Modeling the binding of fulvic acid by goethite: the speciation of adsorbed FA molecules   总被引：1，自引：0，他引：1  

Jeroen D. Filius  David G. Lumsdon  Willem H. van Riemsdijk 《Geochimica et cosmochimica acta》2003,67(8):1463-1474

Under natural conditions, the adsorption of ions at the solid-water interface may be strongly influenced by the adsorption of organic matter. In this paper, we describe the adsorption of fulvic acid (FA) by metal(hydr)oxide surfaces with a heterogeneous surface complexation model, the ligand and charge distribution (LCD) model. The model is a self-consistent combination of the nonideal competitive adsorption (NICA) equation and the CD-MUSIC model. The LCD model can describe simultaneously the concentration, pH, and salt dependency of the adsorption with a minimum of only three adjustable parameters. Furthermore, the model predicts the coadsorption of protons accurately for an extended range of conditions. Surface speciation calculations show that almost all hydroxyl groups of the adsorbed FA molecules are involved in outer sphere complexation reactions. The carboxylic groups of the adsorbed FA molecule form inner and outer sphere complexes. Furthermore, part of the carboxylate groups remain noncoordinated and deprotonated.  相似文献   

Corrections to “The solution of the general geodetic boundary value problem by least squares”     

M. van Gelderen  R. Rummel 《Journal of Geodesy》2002,76(2):121-122

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Detection of sinkholes using 2D electrical resistivity imaging     

Michael van Schoor   《Journal of Applied Geophysics》2002,50(4):165

Sinkholes in dolomitic areas are notoriously difficult geophysical targets, and selecting an appropriate geophysical solution is not straightforward. Electrical resistivity imaging, or tomography (RESTOM) is well suited to mapping sinkholes because of the ability of the technique for detecting resistive features and discriminating subtle resistivity variations. RESTOM surveys were conducted at two sinkhole sites near Pretoria, South Africa. The survey areas are located in the dolomites of the Lyttelton Formation, which forms part of the Malamani Subgroup and Chuniespoort Group of the Transvaal Supergroup. The survey results suggest that RESTOM is an ideal geophysical tool to aid in the detection and monitoring of sinkholes and other subsurface cavities.  相似文献   

Quasi-conservative behaviour of Be in deep waters of the Weddell Sea and the Atlantic sector of the Antarctic Circumpolar Current     

M. Frank  M.M. Rutgers van der LoeffPeter W. Kubik  Augusto Mangini 《Earth and Planetary Science Letters》2002,201(1):171-186

We present the first transect of dissolved ¹⁰Be depth profiles across the Antarctic Circumpolar Current (ACC) in the Atlantic sector. North of the Polar Front the ¹⁰Be concentrations increase continuously from very low values at the surface to values of up to 1600 atoms/g at depth. Deep water ¹⁰Be concentrations of particular water masses are consistent with earlier results obtained further north. South of the Polar Front and in the Weddell Sea the distribution of ¹⁰Be is also characterised by low surface concentrations but below 1000 m depth the concentrations are relatively constant and significantly higher (up to 2000 atoms/g) than further north, probably as a result of mixing and advection of water masses of Pacific origin. Overall the deep water ¹⁰Be distribution is obviously not significantly affected by scavenging processes or ice melt and comparison with the density distribution suggests that ¹⁰Be can be viewed as a quasi-conservative tracer. This provides a tool for an improved understanding of the behaviour of other more particle reactive trace metals in the Southern Ocean such as ²³⁰Th: in deep waters north of the ACC/Weddell Gyre boundary (AWB) ¹⁰Be/²³⁰Th has a relatively constant value (1.7±0.3×10⁹ atoms/dpm) over a wide density range whereas south of the AWB the ratio is significantly lower (1.1±0.2×10⁹ atoms/dpm). This normalisation to ¹⁰Be corroborates that ²³⁰Th is enriched by 50% due to accumulation south of the AWB as a consequence of minimal particulate fluxes. The quasi-conservative behaviour deduced from our results also implies that ¹⁰Be can only be used as a tracer for Southern Ocean particle fluxes in the past if ocean circulation patterns and water mass residence times did not change significantly.  相似文献   

Palynological evidence for the astronomical origin of lignite-detritus sequence in the Middle Pleistocene Marathousa Member, Megalopolis, SW Greece     

M Okuda  N van VugtT Nakagawa  M IkeyaA Hayashida  Y YasudaT Setoguchi 《Earth and Planetary Science Letters》2002,201(1):143-157

The Marathousa Member, Middle Pleistocene strata in the fluvio-lacustrine Megalopolis basin, southwest Greece, displays distinct but complicated lithological cycles comprising first-order alternation of lignites and detrital muds and second-order alternation expressed by frequent intercalation of organic layers. Palynological evidence indicates that the lithological cycles are driven by the Earth’s orbital forcing. All the lignite seams yield temperate oak forest whereas the detrital beds provide semi-arid steppe mainly of Artemisia. This means that the first-order lithological cycle represents the glacial/interglacial cycle (i.e., the 100-kyr eccentricity cycle), providing a timescale of at least 350 kyr to the Marathousa Member. Pollen also detects smaller-scale climate fluctuations in many of the subordinate organic layers, with the total number of fluctuations being five in a complete lignite-detritus couplet. This means that the second-order lithological cycle reflects the 21-kyr insolation cycle. A tentative phase relation between the lithological cycles and the astronomical cycles is shown based on palynostratigraphy and electron spin resonance dating. Lacustrine environments with increased water tables are implied for the glacial periods sedimentologically, in contrast to local swamp vegetation for the interglacial periods. The subordinate organic layers were formed under intermediate environments (climate, water depth, etc.) between full glacials and interglacials.  相似文献   

High-resolution estimates of lithospheric thickness from Missouri to Massachusetts, USA     

Suzan van der Lee 《Earth and Planetary Science Letters》2002,203(1):15-23

This paper presents a new three-dimensional (3-D) model, NA00, of the S-velocity of the upper mantle beneath North America. The model differs from its predecessor NA95 in that it exploits seismograms recorded by a recent dense, broadband array, MOMA, and from independent measurements of North American crustal thickness. Model NA00 is derived by fitting the waveforms of broadband seismic S and surface waves recorded by the MOMA array and inverting them together with the database of waveform fits used for NA95 and the crustal thickness estimates. It is demonstrated that including data from the dense, broadband MOMA array yields a resolving power beneath the array that is of unprecedented quality and relatively constant over a large depth range. This improved resolution provides a unique opportunity for quantifying the structure of the upper mantle in and below the lower, thick Precambrian lithosphere. The high-resolution seismic structure of the imaged high-velocity lithosphere is compared with the thermal structure (estimated from heat flow), compositional structure (estimated from xenoliths and electrical conductivity) and the elastic structure (estimated from gravity and topography). There is a remarkable agreement between the seismic, thermal, and compositional estimates. The seismic lithosphere is 180 km thick below Missouri and Illinois, 200 km thick below Indiana, Ohio and Pennsylvania, practically undefined below New York, and 80 km below Massachusetts and the Atlantic continental shelf. The thick lithosphere is underlain by a layer with lower S-velocities that could represent a relatively low-viscosity channel. However, the S-velocities in this layer are much higher than those of typical oceanic asthenosphere.  相似文献   

Imagining difference: the experiences of 'transnational' Indian IT professionals in Germany     

Louise Meijering  Bettina van Hoven 《Area》2003,35(2):174-182

In this paper we explore the motivations to migrate and the migration experiences of 22 Indian IT professionals in Germany. When studying skilled migration, Germany is an interesting case as it struggled with waves of extreme right activities whilst trying to attract IT professionals from outside the European Union at the same time. In this context, we are interested in the conflicts that the migrants may experience as a result of their desire or obligation to move, their specific cultural baggage and the way in which they encounter the different sides of German society.  相似文献   

Increased heat fluxes near a forest edge   总被引：1，自引：0，他引：1  

W. Klaassen  P. B. van Breugel  E. J. Moors  J. P. Nieveen 《Theoretical and Applied Climatology》2002,72(3-4):231-243

Summary ?Observations of sensible and latent heat flux above forest downwind of a forest edge show these fluxes to be larger than the available energy over the forest. The enhancement averages to 56 W m⁻², or 16% of the net radiation, at fetches less than 400 m, equivalent to fetch to height ratios less than 15. The enhancement of turbulent energy fluxes is explained by advection and increases with the difference in temperature and humidity of the air over the upwind area as compared to the forest. The relatively high temperature and humidity of the upwind air are not caused by high surface heat fluxes, but are explained by the relatively low aerodynamic roughness of the upwind surface. Although the heat fluxes over forest are enhanced, the momentum fluxes are almost adjusted to the underlying forest. The different behaviour of heat and momentum fluxes is explained by absorption of momentum by pressure gradients near the forest edge. It is concluded that fetch requirements to obtain accurate surface fluxes from atmospheric observations need to be more stringent for scalar fluxes as compared to momentum fluxes. Received November 23, 2001; accepted May 13, 2002  相似文献   

Crustal thickness, discontinuity depth, and upper mantle structure beneath southern Africa: constraints from body wave conversions     

Jacek Stankiewicz  S  bastien Chevrot  Rob D. van der Hilst  Maarten J. de Wit 《Physics of the Earth and Planetary Interiors》2002,130(3-4):235-251

The technique of receiver function analysis is applied to the study of crustal and upper mantle structures beneath the Kaapvaal craton in southern Africa and its surroundings. Seismic data were recorded by the seismic array of 82 sites deployed from April 1997 to April 1999 across southern Africa, as well as a dense array of 32 sites near Kimberley, in operation from December 1998 to June 1999. Arrival times for phases converted at the Moho are used to determine crustal thickness. The Moho depth in the south–western section of the craton was found to vary between 37 and 40 km, except for one station that recorded a depth of 43 km (SA23). Farther north along the western block of the craton (into Botswana) the depth increases up to 43 km. The depth increases even further in the north–eastern section of the craton, where results vary from 40 to 52 km. Just north of the Kaapvaal craton, in the neighbouring Zimbabwe craton, the crustal thickness drops significantly. The results obtained there varied from 36 to 40 km. For the Kimberley area, using the dense array, the Moho depth was found to be 37.3 km. Arrivals of the Ps and Ppps phases were used to determine the Poisson’s ratio in the region. This was found to be 0.26±0.01. Arrivals of phases from the 410 and 660 km mantle discontinuities are used to interpret the relative positions of these discontinuities, as well as for comparison of mantle temperatures and seismic velocities in the region with global averages. In the Kimberley area the 410 and 660 km discontinuities were found at their expected depth, implying that mantle temperatures in the region are close to the global average. The seismic velocities above the ‘410’ were found up to 5% faster than the averages from the global iasp91 model, which is fast even by Precambrian standards. In other sections of the Kaapvaal craton, the velocities are also faster than global averages, but not as fast as beneath Kimberley. In these sections, the ‘410’ is also slightly elevated, while the ‘660’ is depressed, which implies a slightly lower mantle temperature relative to the global average. Beneath the Kaapvaal craton we find evidence suggesting the presence of a zone with a reduced wavespeed gradient at an upper bound of approximately 300 km, which may mark the lower chemical boundary of the craton.  相似文献   

On the role of subducting oceanic plateaus in the development of shallow flat subduction   总被引：2，自引：0，他引：2  

Jeroen van Hunen  Arie P. van den Berg  Nico J. Vlaar 《Tectonophysics》2002,352(3-4)

Oceanic plateaus, aseismic ridges or seamount chains all have a thickened crust and their subduction has been proposed as a possible mechanism to explain the occurrence of flat subduction and related absence of arc magmatism below Peru, Central Chile and at the Nankai Trough (Japan). Their extra compositional buoyancy could prohibit the slab from sinking into the mantle. With a numerical thermochemical convection model, we simulated the subduction of an oceanic lithosphere that contains an oceanic crustal plateau of 18-km thickness. With a systematic variation, we examined the required physical parameters to obtain shallow flat subduction. Metastability of the basaltic crust in the eclogite stability field is of crucial importance for the slab to remain buoyant throughout the subduction process. In a 44-Ma-old subducting plate, basalt must be able to survive a temperature of 600–700 °C to keep the plate buoyant sufficiently long to cause a flat-slab segment. We found that the maximum yield stress in the slab must be limited to about 600 MPa to allow for the necessary bending to the horizontal. Young slabs show flat subduction for larger parameter ranges than old slabs, since they are less gravitationally unstable and show less resistance against bending. Hydrous weakening of the mantle wedge area and lowermost continent are required to allow for the necessary deformation of a change in subduction style from steep to flat. The maximum flat slab extent is about 300 km, which is sufficient to explain the observed shallow flat subduction near the Nankai Trough (Japan). However, additional mechanisms, such as active overthrusting by an overriding continental plate, need to be invoked to explain the flat-slab segments up to 500 km long below Peru and Central Chile.  相似文献