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51.
C. Schnitchen D. J. Charman E. Magyari M. Braun I. Grigorszky B. Tóthmérész M. Molnár Zs. Szántó 《Journal of Paleolimnology》2006,36(1):1-17
Peatlands offer the potential for high resolution records of water balance over Holocene timescales, yet this potential is
under-exploited in many areas of the world. Within Europe, peatlands are mostly confined to areas north of 55° N, but several
areas of southern and eastern Europe contain small peatlands which may be suitable for palaeoclimatic reconstruction. In this
paper we test the potential of peatlands in the Carpathian region for deriving quantified estimates of water table changes
using testate amoebae analysis. A training set for palaeohydrological reconstruction from testate amoebae assemblages was
obtained by collecting surface samples from 13 peatlands, including 9 from Hungary and 4 from Transylvania (Romania). Using
a simple measure of mean annual water tables estimated from staining of PVC tape, we found that some peatlands were heavily
influenced by runoff and groundwater, and were therefore not suitable as modern analogues of ombrotrophic climatically sensitive
sites. The relationship between the testate amoebae assemblages in the modern samples and the environmental variables was
explored using CCA. The CCA biplot showed that the most important variables are depth to water table and moisture content,
confirming that hydrology is a key control on taxon distribution. pH was a secondary gradient. A transfer function for % moisture
and depth to water table was established and applied to fossil assemblages from a sequence from Fenyves-tető, Transylvania,
Romania. The reconstructed water table shows a number of variations which have parallels with other palaeoclimatic records
from Europe and the North Atlantic prominent phases of higher water tables are associated with the periods 8000–8300 cal BP,
3000–2500 cal BP and after 600 cal BP. We suggest that these were periods of particular intensification of westerly airflow
which affected eastern Europe as well as western and central Europe. 相似文献
52.
53.
The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt 总被引:4,自引:0,他引:4
J. Sánchez España E. López Pamo E. Santofimia Pastor J. Reyes Andrés J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298
This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD)
waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters
were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO4=) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously
recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and
precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5
(stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates
of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially
sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO4=
anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous
free cations (Pb2+, Zn2+, Cu2+, Cd2+, Mn2+, Co2+, Ni2+) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely
scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10−1) of the SO 4= ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH
< 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co,
Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB. 相似文献
54.
Skier-triggered avalanches are the main cause of avalanche accidents in backcountry skiing. The risk of accidents during backcountry
skiing was analysed statistically and related to factors such as elevation level, aspect, stability rating and the time of
the year. The analysis is based on a database about terrain usage and avalanche accidents from a large heli-skiing operator
in Canada, which makes it possible to study the conditional probability of accidents given the recorded pattern of terrain
usage. This study shows that the historical risk of accidentally triggering an avalanche greater than size 1 depends highly
on the stability rating, with the highest risk occurring during “poor” stability. The risk is greater at high elevations,
and it is lower during the late season than earlier on. Skier risk does not depend as much on aspect as may be indicated from
avalanche data alone. However, it is relatively high in the N–NE–E sector. These factors are not independent of each other
and therefore analyses of combined factors were also performed. Questionnaires and interviews were used to gain knowledge
about the terrain selection of professional mountain guides. These results indicate that when selecting terrain, guides first
look at the overall shape and size of the terrain, but avalanche history of terrain and inclination are also important factors.
Finally, remarks in avalanche reports were analysed, and common human factors identified. 相似文献
55.
56.
G. M. da Costa E. Van San E. De Grave R. E. Vandenberghe V. Barrón L. Datas 《Physics and Chemistry of Minerals》2002,29(2):122-131
A novel method for synthesis of aluminium hematites, based upon the homogeneous precipitation of Fe and Al oxinates in various proportions, is presented. The precursor precipitates are heated in air at 700?°C. X-ray diffraction, thermal analyses, BET, FTIR, optical reflection analysis, TEM and Mössbauer spectroscopy at room temperature and 80?K of the resulting products indicate that single-phase hematites are formed with structural Al substitution of up to 10 at%. Interestingly, the particle size (>100?nm) is not substantially reduced by the Al content. Although it remains difficult to obtain a homogeneously distributed Al substitution in the final hematite, this processing line offers a unique opportunity to separate the effects of grain size and Al substitution on the Morin transition temperature (T M) of Al hematite. From the comparison between the present hematites and a series of Al-substituted hematites with lepidocrocite as precursor, it could be shown that the effect on T M, associated with a change of a factor 10 in grain size, is about 1/3 of the effect caused by a change of 10 in the degree of substitution. Finally, it is suggested that proper thermal treatments under different conditions of the same precursors are likely to produce spinel phases. 相似文献
57.
Traditional models of urban development are no longer adequate to describe current metropolitan transformations. These are
now at the centre of a debate concerning management and administration. In Italy, delays in resolving problems of urban and
metropolitan government, despite the legal framework provided by Law 142/90, have weighed heavily on the larger urban areas
of the country: Rome, Naples, Milan, which have not been able to tackle the issue of metropolitan government. Recent legislation,
while not providing a pre-defined institutional solution, allows separate administrative districts to collectively establish
metropolitan institutions of `variable geometry'. The Milan urban area is not one city, but a system of mutually-dependent
cities, linked to each other and the rest of the world by a transport network still requiring much investment. The vitality
of its economic structure (especially its small firms) is held back by seriously inadequate infrastructure and low external
economic efficiency. The provincial capital may boast `historic centrality' but the most interesting potential for development
is to be found on the periphery and in the administrative districts immediately surrounding it, in the recovery of derelict
industrial areas and dormitory towns established in the 1950s and 1960s, especially to the north. Recovery of derelict areas,
green areas, and better transport links within the urban area and with the outside world are the key elements in the reorganization
of `Greater Milan'. In this situation of rapid transformation the most appropriate political strategies involve negotiated
planning.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
58.
Pilar Drake Alberto M. Arias Francisco Baldó José A. Cuesta Antonio Rodríguez Alfonso Silva-Garcia Ignacio Sobrino Diego García-González Carlos Fernández-Delgado 《Estuaries and Coasts》2002,25(3):451-468
The aquatic macrofauna of the Guadalquivir estuary were sampled (1 mm mesh persiana net) at 5 sampling sites located along the entire (except the tidal freshwater region) estuarine gradient of salinity (outer 50 km). A total of 134 fish and macroinvertebrate species was collected but only 62 were considered common or regularly present in the estuary. Univariate measures of the community structure showed statistically significant differences among sampling sites: species richness, abundance, and biomass decreased in the upstream direction, being positively correlated with the salinity. Temporal differences of these three variables were also statistically significant. While a clear seasonal pattern (minimum densities in winter and maximum in spring-summer) was observed for abundance and biomass, no such pattern existed for the number of species. Mysids was the most dominant group throughout the estuary (96% to 99% of abundance; 49% to 85% of biomass), although fish biomass was also important at the outer estuary (36% to 38%). Multivariate analyses indicated highly significant spatial variation in the macrofaunal communities observed along the salinity gradient. These analyses suggest that the underlying structure was a continuum with more or less overlapping distributions of the species dependent on their ability to tolerate different physicochemical conditions. There were also significant temporal (intermonthly + interannual) variation of the estuarine community; the relative multivariate dispersion indicated that monthly variation was more considerable (relative multivariate dispersion >1) at the outer part of the estuary during the wet year (last 20 km) and was higher in the inner stations during the dry year (32 to 50 km from the river mouth). Since a clear negative exponential relationship was observed between the freshwater input (from a dam located 110 km upstream) and water salinity at all sampling stations, it is concluded that the human freshwater management is probably affecting the studied estuarine communities. While the higher seasonal (long-term) stability of the salinity gradient, due to the human control of the freshwater input, may facilitate the recruitment of marine species juveniles during the meteorologically unstable early-spring, the additional (short-term) salinity fluctuations during the warm period may negatively affect species that complete their lifecycle within the estuary. 相似文献
59.
Roberto J. Llansó Lisa C. Scott Jeffrey L. Hyland Daniel M. Dauer David E. Russell Frederick W. Kutz 《Estuaries and Coasts》2002,25(6):1231-1242
A benthic index of biotic integrity was developed for use in estuaries of the mid-Atlantic region of the United States (Delaware Bay estuary through Albemarle-Pamlico Sound). The index was developed for the Mid-Atlantic Integrated Assessment Program (MAIA) of the U.S. Environmental Protection Agency using procedures similar to those applied previously in Chesapeake Bay and southeastern estuaries, and was based on sampling in July through early October. Data from seven federal and state sampling programs were used to categorize sites as degraded or non-degraded based on dissolved oxygen, sediment contaminant, and sediment toxicity criteria. Various metrics of benthic community structure and function that distinguished between degraded and reference (non-degraded) sites were selected for each of five major habitat types defined by classification analysis of assemblages. Each metric was scored according to thresholds established on the distribution of values at reference sites, so that sites with low scoring metrics would be expected to show signs of degradation. For each habitat, metrics that correctly classified at least 50% of the degraded sites in the calibration data set were selected whenever possible to derive the index. The final index integrated the average score of the combination of metrics that performed best according to several criteria. Selected metrics included measures of productivity (abundance), diversity (number of taxa, Shannon-Wiener diversity, percent dominance), species composition and life history (percent abundance of pollution-indicative taxa, percent abundance of pollution-sensitive taxa, percent abundance of Bivalvia, Tanypodinae-Chironomidae abundance ratio), and trophic composition (percent abundance of deep-deposit feeders). The index correctly classified 82% of all sites in an independent data set. Classification efficiencies of sites were higher in the mesohaline and polyhaline habitats (81–92%) than in the oligohaline (71%) and the tidal freshwater (61%). Although application of the index to low salinity habitats should be done with caution, the MAIA index appeared to be quite reliable with a high likelihood of correctly identifying both degraded and non-degraded conditions. The index is expected to be of great utility in regional assessments as a tool for evaluating the integrity of benthic assemblages and tracking their condition over time. 相似文献
60.
Seismic Hazard Estimate at the Iberian Peninsula 总被引:1,自引:0,他引:1
—?Seismic hazard at the Iberian Peninsula has been evaluated by using a methodology which combines both zonified and non-zonified probabilistic methods. Seismic sources are used when considering zones where certain calculation parameters may be considered homogeneous, as in zonified methods, while, on the other hand, earthquakes are considered wherever it has taken place, as in non-zonified methods. The methodology which is applied in this paper has been originally used to calculate the seismic hazard maps in the United States. In our case, it has been necessary to adapt the method to the specific features of the seismicity in the Iberian Peninsula and its geographical surroundings, not only with respect to its distribution and characteristics, but also with respect to the properties of the seismic catalog used.¶Geographically, the main feature of the result is the fact that it reflects both historical seismicity and current seismic clusters of the region. Despite the smoothing, maps show marked differences between several seismic zones; these differences becoming more noticeable as exposure time increases. Maximum seismic hazard is found to be in the southwestern region of the Peninsula, especially in the area of the Cape St. Vicent, and around Lisbon. The uncertainty of the results, without considering that due to the attenuation laws, as deduced from the other evaluation parameters, is quite stable, being more sensitive to the parameters b and m max of the Gutenberg-Richter relation. 相似文献