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51.
Basin modelling studies are carried out in order to understand the basin evolution and palaeotemperature history of sedimentary basins. The results of basin modelling are sensitive to changes in the physical properties of the rocks in the sedimentary sequences. The rate of basin subsidence depends, to a large extent, on the density of the sedimentary column, which is largely dependent on the porosity and therefore on the rate of compaction. This study has tested the sensitivity of varying porosity/depth curves and related thermal conductivities for the Cenozoic succession along a cross‐section in the northern North Sea basin, offshore Norway. End‐member porosity/depth curves, assuming clay with smectite and kaolinite properties, are compared with a standard compaction curve for shale normally applied to the North Sea. Using these alternate relationships, basin geometries of the Cenozoic succession may vary up to 15% from those predicted using the standard compaction curve. Isostatic subsidence along the cross‐section varies 2.3–4.6% between the two end‐member cases. This leads to a 3–8% difference in tectonic subsidence, with maximum values in the basin centre. Owing to this, the estimated stretching factors vary up to 7.8%, which further gives rise to a maximum difference in heat flow of more than 8.5% in the basin centre. The modelled temperatures for an Upper Jurassic source rock show a deviation of more than 20 °C at present dependent on the thermal conductivity properties in the post‐rift succession. This will influence the modelled hydrocarbon generation history of the basin, which is an essential output from basin modelling analysis. Results from the northern North Sea have shown that varying compaction trends in sediments with varying thermal properties are important parameters to constrain when analysing sedimentary basins.  相似文献   
52.
Diagnostic analyses of hydrological models intend to improve the understanding of how processes and their dynamics are represented in models. Temporal patterns of parameter dominance could be precisely characterized with a temporally resolved parameter sensitivity analysis. In this way, the discharge conditions are characterized, that lead to a parameter dominance in the model. To achieve this, the analysis of temporal dynamics in parameter sensitivity is enhanced by including additional information in a three‐tiered framework on different aggregation levels. Firstly, temporal dynamics of parameter sensitivity provide daily time series of their sensitivities to detect variations in the dominance of model parameters. Secondly, the daily sensitivities are related to the flow duration curve (FDC) to emphasize high sensitivities of model parameters in relation to specific discharge magnitudes. Thirdly, parameter sensitivities are monthly averaged separately for five segments of the FDC to detect typical patterns of parameter dominances for different discharge magnitudes. The three methodical steps are applied on two contrasting catchments (upland and lowland catchment) to demonstrate how the temporal patterns of parameter dynamics represent different hydrological regimes. The discharge dynamic in the lowland catchment is controlled by groundwater parameters for all discharge magnitudes. In contrast, different processes are relevant in the upland catchment, because the dominances of parameters from fast and slow runoff components in the upland catchment are changing over the year for the different discharge magnitudes. The joined interpretation of these three diagnostic steps provides deeper insights of how model parameters represent hydrological dynamics in models for different discharge magnitudes. Thus, this diagnostic framework leads to a better characterization of model parameters and their temporal dynamics and helps to understand the process behaviour in hydrological models. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
53.
The signal measured by heave–pitch–roll directional wave buoys yields the first four coefficients of a Fourier series. Data adaptive methods must be employed to estimate a directional wave spectrum. Marine X-band radars (MRs) have the advantage over buoys that they can measure “model-free” two-dimensional (2D) wave spectra. This study presents the first comprehensive validation of MR-derived multi-directional wave characteristics. It is based on wave data from the 2010 Impact of Typhoons on the Ocean in the Pacific (ITOP) experiment in the Philippine Sea, namely MR measurements from R/V Roger Revelle, Extreme Air–Sea Interaction (EASI) buoy measurements, as well as WAVEWATCH-III (WW3) modeling results. Buoy measurements of mean direction and spreading as function of frequency, which do not require data adaptive methods, are used to validate the WW3 wave spectra. An advanced MR wave retrieval technique is introduced that addresses various shortcomings of existing methods. Spectral partitioning techniques, applied to MR and WW3 results, reveal that multimodal seas are frequently present. Both data sets are in excellent agreement, tracking the evolution of up to 4 simultaneous wave systems over extended time periods. This study demonstrates MR’s and WW3’s strength at measuring and predicting 2D wave spectra in swell-dominated seas.  相似文献   
54.
Wavelet thresholding is used to generate simplified terrain models. This non-linear filtering technique is adaptive in the sense that the large wavelet coefficients in areas of high relief are kept, whereas all coefficients smaller than a threshold value, representing smooth areas, are thrown away. The degree of detail in the simplified model is controlled by the number of wavelet coefficients retained. Two different areas are analysed using this method. The experiments show the smoothing effect of the thresholding, and how the main terrain features survive as the threshold value increases. At large threshold values the method introduces blocking artifacts in the model.  相似文献   
55.
Dendroclimatological sampling of Scots pine (Pinus sylvestris L.) has been made in the province of J?mtland, in the west-central Scandinavian mountains, since the 1970s. The tree-ring width (TRW) chronology spans several thousand years and has been used to reconstruct June?CAugust temperatures back to 1632 bc. A maximum latewood density (MXD) dataset, covering the period ad 1107?C1827 (with gap 1292?C1315) was presented in the 1980s by Fritz Schweingruber. Here we combine these historical MXD data with recently collected MXD data covering ad 1292?C2006 into a single reconstruction of April?CSeptember temperatures for the period ad 1107?C2006. Regional curve standardization (RCS) provides more low-frequency variability than ??non-RCS?? and stronger correlation with local seasonal temperatures (51% variance explained). The MXD chronology shows a stronger relationship with temperatures than the TRW data, but the two chronologies show similar multi-decadal variations back to ad 1500. According to the MXD chronology, the period since ad 1930 and around ad 1150?C1200 were the warmest during the last 900?years. Due to large uncertainties in the early part of the combined MXD chronology, it is not possible to conclude which period was the warmest. More sampling of trees growing near the tree-line is needed to further improve the MXD chronology.  相似文献   
56.
The urban surface wind field in the dry-tropical city of Ouagadougou, Burkina Faso was studied based on data collected at one urban and one suburban station during early dry season. An intra-urban thermal breeze, creating almost opposite wind directions at the two sites, was found during nights with high atmospheric stability. The high atmospheric stability suggests a decoupling of the surface wind layer from the layer above, allowing the wind system to develop due to the strong intra-urban temperature gradients in the city. Frequent temporary breakdowns of the thermal wind system were noticed, generally generating a turn in wind direction towards that of the regional wind, thus indicating a re-coupling with a stronger wind flow in the wind layer above.  相似文献   
57.
The characteristics and forcing mechanisms of high-frequency flow variations (periods of minutes to days) were investigated near Gladden Spit, a reef promontory off the coast of Belize. Direct field observations and a high-resolution (50-m grid size) numerical ocean model are used to describe the flow variations that impact the initial dispersion of eggs and larvae from this site, which serves as a spawning aggregation site for many species of reef fishes. Idealized sensitivity model experiments isolate the role of various processes, such as internal waves, wind, tides, and large-scale flow variations. The acute horizontal curvature and steep topography of the reef intensify the flow, create small-scale convergence and divergence zones, and excite high-frequency oscillations and internal waves. Although the tides in this area are relatively small (∼10-cm amplitude), the model simulations show that tides can excite significant high-frequency flow variations near the reef, which suggests that the preference of fish to aggregate and spawn in the days following the time of full moon may not be coincidental. Even small variations in remote flows (2–5 cm s−1) due to say, meso-scale eddies, are enough to excite near-reef oscillations. Model simulations and the observations further suggest that the spawning site at the tip of the reef provides initial strong dispersion for eggs, but then the combined influence of the along-isobath flow and the westward wind will transport the eggs and larvae downstream of Gladden Spit toward less turbulent region, which may contribute to enhanced larval survival.  相似文献   
58.
This study presents the results of experimental compaction while measuring ultrasonic velocities of sands with different grain size, shape, sorting and mineralogy. Uniaxial mechanical compaction tests up to a maximum of 50 MPa effective stress were performed on 29 dry sand aggregates derived from eight different sands to measure the rock properties. A good agreement was found between the Gassmann saturated bulk moduli of dry and brine saturated tests of selected sands. Sand samples with poor sorting showed low initial porosity while sands with high grain angularity had high initial porosity. The sand compaction tests showed that at a given stress well‐sorted, coarse‐grained sands were more compressible and had higher velocities (Vp and Vs) than fine‐grained sands when the mineralogy was similar. This can be attributed to grain crushing, where coarser grains lead to high compressibility and large grain‐to‐grain contact areas result in high velocities. At medium to high stresses the angular coarse to medium grained sands (both sorted sands and un‐sorted whole sands) showed high compaction and velocities (Vp and Vs). The small grain‐to‐grain contact areas promote higher deformation at grain contacts, more crushing and increased porosity loss resulting in high velocities. Compaction and velocities (Vp and Vs) increased with decreasing sorting in sands. However, at the same porosity, the velocities in whole sands were slightly lower than in the well‐sorted sands indicating the presence of loose smaller grains in‐between the framework grains. Quartz‐poor sands (containing less than 55% quartz) showed higher velocities (Vp and Vs) compared to that of quartz‐rich sands. This could be the result of sintering and enlargement of grain contacts of ductile mineral grains in the quartz‐poor sands increasing the effective bulk and shear stiffness. Tests both from wet measurements and Gassmann brine substitution showed a decreasing Vp/Vs ratio with increasing effective stress. The quartz‐rich sands separated out towards the higher side of the Vp/Vs range. The Gassmann brine substituted Vp and Vs plotted against effective stress provide a measure of the expected velocity range to be found in these and similar sands during mechanical compaction. Deviations of actual well log data from experimental data may indicate uplift, the presence of hydrocarbon, overpressure and/or cementation. Data from this study may help to model velocity‐depth trends and to improve the characterization of reservoir sands from well log data in a low temperature (<80–100o C) zone where compaction of sands is mostly mechanical.  相似文献   
59.
The compound NaFeGe2O6 was grown synthetically as polycrystalline powder and as large single crystals suitable for X-ray and neutron-diffraction experiments to clarify the low temperature evolution of secondary structural parameters and to determine the low temperature magnetic spins structure. NaFeGe2O6 is isotypic to the clinopyroxene-type compound aegirine and adopts the typical HT-C2/c clinopyroxene structure down to 2.5?K. The Na-bearing M2 polyhedra were identified to show the largest volume expansion between 2.5?K and room temperature, while the GeO4 tetrahedra behave as stiff units. Magnetic susceptibility measurements show a broad maximum around 33?K, which marks the onset of low-dimensional magnetic ordering. Below 12?K NaFeGe2O6 transforms to an incommensurately modulated magnetic spin state, with k?=?[0.323, 1.0, 0.080] and a helical order of spins within the M1-chains of FeO6 octahedra. This is determined by neutron-diffraction experiments on a single crystal. Comparison of NaFeGe2O6 with NaFeSi2O6 is given and it is shown that the magnetic ordering in the latter compound, aegirine, also is complex and is best described by two different spin states, a commensurate one with C2??/c?? symmetry and an incommensurate one, best being described by a spin density wave, oriented within the (1 0 1) plane.  相似文献   
60.
At the Kristineberg mine, northern Sweden, sulphidic mine tailings were remediated in an 8-year pilot-scale experiment using sewage sludge to evaluate its applicability as a sealing layer in a composite dry cover. Sediment, leachate water, and pore gas geochemistry were collected in the aim of determining if the sludge was an effective barrier material to mitigate acid rock drainage (ARD) formation. The sludge was an effective barrier to oxygen influx as it formed both a physical obstruction and functioned as an organic reactive barrier to prevent oxygen to the underlying tailings. Sulphide oxidation and consequential ARD formation did not occur. Sludge-borne trace elements accumulated in a reductive, alkaline environment in the underlying tailings, resulting in an effluent drainage geochemistry of Cd, Cu, Pb and Zn below 10 μg/L, high alkalinity (810 mg/L) and low sulphate (38 mg/L). In contrast, the uncovered reference tailings received a 0.35-m deep oxidation front and typical ARD, with dissolved concentrations of Cd, Zn and sulphate, 20.8 μg/L, 16,100 μg/L and 1,390 mg/L, respectively. Organic matter degradation in the sludge may be a limiting factor to the function of the sealing layer over time as 85 % loss of the organic fraction occurred over the 8-year experimental period due to aerobic and anaerobic degradation. Though the cover may function in the short to medium term (100 years), it is unlikely to meet the demands of a long-term remedial solution.  相似文献   
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