Geomaterials related to photovoltaics: a nanostructured Fe-bearing kuramite,Cu<Subscript>3</Subscript>SnS<Subscript>4</Subscript>     

Francesco Di Benedetto  Ilaria Bencistà  Francesco D’Acapito  Silvia Frizzera  Andrea Caneschi  Massimo Innocenti  Alessandro Lavacchi  Giordano Montegrossi  Werner Oberhauser  Maurizio Romanelli  Herbert Dittrich  Luca A. Pardi  Gerold Tippelt  Georg Amthauer 《Physics and Chemistry of Minerals》2016,43(8):535-544

The successful synthesis of nanoparticles of Fe-bearing kuramite, (Cu,Fe)₃SnS₄, is reported in this study. Nanocrystalline powders were obtained through a mild, environmentally friendly and scalable solvothermal approach, in a single run. The sample was the object of a multidisciplinary investigation, including X-ray diffraction and absorption, scanning electron microscopy and microanalysis, electron paramagnetic resonance, diffuse reflectance and Mössbauer spectroscopy as well as SQUID magnetometry. The nanoparticles consist of pure Fe-bearing kuramite, exhibiting tetragonal structure. The valence state of the metal cations was assessed to be Cu⁺, Sn⁴⁺ and Fe³⁺. The material presents a band gap value of 1.6 eV, which is fully compatible with solar cell applications. The uptake of Fe by nanokuramite opens a compositional field where the physical properties can be tuned. We thus foster the application of Fe-bearing nanokuramite for photovoltaics and energy storage purposes.  相似文献   

Investigating fossil hydrothermal systems by means of fluid inclusions and stable isotopes in banded travertine: an example from Castelnuovo dell’Abate (southern Tuscany,Italy)     

Valentina Rimondi  Pilario Costagliola  Giovanni Ruggieri  Marco Benvenuti  Chiara Boschi  Andrea Brogi  Enrico Capezzuoli  Guia Morelli  Massimo Gasparon  Domenico Liotta 《International Journal of Earth Sciences》2016,105(2):659-679

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Laser-Triangulation Optical-Correlation Sensor for ROV Slow Motion Estimation   总被引：1，自引：0，他引：1  

Massimo Caccia 《Oceanic Engineering, IEEE Journal of》2006,31(3):711-727

A laser-triangulation optical-correlation sensor for estimating the motion of underwater vehicles at low speed in the proximity of the seabed is described. Experimental results, obtained by processing image sequences acquired by the instrument mounted below the Romeo remotely operated vehicle (ROV) in operating conditions, are presented  相似文献   

The Lago di Varano: Hydrologic Characteristics and Sediment Composition     

Federico Spagnoli  Antonietta Specchiulli  Tommaso Scirocco  Gerardo Carapella  Paolo Villani  Giovanni Casolino  Primiano Schiavone  Massimo Franchi 《Marine Ecology》2002,23(S1):384-394

Abstract. The Lago di Varano is situated on the north side of the Gargano National Park (southeast Italy) and covers a surface area of about 65 km². It communicates with the Adriatic Sea through two artificial canals (Foce Capoiale and Foce Varano) located at the two ends of a long and narrow coastal dune. This work presents preliminary results of four seasonal surveys (1999–2000) carried out to measure chemical and physical parameters of the water column (temperature, salinity, dissolved oxygen and pH) and to analyse a number of biogeochemical characteristics of surface sediments (organic matter, total phosphorus, total nitrogen and total Hg, As, Pb, Cd, Cr, Cu and Ni content). Water analysis indicated poor exchange between the coastal pond and the open sea, limited to autumn and winter. Surface sediments were rich in organic matter, whose distribution was influenced by chemical-physical and hydrodynamic variations in the water column. At the sediment level, the highest values of Cd were found in the central zone of the basin, while the highest Cr values were measured in the central and southeastern areas. With the exception of Cd and Pb, the metal content did not indicate anthropogenic pollution, in particular when compared with the Venice Lagoon and the Central Adriatic Sea.  相似文献   

The State of the Adriatic Sea Centered on the Small Pelagic Fish Populations   总被引：1，自引：0，他引：1  

Massimo Azzali  rea De  Felice  Manlio Luna  Giulio Cosimi  Flavio Parmiggiani 《Marine Ecology》2002,23(S1):78-91

Abstract. The paper provides an overview of the state of the small pelagic fish in the Adriatic Sea. The North Adriatic is reviewed for the 1976–1998 period and the South Adriatic for the 1987–1998 period. First the fluctuations in time and in space of the pelagic biomass, as a whole and per species, are presented. Then the dramatic collapse of anchovy stock and its apparent association with the decrease of surface temperature is discussed. Finally the changes of the anchovy and sardine catches are compared and analysed with respect to their abundances in the sea. The conclusion is that acoustic and satellite methods are able to provide a large amount of information on the variability in the pelagic populations; this is essential for an appropriate management of these resources. There is still a need, however, to refine the methods and to integrate this kind of information with further environmental data (including natural predators).  相似文献   

Wavelength predictions for the 1s2 2p - 1s2p3p satellite transitions     

Massimo Mazzoni 《Solar physics》1987,108(2):221-225

The energy differences between 1s ²2p 1s2p3p transitions and the corresponding 1s ² 1s3p resonances are expressed by means of a polynomial function of the atomic number. The agreement with experimental data from lithium to potassium is very good. Interpolated values for nitrogen to sodium and argon as well as extrapolation for calcium are reported.  相似文献   

Microscopic impactor debris in the soil around Kamil crater (Egypt): Inventory,distribution, total mass,and implications for the impact scenario          下载免费PDF全文

Luigi Folco  Massimo D'Orazio  Agnese Fazio  Carole Cordier  Antonio Zeoli  Matthias van Ginneken  Ahmed El‐Barkooky 《Meteoritics & planetary science》2015,50(3):382-400

We report on the microscopic impactor debris around Kamil crater (45 m in diameter, Egypt) collected during our 2010 geophysical expedition. The hypervelocity impact of Gebel Kamil (Ni‐rich ataxite) on a sandstone target produced a downrange ejecta curtain of microscopic impactor debris due SE–SW of the crater (extending ~300,000 m², up to ~400 m from the crater), in agreement with previous determination of the impactor trajectory. The microscopic impactor debris include vesicular masses, spherules, and coatings of dark impact melt glass which is a mixture of impactor and target materials (Si‐, Fe‐, and Al‐rich glass), plus Fe‐Ni oxide spherules and mini shrapnel, documenting that these products can be found in craters as small as few tens of meters in diameter. The estimated mass of the microscopic impactor debris (<290 kg) derived from Ni concentrations in the soil is a small fraction of the total impactor mass (~10 t) in the form of macroscopic shrapnel. That Kamil crater was generated by a relatively small impactor is consistent with literature estimates of its pre‐atmospheric mass (>20 t, likely 50–60 t).  相似文献   

A late Triassic 40Ar/39Ar age for the El Hammam high-REE fluorite deposit (Morocco): mineralization related to the Central Atlantic Magmatic Province?     

Alain Cheilletz  Dominique Gasquet  Fouad Filali  Douglas A. Archibald  Massimo Nespolo 《Mineralium Deposita》2010,45(4):323-329

El Hammam is the only fluorite mine in Morocco (production 100,000 t/year). The fluorite mineralization is in an array of fluorite–calcite veins and is characterized by unusually high REE content in carbonate minerals (1,400 ppm in calcite; up to 2,000 ppm in siderite) and in fluorite (about 600 ppm). Since the 1960s, the genesis of the deposit has been attributed to a mesothermal hydrothermal event connected with late-Variscan granitic intrusions. Precise ⁴⁰Ar/³⁹Ar dating of hydrothermal K-feldspar yields an age of formation of the El Hammam deposit at 205 ± 1 Ma. Its genesis is therefore associated in time and space with the development of the Triassic–Jurassic basins and the associated anorogenic continental flood basalts of the Moroccan Mesetian Middle Atlas. The source of the hydrothermal mineralization (magmatic and/or metamorphic) is discussed.  相似文献   

New data for the kinematic interpretation of the Alps–Apennines junction (Northwestern Italy)     

Pietro Mosca  Riccardo Polino  Sergio Rogledi  Massimo Rossi 《International Journal of Earth Sciences》2010,99(4):833-849

Alps and Apennines are juxtaposed within an approximately 100 km-wide area covered by the Upper Eocene to Miocene successions of the Tertiary Piedmont Basin. The Upper Eocene–Oligocene evolution of this area was characterized to the north and west by the propagation of the SE-verging Southalpine thrust-fold belt that can be traced from the Po Plain subsurface until the Torino Hill-Saluzzese area, and to the south by a high-angle, broadly E–W oriented megashear zone that led to the juxtaposition of different crustal levels and controlled the development of a mosaic of partly independent sub-basins. Since the latest Oligocene the N-verging Apenninic tectonics prevailed in the collisional system and the Tertiary Piedmont Basin evolved as a wide thrust-top basin, bounded to the north by the N-verging Monferrato arc and characterized by a tectono-sedimentary evolution recording changes of subsidence and shift of depocentres in relation to crustal structures.  相似文献   

Hydrogeological and thermal characterization of shallow aquifers in the plain sector of Piemonte region (NW Italy): implications for groundwater heat pumps diffusion     

Stefano Lo Russo  Massimo Vincenzo Civita 《Environmental Earth Sciences》2010,60(4):703-713

The low annual and seasonal variability of the shallow groundwater temperature in the alluvial plain aquifers of the Piemonte region (NW Italy) confirmed the potentiality of the low-enthalpy open-loop groundwater heat pumps (GWHP) diffusion to contribute to the reduction of regional greenhouse gas emissions. The distribution of mean groundwater temperatures ranged from a minimum of 10.3°C to a maximum of 17.9°C with a mean of 14.0°C. Differences among diverse areas were slight according with the modest variations in the general climatic condition. Like the air, temperature distribution of the shallow groundwater temperatures is generally similar to topographic elevations in reverse manner. Higher temperature values recorded were typical of summer months (June, July). On the opposite lower values were measured in January and February. No significant difference phase (time) difference between air and groundwater temperature appeared in the data analysis. Besides air-temperature influence (seasonal variability) seemed strictly connected to the depth to groundwater in the measure point and it was negligible when the value was over 9.5 m. For the application of the open-loop systems, extensive examinations of the hydrogeological local conditions should be conducted at site scale and groundwater heat transport modelling should be developed.  相似文献