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31.
Amy L Wolfe Ran Liu Brian W Stewart Rosemary C Capo David A Dzombak 《Geochemical transactions》2007,8(1):9
Background
Standardized sample preparation techniques allow comparison of pyrite dissolution experiments under diverse conditions. Our objective was to assess dry and wet sieving preparation methodologies, and to develop a reproducible technique that yields uniformly size-distributed material within a limited size range of interest. 相似文献32.
Christopher R. C. Paul Stephen K. Donovan Lucy A. Muir Joseph P. Botting Jih‐Pai Lin Yuandong Zhang 《Geological Journal》2016,51(1):143-156
Pelmatozoans diversified primarily during the Middle and Late Ordovician Period, with Early Ordovician records being much more limited, resulting in many gaps in our knowledge of the early stages of their diversification. Dissociated pelmatozoan ossicles have been found abundantly in one section in the Tonggao Formation (Tetragraptus approximatus Biozone, Floian, Early Ordovician). Most of the ossicles are thecal plates and stem ossicles from hemicosmitoid and glyptocystitoid cystoids. Thecal plates of ‘Cheirocrinus’ sp., Polycosmites sp., and other plates of uncertain affinity are described. A different ossicle type, Pentagonopentagonalis (col.), may represent crinoid remains; this would be one of the earliest occurrences of the class. The thecal ossicles and columnals are all considered, as both sets of data are desirable to determine the most complete estimate of generic diversity. The echinoderm ossicles may have been transported in from shallower water palaeoenvironments and clusters of ossicles may represent coprolites or regurgitates. Estimates of Early Ordovician palaeogeography that place this site at 30°S or near the palaeoequator are supported by the physiological requirements of the primitive echinoderms described herein. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
33.
The first fossil echinoids are recorded from the Cayman Islands. A regular echinoid, Arbacia? sp., the spatangoids Brissus sp. cf. B. oblongus Wright and Schizaster sp. cf. S. americanus (Clark), and the clypeasteroid Clypeaster sp. are from the Middle Miocene Cayman Formation. Test fragments of the mellitid clypeasteroid, Leodia sexiesperforata (Leske), are from the Late Pleistocene Ironshore Formation. Miocene echinoids are preserved as (mainly internal) moulds; hence, all species are left in open nomenclature because of uncertainties regarding test architecture. All Miocene taxa are recorded from single specimens apart from the 27 assigned to Brissus. Schizaster sp. cf. S. americanus (Clark) is compared to a species from the Oligocene of the south‐east USA. Brissus sp. cf. B. oblongus is close in gross morphology to a taxon from the Miocene of Malta. Leodia sexiesperforata is identified from fragments with confidence, being the only extant Antillean sand dollar with elongate ambulacral petals that is limited to carbonate substrates. The Miocene echinoids of Grand Cayman, although of limited diversity, are mainly comprised of genera common in comparable mid‐Cenozoic carbonate environments. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
34.
Stephen K. Donovan 《Geological Journal》2016,51(6):965-966
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36.
Veronika S. HEBER Roger C. WIENS Amy J. G. JUREWICZ Nadia VOGEL Daniel B. REISENFELD Heinrich BAUR Kevin D. McKEEGAN Rainer WIELER Donald S. BURNETT 《Meteoritics & planetary science》2011,46(4):493-512
Abstract– We report concentrations and isotopic compositions of He, Ne, and Ar measured with high spatial resolution along a radial traverse of a silicon carbide (SiC) quadrant of the Genesis mission concentrator target. The Ne isotopic composition maps instrumental fractionation as a function of radial position in the target: the maximum observed isotopic fractionation is approximately 33‰ per mass unit between the center and periphery. The Ne fluence is enhanced by a factor of 43 at the target center and decreases to 5.5 times at the periphery relative to the bulk solar wind fluence. Neon isotopic profiles measured along all four arms of the “gold cross” mount which held the quadrants in the concentrator target demonstrate that the concentrator target was symmetrically irradiated during operation as designed. We used implantation experiments of Ne into SiC and gold to quantify backscatter loss and isotopic fractionation and compared measurements with numerical simulations from the code “stopping and range of ions in matter.” The 20Ne fluence curve as a function of radial distance on the target may be used to construct concentration factors relative to bulk solar wind for accurate corrections for solar wind fluences of other light elements to be measured in the concentrator target. The Ne isotopic composition as a function of the radial distance in the SiC quadrant provides a correction for the instrumental mass‐dependent isotopic fractionation by the concentrator and can be used to correct measured solar wind oxygen and nitrogen isotopic compositions to obtain bulk solar wind isotopic compositions. 相似文献
37.
Accretional temperature profiles for Saturn’s large moon Titan are used to determine the conditions needed for accretion to avoid global melting as a function of the timing, duration, and nebular conditions of Titan’s accretion. We find that Titan can accrete undifferentiated in a “gas-starved” disk even with modest quantities of ammonia mixed in with its ices. Simulations of impact-induced core formation are used to show that Titan can remain only partially differentiated after an outer Solar System late heavy bombardment capable of melting its outer layers, permitting some of its rock to consolidate into a core. 相似文献
38.
Recent high-resolution Cassini images of the south polar terrain of Enceladus reveal regions of short-wavelength deformation, inferred to be compressional folds between the Baghdad and Damascus tiger stripes (Spencer, J.R., Barr, A.C., Esposito, L.W., Helfenstein, P., Ingersoll, A.P., Jaumann, R., McKay, C.P., Nimmo, F., Waite, J.H. [2009a]. Enceladus: An active cryovolcanic satellite. In: Saturn after Cassini-Huygens. Springer, New York, pp. 683-722). Here, we use Fourier analysis of the bright/dark variations to show that the folds have a dominant wavelength of 1.1 ± 0.4 km. We use the simple model of lava flow folding from Fink (Fink, J. [1980]. Geology 8, 250-254) to show that the folds could form in an ice shell with an upper high-viscosity boundary layer of thickness <400 m, with a driving stress of 40-80 kPa, and strain rate between 10−14 s−1 and 10−12 s−1. Such deformation rates imply resurfacing of the SPT in 0.05-5 Myr, consistent with its estimated surface age. Measurements of fold topography and more sophisticated numerical modeling can narrow down the conditions of fold formation and provide valuable constraints on the thermal structure of the ice shell on Enceladus. 相似文献
39.
Stable nitrogen isotope analysis is a fundamental tool in assessing dietary preferences and trophic positions within contemporary and ancient ecosystems. In order to assess more fully the dietary contributions to human tissue isotope values, a greater understanding of the complex biochemical and physiological factors which underpin bulk collagen δ15N values is necessary. Determinations of δ15N values of the individual amino acids which constitute bone collagen are necessary to unravel these relationships, since different amino acids display different δ15N values according to their biosynthetic origins. A range of collagen isolates from archaeological faunal and human bone (n = 12 and 11, respectively), representing a spectrum of terrestrial and marine protein origins and diets, were selected from coastal and near-coastal sites at the south-western tip of Africa. The collagens were hydrolysed and δ15N values of their constituent amino acids determined as N-acetylmethyl esters (NACME) via gas chromatography-combustion-isotope ratio mass spectrometry (GC-C-IRMS). The analytical approach employed accounts for 56% of bone collagen nitrogen. Reconstruction of bulk bone collagen δ15N values reveals a 2‰ offset from bulk collagen δ15N values which is attributable to the δ15N value of the amino acids which cannot currently be determined by GC-C-IRMS, notably arginine which comprises 53% of the nitrogen unaccounted for (23% of the total nitrogen). The δ15N values of individual amino acids provide insights into both the contributions of various amino acids to the bulk δ15N value of collagen and the factors influencing trophic position and the nitrogen source at the base of the food web. The similarity in the δ15N values of alanine, glutamate, proline and hydroxyproline reflects the common origin of their amino groups from glutamate. The depletion in the δ15N value of threonine with increasing trophic level indicates a fundamental difference between the biosynthetic pathway of threonine and the other amino acids. The δ15N value of phenylalanine does not change significantly with trophic level, reflecting its conservative nature as an essential amino acid, and thus represents the isotopic composition of the nitrogen at the base of the food web. Δ15NGlu-Phe values in particular are shown to reflect trophic level nitrogen sources within a food web. In relation to the reconstruction of ancient human diet the contribution of marine and terrestrial protein are strongly reflected in Δ15NGlu-Phe values. Differences in nitrogen metabolism are also shown to have an influence upon individual amino acid δ15N values with Δ15NGlu-Phe values emphasising differences between the different physiological adaptations. The latter is demonstrated in tortoises, which can excrete nitrogen in the form of uric acid and urea and display negative Δ15NGlu-Phe values whereas those for marine and terrestrial mammals are positive. The findings amplify the potential advantages of compound-specific nitrogen isotope analysis in the study of nitrogen flow within food webs and in the reconstruction of past human diets. 相似文献
40.