Classification of CM chondrite breccias—Implications for the evaluation of samples from the OSIRIS‐REx and Hayabusa 2 missions     

Sarah Lentfort  Addi Bischoff  Samuel Ebert  Markus Patzek 《Meteoritics & planetary science》2021,56(1):127-147

CM chondrites are complex impact (mostly regolith) breccias, in which lithic clasts show various degrees of aqueous alteration. Here, we investigated the degree of alteration of individual clasts within 19 different CM chondrites and CM‐like clasts in three achondrites by chemical analysis of the tochilinite‐cronstedtite‐intergrowths (TCIs; formerly named “poorly characterized phases”). To identify TCIs in various chondritic lithologies, we used backscattered electron (BSE) overview images of polished thin sections, after which appropriate samples underwent electron microprobe measurements. Thus, 75 lithic clasts were classified. In general, the excellent work and specific criteria of Rubin et al. (2007) were used and considered to classify CM breccias in a similar way as ordinary chondrite breccias (e.g., CM2.2‐2.7). In BSE images, TCIs in strongly altered fragments in CM chondrites (CM2.0‐CM2.2) appear dark grayish and show a low contrast to the surrounding material (typically clastic matrix), and can be distinguished from TCIs in moderately (CM2.4‐CM2.6) or less altered fragments (CM2.7‐CM2.9); the latter are bright and have high contrast to the surroundings. We found that an accurate subclassification can be obtained by considering only the “FeO”/SiO₂ ratio of the TCI chemistry. One could also consider the TCIs’ S/SiO₂ ratio and the metal abundance, but these were not used for classification due to several disadvantages. Most of the CM chondrites are finds that have suffered terrestrial weathering in hot and cold deserts. Thus, the observed abundance of metal is susceptible to weathering and may not be a reliable indicator of subtype classification. This study proposes an extended classification scheme based on Rubin’s scale from subtypes CM2.0‐CM2.9 that takes the brecciation into account and includes the minimum to maximum degree of alteration of individual clasts. The range of aqueous alteration in CM chondrites and small spatial scale of mixing of clasts with different alteration histories will be important for interpreting returned samples from the OSIRIS‐REx and Hayabusa 2 missions in the future.  相似文献   

The Bear Brook Watershed in Maine: Multi-decadal whole-watershed experimental acidification     

Kaizad F. Patel  Ivan J. Fernandez  Sarah J. Nelson  Stephen A. Norton  Cheryl J. Spencer 《水文研究》2021,35(5):e14147

The Bear Brook Watershed in Maine (BBWM) is a long-term research site established to study the response of forest ecosystem function to environmental disturbances of chronic acidic deposition and ecosystem nitrogen enrichment. Starting in 1989, the West Bear (treated) watershed received bimonthly applications of ammonium sulfate [(NH₄)₂SO₄] fertilizer from above the canopy, whereas East Bear (reference) received ambient deposition. The treatments were stopped in 2016, marking the beginning of the recovery phase. Research at the site has focused on soils, streams, and vegetation. Here, we describe data collected over three decades at the BBWM—input and stream output nutrient fluxes, quantitative soil pits and soil chemistry, and soil temperature and moisture.  相似文献   

Effectiveness of post-fire salvage logging stream buffer management for hillslope erosion in the U.S. Inland Northwest Mountains     

Peter R. Robichaud  Edwin D. Bone  Sarah A. Lewis  Erin S. Brooks  Robert E. Brown 《水文研究》2021,35(1):e13943

Active wildfire seasons in the western U.S. warrant the evaluation of post-fire forest management strategies. Ground-based salvage logging is often used to recover economic loss of burned timber. In unburned forests, ground-based logging often follows best management practices by leaving undisturbed areas near streams called stream buffers. However, the effectiveness of these buffers has not been tested in a post-wildfire setting. This experiment tested buffer width effectiveness with a novel field-simulated rill experiment using sediment-laden runoff (25 g/L) released over 40 min at evenly timed flow rates (50, 100 and 150 L/min) to measure surface runoff travel length and sediment concentration under unburned and high and low soil burn severity conditions at 2-, 10- and 22-month post-fire. High severity areas 2-month post-fire had rill lengths of up to 100 m. Rill length significantly decreased over time as vegetation regrowth provided ground cover. Sediment concentration and sediment dropout rate also varied significantly by soil burn severity. Sediment concentrations were 19 g/L for the highest flow 2-month post-fire and reduced to 6.9–14 g/L 10-month post-fire due to abundant vegetation recovery. The amount of sediment dropping out of the flow consistently increased over the study period with the low burn severity rate of 1.15 g L⁻¹ m⁻¹ approaching the unburned rate of 1.29 g L⁻¹ m⁻¹ by 2-year post-fire. These results suggest that an often-used standard, 15 m buffer, was sufficient to contain surface runoff and reduce sediment concentration on unburned sites, however buffers on high burn severity sites need to be eight times greater (120 m) immediately after wildfire and four times greater (60 m) 1-year post-fire. Low burn severity areas 1-year post-fire may need to be only twice the width of an unburned buffer (30 m), and 2-year post-fire these could return to unburned widths.  相似文献   

The role of fog,orography, and seasonality on precipitation in a semiarid,tropical island          下载免费PDF全文

Sarah R. Schmitt  Diego A. Riveros‐Iregui  Jia Hu 《水文研究》2018,32(18):2792-2805

Isotopes of water (²H/¹H and ¹⁸O/¹⁶O) are commonly used to trace hydrological processes such as moisture recycling, evaporation loss, and moisture source region and often vary temporally in a given region. This study provides a first‐ever characterization of temporally variable precipitation mechanisms of San Cristóbal Island, Galápagos. We collected fog, rain, and throughfall samples over three field seasons to understand the mechanisms driving seasonal‐ and event‐based variability in the isotopic composition of precipitation in Galápagos. We establish that fog is a common phenomenon in San Cristóbal, especially during the dry season, and we found that fog, compared with cocollected rainfall, is consistently enriched. We further suggest that the relative contribution of fog formed via different mechanisms (orographic, advective, radiation) varied seasonally. We found that the source region is the most dominant control of the isotopic composition of rainfall in the Galápagos at both the seasonal and event scales, but subcloud evaporative processes (the nontraditional manifestation of the amount effect) became a dominant control on the isotopic composition of rainfall during the dry season. Overall, our findings suggest that understanding seasonally variable water‐generating mechanisms is required for effective water resource management in San Cristóbal Island and other semiarid island ecosystems under current and future regimes of climate change.  相似文献   

Faecal indicator bacteria in New Zealand freshwater fish: a pilot study     

Sarah Coxon  Jon S Harding  Brent Gilpin 《新西兰海洋与淡水研究杂志》2019,53(3):470-479

Recent studies have suggested that poikilothermic animals, such as fish, may represent a previously overlooked source of the faecal indicator bacteria (FIB) used for the assessment of water quality. However, quantitative studies of FIB in poikilotherms are scarce. We investigated the presence of FIB in the faeces of five freshwater fish species. E. coli and enterococci were detected in 71 and 76% of faecal samples, respectively. Concentrations were highly variable, with maximum concentrations (2.1?×?10⁴ E. coli and 1.3?×?10⁶ enterococci per gram of faecal material) up to four orders of magnitude higher than present in the water column. FIB were not detected in faecal samples from marine fish. Our findings suggest that FIB ingested from the environment may be capable of replication within the fish gut, making fish a potential source and transport mechanism for FIB in New Zealand freshwaters. This may have implications for water quality monitoring.  相似文献   

Spinel assemblages in lunar meteorites Graves Nunataks 06157 and Dhofar 1528: Implications for impact melting and equilibration in the Moon's upper mantle     

Axel Wittmann  Randy L. Korotev  Bradley L. Jolliff  Paul K. Carpenter 《Meteoritics & planetary science》2019,54(2):379-394

Magnesium‐rich spinel assemblages occur in the two lunar vitric breccia meteorites—Dhofar (Dho) 1528 and Graves Nunataks (GRA) 06157. Dho 1528 contains up to ~0.7 mm cumulate Mg‐rich spinel crystals associated with Mg‐rich olivine, Mg‐ and Al‐rich pyroxene, plagioclase, and rare cordierite. Using thermodynamic calculations of these mineral assemblages, we constrain equilibration depths and discuss an origin of these lithologies in the upper mantle of the Moon. In contrast, small, 10 to 20 μm spinel phenocryst assemblages in glassy melt rock clasts in Dho 1528 and GRA 06157 formed from the impact melting of Mg‐rich rocks. Some of these spinel phenocrysts match compositional constraints for spinel associated with “pink spinel anorthosites” inferred from remote sensing data. However, such spinel phenocrysts in meteorites and Apollo samples are typically associated with significant amounts of olivine ± pyroxene that exceed the compositional constraints for pink spinel anorthosites. We conclude that the remotely sensed “pink spinel anorthosites” have not been observed in the collections of lunar rocks. Moreover, we discuss impact‐excavation scenarios for the spinel‐bearing assemblages in Dhofar 1528 and compare the bulk rock composition of Dho 1528 to strikingly similar compositions of Luna 20 samples that contain ejecta from the Crisium impact basin.  相似文献   

DISOLV: A Python Package for the Interpretation of Borehole Dilution Tests     

Sarah L. Collins  Marco Bianchi 《Ground water》2020,58(5):805-812

Single borehole dilution tests (SBDTs) are an inexpensive but effective technique for hydrogeological characterization of hard-rock aquifers. We present a freely available, easy-to-use, open-source Python package, DISOLV, for plotting, analyzing, and modeling SBDT data. DISOLV can significantly reduce the time spent interpreting field data by helping to identify flowing fractures intersecting the borehole and estimate the corresponding flow rates. DISOLV is successfully benchmarked against two analytical solutions. We also present an example application to real data collected in a borehole in a crystalline basement aquifer in southern India.  相似文献   

Traces of volcanic ash from the Mediterranean,Iceland and North America in a Holocene record from south Wales,UK     

Gwydion Jones  Siwan M. Davies  Richard A. Staff  Neil J. Loader  Sarah J. Davies  Michael J. C. Walker 《第四纪科学杂志》2020,35(1-2):163-174

A tephra record is presented for a sediment core from Llyn Llech Owain, south Wales, spanning the early- to mid-Holocene. Seven cryptotephra deposits are discovered with three thought to correlate with known eruptions and the remaining four considered to represent previously undocumented events. One deposit is suggested to correlate with the ~6.9 cal ka bp Lairg A tephra from Iceland, whereas more distant sources are proposed as the origin for two of the tephra deposits. A peak of colourless shards in early-Holocene sediments is thought to tentatively correlate with the ~9.6 cal ka bp Fondi di Baia tephra (Campi Flegrei) and a second cryptotephra is tentatively correlated with the ~3.6 cal ka bp Aniakchak (CFE) II tephra (Alaska). The Fondi di Baia tephra has never been recorded beyond proximal sites and its discovery in south Wales significantly extends the geographical distribution of ash from this eruption. The remaining four cryptotephra deposits are yet to be correlated with known eruptions, demonstrating that our current understanding of widespread tephra deposits is incomplete. This new tephra record highlights the potential for sites at more southerly and westerly locations in northwest Europe to act as repositories for ash from several volcanic regions.  相似文献   

Compartmentalisation and groundwater–surface water interactions in a prospective shale gas basin: Assessment using variance analysis and multivariate statistics on water quality data     

Miles P. Wilson  Fred Worrall  Sarah A. Clancy  Chris J. Ottley  Alwyn Hart  Richard J. Davies 《水文研究》2020,34(15):3271-3294

An environmental concern with hydraulic fracturing for shale gas is the risk of groundwater and surface water contamination. Assessing this risk partly involves the identification and understanding of groundwater–surface water interactions because potentially contaminating fluids could move from one water body to the other along hydraulic pathways. In this study, we use water quality data from a prospective shale gas basin to determine: if surface water sampling could identify groundwater compartmentalisation by low-permeability faults; and if surface waters interact with groundwater in underlying bedrock formations, thereby indicating hydraulic pathways. Variance analysis showed that bedrock geology was a significant factor influencing surface water quality, indicating regional-scale groundwater–surface water interactions despite the presence of an overlying region-wide layer of superficial deposits averaging 30–40 m thickness. We propose that surface waters interact with a weathered bedrock layer through the complex distribution of glaciofluvial sands and gravels. Principal component analysis showed that surface water compositions were constrained within groundwater end-member compositions. Surface water quality data showed no relationship with groundwater compartmentalisation known to be caused by a major basin fault. Therefore, there was no chemical evidence to suggest that deeper groundwater in this particular area of the prospective basin was reaching the surface in response to compartmentalisation. Consequently, in this case compartmentalisation does not appear to increase the risk of fracking-related contaminants reaching surface waters, although this may differ under different hydrogeological scenarios.  相似文献   

Strong slope-aspect control of regolith thickness by bedrock foliation     

Jordan D. Leone  W. Steven Holbrook  Clifford S. Riebe  Jon Chorover  Ty P.A. Ferré  Bradley J. Carr  Russell P. Callahan 《地球表面变化过程与地形》2020,45(12):2998-3010

The porous near-surface layer of the Earth's crust – the critical zone – constitutes a vital reservoir of water for ecosystems, provides baseflow to streams, guides recharge to deep aquifers, filters contaminants from groundwater, and regulates the long-term evolution of landscapes. Recent work suggests that the controls on regolith thickness include climate, tectonics, lithology, and vegetation. However, the relative paucity of observations of regolith structure and properties at landscape scales means that theoretical models of critical zone structure are incompletely tested. Here we present seismic refraction and electrical resistivity surveys that thoroughly characterize subsurface structure in a small catchment in the Santa Catalina Mountains, Arizona, USA, where slope-aspect effects on regolith structure are expected based on differences in vegetation. Our results show a stark contrast in physical properties and inferred regolith thickness on opposing slopes, but in the opposite sense of that expected from environmental models and observed vegetation patterns. Although vegetation (as expressed by normalized difference vegetation index [NDVI]) is denser on the north-facing slope, regolith on the south-facing slope is four times thicker (as indicated by lower seismic velocities and resistivities). This contrast cannot be explained by variations in topographic stress or conventional hillslope morphology models. Instead, regolith thickness appears to be controlled by metamorphic foliation: regolith is thicker where foliation dips into the topography, and thinner where foliation is nearly parallel to the surface. We hypothesize that, in this catchment, hydraulic conductivity and infiltration capacity control weathering: infiltration is hindered and regolith is thin where foliation is parallel to the surface topography, whereas water infiltrates deeper and regolith is thicker where foliation intersects topography at a substantial angle. These results suggest that bedrock foliation, and perhaps by extension sedimentary layering, can control regolith thickness and must be accounted for in models of critical zone development. © 2020 John Wiley & Sons, Ltd.  相似文献