović Vladimir Simić Branimir Jovančićević Goran Roglić Vladisav Erić 《Chemie der Erde / Geochemistry》2014
Sedimentary rocks from the saline formation of the Lopare Basin were investigated. Sediments contain a moderate amount of immature to marginally mature algal organic matter deposited under slightly reducing to anoxic and slightly saline to hypersaline conditions. Almost all of the samples contain β-carotane in a relatively high quantity, and in some, it represents the most abundant compound in the total distribution of hydrocarbons. The objective of the study was to determine the conditions that are favourable to precursors of β-carotene and/or the preservation of the carotenoid hydrocarbon skeleton. Moreover, the dominant transformation pathways of β-carotene under different redox and salinity conditions, which lead to the formation of aromatic carotenoids were defined. 相似文献
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This paper describes the implementation of process-based models reflecting relative groundwater nitrate vulnerability of the
shallow alluvial Lower Savinja Valley (LSV) aquifer in Slovenia. A spatially explicit identification of the potentially vulnerable
priority areas within groundwater bodies at risk from a chemical point of view is being required for cost-effective measures
and monitoring planning. The shallow LSV unconfined aquifer system consists of high-permeable Holocene and middle- to low-permeable
Pleistocene gravel and sand, with a maximum thickness of about 30 m, mainly covered by shallow eutric fluvisoils or variously
deep eutric cambisoil. The hydrogeological parameters, e.g. the depth to the groundwater, hydrological role of the topographic
slope, etc. usually used in different point count schemes are, in the case of the lowland aquifer and shallow groundwater,
spatially very uniform with low variability. Furthermore, the parametric point count methods are generally not able to illustrate
and analyze important physical processes, and validation of the results is difficult and expensive. Instead of a parametric
point count scheme, we experimentally used the Arc-WofE extension for weights-of-evidence (WofE) modelling. All measurement
locations with a concentration higher than the value of 20 mg NO3
− per litre of groundwater have been considered as training points (173), and the three process-based models generalized output
layers of groundwater recharge (GROWA), nitrate leached from the soil profile (SWAT) and groundwater flow velocity (FEFLOW),
served as evidential themes. The technique is based on the Bayesian idea of phenomena occurrences probability before (prior
probability) and after consideration of any evidential themes (posterior probability), which were measured by positive and
negative weights as an indication of the association between a phenomena and a prediction pattern. The response theme values
describe the relative probability that a 100 × 100 m spatial unit will have a groundwater nitrate concentration higher than
the training points’ limit values with regard to prior probability value. The lowest probability of groundwater nitrate occurrence
is in the parts of the LSV aquifer, which are known as anoxic condition areas with very likely denitrification processes.
The cross-validation of the dissolved oxygen and dissolved nitrate response theme confirmed the accuracy of the groundwater
nitrate prediction. The WofE model results very clearly indicate regional groundwater nitrate distribution and enable spatial
prediction of the probability for increased groundwater nitrate concentration in order to plan the groundwater nitrate reduction
measures and optimize the programme for monitoring the effects of these measures. 相似文献
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Water flow and solute transport model of potentially toxic elements through unsaturated zone at regional wellfield Kosnica 
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下载免费PDF全文 Stanko Ružičić Marta Mileusnić Kristijan Posavec Zoran Nakić Goran Durn Vilim Filipović 《水文研究》2016,30(22):4113-4124
The objective of this work was to build a prognostic water flow model and potentially toxic elements (lead, cadmium, zinc) transport model in the unsaturated zone. Research was conducted in the catchment area of Kosnica regional wellfield, where the unsaturated zone is characterised by Fluvisol. Lower sorption capacities were determined in the first horizons for all three potentially toxic elements. Correlation coefficient of the measured and simulated values of tracer concentration is 0.58 for the AC horizon and 0.84 for the 2C/C1 horizon. Based on calibrated water flow and transport parameters, a prognostic water flow model and potentially toxic elements (lead, cadmium, zinc) transport model in the unsaturated zone was built. In case of an accidental spill of potentially toxic elements with concentrations of 1000 mg/l, the risk of contamination of the aquifer is present. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
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Furdek M Vahčič M Ščančar J Milačič R Kniewald G Mikac N 《Marine pollution bulletin》2012,64(2):189-199
In this work, data on the level of organotin compounds (OTCs) in seawater and mussels collected along the entire Croatian Adriatic Coast are presented. The samples were collected in 2009 and 2010 at 48 locations representing different levels of maritime activities, including marinas, ports and reference sites. Butyltins (BuTs) were found in all analyzed samples, representing >97% of OTCs, and ranged from 0.46 to 27.98 ng Sn L(-1) in seawater and from <6 to 1675 ng Sn g(-1) in mussels. The results indicate a recent input of TBT, with the highest concentrations of BuTs found in the marinas. It appears that the Adriatic coast is still polluted with TBT despite the fact that TBT-containing antifouling paints have been banned in Croatia since 2008. It is questionable how much TBT pollution decreased since 2005, when a high incidence of imposex was established in the same area. 相似文献
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Thébault H Rodriguez Y Baena AM Andral B Barisic D Albaladejo JB Bologa AS Boudjenoun R Delfanti R Egorov VN El Khoukhi T Florou H Kniewald G Noureddine A Patrascu V Pham MK Scarpato A Stokozov NA Topcuoglu S Warnau M 《Marine pollution bulletin》2008,57(6-12):801-806
The common mussel Mytilus galloprovincialis was selected as unique biomonitor species to implement a regional monitoring programme, the CIESM Mediterranean Mussel Watch (MMW), in the Mediterranean and Black Seas. As of today, and upon standardization of the methodological approach, the MMW Network has been able to quantify (137)Cs levels in mussels from 60 coastal stations and to produce the first distribution map of this artificial radionuclide at the scale of the entire Mediterranean and Black Seas. While measured (137)Cs levels were found to be very low (usually < 1 Bq kg(-1) wet wt) (137)Cs activity concentrations in the Black Sea and North Aegean Sea were up to two orders of magnitude higher than those in the western Mediterranean Basin. Such effects, far from representing a threat to human populations or the environment, reflect a persistent signature of the Chernobyl fallout in this area. 相似文献
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Elisabetta Boaretto Charlotte Bryant Israel Carmi Gordon Cook Steinar Gulliksen Doug Harkness Jan Heinemeier John McClure Edward McGee Philip Naysmith Goran Possnert Marian Scott Hans van der Plicht Mark van Strydonck 《第四纪科学杂志》2002,17(7):633-637
Interlaboratory comparisons have been widely used in applied radiocarbon science. These are an important part of ongoing quality assurance (QA) programmes, which are vital to the appropriate interpretation of the evidence provided by the 14C record in Quaternary applications (including climate change and environmental reconstruction). International comparisons of laboratory performance are an essential component of the quality assurance process in radiocarbon dating. If the user community is to have confidence in radiocarbon results, it needs to be assured that laboratories world wide are producing measurements that are reliable and in accordance with ‘good practice’. The findings from the most recent (completed in 2001) and extensive (more than 90 participating laboratories) radiocarbon intercomparison (FIRI) are reported here. This study was designed (i) to assess comparability, or otherwise, of the results from different laboratories and (ii) to quantify the extent and possible causes of any interlaboratory variation. The results demonstrate that there are no significant differences amongst the main measurement techniques (gas proportional counting, liquid scintillation counting and accelerator mass spectrometry (AMS)) but there is evidence of small laboratory offsets relative to known age samples for some laboratories. There is also evidence in some cases of underestimation of measurement precision. Approximately 10% of all results were classified as extreme (outliers) and these results were generated by 14% of the laboratories. Overall, the evidence supports the fact that radiocarbon laboratories are generally accurate and precise but that, notwithstanding internal QA procedures, some problems still occur, which can best be detected by participation in independent intercomparisons such as FIRI, where the results allow individual laboratories to assess their performance and to take remedial measures where necessary. The results from FIRI are significant in that they show a broad measure of agreement between measurements made in different laboratories on a wide range of materials and they also demonstrate no statistically significant difference between measurements made by radiometric or AMS techniques. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献