Evolution of structural and physical parameters of clays during experimental compaction     

G. Vasseur  I. Djeran-Maigre  D. Grunberger  G. Rousset  D. Tessier  B. Velde 《Marine and Petroleum Geology》1995,12(8)

To provide a better understanding of sedimentary basin geological history, it is important to describe correctly the evolution of the various physical, mechanical and hydraulic properties of clayey rocks as a function of burial depth. As a contribution to this field, a programme of experimental studies on reworked clay samples compacted under various load pressures in oedometric conditions has been set up. The evolution of samples under compaction was followed with microscopic and macroscopic measurements. In a specially designed oedometric cell, samples are compacted under different total stresses from 0.1 to 50 MPa. In this cell, cylindrical cores are submitted to progressive loading from both ends under controlled pore pressure conditions. The symmetrical loading allows more even deformation about the midplane of the sample. This device allows the evolution of hydraulic pressure, radial stress, displacement and expelled pore fluid to be followed as a function of time. In a first step, kaolinite was chosen because it retains a high permeability (compared with other clays such as illite or smectite), which allows compaction tests to be performed within a few days. A complete set of measurements was performed after the tests. These measurements are: (1) micro-structures investigated by means of transmission electron microscopy (TEM), mercury porosimetry, water removal under low water vapour pressure, granulometry and specific area measured by ethylene glycol adsorption; and (2) various physical parameters measured including hydraulic conductivity and thermal conductivity. TEM gives an understanding of the arrangement of particles. It was found that each particle is composed of several crystal units, each unit formed by ≈25 individual kaolinite layers. During compaction, these particles remain undeformed, but are rotated. The angular distribution of grain orientation is a function of the applied effective stress. This reorientation is in agreement with the observed decrease in porosity and pore size. It also explains the occurrence of a strong anisotropy in the thermal conductivity and hydraulic permeability. The combination of these experimental results allows a qualitative and quantitative understanding of the behaviour of kaolinite with respect to parameters such as permeability, porosity, mechanical and thermal properties, the knowledge of which are necessary for basin modelling.  相似文献   

Mercury methylation/demethylation and volatilization pathways in estuarine sediment slurries using species-specific enriched stable isotopes     

R.C. Rodr&#x;&#x;guez Mart&#x;&#x;n-Doimeadios  E. Tessier  D. Amouroux  R. Guyoneaud  R. Duran  P. Caumette  O.F.X. Donard 《Marine Chemistry》2004,90(1-4):107

Species-specific enriched stable isotopes have been used to study mercury transformations (methylation, demethylation and volatilization) in estuarine sediments under different environmental conditions (both biotic and abiotic and oxic and anoxic). These experiments have demonstrated the potential for the isotopically enriched species in combination with highly sensitive measurement methods (ICP MS) to facilitate the study of mercury speciation and reactivity. Sediments (sterilized and nonsterilized) were spiked with both isotopically enriched inorganic (¹⁹⁹Hg) and monomethylmercury (MM²⁰¹Hg) at environmental levels to avoid perturbing the system and incubated under both aerobic and anaerobic conditions. The formation of MM¹⁹⁹Hg and the degradation of MM²⁰¹Hg were measured simultaneously during time series experiments by capillary gas chromatography-inductively coupled mass spectrometry. Specific methylation and demethylation rate constants (K_m and K_d) were calculated. Results clearly showed that methylmercury levels in sediments are controlled by competing and simultaneous methylation and demethylation reactions. Operating conditions, likely to drastically modify the reactivity of the media, were of primary importance to assess the relative significance of each mechanism. In estuarine sediments, mercury methylation was enhanced under anaerobic nonsterile conditions, whereas other environmental conditions were either less favorable for monomethylmercury production or more effective for its degradation. The production of total gaseous mercury was found to be minimal, although it could be demonstrated that it was related to the fate and transformation of methylmercury.  相似文献   

Threshold of motion and settling velocities of mollusc shell debris: Influence of faunal composition     

Alissia Rieux  Pierre Weill  Dominique Mouaze  Clement Poirier  Farid Nechenache  Laurent Perez  Bernadette Tessier 《Sedimentology》2019,66(3):895-916

Bioclastic particles derived from mollusc shell debris can represent a significant fraction of sandy to gravelly sediments in temperate and cool‐water regions with high carbonate productivity. Their reworking and subsequent transport and deposition by waves and currents is highly dependent on the shape and density of the particles. In this study, the hydrodynamic behaviour of shell debris produced by eight mollusc species is investigated for several grain sizes in terms of settling velocity (measurements in a settling tube) and threshold of motion under unidirectional current (flume experiments using an acoustic profiler). Consistent interspecific differences in settling velocity and critical bed shear stress are found, related to differences in shell density, shell structure imaged by scanning electron microscopy and grain shape. Drag coefficients are proposed for each mollusc species, based on an interpolation of settling velocity data. Depending on the shell species, the critical bed shear stress values obtained for bioclastic particles fall within or slightly below empirical envelopes established for siliciclastic particles, despite very low settling velocity values. The results suggest that settling velocity, often used to describe the entrainment of sediment particles through the equivalent diameter, is not a suitable parameter to predict the initiation of motion of shell debris. The influence of the flat shape of bioclastic particles on the initiation of motion under oscillatory flows and during bedload and saltation transport is yet to be elucidated.  相似文献   

Return migration and the reiteration of gender norms in water management politics: Insights from a Chinese village     

Jinghua Ge  Bernadette P. Resurreccion 《Geoforum》2011,42(2):133-142

Recent work on return migration in China suggests return migrants bring with them new knowledge, skills, and potentially beneficial relationships accumulated during their sojourns, enabling them to introduce new forms of leadership and community action. Social remittances of this kind could be read as carrying the potential to enhance collective action in support of sustainable local natural resource-based livelihoods. This study of the links between return migration, leadership and collective action in water management sounds a more cautionary note, demonstrating that home communities may respond to return migrants in ways that repeatedly mark and reiterate gender and kinship norms, reiterating gender, generational and clan-based social hierarchies. The paper draws on and contributes to recent feminist political ecology approaches to show how migrant returnees’ ’social remittances’ translate into leadership in collective action in a rural Chinese village in ways that reinforce existing gender hierarchies and social positions within the community, thus questioning the extent to which any influx of new ideas, relationships and practices acquired from migrant experiences necessarily destabilizes power and authority in the village in any meaningful way.  相似文献   

Internal architecture and evolution of bioclastic beach ridges in a megatidal chenier plain: Field data and wave flume experiment     

Pierre Weill  Dominique Mouazé  Bernadette Tessier 《Sedimentology》2013,60(5):1213-1230

Beach ridges in macrotidal environments experience strong multi‐annual to multi‐decennial fluctuations of tidal inundation. The duration of tide flooding directly controls the duration of sediment reworking by waves, and thus the ridge dynamics. Flume modelling was used to investigate the impact of low‐frequency tidal cycles on beach ridge evolution and internal architecture. The experiment was performed using natural bioclastic sediment, constant wave parameters and low‐frequency variations of the mean water level. The morphological response of the beach ridge to water level fluctuations and the preservation of sedimentary structures were monitored by using side‐view and plan‐view photographs. Results were compared with the internal architecture of modern bioclastic beach ridges in a macrotidal chenier plain (Mont St. Michel Bay, France) surveyed with ground‐penetrating radar. The experimentally obtained morphologies and internal structures matched those observed in the field, and the three ridge development stages identified in ground‐penetrating radar profiles (early transgressive, late transgressive and progradational) were modelled successfully. Flume experiments indicate that flat bioclastic shapes play a key role in sediment sorting in the breaker zone, and in sediment layering in the beach and washover fans. Water level controls washover geometry, beach ridge evolution and internal structure. Low water levels allow beach ridge stabilization and sediment accumulation lower on tidal flats. During subsequent water level rise, accumulated sediment becomes available for deposition of new washover units and for bayward extension of the beach ridges. In the field, low‐frequency water level fluctuations are related to the 4·4 year and 18·6 year tidal cycles. Experimental results suggest that these cycles may represent the underlying factor in the evolution of the macrotidal chenier coast at the multi‐decadal to centennial time scale.  相似文献   

Tracing industrial sulfur contributions to atmospheric sulfate deposition in the Athabasca oil sands region,Alberta, Canada     

Bernadette C. Proemse  Bernhard Mayer  Mark E. Fenn 《Applied Geochemistry》2012

Anthropogenic S emissions in the Athabasca oil sands region (AOSR) in Alberta, Canada, affect SO₄ deposition in close vicinity of industrial emitters. Between May 2008 and May 2009, SO₄-S deposition was monitored using open field bulk collectors at 15 sites and throughfall collectors at 14 sites at distances between 3 and 113 km from one of the major emission stacks in the AOSR. At forested plots >90 km from the operations, SO₄ deposition was ∼1.4 kg SO₄-S ha⁻¹ yr⁻¹ for bulk deposition and ∼3.3 kg SO₄-S ha⁻¹ yr⁻¹ for throughfall deposition. Throughfall SO₄ deposition rates in the AOSR exceeded bulk deposition rates at all sites by a factor of 2–3, indicating significant inputs of dry deposition especially under forest canopies. Both bulk and throughfall SO₄ deposition rates were elevated within 29 km distance of the industrial operations with deposition rates as high as 11.7 kg SO₄-S ha⁻¹ yr⁻¹ for bulk deposition and 39.2 kg SO₄-S ha⁻¹ yr⁻¹ for throughfall at industrial sites. Sulfur isotope ratio measurements of atmospheric SO₄ deposited in the AOSR revealed that at a few selected locations ³⁴S-depleted SO₄, likely derived from H₂S emissions from tailing ponds contributes to local atmospheric SO₄ deposition. In general, however, δ³⁴S values of SO₄ deposition at distant forested plots (>74 km) with low deposition rates were not isotopically different from δ³⁴S values at sites with high deposition rates in the AOSR and are, therefore, not suitable to determine industrial S contributions. However, O isotope ratios of atmospheric SO₄ in bulk and throughfall deposition in the AOSR showed a distinct trend of decreasing δ¹⁸O-SO₄ values with increasing SO₄ deposition rates allowing quantification of industrial contributions to atmospheric SO₄ deposition. Two-end-member mixing calculations revealed that open field bulk SO₄ deposition especially at industrial sites in close proximity (<29 km) to the operations is significantly (17–59%) affected by industrial S emissions and that throughfall generally contained 49–100% SO₄ of industrial origin. Hence, it is suggested that δ¹⁸O values of SO₄ may constitute a suitable tracer for quantifying industrial contributions to atmospheric SO₄ deposition in the AOSR.  相似文献   

Geochemical and anthropogenic enrichments of Mo in sediments from perennially oxic and seasonally anoxic lakes in Eastern Canada   总被引：1，自引：0，他引：1  

Anthony Chappaz  André Tessier 《Geochimica et cosmochimica acta》2008,72(1):170-184

We measured the vertical distributions of Mo, Fe, Mn, sulfide, sulfate, organic carbon, major ions, and pH in sediment porewater from one perennially oxic and three seasonally anoxic lacustrine basins in Eastern Canada, as well as those of Mo, acid volatile sulfide, Fe, Mn, Al, organic C, ²¹⁰Pb and ¹³⁷Cs in sediment cores from the same sites. The only input of anthropogenic Mo to these lakes comes from atmospheric deposition.The relatively monotonous distribution of Mo in the porewater of three seasonally anoxic basins suggests that Mo is not redistributed in the sedimentary column during periods of anoxia. In contrast, porewater Mo profiles obtained at three sampling dates in a perennially oxic basin display sharp Mo peaks below the sediment-water interface, indicating redistribution subsequent to deposition. Modeling of these latter porewater Mo profiles with a diagenetic reaction-transport equation coupled to comparisons among the various porewater and solid phase profiles reveal that Mo is released at 1-2 cm depth as a consequence of the reductive dissolution of Fe oxyhydroxides and scavenged both at the vicinity of the sediment-water interface, by re-adsorption onto authigenic Fe oxyhydroxides, and deeper in the sediments where dissolved sulfide concentrations are higher. The estimated rate constant for the adsorption of Mo onto Fe oxyhydroxides is 36 ± 45 cm³ mol⁻¹ s⁻¹.Diagenetic modeling indicates that authigenic Mo in sediments of the perennially oxic basin represents about one-third of the total solid phase Mo in the first cm below the sediment-water interface and only one tenth below this horizon. If we assume that no authigenic Mo is accumulated in the seasonally anoxic lake sediments we conclude that the sediment Mo concentrations, which are up to 3-16 times higher than the average lithogenic composition, depending on the lake, are mainly due to atmospheric deposition of anthropogenic Mo and not to the formation of authigenic Mo phases. Reconstructed historical records of the atmospheric Mo deposition indicate maximum values in the 1970s and 1980s and significant decreases since then. Emissions to the atmosphere associated with the smelting of non-ferrous ores and coal combustion appear to be the most important sources of anthropogenic Mo.  相似文献   

Aerosol optical properties and its radiative forcing over Yulin,China in 2001 and 2002     

车慧正  张小曳  赵剑琦 《大气科学进展》2009,26(3):564-576

The aerosol optical properties and direct radiative forcing over the Mu Us desert of northern China, acquired through a CE318 sunphotometer of the ground-based Aerosol Robotic Network (AERONET), are analyzed. The seasonal variations in the aerosol optical properties are examined. The effect of meteorological elements (pressure, temperature, water vapor pressure, relative humidity and wind speed) on the aerosol optical properties is also studied. Then, the sources and optical properties under two different cases, a dust event and a pollution event, are compared. The results show that the high aerosol optical depth (AOD) found in Yulin was mostly attributed to the occurrence of dust events in spring from the Mu Us desert and deserts of West China and Mongolia, as well as the impacts of anthropogenic pollutant particles from the middle part of China in the other seasons. The seasonal variation and the probability distribution of the radiative forcing and the radiative forcing efficiency at the surface and the top of the atmosphere are analyzed and regressed using the linear and Gaussian regression methods.  相似文献   

Concentrations and transport of trace metals in the St. Lawrence River     

Bernadette Quémerais  Ken R. Lum  Claire Lemieux 《Aquatic Sciences - Research Across Boundaries》1996,58(1):52-68

Samples of raw water were collected in the St. Lawrence River during six sampling trips from August 1990 to April 1992. Water samples were analyzed for both dissolved and particulate phases for five trace metals. Partition coefficients (Kd) and metal fluxes were calculated in order to determine metal transport. A mass balance equation was used for the determination of the major metal sources to the St. Lawrence River and an estimation of metal loadings to the estuary was made. Average dissolved metal concentrations were found to be Cd 10 ng/L, Co 74 ng/L, Cu 64 ng/L, Fe 69 µg/L and Mn 700 ng/L. Particulate concentrations were (in µg/g) 1.68 for Cd, 31 for Co, 73 for Cu, 25 mg/g for Fe and 1.69 mg/g for Mn. Co, Fe and Mn were transported essentially in the particulate phase while Cd and Cu were predominantly found in the dissolved phase at 56% and 48% of the total metal concentration respectively. Log Kd values varied from 5.1 (for Cu) to 6.8 (for Mn). In the dissolved phase the major sources were found to be the Great Lakes and the Ottawa River whereas in the particulate phase Québec tributaries appear to be the most important. Industrial inputs are quite important in both the dissolved and the particulate phases for Cd, whereas other sources are very variable, especially for the dissolved phase.  相似文献   

Distribution of mercury and methylmercury in deep-sea surficial sediments of the Mediterranean Sea     

Nives Ogrinc  Mathilde Monperrus  Jože Kotnik  Vesna Fajon  Klara Vidimova  David Amouroux  David Kocman  Emmanuel Tessier  Suzana Žižek  Milena Horvat 《Marine Chemistry》2007

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