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351.
352.
Jianzhong Zhang Claudia Kuenzer Anke Tetzlaff Dieter Oertel Boris Zhukov Wolfgang Wagner 《Journal of Applied Geophysics》2007,63(3-4):135-147
In this paper we present thermal characteristics of coal fires as measured during simulated fires under an experimental setting in Germany in July 2002. It is thus a continuation of the previously published paper “Thermal surface characteristics of coal fire 1: Results of in-situ measurement”, in which we presented temperature measurements of real subsurface coal fires in China [Zhang, J., Kuenzer, C., accepted for publication. Thermal Surface Characteristics of Coal Fires 1: Results of in-situ measurements. Accepted for publication at Journal of Applied Geophysics.]. The focus is on simulated coal fires, which are less complex in nature than fires under natural conditions. In the present study we simulated all the influences usually occurring under natural conditions in a controllable manner (uniform background material of known thermal properties, known ventilation pathways, homogeneous coal substrate), creating two artificial outdoor coal fires under simplified settings. One surface coal fire and one subsurface coal fire were observed over the course of 2 days. The set up of the fires allowed for measurements not always feasible under “real” in-situ conditions: thus compared to the in-situ investigations presented in paper one we could retrieve numerous temperature measurements inside of the fires. Single temperature measurements, diurnal profiles and airborne thermal surveying present the typical temperature patterns of a small surface-and a subsurface fire under undisturbed conditions (easily accessible terrain, 24 hour measurements period, homogeneous materials). We found that the outside air temperature does not influence the fire's surface temperature (up to 900 °C), while fire centre temperatures of up to 1200 °C strongly correlate with surface temperatures of the fire. The fires could heat their surrounding up to a distance of 4.5 m. However, thermal anomalies on the background surface only persist as long as the fire is burning and disappear very fast if the heat source is removed. Furthermore, heat outside of the fires is transported mainly by convection and not by radiation. In spatial thermal line scanner data the diurnal thermal patterns of the coal fire are clearly represented. Our experiments during that data collection also visualize the thermal anomaly differences between covered (underground) and uncovered (surface) coal fires. The latter could not be observed in-situ in a real coal fire area. Sub-surface coal fires express a much weaker signal than open surface fires and contrast only by few degrees against the background. In airborne thermal imaging scanner data the fires are also well represented. Here we could show that the mid-infrared domain (3.8 μm) is more suitable to pick up very hot anomalies, compared to the common thermal (8.8 μm) domain. Our results help to understand coal fires and their thermal patterns as well as the limitations occurring during their analysis. We believe that the results presented here can practicably help for the planning of coal fire thermal mapping campaigns — including remote sensing methods and the thermal data can be included into numerical coal fire modelling as initial or boundary conditions. 相似文献
353.
354.
Mercury concentrations were determined in marine algae and three species of gastropod molluscs collected from three sites on the Mediterranean shoreline of Israel. The results are discussed in relation to local pollution variations. Mercury concentrations were highest in the vicinity of an industrialized area. It was concluded that local industrial pollution directly affected the area studied. However, little is known of the overall effects of toxic wastes, and further study is required. 相似文献
355.
Pedro?RauEmail authorView authors OrcID profile Luc?Bourrel David?Labat Frédéric?Frappart Denis?Ruelland Waldo?Lavado Boris?Dewitte Oscar?Felipe 《Theoretical and Applied Climatology》2018,134(1-2):139-153
Peruvian Pacific drainage catchments only benefit from 2% of the total national available freshwater while they concentrate almost 50% of the population of the country. This situation is likely to lead a severe water scarcity and also constitutes an obstacle to economic development. Catchment runoff fluctuations in response to climate variability and/or human activities can be reflected in extreme events, representing a serious concern (like floods, erosion, droughts) in the study area. To document this crucial issue for Peru, we present here an insightful analysis of the water quantity resource variability of this region, exploring the links between this variability and climate and/or anthropogenic pressure. We first present a detailed analysis of the hydroclimatologic variability at annual timescale and at basin scale over the 1970–2008 period. In addition to corroborating the influence of extreme El Niño events over precipitation and runoff in northern catchments, a mean warming of 0.2 °C per decade over all catchments was found. Also, higher values of temperature and potential and actual evapotranspiration were found over northern latitudes. We chose to apply the Budyko-Zhang framework that characterizes the water cycle as a function of climate only, allowing the identification of catchments with significant climatic and anthropogenic influence on water balance. The Budyko-Zhang methodology revealed that 11 out of 26 initial catchments are characterized by low water balance disparity related to minor climatic and anthropogenic influence. These 11 catchments were suitable for identifying catchments with contrasting change in their hydroclimatic behavior using the Budyko trajectories. Our analysis further reveals that six hydrological catchment responses can be characterized by high sensitivity to climate variability and land use changes. 相似文献
356.
Ulrich G. Wortmann Boris Chernyavsky Benjamin Brunner Peter K. Swart 《Geochimica et cosmochimica acta》2007,71(17):4221-4232
Microbially mediated sulfate reduction affects the isotopic composition of dissolved and solid sulfur species in marine sediments. Experiments and field data show that the composition is also modified in the presence of sulfate-reducing microorganisms. This has been attributed either to a kinetic isotope effect during the reduction of sulfate to sulfite, cell-internal exchange reactions between enzymatically-activated sulfate (APS), and/or sulfite with cytoplasmic water. The isotopic fingerprint of these processes may be further modified by the cell-external reoxidation of sulfide to elemental sulfur, and the subsequent disproportionation to sulfide and sulfate or by the oxidation of sulfite to sulfate. Here we report values from interstitial water samples of ODP Leg 182 (Site 1130) and provide the mathematical framework to describe the oxygen isotope fractionation of sulfate during microbial sulfate reduction. We show that a purely kinetic model is unable to explain our data, and that the data are well explained by a model using oxygen isotope exchange reactions. We propose that the oxygen isotope exchange occurs between APS and cytoplasmic water, and/or between sulfite and adenosine monophosphate (AMP) during APS formation. Model calculations show that cell external reoxidation of reduced sulfur species would require up to 3000 mol/m3 of an oxidant at ODP Site 1130, which is incompatible with the sediment geochemical data. In addition, we show that the volumetric fluxes required to explain the observed data are on average 14 times higher than the volumetric sulfate reduction rates (SRR) obtained from inverse modeling of the porewater data. The ratio between the gross sulfate flux into the microbes and the net sulfate flux through the microbes is depth invariant, and independent of sulfide concentrations. This suggests that both fluxes are controlled by cell density and that cell-specific sulfate reduction rates remain constant with depth. 相似文献
357.
Tov Elperin Andrew Fominykh Boris Krasovitov 《Meteorology and Atmospheric Physics》2014,125(3-4):197-211
We suggest a non-isothermal one-dimensional model of precipitation scavenging of highly soluble gaseous pollutants in inhomogeneous atmosphere. When gradients of soluble trace gases’ concentrations and temperature in the atmosphere are small, scavenging of gaseous pollutants is governed by two linear wave equations that describe propagation of a scavenging and temperature waves in one direction. If wash-down front velocity is much larger than the velocity of the temperature front, scavenging is determined by propagating scavenging front in the atmosphere with inhomogeneous temperature distribution. We solved the derived equation by the method of characteristics and determined scavenging coefficient and the rates of precipitation scavenging for wet removal of sulfur dioxide using measured initial distributions of trace gases and temperature in the atmosphere. It is shown that in the case of exponential initial distribution of soluble trace gases and linear temperature distribution in the atmosphere, scavenging coefficient in the region between the ground and the position of a scavenging front is proportional to rainfall rate, solubility parameter in the under-cloud region, adjacent to a bottom of a cloud and to the growth constant in the formula for the initial profile of a soluble trace gas in the atmosphere. The derived formula yields the same value of scavenging coefficient for sulfur dioxide scavenging by rain as field estimates presented by McMahon and Denison (Atmos Environ 13:571–585, 1979). It is demonstrated that in the case when the altitude variation of temperature in the atmosphere is determined by the environmental lapse rate, scavenging coefficient increases with height in the region between the scavenging front and the ground. In the case when altitude temperature variation in the atmosphere is determined by temperature inversion, scavenging coefficient decreases with height in a region between the scavenging front and the ground. Theoretical predictions of the value of the scavenging coefficient for sulfur dioxide washout by rain and of the dependence of the magnitude of the scavenging coefficient on rain intensity are in good agreements with the atmospheric measurements of Martin (Atmos Environ 18:1955–1961, 1984). 相似文献
358.
The homeomorphic imaging (HI) approach is a generalization of the common mid-point (CMP) stack to media of arbitrary structures with the following key properties: it collects and enhances useful waves; no knowledge about the velocity structure of the overburden is required for correlation and stacking; and neither the resolution of nor the information about the target objects is degraded by stacking the data. The so-called common reflecting element (CRE) method, which has all three properties, was proposed by Gelchinsky [Gelchinsky, B., 1988. Common reflecting element (CRE) method. Explor. Geophys. 19, 71–75]. However, the CRE method did not only provide a generalization of the CMP method with the key properties; it also has a topological feature that led to the creation of the HI approach. Today, HI can be regarded as a system of methods and schemes for the study of seismic structures that are based on asymptotic wave theory and on fundamental topological ideas. HI is based on a single supposition: it assumes that a target wave exists on the chosen central trace. The next step makes use of the ensemble of all possible wave fronts that can be formed in the vicinity of the central ray corresponding to the chosen central trace. This approach is applicable to a medium of arbitrary structure without the assumption of a seismic model or its parameters. 相似文献
359.
Chemical processes associated with meteoroid bombardment of Mercury are considered. Meteoroid impacts lead to production of metal atoms as well as metal oxides and hydroxides in the planetary exosphere. By using quenching theory, the abundances of the main Na-, K-, Ca-, Fe-, Al-, Mg-, Si-, and Ti-containing species delivered to the exosphere during meteoroid impacts were estimated. Based on a correlation between the solar photo rates and the molecular constants of atmospheric diatomic molecules, photolysis lifetimes of metal oxides and SiO are estimated. Meteoroid impacts lead to the formation of hot metal atoms (0.2-0.4 eV) produced directly during impacts and of very hot metal atoms (1-2 eV) produced by the subsequent photolysis of oxides and hydroxides in the exosphere of Mercury. The concentrations of impact-produced atoms of the main elements in the exosphere are estimated relative to the observed concentrations of Ca, assumed to be produced mostly by ion sputtering. Condensation of dust grains can significantly reduce the concentrations of impact-produced atoms in the exosphere. Na, K, and Fe atoms are delivered to the exosphere directly by impacts while Ca, Al, Mg, Si, and Ti atoms are produced by the photolysis of their oxides and hydroxides. The chemistry of volatile elements such as H, S, C, and N during meteoroid bombardment is also considered. Our conclusions about the temperature and the concentrations of impact-produced atoms in the exosphere of Mercury may be checked by the Messenger spacecraft in the near future and by BepiColombo spacecraft some years later. 相似文献
360.
Jenni E. Sherriff Keith N. Wilkinson Poppy Harding Hayley Hawkins Rhys G. O. Timms Daniel S. Adler Emily J. Beverly Simon P. E. Blockley Boris Gasparyan Christina J. Manning Darren Mark Samvel Nahapetyan Katie J. Preece 《第四纪科学杂志》2022,37(1):6-27
The significance of the southern Caucasus in understanding Pleistocene hominin expansions is well established. However, the palaeoenvironments in which Palaeolithic occupation of the region took place are presently poorly defined. The Hrazdan river valley, Armenian Highlands, contains a rich Palaeolithic record alongside Middle Pleistocene volcanic, fluvial and lacustrine strata, and thus offer exciting potential for palaeoenvironmental reconstruction. We present the first results of sedimentological, geochemical, tephrostratigraphical and biological (diatoms) study of the sequence of Bird Farm 1, located in the central part of the valley. These data show six phases of landscape development during the interval 440–200 ka. The sequence represents the first quantitative Pleistocene diatom record from the Armenian Highlands and the southern Caucasus, and indicates the persistence of a deep, stratified lacustrine system, with evidence for changing lake productivity that is tentatively linked to climate. Furthermore, major element chemical characterization of visible and crypto-tephra horizons in the sequence enables the first stages of the development of a regional tephrostratigraphy. Together, the evidence from Bird Farm 1 demonstrates the importance of lacustrine archives in the region for palaeoenvironmental reconstruction and highlights the potential for linkages between archives on both a local and regional scale. 相似文献