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It is demonstrated that single titanium dioxide (TiO2) has high potential for photodegradation of pollutants. However, it is still far from becoming an effective photocatalyst system, due to issues of adsorption process, separation, as well as dissolution. Therefore, this study highlights the high adsorption capacity, simplified separation, and the promising stability of TiO2(SY) (synthesized via sol–gel method) photocatalyst, fabricated using chitosan–TiO2(SY) and supported by glass substrate (Cs–TiO2(SY)/glass substrate) photocatalysts. Chitosan (Cs), with abundant –R–NH and NH2 groups, promotes the adsorption sites of methyl orange (MO) and OH groups for major attachment to TiO2(SY). Meanwhile, the glass substrate increases stability and assists separation of the photocatalysts. Initially, nano-TiO2(SY) has been characterized using high-resolution transmission electron microscope. Cs–TiO2(SY)/glass substrate was fabricated via dip-coating. The distribution and interface between the photocatalytic components were characterized by Fourier transform infrared absorption spectroscopy, UV–Vis diffuse reflectance spectroscopy, field emission scanning electron microscopy, and energy-dispersive spectrometer. UV–Vis analysis of the multilayer photocatalyst (2, 4, 6, and 8 layers) was further carried out by the adsorption–photodegradation, with MO as model of pollutant. Seventy percent of the total removal of MO via optimized eight layers of photocatalyst was achieved within 1 h of UV irradiation. The adsorption photocatalyst achieved 50 % with no exposure to UV light for 15 min of irradiation. It is concluded that suitable photocatalytic conditions and sample parameters possessing the multilayer photocatalyst of Cs–TiO2(SY) are beneficial toward the adsorption–photodegradation process in wastewater treatment.  相似文献   
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Unfortunately in developing countries, human activities without attention to the environmental aspects damage to nature. For example, construction of large dams dries wetlands in southwest of Iran. Also, construction of dams is a very important factor for morphological changes. The case study of this research is downstream of the Karkheh dam. This dam is the largest Earth dam in Iran and locates in southwest of Iran. It was constructed in 1999. Small sinuosity coefficient of zone near to dam has been illustrated by satellite images in 2002 and 2014. This subject shows instability of this part of reach; also, the results of Shulits equation illustrate that this part is instable. But, increasing of morphological characteristics (sinuosity coefficient, central angle, and relative radius) show that stability of this reach is increasing. Surveying confirm this matter and shows that severe erosion in upstream and sedimentation in downstream of reach is finishing. Also, it is observed that flow discharge reduced (?56 %) after construction of dam and average width of river reduced (?21 %) from 2002 to 2014. In the early years after the construction of the dam, sediment discharge reduced considerably (?14 %) from Pay-e-Pol to Abdol Khan hydrometric stations. Increasing of morphological characteristics (especially at zones near to dam) and decreasing changes of bed level (sedimentation and erosion) prove that effects of dam are overcoming on effects of other factors, and these effects are permanent in long term.  相似文献   
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Acta Geotechnica - This paper introduces a theory-guided machine learning (TGML) framework, which combines a theoretical model (TM) and a machine learning (ML) algorithm to predict compaction...  相似文献   
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Climatic Change - By combining long-term ground-based data on water withdrawal with climate model projections, this study quantifies the compounding effects of human activities and climate change...  相似文献   
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Dam break flows and resulting river bed erosion can have disastrous impacts on human safety,infrastructure,and environmental quality.However,there is a lack of research on the mobility of non-uniform sediment mixtures resulting from dam break flows and how these differ from uniform sized sediment.In this paper,laboratory flume experiments revealed that coarse and fine fractions in non-uniform sediment had a higher and a lower bed-load parameter,respectively,than uniform sediments of the same size.Thus,the finer fractions were more stable and the coarser fractions were more erodible in a nonuniform bed compared to a uniform-grained bed.These differences can be explained by the hiding and protrusion of these fractions,respectively.By investigating changes in mobility of the mixed-size fractions with reservoir water levels,the results revealed that at low water levels,when the coarser fractions were only just mobile,the bed-load parameter of the finer fractions was higher than the coarser fractions.The opposite was observed at a higher water level,when a significant proportion of the coarsest fractions was mobilized.The higher protrusion of these grains had an important effect on their mobility relative to the finer grains.The transported sediment on these mixed-sized beds was coarser than the initial bed sediment,and became coarser with an increase in reservoir water level.  相似文献   
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Modeling reactive transport in porous media, using a local chemical equilibrium assumption, leads to a system of advection–diffusion PDEs coupled with algebraic equations. When solving this coupled system, the algebraic equations have to be solved at each grid point for each chemical species and at each time step. This leads to a coupled non-linear system. In this paper, a global solution approach that enables to keep the software codes for transport and chemistry distinct is proposed. The method applies the Newton–Krylov framework to the formulation for reactive transport used in operator splitting. The method is formulated in terms of total mobile and total fixed concentrations and uses the chemical solver as a black box, as it only requires that one be able to solve chemical equilibrium problems (and compute derivatives) without having to know the solution method. An additional advantage of the Newton–Krylov method is that the Jacobian is only needed as an operator in a Jacobian matrix times vector product. The proposed method is tested on the MoMaS reactive transport benchmark.  相似文献   
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