Measurements of the Henry's Law Coefficients of 2-Methyl-3-buten-2-ol, Methacrolein, and Methylvinyl Ketone   总被引：1，自引：0，他引：1  

Laura T. Iraci  Bradly M. Baker  Geoffrey S. Tyndall  John J. Orlando 《Journal of Atmospheric Chemistry》1999,33(3):321-330

Using an equilibrium headspace technique, Henry's law coefficients were measured for methacrolein (H = 6.5 ± 0.7 M atm-1) and methylvinyl ketone (41 ± 7.0 M atm-1) in water at 25 °C. In addition, 2-methyl-3-buten-2-ol was studied at 30 °C in water and in an aqueous ionic solution representative of plant tissue. Similar values were found in deionized water (65 ± 3.5 M atm-1) and in a 0.05 mol kg-1 Ca2+, K+, NO3-, SO42- solution (62 ± 0.8 M atm-1). These Henry's Law coefficients are too small to allow for significant partitioning of methacrolein, methylvinyl ketone or methylbutenol into cloud water under equilibrium conditions.  相似文献   

Candidate high-redshift and primeval galaxies in Hubble Deep Field South     

D. L. Clements  S. A. Eales  A. C. Baker 《Monthly notices of the Royal Astronomical Society》1999,308(1):L11-L16

We present the results of colour selection of candidate high-redshift galaxies in Hubble Deep Field South (HDF-S) using the Lyman dropout scheme. The HDF-S data we discuss were taken in a number of different filters extending from the near-UV (F300W) to the infrared (F222M) in two different fields. This allows us to select candidates with redshifts from z ∼3 to z ∼12. We find 15 candidate z ∼3 objects (F300W dropouts), one candidate z ∼4 object (F450W dropout) and 16 candidate z ∼5 objects (F606W dropouts) in the ∼4.7‐arcmin² WFPC-2 field, and four candidate z ∼6 objects (optical dropouts) and one candidate z ∼8 object (F110W dropout) in the 0.84-arcmin² NICMOS-3 field. No F160W dropouts are found ( z ∼12). We compare our selection technique with existing data for Hubble Deep Field North (HDF-N) and discuss alternative interpretations of the objects. We conclude that there are a number of lower redshift interlopers in the selections, including one previously identified object, and reject those objects most likely to be foreground contaminants. Even after this we conclude that the F606W dropout list is likely to still contain substantial foreground contamination. The lack of candidate very-high-redshift UV-luminous galaxies supports earlier conclusions by Lanzetta et al. We discuss the morphologies and luminosity functions of the high-redshift objects, and their cosmological implications.  相似文献   

Ground motion spatial correlation fitting methods and estimation uncertainty     

Jack W. Baker  Yilin Chen 《地震工程与结构动力学》2020,49(15):1662-1681

Ground shaking intensity varies spatially in earthquakes, and many studies have estimated correlations of intensity from past earthquake data. This paper presents a framework for quantifying uncertainty in the estimation of correlations and true variability in correlations from earthquake to earthquake. A procedure for evaluating estimation uncertainty is proposed and used to evaluate several methods that have been used in past studies to estimate correlations. The results indicate that a weighted least squares algorithm is most effective in estimating spatial correlation models and that earthquakes with at least 100 recordings are needed to produce informative earthquake-specific estimates of spatial correlations. The proposed procedure is also used to distinguish between estimation uncertainty and the true variability in model parameters that exist in a given data set. The estimation uncertainty is seen to vary between well-recorded and poorly recorded earthquakes, whereas the true variability is more stable.  相似文献   

Outflows at the Edges of an Active Region in a Coronal Hole: A Signature of Active Region Expansion?     

M. J. Murray  D. Baker  L. van Driel-Gesztelyi  J. Sun 《Solar physics》2010,261(2):253-269

Outflows of plasma at the edges of active regions surrounded by quiet Sun are now a common observation with the Hinode satellite. While there is observational evidence to suggest that the outflows are originating in the magnetic field surrounding the active regions, there is no conclusive evidence that reveals how they are driven. Motivated by observations of outflows at the periphery of a mature active region embedded in a coronal hole, we have used a three-dimensional simulation to emulate the active region’s development in order to investigate the origin and driver of these outflows. We find that outflows are accelerated from a site in the coronal hole magnetic field immediately surrounding the active region and are channelled along the coronal hole field as they rise through the atmosphere. The plasma is accelerated simply as a result of the active region expanding horizontally as it develops. Many of the characteristics of the outflows generated in the simulation are consistent with those of observed outflows: velocities up to 45 km s⁻¹, properties akin to the coronal hole, proximity to the active region’s draining loops, expansion with height, and projection over monopolar photospheric magnetic concentrations. Although the horizontal expansion occurs as a consequence of the active region’s development in the simulation, expansion is also a general feature of established active regions. Hence, it is entirely possible and plausible that the expansion acceleration mechanism displayed in the simulation is occurring in active regions on the Sun and, in addition to reconnection, is driving the outflows observed at their edges.  相似文献   

A high magnitude storm and flood in a hyperarid catchment,Nahal Zin,Negev Desert,Israel     

Noam Greenbaum  Adina Margalit  Asher P. Schick  David Sharon  Victor R. Baker 《水文研究》1998,12(1):1-23

In October 1991 a high magnitude rainstorm flood, estimated return period 40 years, occurred in Nahal Zin, a 1400 km² catchment in the hyperarid Negev Desert. The meso-scale structure of the storm was a curved squall line that developed from a thunderstorm in accordance with the topography of the catchment divide, by which it was strongly affected. Tropical moisture reached the area via the subtropical jet stream, in conjunction with a lower level northward intrusion of the Red Sea trough (RST-N) into the Mediterranean Sea. Rainfall, as measured at the few and sparse gauging stations, was much too small to account for the resulting large flood. Peak flow and other hydraulic characteristics of the flood were indirectly reconstructed. The techniques of palaeoflood hydrology used were based on sedimentological evidence of fine-grained flood sediments deposited in back-flooded tributaries, as well as on other stage indicators. The HEC-2 procedure was employed to determine water surface profiles. The spatial and temporal characteristics of the event were studied through a combination of rainstorm analysis, remote sensing, hydrological and sedimentological data; they jointly explain the magnitude and timing of tributary contributions producing the integrated flood in the main channel. The flood as reconstructed reveals a three-peak hydrograph: two peaks were generated by the same storm but had different floodwave arrival times in the main channel; the third resulted from a local rainstorm which occurred on the following day and covered only one tributary. The curved structure of the storm and its dynamics in relation to catchment orientation resulted in storm move- ment in tandem with the floodwave. The synchronous contribution from all main tributaries preserved evidence of the floodwave both in stage and volume by replacing the transmission losses in the sections with thick alluvium. Other high magnitude floods on record for the large Negev Desert catchments are caused by a cold upper air incursion associated with the RST-N. Most of them occur in the autumn and are caused by storms with high-intensity rainfall. This is in stark contrast with the flooding behaviour of the semi-arid zone further north, which is linked primarily to the core of the Mediterranean winter. The complexities involved in the generation of a large desert flood, as revealed by this study, illustrate the fallacy of applying routine hydrological modelling to such events, and underline the need to study the processes involved in adequate detail. © 1998 John Wiley & Sons, Ltd.  相似文献   

Archaeological stone of Easter Island     

P. E. Baker 《Geoarchaeology》1993,8(2):127-139

With the scarcity of other resources, stone assumed great importance in the culture of Easter Island. The volcanic rocks display a compositional continuum paralleled by changes in physical characteristics. The most abundant rock type, porphyritic hawaiite, was the least useful as it is poorly jointed and difficult to work. Mugearites and benmoreites usually have a flaggy structure and were used as dressed stone in the early ahu, in the houses of Orongo and in stone implements. Rhyolitic obsidian was used for scrapers, knives, and a variety of weapons, especially the tanged mataa. Statue carving reached its zenith on Easter Island largely because of the availability of a suitable rock type, the Rano Raraku tuff. The tuff was not erupted from the present Rano Raraku crater but from another vent southeast of the surviving portion of the cone. Red scoria from Puna Pau was quarried for the topknots. © 1993 John Wiley & Sons, Inc.  相似文献   

Geoarchaeology: Exploration,environments, resources     

Andy J. Howard 《Geoarchaeology》2000,15(8):822-824

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Scientific detector workshop 2022 on-sky performance verification of near-infrared e−APD technology for wavefront sensing and demonstration of e−APD pixel performance to improve the sensitivity of large science focal planes     

Gert Finger  Frank Eisenhauer  Reinhard Genzel  Christopher Mandla  Ian Baker  Domingo Alvarez  Antonio Amorim  Wolfgang Brandner  Christophe Dupuy  Casey Deen  Derek Ives  Leander Mehrgan  Manfred Meyer  Karin Perraut  Guy Perrin  Jörg Stegmeier  Christian Straubmeier  Harald J. Weller  Vincent Isgar 《Astronomische Nachrichten》2023,344(8-9):e20230069

Near-infrared adaptive optics as well as fringe tracking for coherent beam combination in optical interferometry require the development of high-speed sensors. Because of the high speed, a large analog bandwidth is required. The short exposure times result in small signal levels which require noiseless detection. Both requirements cannot be met by state-of-the-art conventional CMOS technology of near-infrared arrays as has been attempted previously. A total of five near-infrared SAPHIRA 320 × 256 pixel HgCdTe e⁻APD arrays have been deployed in the wavefront sensors and in the fringe tracker of the VLTI instrument GRAVITY. The current limiting magnitude for coherent exposures with GRAVITY is m_k = 19, which is made possible with ADP technology. New avalanche photo-diode array (APD) developments since GRAVITY include the extension of the spectral sensitivity to the wavelength range from 0.8 to 2.5 μm. After GRAVITY a larger format array with 512 × 512 pixels has been developed for both AO applications at the ELT and for long integration times. Since dark currents of <10⁻³ e⁻/s have been demonstrated with 1Kx1K e⁻APD arrays and 2Kx2K e⁻APD arrays have already been developed, the possibilities and adaptations of e⁻APD technology to provide noiseless large-format science-grade arrays for long integration times are also discussed.  相似文献