Assessment of the design displacement values at seismic fault crossings and of their excess probability     

STROM Alexander  IVASCHENKO Alexey  KOZHURIN Andrey 《山地科学学报》2011,8(2):228-233

Line structures such as pipelines that cross active faults should be designed to retain leak-tightness if the design displacement (Ddesign) occurs. Principal approaches to the Ddesign and rupture kinematics assessment are described. They are based on relationships between earthquake magnitude, rupture length and displacement, and on the detailed field data on a specific fault that crosses the pipeline route. Since the future offset at the crossing may exceed the design value, the probability of a displacement occurrence where the safety of the structure can not be ensured should be estimated. Assessment method on such event probability is described and exemplified through active fault studies carried out at several pipeline projects in Russia.  相似文献   

The Archean komatiite-hosted, PGE-bearing Ni–Cu sulfide deposit at Vaara, eastern Finland: evidence for assimilation of external sulfur and post-depositional desulfurization     

J. P. Konnunaho  E. J. Hanski  A. Bekker  T. A. A. Halkoaho  R. S. Hiebert  B. A. Wing 《Mineralium Deposita》2013,48(8):967-989

Archean komatiites host important resources of Ni, Cu, Co, and PGE, particularly in Western Australia and Canada. In Finland, several small, low-grade sulfide deposits have been found in komatiites, including the ca. 2.8 Ga Vaara deposit in the Archean Suomussalmi greenstone belt. It occurs in the central part of the serpentinized olivine cumulate zone of a komatiitic extrusive body and is composed of disseminated interstitial sulfides consisting of pyrite, pentlandite, millerite, violarite, and chalcopyrite accompanied by abundant magnetite. Although currently subeconomic, the mineralization is interesting due to the very high chalcophile element contents of the sulfide fraction (38 wt% Ni, 3.4 wt% Cu, 0.7 wt% Co, 22.4 ppm Pd, and 9.5 ppm Pt). The sulfides occur in relatively Cr-poor olivine cumulates suggesting involvement of a chromite-undersaturated magma. The parental magma was an Al-undepleted komatiite with an estimated MgO content of at least 24 wt%. In contrast to the common komatiite types in the eastern Finland greenstone belts, the Vaara rocks are moderately enriched in LREE relative to MREE, suggesting that crustal contamination played an important role in the genesis of the Vaara deposit. Multiple sulfur isotope data reveal considerable mass-independent sulfur isotope fractionation both in country rock sedimentary sulfides (Δ³³S ranges from ?0.50 to +2.37?‰) and in the Vaara mineralization (Δ³³S ranges from +0.53 to +0.66?‰), which provides strong evidence for incorporation of crustal sulfur. Extensive replacement of interstitial sulfides by magnetite and the presence of millerite- and violarite-bearing, pyrrhotite-free sulfide assemblages indicate significant post-magmatic, low-temperature hydrothermal oxidation of the primary magmatic pyrrhotite-pentlandite-chalcopyrite assemblages and associated sulfur loss that led to a significant upgrading of the original metal tenors of the Vaara deposit.  相似文献   

K2O prograde zoning pattern in clinopyroxene from the Kokchetav diamond-grade metamorphic rocks: Missing part of metamorphic history and location of second critical end point for calc-silicate system     

Anastasiya O. Mikhno  Andrey V. Korsakov 《Gondwana Research》2013,23(3):920-930

Despite extensive studies of calc-silicate rocks of the Kokchetav massif, there is no satisfactory explanation of the origin of potassium-bearing clinopyroxene in alkali poor metamorphic rocks. In this paper we report the finding of potassium-bearing clinopyroxene with prograde zonation (K₂O increases from core to rim) from diamond-grade, but diamond-free UHP calc-silicate rocks of the Kokchetav massif. We believe that the crystallization of potassium-bearing clinopyroxene started on the prograde stage and slightly prior to the peak of UHP metamorphism. Thus, prograde metamorphic history is only traceable in diamond-free UHP calc-silicate rocks, while in diamond-bearing UHPM rocks it is completely reset. Fluid and polyphase solid inclusions, originally representing melt inclusions, occur in the core of potassium-bearing clinopyroxene and imply that melt and fluid may coexist in calc-silicate rocks even at 1000–1100 °C and 6–7 GPa.  相似文献   

Surface phase transformations,surface complexation and solubilities of hydroxyapatite in the absence/presence of Cd(II) and EDTA     

Karin Viipsi  Staffan Sjöberg  Andrey Shchukarev  Kaia Tõnsuaadu 《Applied Geochemistry》2012

The removal of Cd from aqueous solutions by hydroxyapatite (HAP) was investigated with and without EDTA being present. Batch experiments were carried out using synthetic hydroxyapatite with Ca/P 1.57 and a specific surface area of 37.5 m²/g in the pH range 4–9 (25 °C; 0.1 M KNO₃). The surface composition of the solid phases were analysed by X-ray Photoelectron Spectroscopy (XPS). The surface layer of HAP was found to undergo a phase transformation with a (Ca + Cd)/P atomic ratio of 1.4 and the involvement of an ion exchange process (Ca²⁺ ↔ Cd²⁺). The amount of Cd removed from the solution increased with increasing pH, reaching ≈100% at pH 9. In the presence of EDTA Cd removal was reduced due to the formation of [CdEDTA]²⁻ in solution. The solubility of HAP increases in the presence of EDTA at pH values above 5, mainly due to the formation of [CaEDTA]²⁻. In contrast to this, the solubility was found to decrease in the presence of Cd²⁺ and CdEDTA²⁻. Using XPS the formation of a Cd-enriched HAP surface was found, which was interpreted as the formation of a solid solution of the general composition: Ca_8.4-xCd_x(HPO_4)1.6(PO_4)4.4(OH_)0.4${\text{Ca}}_{8.4-x}{\text{Cd}}_x({\text{HPO}}_4{)}_{1.6}({\text{PO}}_4{)}_{4.4}(\text{OH}{)}_{0.4}$.  相似文献   

Sampling error distribution for the ensemble Kalman filter update step     

Andrey Kovalenko  Trond Mannseth  Geir N?vdal 《Computational Geosciences》2012,16(2):455-466

In recent years, data assimilation techniques have been applied to an increasingly wider specter of problems. Monte Carlo variants of the Kalman filter, in particular, the ensemble Kalman filter (EnKF), have gained significant popularity. EnKF is used for a wide variety of applications, among them for updating reservoir simulation models. EnKF is a Monte Carlo method, and its reliability depends on the actual size of the sample. In applications, a moderately sized sample (40–100 members) is used for computational convenience. Problems due to the resulting Monte Carlo effects require a more thorough analysis of the EnKF. Earlier we presented a method for the assessment of the error emerging at the EnKF update step (Kovalenko et al., SIAM J Matrix Anal Appl, in press). A particular energy norm of the EnKF error after a single update step was studied. The energy norm used to assess the error is hard to interpret. In this paper, we derive the distribution of the Euclidean norm of the sampling error under the same assumptions as before, namely normality of the forecast distribution and negligibility of the observation error. The distribution depends on the ensemble size, the number and spatial arrangement of the observations, and the prior covariance. The distribution is used to study the error propagation in a single update step on several synthetic examples. The examples illustrate the changes in reliability of the EnKF, when the parameters governing the error distribution vary.  相似文献   

Information and complexity measures applied to observed and simulated soil moisture time series     

Feng Pan  Yakov A. Pachepsky  Andrey K. Guber  Robert L. Hill 《水文科学杂志》2013,58(6):1027-1039

Abstract

Time series of soil moisture-related parameters provide important insights into the functioning of soil water systems. Analysis of patterns within such time series has been used in several studies. The objective of this work was to compare patterns in observed and simulated soil moisture contents to understand whether modelling leads to a substantial loss of information or complexity. The time series were observed at four plots in sandy soils within the USDA-ARS OPE3 experimental watershed, for a year; precipitation and evapotranspiration (ET) were measured and estimated, respectively, and used for soil water flow simulation with the HYDRUS-1D software. The information content measures are the metric entropy and the mean information gain, and complexity measures are the fluctuation complexity and the effective measure complexity. These measures were computed based on the binary encoding of soil moisture time series, and used probabilities of patterns, i.e. probabilities of joint or sequential appearance of symbol sequences. The information content of daily soil moisture time series was much smaller than that of rainfall data, and had higher complexity, indicating that soil worked essentially as an information filter. Information content and complexity decreased and increased with depth, respectively, demonstrating the increase in the information filtering action of soil. The information measures of simulated soil moisture content were close to those of the measurements, indicating the successful simulation of patterns in the data. The spatial variability of the information measures for simulated soil moisture content at all depths was less pronounced than the one of measured time series. Compared with precipitation and estimated ET, soil moisture time series had more structure and less randomness in this work. The information measures can provide useful complementary knowledge about model performance and patterns in observation and modelling results.

Citation Pan, F., Pachepsky, Y. A., Guber, A. K., & Hill, R. L. (2011) Information and complexity measures applied to observed and simulated soil moisture time series. Hydrol. Sci. J. 56(6), 1027–1039.  相似文献   

Analytical Approach to Calculate Quasi-thermal Noise Spectrum in Irregular Plasma     

Nikolay A. Zabotin  Andrey G. Bronin  Yury V. Chugunov  Evgene A. Mareev 《Astrophysics and Space Science》2001,277(1-2):319-322

Basic properties of quasi-thermal noise spectrum in irregular plasma have been investigated using an analytical point of view. A simple formula for the plasma frequency splitting effect has been obtained for ionospheric conditions. A passive electric antenna, immersed in a stable plasma, detects the fluctuations of the electric potential due to thermal motion of the ambient particles. Properties of this quasi-thermal noise spectrum in homogeneous plasma are relatively well known and are effectively used for diagnostics of space plasma (Aksenov et al., 1978; Trakhtengerts and Chugunov, 1978; Kellog, 1981; Meyer-Vernet and Perche, 1989). Especially, in the Earth's ionosphere or solar wind plasma, random irregularities of electron density are always present. These irregularities may substantially change properties of these media through electromagnetic radiation and may also modify quasi-thermal noise spectrum, which depends on the effective dielectric permittivity tensor. This tensor is defined as the dielectric permittivity tensor of some imaginary `effective' regular medium in which the field of point source is the same as the mean field in the medium with random irregularities (Ryzhov, Tamoikin and Tatarskii, 1965; Ryzhov 1968). Since the correlation function of electric field fluctuations in random medium may be expressed through the effective dielectric constant tensor (Ryzhov, 1968), it may be used for direct calculation of quasi-thermal noise spectrum. In Zabotin et al. (2000), the Born approximation was used to calculate numerically the effective dielectric permittivity tensor and the modified noise spectrum while we analytically estimate herein the modified noise spectrum. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Oxygen isotope heterogeneity and disequilibria of olivine crystals in large volume Holocene basalts from Iceland: Evidence for magmatic digestion and erosion of Pleistocene hyaloclastites   总被引：1，自引：0，他引：1  

Ilya Bindeman  Andrey Gurenko  Olgeir Sigmarsson  Marc Chaussidon 《Geochimica et cosmochimica acta》2008,72(17):4397-4420

This work considers petrogenesis of the largest Holocene basaltic fissure eruptions of Iceland, which are also the largest in the world: Laki (1783-84 AD, 15 km³), Eldgjá (934 AD, 18 km³), Veidivötn (900, 1480 AD, multiple eruptions, >2 km³), Núpahraun (ca. 4000 BP, >1 km³) and Thjórsárhraun (ca 8000 BP, >20 km³). We present oxygen isotope laser fluorination analyses of 55 individual and bulk olivine crystals, coexisting individual and bulk plagioclase phenocrysts, and their host basaltic glasses with average precision of better than 0.1‰ (1SD). We also report O isotope analyses of cores and rims of 61 olivine crystals by SIMS with average precision on single spots of 0.24‰ (1SD) in 13 samples coupled with electron microprobe data for major and trace elements in these olivines. Within each individual sample, we have found that basaltic glass is relatively homogeneous with respect to oxygen isotopes, plagioclase phenocrysts exhibit crystal to crystal variability, while individual olivines span from the values in equilibrium with the low-δ¹⁸O matrix glass to those being three permil higher in δ¹⁸O than the equilibrium. Olivine cores with maximum value of 5.2‰ are found in many of these basalts and suggest that the initial magma was equilibrated with normal-δ¹⁸O mantle. No olivines or their intracrystalline domains are found with bulk or spot value higher than those found in MORB olivines. The δ¹⁸O variability of 0.3-3‰ exists for olivine grains from different lavas, and variable core-to-rim oxygen isotopic zoning is present in selected olivine grains. Many olivines in the same sample are not zoned, while a few grains are zoned with respect to oxygen isotopes and exhibit small core-to-core variations in Fe-Mg, Ni, Mn, Ca. Grains that are zoned in both Mg# and δ¹⁸O exhibit positive correlation of these two parameters. Electron microprobe analysis shows that most olivines equilibrated with the transporting melt, and thin Fe-richer rim is present around many grains, regardless of the degree of olivine-melt oxygen isotope disequilibrium.The preservation of isotopic and compositional zoning in selected grains, and subtle to severe Δ¹⁸O (melt-olivine) and Δ¹⁸O (plagioclase-olivine) disequilibria suggests rather short crystal residence times of years to centuries. Synglacially-altered upper crustal, tufaceous hyaloclastites of Pleistocene age serve as a viable source for low-δ¹⁸O values in Holocene basalts through assimilation, mechanical and thermal erosion, and devolatilization of stoped blocks. Cumulates formed in response to cooling during assimilation, and xenocrysts derived from hyaloclastites, contribute to the diverse δ¹⁸O crystalline cargo. The magma plumbing systems under each fissure are likely to include a network of interconnected dikes and sills with high magma flow rates that contribute to the efficacy of magmatic erosion of large quantities (10-60% mass) of hyaloclastites required by isotopic mass balance.Olivine diversity and the pervasive lack of phenocryst-melt oxygen isotopic equilibrium suggest that a common approach of analyzing bulk olivine for oxygen isotopes, as a proxy for the basaltic melt or to infer mantle δ¹⁸O value, needs to proceed with caution. The best approach is to analyze olivine crystals individually and demonstrate their equilibrium with matrix.  相似文献   

X-ray single-crystal and Raman study of (Na<Subscript>0.86</Subscript>Mg<Subscript>0.14</Subscript>)(Mg<Subscript>0.57</Subscript>Ti<Subscript>0.43</Subscript>)Si<Subscript>2</Subscript>O<Subscript>6</Subscript>, a new pyroxene synthesized at 7 GPa and 1700 °C     

Ekaterina A. Sirotkina  Andrey V. Bobrov  Anna V. Spivak  Luca Bindi  Dmitry Yu. Pushcharovsky 《Physics and Chemistry of Minerals》2016,43(10):731-738

A new pyroxene with formula (Na_0.86Mg_0.14)(Mg_0.57Ti_0.43)Si₂O₆, synthesized in a high-pressure toroidal ‘anvil-with-hole’ apparatus at P = 7 GPa and T = 1700 °C, was characterized by X-ray single-crystal diffraction and Raman spectroscopy. The compound was found to be monoclinic (R1 = 2.56 %), space group C2/c, with lattice parameters a = 9.687(2), b = 8.814(1), c = 5.290(1) Å, β = 107.853(2)°, V = 430.08(1) ų. The coexistence of Mg and Ti⁴⁺ at the M1 site does not induce strong modifications either to the M1 site or to the adjacent M2 site. The Raman spectrum of synthetic Na–Ti-pyroxene was obtained for the first time and compared with that of Mg₂Si₂O₆ (with very low concentrations of Na and Ti). The structural characterization of the Na–Ti–Mg-pyroxene is important, because the study of its thermodynamic constants provides new constraints on thermobarometry of the upper mantle assemblages.  相似文献   

Structure of Turbulence in Katabatic Flows Below and Above the Wind-Speed Maximum   总被引：2，自引：2，他引：0  

Andrey A. Grachev  Laura S. Leo  Silvana Di Sabatino  Harindra J. S. Fernando  Eric R. Pardyjak  Christopher W. Fairall 《Boundary-Layer Meteorology》2016,159(3):469-494

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