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1.
Jennifer S. Harkness Kelley Swana William K. Eymold Jodie Miller Ricky Murray Siep Talma Colin J. Whyte Myles T. Moore Erica L. Maletic Avner Vengosh Thomas H. Darrah 《Ground water》2018,56(2):187-203
Enhanced production of unconventional hydrocarbons in the United States has driven interest in natural gas development globally, but simultaneously raised concerns regarding water quantity and quality impacts associated with hydrocarbon extraction. We conducted a pre‐development assessment of groundwater geochemistry in the critically water‐restricted Karoo Basin, South Africa. Twenty‐two springs and groundwater samples were analyzed for major dissolved ions, trace elements, water stable isotopes, strontium and boron isotopes, hydrocarbons and helium composition. The data revealed three end‐members: a deep, saline groundwater with a sodium‐chloride composition, an old, deep freshwater with a sodium‐bicarbonate‐chloride composition and a shallow, calcium‐bicarbonate freshwater. In a few cases, we identified direct mixing of the deep saline water and shallow groundwater. Stable water isotopes indicate that the shallow groundwater was controlled by evaporation in arid conditions, while the saline waters were diluted by apparently fossil meteoric water originated under wetter climatic conditions. These geochemical and isotopic data, in combination with elevated helium levels, suggest that exogenous fluids are the source of the saline groundwater and originated from remnant seawater prior to dilution by old meteoric water combined with further modification by water‐rock interactions. Samples with elevated methane concentrations (>14 ccSTP/kg) were strongly associated with the sodium‐chloride water located near dolerite intrusions, which likely provide a preferential pathway for vertical migration of deeply sourced hydrocarbon‐rich saline waters to the surface. This pre‐drill evaluation indicates that the natural migration of methane‐ and salt‐rich waters provides a source of geogenic contamination to shallow aquifers prior to shale gas development in the Karoo Basin. 相似文献
2.
Rivka Amit Ori Simhai Avner Ayalon Yehouda Enzel Ari Matmon Onn Crouvi Naomi Porat Eric McDonald 《Quaternary Science Reviews》2011,30(3-4):312-323
The time at which deserts established their current arid or hyper-arid conditions remains a fundamental question regarding the history of Earth. Cosmogenic isotope exposure ages of desert pavement and welded, calcic–gypsic–salic Reg soils that developed on relatively flat alluvial surfaces ～2 Ma ago in the Negev Desert indicate long geomorphic stability under extremely dry conditions. Over a short interval during their initial stage of development between 1–2 Ma, these cumulative soils are characterized by calcic soils reaching maximum stage III of carbonate morphology. This interval is the only period when calcic soil horizons formed on stable abandoned alluvial surfaces in the southern Negev Desert. Since ～1 Ma pedogenesis changed toward more arid soil environment and the formation of gypsic–salic soil horizons that were later followed by dust accumulation. The dichotomy of only moderately-developed calcic soil (stages II–III) during a relatively long time interval (105–106 years) indicates an arid environment that does not support continuous development but only occasional calcic soil formation. The very low δ18O and relatively high δ13C values of these early pedogenic carbonates support soil formation under arid climatic conditions. Such an environment was probably characterized by rare and relatively longer duration rainstorms which occasionally allowed deeper infiltration of rainwater and longer retention of soil moisture. This, in turn enabled the growth of sparse vegetation that enhanced deposition of pedogenic carbonate. At ～1 Ma these rare events of slightly wetter conditions ceased and less atmospheric moisture reached the southern Negev Desert leading to deposition of soluble salts and dust deposited in the soils. The combination of long-term hyperaridity, scarcity of vegetation and lack of bioturbation, salts cementation, dust accumulation and tight desert pavement cover, has protected the surfaces from erosion forming one of the most remarkably stable landscapes on Earth, a landscape that essentially has not eroded, but accumulated salt and dust for more than 106 yr. 相似文献
3.
Estimation of Rn transfer from water to indoor air based on multi-day measurements may underestimate alpha exposure that occurs at short time scales in confined spaces, such as from showering, in houses with high Rn activities in the water supply. In order to examine one such incremental increase in exposure, variations in Rn in water and indoor air in 18 houses with private wells in western North Carolina (USA) were investigated. Radon in well water ranged from 158 to 811 Bq L−1 (median 239 Bq L−1). After 20-min showers in bathrooms with closed doors, peak Rn in air increases (above background) ranged from 71 to 4420 Bq m−3 (median 1170 Bq m−3). Calculated transfer coefficients at the scale of a 40-min closed bathroom (20-min shower plus 20 min post-shower) are described by a lognormal distribution whose geometric mean exceeds the widely-used ∼10−4 whole-house transfer coefficient by about one order of magnitude. As short-lived decay products grow from shower-derived Rn, short-term alpha energy exposure occurs in bathrooms in addition to the exposure caused by Rn mixed throughout the volume of the house. Due to the increasing ratio of Rn decay products to Rn, alpha energy exposure is greatest several minutes after the shower is turned off. For a 7.2-min shower with 10 min of additional exposure before opening the door, a geometric mean 5.6% increase in exposure over the ∼10−4 whole-house transfer coefficient derived from longer measurement periods was estimated. In addition to Rn activity in water, short-term shower exposure to Rn progeny depends on exposure time, ventilation, attachment and deposition, among other variable factors that characterize individual houses and residents. 相似文献
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Anton VaksMiryam Bar-Matthews Avner AyalonBettina Schilman Mabs GilmourChris J Hawkesworth Amos FrumkinAaron Kaufman Alan Matthews 《Quaternary Research》2003,59(2):182-193
High-resolution 230Th/234U ages and δ18O and δ13C compositions of speleothems in Ma’ale Efrayim Cave located to the east of the central mountain ridge of Israel enable us to examine the nature of the rain shadow aridity during glacial and interglacial intervals. Speleothem growth occurred during marine glacial isotopic periods, with no growth during the two last marine isotope interglacial intervals and during the peak of the Last Glacial Maximum. This contrasts with speleothem growth in caves located on the western flank of the central mountain ridge, in the Eastern Mediterranean semiarid climatic zone, which continued throughout the last 240,000 yr. Thus, during glacial periods water reached both sides of the central mountain ridge. A comparison of the present-day rain and cave water isotopic compositions and amounts at the Ma’ale Efrayim Cave site with those on the western flank shows that evaporation and higher temperatures on the eastern flank are major influences on isotopic composition and the lack of rainfall. The δ18O and δ13C profiles of the speleothems deposited between 67,000 and 25,000 yr B.P. match the general trends of the isotopic profiles of Soreq Cave speleothems, suggesting a similar source (eastern Mediterranean Sea) and similar climatic conditions. Thus, during glacial periods the desert boundary effectively migrated further south or east from its present-day location on the eastern flank, whereas interglacial periods appear to have been similar to the present, with the desert boundary at the same position. The decrease in overall temperature and a consequent reduction in the evaporation to precipitation ratios on the eastern flank are viewed as the major factors controlling the decay of the rain shadow effect during glacial periods. 相似文献
6.
David S. Vinson Avner Vengosh Daniella Hirschfeld Gary S. Dwyer 《Chemical Geology》2009,260(3-4):159-171
Naturally-occurring radionuclides (uranium, radium, and radon), major dissolved constituents, and trace elements were investigated in fresh groundwater in 117 wells in fractured crystalline rocks from the Piedmont region (North Carolina, USA). Chemical variations show a general transition between two water types: (1) slightly acidic (pH 5.0–6.0), oxic, low-total dissolved solids (TDS) waters, and (2) near neutral, oxic to anoxic, higher-TDS waters. The uranium, radium, and radon levels in groundwater associated with granite (Rolesville Granite) are systematically higher than other rock types (gneiss, metasedimentary, and metavolcanic rocks). Water chemistry plays a secondary role on radium and radon distributions as the 222Rn/226Ra activity ratio is correlated with redox-sensitive solutes such as dissolved oxygen and Mn concentrations, as well as overall dissolved solids content including major divalent cations and Ba. Since 224Ra/228Ra activity ratios in groundwater are close to 1, we suggest that mobilization of Ra and Rn is controlled by alpha recoil processes from parent nuclides on fracture surfaces, ruling out Ra sources from mineral dissolution or significant long-distance Ra transport. Alpha recoil is balanced by Ra adsorption that is influenced by redox conditions and/or ion concentrations, resulting in an approximately one order of magnitude decrease (~ 20,000 to ~ 2000) in the apparent Ra distribution coefficient between oxygen-saturated and anoxic conditions and also across the range of dissolved ion concentrations (up to ~ 7 mM). Thus, the U and Th content of rocks is the primary control on observed Ra and Rn activities in groundwater in fractured crystalline rocks, and in addition, linked dissolved solids concentrations and redox conditions impart a secondary control. 相似文献
7.
A. Gopher A. Ayalon M. Bar-Matthews R. Barkai A. Frumkin P. Karkanas R. Shahack-Gross 《Quaternary Geochronology》2010,5(6):644-656
We present here the results of a U–Th dating project at Qesem Cave, a Middle Pleistocene, late Lower Paleolithic site in Israel. It provides 54 new MC-ICP-MS U–Th ages for speleothems from the cave. The results indicate that human occupation started sometime between ～420 and 320 ka and ended between 220 and 194 ka. A survey of dates from culturally similar sites in the Levant indicates that the general range of ca. 400–ca. 200 ka is an appropriate estimate for the life span of the Acheulo-Yabrudian Cultural Complex (AYCC). 相似文献
8.
Structural and Hydrogeological Controls on Hydrocarbon and Brine Migration into Drinking Water Aquifers in Southern New York 
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下载免费PDF全文 Rebecca L. Kreuzer Thomas H. Darrah Benjamin S. Grove Myles T. Moore Nathaniel R. Warner William K. Eymold Colin J. Whyte Gautam Mitra Robert B. Jackson Avner Vengosh Robert J. Poreda 《Ground water》2018,56(2):225-244
Environmental concerns regarding the potential for drinking water contamination in shallow aquifers have accompanied unconventional energy development in the northern Appalachian Basin. These activities have also raised several critical questions about the hydrogeological parameters that control the naturally occurring presence and migration of hydrocarbon gases in shallow aquifers within petroliferous basins. To interrogate these factors, we analyzed the noble gas, dissolved ion, and hydrocarbon gas (molecular and isotopic composition) geochemistry of 98 groundwater samples from south‐central New York. All samples were collected ?1km from unconventional drilling activities and sample locations were intentionally targeted based on their proximity to various types of documented fault systems. In agreement with studies from other petroliferous basins, our results show significant correlations between elevated levels of radiogenic [4He], thermogenic [CH4], and dissolved ions (e.g., Cl, Br, Sr, Ba). In combination, our data suggest that faults have facilitated the transport of exogenous hydrocarbon‐rich brines from Devonian source rocks into overlying Upper Devonian aquifer lithologies over geologic time. These data conflict with previous reports, which conclude that hydrodynamic focusing regulates the occurrence of methane and salt in shallow aquifers and leads to elevated levels of these species in restricted flow zones within valley bottoms. Instead, our data suggest that faults in Paleozoic rocks play a fundamental role in gas and brine transport from depth, regulate the distribution of their occurrence in shallow aquifers, and influence the geochemistry of shallow groundwater in this petroliferous basin. 相似文献
9.
Climate change, water resources, and the politics of adaptation in the Middle East and North Africa 总被引：2，自引：0，他引：2
Through an examination of global climate change models combined with hydrological data on deteriorating water quality in the Middle East and North Africa (MENA), we elucidate the ways in which the MENA countries are vulnerable to climate-induced impacts on water resources. Adaptive governance strategies, however, remain a low priority for political leaderships in the MENA region. To date, most MENA governments have concentrated the bulk of their resources on large-scale supply side projects such as desalination, dam construction, inter-basin water transfers, tapping fossil groundwater aquifers, and importing virtual water. Because managing water demand, improving the efficiency of water use, and promoting conservation will be key ingredients in responding to climate-induced impacts on the water sector, we analyze the political, economic, and institutional drivers that have shaped governance responses. While the scholarly literature emphasizes the importance of social capital to adaptive governance, we find that many political leaders and water experts in the MENA rarely engage societal actors in considering water risks. We conclude that the key capacities for adaptive governance to water scarcity in MENA are underdeveloped. 相似文献
10.
M.R. Box M.D. Krom R.A. Cliff M. Bar-Matthews A. Almogi-Labin A. Ayalon M. Paterne 《Quaternary Science Reviews》2011,30(3-4):431-442
Changes in 87Sr/86Sr and major element geochemistry, from two sediment cores (9509 and 9501) in the Eastern Mediterranean (EM), were used to resolve changes in sediment provenance and, hence, determine climate changes in the Nile catchment and Eastern Sahara desert over the past 25 ka. The sediment was described by a three end-member system comprising Blue Nile (BN; 87Sr/86Sr = 0.7506; Sr = 210 ppm), White Nile (WN; 87Sr/86Sr = 0.7094; Sr = 72.5 ppm) and Saharan dust (SD; 87Sr/86Sr = 0.7183; Sr = 99 ppm). The sedimentary record of these cores represents the suspended load carried down the Nile river and discharged into the S.E. Levantine basin and thus records palaeoclimatically controlled changes in erosion and transport in the catchment. During arid periods (0–5 ka BP) and prior to 11 ka BP, fluxes of BN sediment at 9509 (～6 g/cm2/yr & 10–12 g/cm2/yr, respectively) were greater than during the peak of the African Humid Period (AHP) from 5 to 11 ka BP (<2 g/cm2/yr); this latter period witnessed the deposition of the youngest organic-rich sediment, termed sapropel (S-1), in the EM basin. By contrast the flux of WN increased during the AHP from ～5 g/cm2/yr at ～13 ka BP to >15 g/cm2/yr. In the Ethiopian Highlands (BN catchment) increases in the amount and duration of the monsoon during the AHP caused more vegetation to grow resulting in less soil erosion. In the WN catchment increased rainfall caused more catchment erosion and higher sediment flux through the Sudd marshes. The sedimentation rate in core 9509 increased during the AHP because of the greater importance of the WN sediment flux relative to the BN sediment flux. Saharan dust flux also decreased during the AHP reaching a minimum at ～6 ka BP (core 9509) due to ‘greening’ of the Sahara desert. At the onset of S-1, the changes in Nile flow as determined by 87Sr/86Sr and climatic changes in the EM basin determined by δ18O of planktonic foraminifera were simultaneous, confirming that such isotopic tracers cannot be used directly to determine the cause of the circulation changes in the EM at this time. The increase in the proportion of BN sediment at 9509 with a somewhat higher grain size during the H-1 period (15–17 ka BP) was caused by erosion and redistribution of sediment from the Nile delta and/or the Israeli coast as sea-level rose. 相似文献