Buchbesprechungen     

W. Mörikofer  F. Steinhauser 《Theoretical and Applied Climatology》1964,13(2):287-302

Ohne Zusammenfassung  相似文献   

Equilibrium and structural studies of silicon(iv) and aluminium(iii) in aqueous solution. V. Acidity constants of silicic acid and the ionic product of water in the medium range 0.05–2.0 M Na(CI) at 25°C     

Staffan Sjöberg  Yvonne Hägglund  Agneta Nordin  Nils Ingri 《Marine Chemistry》1983,13(1):35-44

The apparent ionization constants for silicic acid, k₁ and k₂, and the ionic product of water, k_w, have been determined in 0.05, 0.1, 0.2, 0.4 and 2.0 M Na(CI) media at 25°C. The medium dependence of these constants was found to fit equations of the form where K₁ is the ionization constant in pure water, α_i and b_i are parameters of which b_i has been adjusted to present data. The following results were obtained (α_i, b_i): pK₁ = 9.84, (1.022, ?0.11); pK₂ = 13.43, (2.044, ?0.20); and pK_w = 14.01 (1.022, ?0.22). k_i values are collected in Tables I and II. Attempts have been made to explain the medium dependence of k₁ and k₂ with weak sodium silicate complexing according to the equilibria giving k₁₁ = 0.37M^?1 and k₂₁= 3.0M^?1. However, these weak interactions cannot be interpreted unambiguously from potentiometric data at different 1-levels. Probably the medium dependence could equally well be expressed by variations in the activity coefficients.The measurements were performed as potentiometric titrations using a hydrogen electrode. The average number of OH^- reacted per Si(OH)₄, Z, has been varied within the limits 0 ? Z ? 1.1 and B₁, the total concentration of Si(OH)₄, between 0.001 M and 0.008 M. k₁ was evaluated from experimental data with B ? 0.003 M, and k₂ with B ? 0.008 M and Z ? 0.95.  相似文献   

Upper cretaceous and paleogene sediments from the Northern Kerguelen Plateau     

François Fröhlich  Emmanuelle Wicquart 《Geo-Marine Letters》1989,9(3):127-133

Upper Cretaceous and Paleogene pelagic sediments sampled from the Northern Kerguelen Plateau during cruise MD35 of theMarion Dufresne are described and correlated with the Late Paleogene sequence drilled at site ODP 737 (Leg 119). Taking into account geophysical data obtained by the cruise MD26, a Lower Cretaceous age is computed for the unsampled acoustic basement. A major tectonic/volcanic event in the Late Paleogene, related to rifting, gave rise to a marked unconformity and hiatus termed the “Acoustic Discordance.” Tertiary sediment facies changes were strongly influenced by the evolution of the Antarctic environment.  相似文献   

The estimation of hidden seal-inflicted losses in the Baltic Sea set-trap salmon fisheries   总被引：1，自引：2，他引：1  

Fjalling  Arne 《ICES Journal of Marine Science》2005,62(8):1630-1635

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Efficiency of reduced-order, time-dependent adjoint data assimilation approaches     

Ibrahim Hoteit  Armin Köhl 《Journal of Oceanography》2006,62(4):539-550

Applications of adjoint data assimilation, which is designed to bring an ocean circulation model into consistency with ocean observations, are computationally demanding. To improve the convergence rate of an optimization, reduced-order optimization methods that reduce the size of the control vector by projecting it onto a limited number of basis functions were suggested. In this paper, we show that such order reduction can indeed speed up the initial convergence rate of an assimilation effort in the eastern subtropical North Atlantic using in situ and satellite data as constraints. However, an improved performance of the optimization was only obtained with a hybrid approach where the optimization is started in a reduced subspace but is continued subsequently using the full control space. In such an experiment about 50% of the computational cost can be saved as compared to the optimization in the full control space. Although several order-reduction approaches seem feasible, the best result was obtained by projecting the control vector onto Empirical Orthogonal Functions (EOFs) computed from a set of adjusted control vectors estimated previously from an optimization using the same model configuration.  相似文献   

2-D and 3-D modelling of wide-angle seismic data: an example from the Vøring volcanic passive margin     

Stéphane Rouzo  Frauke Klingelhöfer  Hélène Jonquet-Kolstø  Ridvan Karpuz  Karl Kravik  Rolf Mjelde  Yoshio Murai  Thomas Raum  Hideki Shimamura  Paul Williamson  Louis Géli 《Marine Geophysical Researches》2006,27(3):181-199

This study presents the modelling of 2-D and 3-D wide-angle seismic data acquired on the complex, volcanic passive margin of the Vøring Plateau, off Norway. Three wide-angle seismic profiles were shot and recorded simultaneously by 21 Ocean Bottom Seismometers, yielding a comprehensive 3-D data set, in addition to the three in-line profiles. Coincident multi-channel seismic profiles are used to better constrain the modelling, but the Mesozoic and deeper structures are poorly imaged due to the presence of flood basalts and sills. Velocity modelling reveals an unexpectedly large 30 km basement high hidden below the flood basalt. When interpreted as a 2-D structure, this basement high produces a modelled gravity anomaly in disagreement with the observed gravity. However, both the gravity and the seismic data suggest that the structure varies in all three directions. The modelling of the entire 3-D set of travel times leads to a coherent velocity structure that confirms the basement high; it also shows that the abrupt transition to the slower Cretaceous basin coincides in position and orientation with the fault system forming the Rån Ridge. The positive gravity anomaly over the Rån Ridge originates from the focussed and coincident elevation of the high velocity lower crust and pre-Cretaceous basement. Although the Moho is not constrained by the seismic data, the gravity modelled from the 3-D velocity model shows a better fit along the profiles. This study illustrates the interest of a 3-D acquisition of wide-angle seismic over complex structures and the benefit of the subsequent integrated interpretation of the seismic and gravity data.  相似文献   

Buchbesprechungen     

F. Steinhauser  J. Drimmel  P. Steinhauser  W. Mörikofer 《Meteorology and Atmospheric Physics》1967,16(2-3):273-280

Ohne Zusammenfassung  相似文献   

On lipid surface films on the sea. I. A simple method for sampling and studies of composition     

Kåre Larsson  Göran Odham  Anders Södergren 《Marine Chemistry》1974,2(1):49-57

A method for collection of surface films on the sea has been developed and tested at various places along the Swedish West Coast. Considerable amounts of lipids on the sea surface were found even when no seaslicks were observed. Triglycerides, free fatty acids, and wax esters are the dominating constituents, and there are characteristic deviations in the fatty-acid patterns compared to the corresponding lipids dissolved in the sub-surface water. Organochlorine residues, phthalic acid esters and heavy metals also occur in considerable amounts.  相似文献   

Disorder and recovery of environmental health monitored by means of lysosomal stability in liver of European flounder (Platichthys flesus L.)     

Broeg K  Köhler A  Westernhagen Hv 《Marine environmental research》2002,54(3-5):569-573

From 1995 to 2000 biological effects were studied in liver of flounder (Platichtysflesus L.) from the German Bight. During the study period deleterious consequences of acute discharges of DDT and PCBs in early spring 1996 and after 1998 due to remobilization of contaminants from riverbed deepening of the River Elbe became evident. As core biomarker which reflects toxically induced liver pathologies and integrates effects of various classes of pollutants we measured the integrity of lysosomal membranes in individual flounder liver. During the study period, twice statistically significant disturbances of lysosomal function was detected in fish from the River Elbe: in summer 1996 and in spring 1999. Yet, the detrimental contaminant effects were not only restricted to individuals from the Elbe but expanded to those flounder inhabiting formerly less polluted reference areas. In contrast to flounder of the Elbe, their ability to recover from the lysosomal disorders were limited. While in autumn 2000 Elbe individuals showed clear signs of recovery, those fish caught in areas more distant to the source of toxicant input still maintained significantly decreased lysosomal membrane integrity. It can be speculated that fish populations which are not continuously exposed to chronic anthropogenic stress may have a lower potential or need a longer period to recover from the effects of pollution.  相似文献   

Sedimentological parameters and erosion behaviour of submarine coastal sediments in the south-western Baltic Sea   总被引：9，自引：0，他引：9  

Kai Ziervogel  Björn Bohling 《Geo-Marine Letters》2003,23(1):43-52

The aim of this study was to evaluate the erodibility of submarine coastal sediments for the purpose of modelling sediment dynamics in Mecklenburg Bay, south-western Baltic Sea. Erosion thresholds derived from experiments with a device microcosm on cores of fine sand (n=5, mean grain size=132 µm) and mud (n=5, medium silt size, mean=21 µm), collected at different times of the year, were compared to theoretical critical shear stress velocities based on grain-size measurements. For this purpose, a sedimentological map of natural surface sediments was constructed for the study area. Calculated values for critical shear stress velocities (u* _{cr-Hjulström} ) are 1.2 cm s^?1 for fine sand, and 3.75 cm s^?1 for cohesive mud. At the mud station, erosion experiments showed an initial transport of the fluffy surface layer (u* _cr-initial ) at a mean critical shear stress velocity of 0.39 cm s^?1. Initial rolling transport at the fine sand station for single sand grains was recorded at values of 0.5 cm s^?1. At higher shear stress velocities, the two sediment types showed diverging erosion behaviour. Measurable erosion (ε>5.0×10^?6 kg m^?2 s^?1) of fine sand starts at a mean critical shear stress velocity (u* _cr-erosion ) of 1.15 cm s^?1 whereas fluffy surface material on mud cores was eroded at mean u* _cr-erosion of 0.62 cm s^?1. This indicates that measured erosion thresholds at the fine sand site fit well to calculated critical shear stress velocities whereas calculated erosion thresholds for cohesive mud are roughly 6 times higher than measured values. As erosion behaviour at the mud station was dominated by fluffy surface material, the comparability of measured and calculated threshold values may be reduced. The underlying silt-sized sediment itself was stable due to cohesive effects. This behaviour has to be taken into consideration by using sediment types instead of mean grain sizes for mapping and modelling sediment dynamics. A comparison of the near-bottom hydrodynamic conditions in the study area and experimentally derived critical shear stress velocities suggests that particle transport is controlled by storm events whereas under calm conditions shear stress velocities do not exceed the critical values.  相似文献