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91.
Thomas E. Thorpe 《Icarus》1973,20(4):482-489
The large quantity of Mariner 9 television pictures taken at phase angles ranging up to twice those accessible from Earth has been used to describe intergrated photometric properties of Mars. Although frame-to-frame variations emphasize the shortcomings of vidicon cameras when used in a photometric mode, statistical trends have yielded data comparable with Earth-based observations.Analysis of atmospheric parameters over a period of changing opacity, November 1971 through March 1972, has provided time-varying optical depths and light-scattering information. Linear function characterization of the Mars reflectance is clearly discrepant at large incidence or emission angles and at phase angles greater than 40°.  相似文献   
92.
93.
Abstract

Experiments have been made using shadowgraphs to examine the development of secondary structures in Kelvin-Helmhoitz billows at the diffuse interface between two layers of different densities moving in shear at moderate Reynolds numbers and high Prandtl number. The onset of turbulence in billows reported in earlier work resulted from an interaction between the billows and the side walls of the apparatus. Secondary structure within the billows remote from the side walls occurs later and is, in its early stages, well organised. Regular longitudinal bands lying parallel to the mean flow develop near the vertical boundaries of the billows and extend across their widths. The initial development and scale of the spanwise bands are similar to that of the convective rolls predicted to occur in billows by Klaassen and Peltier (1985a) using a numerical model. No longitudinal instability is observed to occur at the same time in the braids between the billows. Fine scale “turbulence” occurs in the billows about one stability period (for the original interface) after the secondaries first appear, so that the transition is not, as previously thought, “explosive” but is relatively slow. Two other “transitional” structures are reported. One has a tube-like appearance extending from one billow to its neighbour. Disturbances are transmitted down the tube and these ultimately initiate turbulence in the second billow. The second structure is a “knot” due to the spanwise amalgamation of two-billows into one.

The relevance of the observations to geophysical flows is discussed. Earlier estimates of the efficiency of mixing due to Kelvin-Helmhoitz instability are put into doubt. Billows typical of those observed by Woods (1968) in the oceanic seasonal thermocline should develop secondary bands at a scale of about 2 cms.  相似文献   
94.
95.
The North Pennine Orefield Alston Block has produced approximately 4 Mt Pb, 0.3 Mt Zn, 2.1 Mt fluorite, 1.5 Mt barite, 1 Mt witherite, plus a substantial amount of iron ore and copper ore from predominantly vein-hosted mineralisation in Carboniferous limestones. However, a significant proportion of this production (ca. 20%) came from stratabound deposits. Though much is known about the vein mineralisation, the relationship between the veins and the stratabound mineralisation is not well-understood. New petrographic, isotopic and fluid inclusion data derived from samples of stratabound mineralisation allow us to present a unified model that addresses the genesis of both the vein and stratabound styles of mineralisation. The mineralisation can be considered in terms of three episodes:
1.  Dolomitisation and ankeritisation Limestones in the vicinity of the stratabound mineralisation were pervasively dolomitised/ankeritised, and developed vuggy porosity in the presence of a high-salinity brine consistent with fluids derived from adjacent mud and shale-filled basins.
2.  Main stage fluoritequartzsulphide mineralisation Metasomatism of limestone was accompanied by brecciation, dissolution and hydrothermal karstification with modification of the existing pore system. The open space was filled with fluorite, galena, sphalerite, quartz and barite, formed in response to mixing of low-salinity sodic groundwater with high-salinity calcic brine with elevated metal contents (particularly Fe up to 7,000 ppm) relative to “normal” high total dissolved solids sedimentary brines.
3.  Late-stage barite mineralisation paragenetically appears to represent either the waning stages or the distal portions of the main hydrothermal circulation system under cooler conditions.
  相似文献   
96.
97.
The Mars 2020/Mars Sample Return (MSR) Sample Depot Science Community Workshop was held on September 28 and 30, 2022, to assess the Scientifically-Return Worthy (SRW) value of the full collection of samples acquired by the rover Perseverance at Jezero Crater, and of a proposed subset of samples to be left as a First Depot at a location within Jezero Crater called Three Forks. The primary outcome of the workshop was that the community is in consensus on the following statement: The proposed set of ten sample tubes that includes seven rock samples, one regolith sample, one atmospheric sample, and one witness tube constitutes a SRW collection that: (1) represents the diversity of the explored region around the landing site, (2) covers partially or fully, in a balanced way, all of the International MSR Objectives and Samples Team scientific objectives that are applicable to Jezero Crater, and (3) the analyses of samples in this First Depot on Earth would be of fundamental importance, providing a substantial improvement in our understanding of Mars. At the conclusion of the meeting, there was overall community support for forming the First Depot as described at the workshop and placing it at the Three Forks site. The community also recognized that the diversity of the Rover Cache (the sample collection that remains on the rover after placing the First Depot) will significantly improve with the samples that are planned to be obtained in the future by the Perseverance rover and that the Rover Cache is the primary target for MSR to return to Earth.  相似文献   
98.
The Pacific Atmospheric Sulfur Experiment (PASE) is the first sulfur-budget field experiment to feature simultaneous flux measurements of DMS marine emissions and SO2 deposition to the ocean surface. We make use of these data to constrain a 1-D chemical transport model to study the production and loss pathways for DMS and SO2 over the equatorial Pacific. Model results suggest that OH is the main sink for DMS in the boundary layer (BL), and the average DMS-to-SO2 conversion efficiency is ~73%. In an exploratory run involving the addition of 1 pptv of BrO as a second oxidant, a 14% increase in the DMS flux is needed beyond that based on OH oxidation alone. This BrO addition also reduces the DMS-to-SO2 conversion efficiency from 73% to 60%. The possibility of non-DMS sources of marine sulfur influencing the estimated conversion efficiency was explored and found to be unconvincing. For BL conditions, SO2 losses consist of 48% dry deposition, while transport loss to the BuL and aerosol scavenging each account for another 19%. The conversion of SO2 to H2SO4 consumes the final 14%. In the BuL, cloud scavenging removes 85% of the SO2, thus resulting in a decreasing vertical profile for SO2. The average SO2 dry deposition velocity from direct measurements (i.e., 0.36 cm sec−1) is approximately 50% of what is calculated from the 1-D model and the global GEOS-Chem model. This suggests that the current generation of global models may be significantly overestimating SO2 deposition rates over some tropical marine areas. Although the specific mechanism cannot be determined, speculation here is that the dry deposition anomalous results may point to the presence of a micro-surface chemical phenomenon involving partial saturation with either S(IV) and/or S(VI) DMS oxidation products. This could also appear as a pH drop in the ocean’s surface microfilm layer in this region. Finally, we propose that the enhanced SO2 level observed in the lower free troposphere versus that in the upper BuL during PASE is most likely the result of transported DMS/SO2-rich free-tropospheric air parcels from the east of the PASE sampling area, rather than an inadequate representation in the model of local convection.  相似文献   
99.
The Pacific Atmospheric Sulfur Experiment (PASE) was a comprehensive airborne study of the chemistry and dynamics of the tropical trade wind regime (TWR) east of the island of Kiritibati (Christmas Island, 157º, 20?? W, 2º 52?? N). Christmas Island is located due south of Hawaii. Geographically it is in the northern hemisphere yet it is 6?C12º south of the intertropical convergence zone (ITCZ) which places it in the southern hemisphere meteorologically. Christmas Island trade winds in August and September are from east south east at 3?C15 ms?1. Clouds, if present, are fair weather cumulus located in the middle layer of the TWR which is frequently labeled the buffer layer (BuL). PASE provided clear support for the idea that small particles (80 nm) were subsiding into the tropical trade wind regime (TWR) where sulfur chemistry transformed them to larger particles. Sulfur chemistry promoted the growth of some of these particles until they were large enough to activate to cloud drops. This process, promoted by sulfur chemistry, can produce a cooling effect due to the increase in cloud droplet density and changes in cloud droplet size. These increases in particle size observed in PASE promote additional cooling due to direct scattering from the aerosol. These potential impacts on the radiation balance in the TWR are enhanced by the high solar irradiance and ocean albedo of the TWR. Finally because of the large area involved there is a large factional impact on earth??s radiation budget. The TWR region near Christmas Island appears to be similar to the TWR that persists in August and September, from southwest of the Galapagos to at least Christmas Island. Transport in the TWR between the Galapagos and Christmas involves very little precipitation which could have removed the aerosol thus explaining at least in part the high concentrations of CCN (??300 at 0.5% supersaturation) observed in PASE. As expected the chemistry of sulfur in the trade winds was found to be initiated by the emission of DMS into the convective boundary layer (BL, the lowest of three layers). However, the efficiency with which this DMS is converted to SO2 has been brought into further question by this study. This unusual result has come about as result of our using two totally different approaches for addressing this long standing question. In the first approach, based on accepted kinetic rate constants and detailed steps for the oxidation of DMS reflecting detailed laboratory studies, a DMS to SO2 conversion efficiency of 60?C73% was determined. This range of values lies well within the uncertainties of previous studies. However, using a completely different approach, involving a budget analysis, a conversion value of 100% was estimated. The latter value, to be consistent with all other sulfur studies, requires the existence of a completely independent sulfur source which would emit into the atmosphere at a source strength approximately half that measured for DMS under tropical Pacific conditions. At this time, however, there is no credible scientific observation that identifies what this source might be. Thus, the current study has opened for future scientific investigation the major question: is there yet another major tropical marine source of sulfur? Of equal importance, then, is the related question, is our global sulfur budget significantly in error due to the existence of an unknown marine source of sulfur? Pivotal to both questions may be gaining greater insight about the intermediate DMS oxidation species, DMSO, for which rather unusual measurements have been reported in previous marine sulfur studies. The 3 pptv bromine deficit observed in PASE must be lost over the lifetime of the aerosol which is a few days. This observation suggests that the primary BrO production rate is very small. However, considering the uncertainties in these observations and the possible importance of secondary production of bromine radicals through aerosol surface reactions, to completely rule out the importance of bromine chemistry under tropical conditions at this time cannot be justified. This point has been brought into focus from prior work that even at levels of 1 pptv, the effect of BrO oxidation on DMS can still be quite significant. Thus, as in the case of DMS conversion to SO2, future studies will be needed. In the latter case there will need to be a specific focus on halogen chemistry. Such studies clearly must involve specific measurements of radical species such as BrO.  相似文献   
100.
Three-dimensional framework models are the state of the art to present geologists’ understanding of a region in a form that can be used to support planning and decision making. However, there is little information on the uncertainty of such framework models. This paper reports an experiment in which five geologists each produced a framework model of a single region in the east of England. Each modeller was provided with a unique set of borehole observations from which to make their model. Each set was made by withholding five unique validation boreholes from the set of all available boreholes. The models could then be compared with the validation observations. There was no significant between-modeller source of variation in framework model error. There was no evidence of systematic bias in the modelled depth for any unit, and a statistically significant but small tendency for the mean error to increase with depth below the surface. The confidence interval for the predicted height of a surface at a point ranged from ±5.6 m to ±6.4 m. There was some evidence that the variance of the model error increased with depth, but no evidence that it differed between modellers or varied with the number of close-neighbouring boreholes or distance to the outcrop. These results are specific to the area that has been modelled, with relatively simple geology, and reflect the relatively dense set of boreholes available for modelling. The method should be applied under a range of conditions to derive more general conclusions.  相似文献   
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