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11.
Atoll‐like structures of the endemic Mediterranean seagrass Posidonia oceanica were encountered in the innermost area of the Stagnone di Marsala, a semi‐enclosed coastal lagoon along the western coasts of Sicily. The area is characterized by limited water exchange with the open sea and by a marked seasonal variation of water salinity and temperature, reaching beyond the theoretical tolerance limits of the species. In the present study we determined the genetic composition of the atoll‐like structures, as well as the growth performance and flowering rate of these stands. We also assessed whether and to what extent the atoll‐like structures are genetically isolated from plants growing in meadows outside the lagoon. For this purpose we utilized 13 microsatellite markers to genotype single shoots sampled inside and outside the lagoon. Lepidochronological analyses were performed on the same shoots to determine the annual rhizome growth rate, the number of leaves and the inflorescences formed as an estimate of growth‐ and reproductive performance over the years. The innermost area of the lagoon showed a lower number of alleles, a lower percentage of polymorphic loci, a lower clonal diversity, but higher heterozygosis excess with respect to the other areas analysed. Spatial autocorrelation was here significant, up to slightly below 300 m. Shoots collected in the atolls exhibited a 25% lower vertical growth rate and 16% lower leaf formation in comparison to those in open‐sea meadows. No flowering events were recorded during 24 years of investigation, whereas inflorescences were observed frequently in meadows outside the lagoon. Results from Fst and factorial correspondence analysis confirmed the expected genetic isolation of the confined atolls with respect to the meadows outside the lagoon and revealed limited gene flow within the lagoon itself. Apparently, the enclosed system of the Stagnone lagoon is genetically isolated, with a possible selection of genotypes adapted to persistent stressful conditions, consistent with reduced growth and lack of flowering events.  相似文献   
12.
The intensive mussel culture carried out in the past 40 years in the Rias of Vigo and Arousa (Galicia-NW Spain) has led to substantial changes in the ecology and geochemistry of the seabed in these areas. Organic C enrichment of the seabed has generated strongly reducing conditions that directly affect the geochemistry of Fe and S. In the present study a total of six sediment cores were collected from the seabed under mussel rafts, and two different layers were distinguished: the biodeposit generated by the mussels, and the sediment situated immediately below this. Samples of each were analyzed to determine the pH, redox potential, sulphate and chloride in the interstitial water, as well as total percentage of organic C (TOC), N and S. Sequential extraction of the samples differentiated six fractions of Fe: exchangeable, carbonate, ferrihydrite, lepidocrocite, goethite and pyrite. The contents of total Fe, Fe associated with silicates, Fe soluble in 1 M HCl and AVS-Fe were also determined. In general, both the biodeposit and the sediment were anoxic (Eh < 100 mV) and there were no significant differences between the two in the total Fe or in the Fe associated with silicates, which appears to indicate that the input of Fe to the system did not vary greatly. However, there were significant differences between the sediment and the biodeposit in terms of the forms of Fe in each layer. The concentrations of pyrite in the biodeposit (0.37 ± 0.25 μmol g−1) were high but significantly lower than in the sediment (1.10 ± 0.20 μmol g−1), and there remained large quantities of reactive-Fe that were susceptible to pyritisation. In contrast, in the sediment, the reactive-Fe was intensively pyritised, and judging from the ratio of TOC–DOP, it limited synthesis of pyrite. Furthermore, a plot of the concentration of pyrite-S against TOC revealed an excess of ∼15% of pyrite-S, which is explained by the partial decoupling of pyrite formation from organic matter accumulation, caused by the formation of pyrite from the H2S generated by the anaerobic oxidation of methane. The latter process also appears to favour, although to a lesser extent, the precipitation of Ca carbonate, with incorporation of Fe.  相似文献   
13.
Meteorological observations made on board ships prior to 1854 have until now been overlooked in climatological research largely as a result of the lack of rigorous abstraction and treatment criteria. However, the CLIWOC project has shown that millions of potentially valuable observations have been preserved throughout Europe in the many logbooks that were prepared by officers in the navies of the great powers. Moreover these data can be used and treated in a fashion similar to today's ship-based instrumental observations. The most significant logbook collections are from Spain, the UK, the Netherlands and France. This paper describes the main archives where the logbooks can be found and provides an account of their contents and of the manner in which they were set out. The potential of this source is emphasised by the fact that whilst the CLIWOC project abstracted data for 300,000 days, nearly 90% of the European logbook collections have yet to be examined. This paper concludes with a discussion as to the direction of future studies in this important field.  相似文献   
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17.
In this study we present optically stimulated luminescence (OSL) dating results obtained at one of the most important open‐air Middle Palaeolithic sites in the Sierra de Atapuerca foothills – Hotel California. We also assess the possibility of obtaining extended‐range OSL chronologies for a nearby Middle Pleistocene fluvial deposit using several novel methods, namely OSL dating of individual quartz ‘supergrains’, multi‐grain aliquot thermally transferred OSL (TT‐OSL) dating and the first application of a single‐grain TT‐OSL dating procedure. Four single‐grain OSL ages constrain the Middle Palaeolithic occupation of Hotel California to between 71±6 and 48±3 ka. The Hotel California single‐grain equivalent dose (De) distributions are highly overdispersed and contain several dose populations, which are probably attributable to post‐depositional sediment mixing, partial bleaching and intrinsic scatter. The reliability of multi‐grain aliquot OSL dating is compromised by the complex underlying De dispersion affecting these samples, as well as by biasing multi‐grain averaging effects. Extended‐range OSL and TT‐OSL chronologies for the nearby Pico River terrace are consistent with each other and with broad independent age control. These experimental approaches yield a weighted average age of 348±16 ka for terrace TA9 of the Arlanzón River sequence. Our results highlight the benefits of comparing ages obtained using several OSL methodologies to improve the robustness of luminescence chronologies. They also demonstrate the potential that single‐grain OSL techniques offer for establishing improved age constraints on the many other Middle Palaeolithic sites found at Atapuerca and elsewhere across north‐central Spain.  相似文献   
18.
Shoreline gypsiferous sediments of an inland lake in central Spain furnishes valuable insight into reconstructions of early sedimentary changes related to shore fly–microbial mat interactions in fossil gypsum precipitating saline lake systems. The association of adult and larval forms of Ephydra (Diptera) with microbial matgrounds overlying the lake margin results in the formation of gypsiferous meniscate back‐filled burrows that provide an analogue for recurring, extensively developed trace fossils that occur in Cenozoic, but not older, lacustrine gypsum rocks. In this setting, sediment burrowing by ephydridae hinders significant preservation of microbialites. The overwhelming rise of Diptera at the onset of the Cenozoic resulted in extensive feeding and dwelling activity and contributed to reshape the saline aquatic habitat where microbial mats thrived, thus leading to the formation of specific trace fossils that are illustrative of the existence of microbes in the paleoenvironment.  相似文献   
19.
Reported herein are the results of eight soil CO2 efflux surveys performed from 2006 to 2011 at Timanfaya Volcanic Field (TVF), Lanzarote Island with the aim of evaluating the long- and short-term temporal variations of the diffuse CO2 emission. Soil CO2 efflux values ranged from non-detectable up to 34.2 g m−2 d−1, with the highest values measured in September 2008. Conditional sequential Gaussian simulations (sGs) were applied to construct soil CO2 efflux distribution maps and to estimate the total CO2 output from the studied area at the TVF. Soil CO2 efflux maps showed a high spatial and temporal variability. Total CO2 emission rates ranged between 41 and 518 t d−1, February 2011 (winter) being the season when maximum diffuse CO2 emission rates were observed. To investigate the influence of external variables on the soil CO2 efflux, a geochemical station (LZT01) was installed at TVF to measure continuously the soil CO2 efflux between July 2010 and March 2012 Since external factors such as barometric pressure, rainfall, soil water content, soil and air temperatures, and wind speed influence strongly the observed soil CO2 effluxes, multiple regression analysis was applied to the time series recorded by the automatic geochemical station LZT01 to remove the contribution of these external factors. The influence of meteorological variables on soil CO2 efflux oscillations accounts for 13% of total variance, with barometric pressure, rainfall and/or soil water content having the most influence in the control of the soil CO2 efflux. These observations along with the results from the eight soil gas surveys performed at TVF indicate that the short and long-term trends in the diffuse CO2 degassing are mainly controlled by environmental factors.  相似文献   
20.
The efficiency of inorganic fertilizers as stimulating agents for the bioremediation of oil-polluted environments can be increased with the addition of selected biostimulating compounds. In this study, the efficacy of different biostimulation treatments in the remediation of diesel-polluted soil in purpose-built microcosms has been evaluated. The treatments involved combinations of inorganic fertilizer with (a) Ivey surfactant, (b) Biorem organic fertilizer and (c) ethanol. Microbial activity was evaluated by monitoring the growth of heterotrophic and degrading bacteria and their dehydrogenase activity and carbon dioxide production. Hydrocarbon degradation was monitored by gas chromatography/mass spectrometry. The results showed that all treatments enhanced microbial activity in comparison with natural attenuation and also that the combined treatments generally enhanced hydrocarbon biodegradation in comparison to both natural attenuation and the single inorganic fertilizer treatment. The inorganic fertilizer plus Ivey? surfactant was the most efficient treatment in terms of Total Petroleum Hydrocarbon and light and heavy n-alkanes, showing an index of degradation of 1.4 and 1.3, respectively. Furthermore, biodegradation of heavy and branched n-alkanes was higher in microcosms treated with inorganic fertilizer plus ethanol (Index of degradation values of 1.6 and 1.5, respectively) indicating that combined treatments can be very effective in restoration of contaminated soil.  相似文献   
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