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41.
The mathematical structure and numerical analysis of classical small deformation elasto–plasticity is generally well established. However, development of large deformation elastic–plastic numerical formulation for dilatant, pressure sensitive material models is still a research area. In this paper we present development of the finite element formulation and implementation for large deformation, elastic–plastic analysis of geomaterials. Our developments are based on the multiplicative decomposition of the deformation gradient into elastic and plastic parts. A consistent linearization of the right deformation tensor together with the Newton method at the constitutive and global levels leads toward an efficient and robust numerical algorithm. The presented numerical formulation is capable of accurately modelling dilatant, pressure sensitive isotropic and anisotropic geomaterials subjected to large deformations. In particular, the formulation is capable of simulating the behaviour of geomaterials in which eigentriads of stress and strain do not coincide during the loading process. The algorithm is tested in conjunction with the novel hyperelasto–plastic model termed the B material model, which is a single surface (single yield surface, affine single ultimate surface and affine single potential surface) model for dilatant, pressure sensitive, hardening and softening geomaterials. It is specifically developed to model large deformation hyperelasto–plastic problems in geomechanics. We present an application of this formulation to numerical analysis of low confinement tests on cohesionless granular soil specimens recently performed in a SPACEHAB module aboard the Space Shuttle during the STS‐89 mission. We compare numerical modelling with test results and show the significance of added confinement by the thin hyperelastic latex membrane undergoing large stretching. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   
42.
The solubility of gold was measured in KCl solutions (0.001-0.1 m) at near-neutral to weakly acidic pH in the presence of the K-feldspar-muscovite-quartz, andalusite-muscovite-quartz, and pyrite-pyrrhotite-magnetite buffers at temperatures 350 to 500°C and pressures 0.5 and 1 kbar. These mineral buffers were used to simultaneously constrain pH, f(S2), and f(H2). The experiments were performed using a CORETEST flexible Ti-cell rocking hydrothermal reactor enabling solution sampling at experimental conditions. Measured log m(Au) (mol/kg H2O) ranges from −7.5 at weakly acid pH to −5.9 in near-neutral solutions, and increases slightly with temperature. Gold solubility in weakly basic and near-neutral solutions decreases with decreasing pH at all temperatures, which implies that Au(HS)2 is the dominant Au species in solution. In more acidic solutions, solubility is independent of pH. Comparison of the experimentally measured solubilities with literature values for Au hydrolysis constants demonstrates that at 350°C dominates Au aqueous speciation at the weakly acidic pH and f(S2)/f(H2) conditions imposed by the pyrite-pyrrhotite-magnetite buffer. In contrast, at temperatures >400°C becomes less important and predominates in weakly acid solutions. Solubility data collected in this study were used to calculate the following equilibrium reaction constants:
  相似文献   
43.
The Ayopaya province in the eastern Andes of Bolivia, 100 km NW of Cochabamba, hosts a Cretaceous alkaline rock series within a Palaeozoic sedimentary sequence. The alkaline rock association comprises nepheline-syenitic/foyaitic to ijolitic intrusions, carbonatite, kimberlite, melilititic, nephelinitic to basanitic dykes and diatremes, and a variety of alkaline dykes. The carbonatites display a wide petrographic and geochemical spectrum. The Cerro Sapo area hosts a small calciocarbonatite intrusion and a multitude of ferrocarbonatitic dykes and lenses in association with a nepheline-syenitic stock. The stock is crosscut by a spectacular REE-Sr-Th-rich sodalite-ankerite-baryte dyke system. The nearby Chiaracke complex represents a magnesiocarbonatite intrusion with no evidence for a relationship to igneous silicate rocks. The magnesiocarbonatite ( REE up to 1.3 wt%) shows strong HREE depletion, i.e. unusually high La/Yb ratios (520–1,500). Calciocarbonatites ( REE up to 0.5 wt%) have a flatter REE distribution pattern (La/Yb 95–160) and higher Nb and Zr contents. The sodalite-ankerite-baryte dyke system shows geochemical enrichment features, particularly in Na, Ba, Cl, Sr, REE, which are similar to the unusual natrocarbonatitic lavas of the recent volcano of Oldoinyo Lengai, Tanzania. The Cerro Sapo complex may be regarded as an intrusive equivalent of natrocarbonatitic volcanism, and provides an example for carbonatite genesis by late-stage crystal fractionation and liquid immiscibility. The magnesiocarbonatite intrusion of Chiaracke, on the other hand, appears to result from a primary carbonatitic mantle melt. Deep seated mantle magmatism/metasomatism is also expressed by the occurrence of a kimberlite dyke. Neodymium and strontium isotope data (Nd 1.4–5.4, 87Sr/86 Sr<Bulk Earth) indicate a depleted mantle source for the alkaline magmatism. The magmatism of the Ayopaya region is attributed to failed rifting of western South America during the Mesozoic and represents the only occurrence of carbonatite and kimberlite rocks in the Andes.  相似文献   
44.
In order to understand the change in oceanic variability associated with the climate shift of the mid-1970s, we analyze the contribution of momentum forcing to the leading baroclinic modes over the tropical Pacific using Simple Ocean Data Assimilation (SODA, version 2.0.2) for the period of 1958–1997. Specifically, we look at the statistical relationship between the wind projection coefficients and climate indices and attempt to provide a physical explanation for the observed changes. It is found that the wind stress projection coefficients according to the oceanic baroclinic modes are different in terms of their magnitude and phase in the tropical Pacific, reflecting a specific forcing associated with each mode before and after the 1976 climate shift. Compared to that before the 1970s, the first baroclinic mode is had a greater effect on the interannual sea surface temperature due to equatorial wave dynamics, and there was an increased delayed response of the second baroclinic mode variability to the interannual atmospheric forcing after the late 1970s. This reflects changes in ENSO feedback processes associated with the climate shift. Our analysis further indicates that, after the late 1970s, there was a decrease in the wind stress forcing projecting onto the Ekman layer, which is associated with increased mixed-layer depth. This result suggests that the changes in the ENSO properties before and after the late 1970s are largely associated with the changes in the way in which the wind stress forcing is dynamically projected onto the surface layer of the tropical Pacific Ocean over interannual timescales.  相似文献   
45.
Global changes in extreme events: regional and seasonal dimension   总被引:3,自引:0,他引:3  
This study systematically analyzes the complete IPCC AR4 (CMIP3) ensemble of GCM simulations with respect to changes in extreme event characteristics at the end of the 21st century compared to present-day conditions. It complements previous studies by investigating a more comprehensive database and considering seasonal changes beside the annual time scale. Confirming previous studies, the agreement between the GCMs is generally high for temperature-related extremes, indicating increases of warm day occurrences and heatwave lengths, and decreases of cold extremes. However, we identify issues with the choice of indices used to quantify heatwave lengths, which do overall not affect the sign of the changes, but strongly impact the magnitude and patterns of projected changes in heatwave characteristics. Projected changes in precipitation and dryness extremes are more ambiguous than those in temperature extremes, despite some robust features, such as increasing dryness over the Mediterranean and increasing heavy precipitation over the Northern high latitudes. We also find that the assessment of projected changes in dryness depends on the index choice, and that models show less agreement regarding changes in soil moisture than in the commonly used ‘consecutive dry days’ index, which is based on precipitation data only. Finally an analysis of the scaling of changes of extreme temperature quantiles with global, regional and seasonal warming shows that much of the extreme quantile changes are due to a seasonal scaling of the regional annual-mean warming. This emphasizes the importance of the seasonal time scale also for extremes. Changes in extreme quantiles of temperature on land scale with changes in global annual mean temperature by a factor of more than 2 in some regions and seasons, implying large changes in extremes in several countries, even for the commonly discussed global 2°C-warming target.  相似文献   
46.
We investigate the properties of optically passive spirals and dusty red galaxies in the A901/2 cluster complex at redshift ∼0.17 using rest-frame near-ultraviolet–optical spectral energy distributions, 24-μm infrared data and Hubble Space Telescope morphologies from the STAGES data set. The cluster sample is based on COMBO-17 redshifts with an rms precision of  σ cz ≈ 2000 km s−1  . We find that 'dusty red galaxies' and 'optically passive spirals' in A901/2 are largely the same phenomenon, and that they form stars at a substantial rate, which is only four times lower than that in blue spirals at fixed mass. This star formation is more obscured than in blue galaxies and its optical signatures are weak. They appear predominantly in the stellar mass range of  log  M */M=[10, 11]  where they constitute over half of the star-forming galaxies in the cluster; they are thus a vital ingredient for understanding the overall picture of star formation quenching in clusters. We find that the mean specific star formation rate (SFR) of star-forming galaxies in the cluster is clearly lower than in the field, in contrast to the specific SFR properties of blue galaxies alone, which appear similar in cluster and field. Such a rich red spiral population is best explained if quenching is a slow process and morphological transformation is delayed even more. At  log  M */M < 10  , such galaxies are rare, suggesting that their quenching is fast and accompanied by morphological change. We note that edge-on spirals play a minor role; despite being dust reddened they form only a small fraction of spirals independent of environment.  相似文献   
47.
In the present study, the quantitative determination of the diamondoid compound adamantane in organic solvents via infrared attenuated total reflection (IR-ATR) spectroscopy at unmodified waveguide surfaces was established. Limits of detection (LOD) and quantification (LOQ) of adamantane in dichloromethane, hexane and carbon tetrachloride were determined. Quantitative IR-ATR measurements additionally facilitated the determination of adamantane solubility limit in dichloromethane, hexane and carbon tetrachloride. The developed analytical strategy further enabled the successful detection and quantification of adamantane in crude oil matrices. Consequently, IR-ATR spectroscopy provides a promising strategy for on ship and in situ diamondoid analysis in harsh real world environments.  相似文献   
48.
We present a high-resolution dark matter reconstruction of the   z = 0.165  Abell 901/902 supercluster from a weak lensing analysis of the Hubble Space Telescope STAGES survey. We detect the four main structures of the supercluster at high significance, resolving substructure within and between the clusters. We find that the distribution of dark matter is well traced by the cluster galaxies, with the brightest cluster galaxies marking out the strongest peaks in the dark matter distribution. We also find a significant extension of the dark matter distribution of Abell 901a in the direction of an infalling X-ray group Abell 901α. We present mass, mass-to-light and mass-to-stellar mass ratio measurements of the structures and substructures that we detect. We find no evidence for variation of the mass-to-light and mass-to-stellar mass ratio between the different clusters. We compare our space-based lensing analysis with an earlier ground-based lensing analysis of the supercluster to demonstrate the importance of space-based imaging for future weak lensing dark matter 'observations'.  相似文献   
49.
Páramos, a neotropical alpine grassland-peatland biome of the northern Andes and Central America, play an essential role in regional and global cycles of water, carbon, and nutrients. They act as water towers, delivering water and ecosystem services from the high mountains down to the Pacific, Caribbean, and Amazon regions. Páramos are also widely recognized as a biodiversity and climate change hot spots, yet they are threatened by anthropogenic activities and environmental changes. Despite their importance for water security and carbon storage, and their vulnerability to human activities, only three decades ago, páramos were severely understudied. Increasing awareness of the need for hydrological evidence to guide sustainable management of páramos prompted action for generating data and for filling long-standing knowledge gaps. This has led to a remarkably successful increase in scientific knowledge, induced by a strong interaction between the scientific, policy, and (local) management communities. A combination of well-established and innovative approaches has been applied to data collection, processing, and analysis. In this review, we provide a short overview of the historical development of research and state of knowledge of the hydrometeorology, flux dynamics, anthropogenic impacts, and the influence of extreme events in páramos. We then present emerging technologies for hydrology and water resources research and management applied to páramos. We discuss how converging science and policy efforts have leveraged traditional and new observational techniques to generate an evidence base that can support the sustainable management of páramos. We conclude that this co-evolution of science and policy was able to successfully cover different spatial and temporal scales. Lastly, we outline future research directions to showcase how sustainable long-term data collection can foster the responsible conservation of páramos water towers.  相似文献   
50.
This is a crucial time in the history of astronomy with major all-sky surveying work being carried out in all spectral bands, as well as in astrometry. The results of this activity are advancing all fields of astrophysical research, from the investigation of exo-planetary systems to the study of the chemical evolution of the Universe. Full sky surveys are available from the radio domain to X-ray wavelengths but not in the ultraviolet range (UV). While large UV missions are currently under discussion within the astrophysical community and at the major Space Agencies, the efficient use of resources requires preparatory work that can fill the UV surveying gap. This article summarizes the research and on-going activities in this field.  相似文献   
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