The effects of clay minerals and organic matter on nanoscale pores in Lower Paleozoic shale gas reservoirs,Guizhou, China     

Yuantao Gu  Quan Wan  Wenbin Yu  Xiaoxia Li  Zhongbin Yu 《中国地球化学学报》2018,37(6):791-804

In organic-rich gas shales, clay minerals and organic matter (OM) have significant influences on the origin, preservation, and production of shale gas. Because of the substantial role of nanoscale pores in the generation, storage, and seepage of shale gas, we examined the effects of clay minerals and OM on nanoscale pore distribution characteristics in Lower Paleozoic shale gas reservoirs. Using the Niutitang and Longmaxi shales as examples, we determined the effects of clay minerals and OM on pores through sedimentation experiments. Field emission–scanning electron microscopy combined with low-pressure N₂ adsorption of the samples before and after sedimentation showed significant differences in pore location and pore size distribution between the Niutitang and Longmaxi shales. Nanoscale pores mostly existed in OM in the Longmaxi shale and in clay minerals or OM–clay composites in the Niutitang shale. The distribution differences were attributed largely to variability in thermal evolution and tectonic development and might account for the difference in gas-bearing capacity between the Niutitang and Longmaxi reservoirs. In the nanoscale range, mesopores accounted for 61–76% of total nanoscale pore volume. Considerably developed nanoscale pores in OM were distributed in a broad size range in the Longmaxi shale, which led to good pore connectivity and gas production. Numerous narrow pores (i.e., pores?<?20 nm) in OM–clay composites were found in the Niutitang shale, and might account for this shale’s poor pore connectivity and low gas production efficiency. Enhancing the connectivity of the mesopores (especially pores?<?20 nm and those developed in OM–clay composites) might be the key to improving development of the Niutitang shale. The findings provide new insight into the formation and evolutionary mechanism of nanoscale pores developed in OM and clay minerals.  相似文献   

A New Ootype of Dinosaur Egg (Faveoloolithidae: Duovallumoolithus shangdanensis oogen. et oosp. nov.) from the Late Cretaceous in the Shangdan Basin,Shaanxi Province,China     

ZHENG Tingting  BAI Yi  WANG Qiang  ZHU Xufeng  FANG Kaiyong  YAO Yuan  ZHAO Yongqiang  WANG Xiaolin 《《地质学报》英文版》2018,92(3):897-903

A new ootype collected from the Upper Cretaceous Lijiacun Formation in the Shangdan Basin, Shaanxi Province is described in this paper. Based on general external shape, size, eggshell thickness and honeycomb‐like eggshell microstructure, eggs are referable to the oofamily Faveoloolithidae. Compared with other members of Faveoloolithidae, specimens described in this paper show special characteristics: adjacent pores are usually separated by two eggshell units between which often develop interspaces; columnar eggshell units are relatively closely arranged in radial view. According to these characteristics, we erect a new oogenus and a new oospecies: Duovallumoolithus shangdanensis oogen. et oosp. nov. The new discovery expands the diversity of Faveoloolithidae.  相似文献   

Detailed structure of the lithosphere and deep dynamics beneath the Three River belt and western edge of the Yangtze craton     

LI Qiusheng  FENG Shaoying  BAI Zhiming  GAO Yuan  GAO Song  XIONG Xiaosong  WANG Xiaoran 《《地质学报》英文版》2018,92(Z1):45-46

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塔里木盆地西南坳陷齐姆根凸起侏罗系钻获油气显示          下载免费PDF全文

白忠凯  杨有星  邱海峻  张金虎  韩淼  李清瑶  孙智超 《中国地质》2018,45(1):193-194

正1研究目的(Objective)研究区位于塔里木盆地塔西南坳陷齐姆根凸起英吉沙背斜构造单元西南。该区勘探程度低,此前未进行高覆盖次数地震勘探、无钻井,石油地质条件尚不清楚。本次研究的目的是落实英吉沙—莎车地区齐姆根凸起侏罗系杨叶组烃源岩有效性;厘清英吉沙—莎车地区地层发育情况,确定苏盖特构造侏罗系与周边露头剖面对比关系;获取钻井地质资料,为该区地震地质层位标定提供依据,了解区内的地层及储盖组合发育情况,为进一步油气勘探评价提供基础资料。  相似文献   

西藏塔惹增地区下白垩统捷嘎组的厘定及其地质意义          下载免费PDF全文

白培荣  熊兴国  李月森  马德胜  曾禹人  廖铸敏  蒋开源  张厚松  吴滔  黄建国  符宏斌  龙胜清 《贵州地质》2018,35(3):197-204

笔者于西藏仲巴县塔惹增地区一带前人划分的一套早白垩世早期则弄群中发现了具有典型意义的、代表早白垩世晚期的Ampullina xainzaensis Yu,Ampullina cf. larteli Landerer,Tylostoma cf. brasilianus Maury,Pseudamaura cf. subfournaeti (Pcelincev),Gyrodes gaultiana Orbigny,Leviathania cf. gerassimovi(Pcelincev),Gymnentome cf. pizcuetana(Vilanova)等腹足类化石,以及较为丰富的中圆笠虫Mesorbitolina sp.和达克斯虫Daxia sp。表明在该区则弄群中至少有一部分以前没有被识别出的早白垩世晚期地层。通过岩石组合特征、基本层序、生物化石时代对比,将该套地层归属于捷嘎组。这一地层的确定为冈底斯带白垩系地层划分对比、地层格架建立提供了重要的依据,并丰富了该地层的古生物资料,且为中生代盆地的演化历史、古地理轮廓的确定提供了新的基础资料。  相似文献   

小兴安岭霍吉河钼矿床成矿过程——透岩浆成矿作用     

王泉  刘东舟  郭鸿斌 《地质与资源》2018,27(3):243-250

传统上将小兴安岭霍吉河钼矿床归类为斑岩型钼矿.通过对矿区地质特征的研究,即矿区无斑岩体、矿体围绕隐爆角砾岩呈环状出露、石英细脉-网脉状和浸染状矿石结构、成矿年龄明显晚于赋矿围岩形成时间等,认为该矿床是透岩浆成矿作用的结果.早中生代伊春-延寿花岗岩岩基带上相伴的大型-超大型钼矿是典型的透岩浆成矿作用的产物,是岩基后成矿作用.  相似文献   

大兴安岭十八站—韩家园地区晚中生代火山岩年龄、地球化学特征及其构造意义     

柴明春  王泉  赵国英  高溯  曹昆 《地质通报》2018,37(10):1866-1881

大兴安岭十八站—韩家园地区发育晚中生代基性-中酸性火山岩。选取粗面安山岩、粗面岩、流纹岩进行年代学和岩石地球化学研究。粗面安山岩LA-ICP-MS锆石U-Pb年龄为125.2±0.9 Ma,为早白垩世火山作用的产物。岩石地球化学特征表明,中酸性火山岩属于高钾钙碱性-钾玄岩系列。岩石稀土元素总量∑REE=121.42×10~(-6)~154.43×10~(-6),轻、重稀土元素分异明显(La/Yb)_N=19.25~31.98,在稀土元素配分图上显示右倾型,除一个流纹岩样品具显著负Eu异常外,多数样品无明显Eu负异常(δEu=0.45~0.90)。岩石具弱富集大离子亲石元素Ba、Sr,明显亏损高场强元素Nb、Ta、Ti的特征。结合区域资料,认为十八站—韩家园地区早白垩世中酸性火山岩形成于蒙古-鄂霍茨克洋闭合机制下后碰撞伸展背景。粗面安山岩、粗面岩和流纹岩系同源岩浆部分熔融与结晶分异作用的结果,岩浆来源于受俯冲流体交代的富集岩石圈地幔。  相似文献   

基于无人机载LiDAR的采煤沉陷监测技术方法——以宁东煤矿基地马连台煤矿为例   总被引：1，自引：0，他引：1  

张永庭  徐友宁  梁伟  魏采用  李樵民  杨雪茹  拜剑虹 《地质通报》2018,37(12):2270-2277

探索采煤地表沉陷的高新监测技术方法是推动采煤沉陷监测的重要工作,无人机载LiDAR采煤塌陷监测技术是无人机与LiDAR构建的一种新型低空三维空间测量技术。以宁东煤炭基地马莲台煤矿采煤沉陷区为例,采用无人机机载LiDAR监测技术获取了2017年4月及8月2期三维点云数据,通过数据三维建模和沉降信息提取,得到了地面沉陷情况的三维立体图,监测出了3处地面沉降区,并利用实测水准点和已有GPS自动监测站数据,对该技术监测地面沉降的精度进行评估。研究结果表明,无人机机载LiDAR监测技术方法可满足采煤塌陷的立体监测需求,具有机动灵活、成本低、效率高、精度高等特点,未来可在类似地区推广应用。  相似文献   

山西省地热资源及其开发利用模式探讨          下载免费PDF全文

韩颖  白雪峰  张欣 《中国地质调查》2018,5(5):13-20

山西省地热资源丰富,但分布不均,总体开发利用程度偏低,存在资源勘查研究程度低、分散开采普遍、重开采、轻回灌、创新发展研究重视不够等问题,对地热资源可持续利用不利。在山西省地热资源现状调查评价的基础上,系统总结了山西省地热资源的分布规律、主要热储类型、特征以及水热型地热资源开发利用现状,按照不同热储类型及地热资源赋存地质条件,提出地热资源开发利用模式建议,并提出在山西省打造温泉小镇的构想。  相似文献   

大兴安岭十八站—韩家园地区中酸性侵入岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其地质意义     

柴明春  赵国英  覃小锋  王泉  高溯  曹昆 《地质论评》2018,64(3):569-583

大兴安岭北部塔河县十八站—呼玛县韩家园地区发育早古生代中酸性侵入岩。文章选取二长闪长岩和二长花岗岩开展岩石年代学与地球化学研究。二长闪长岩LA-ICP-MS锆石U-Pb年龄为512.4±3.5 Ma,为早—中寒武世岩浆作用的产物。岩石地球化学分析表明,中酸性侵入岩归属于准铝质—弱过铝质(A/CNK=0.77~1.04)钙碱性—高钾钙碱性系列。岩石稀土总量∑REE=69.51×10~(-6)~275.83×10~(-6),轻重稀土分异明显(La/Yb)_N=9.11~26.64。在稀土元素配分图上,显示为LREE富集、HREE相对平缓的右倾型,Eu异常不显著(δEu=0.90~1.35)。微量元素组成具明显富集大离子亲石元素Ba、Sr,显著亏损高场强元素Nb、Ta、Ti的特征。结合区域资料和本文研究,初步分析认为早古生代侵入体形成于活动大陆边缘或岛弧环境,为前古亚洲洋闭合背景下萨拉伊尔造山作用的产物。  相似文献