Stability and chemical equilibrium of amphibole in calc-alkaline magmas: an overview, new thermobarometric formulations and application to subduction-related volcanoes   总被引：33，自引：9，他引：24  

Filippo Ridolfi  Alberto Renzulli  Matteo Puerini 《Contributions to Mineralogy and Petrology》2010,160(1):45-66

This work focuses on a rigorous analysis of the physical–chemical, compositional and textural relationships of amphibole stability and the development of new thermobarometric formulations for amphibole-bearing calc-alkaline products of subduction-related systems. Literature experimental results (550–1,120°C, <1,200 MPa, −1 ≤ ΔNNO ≤ +5), H₂O–CO₂ solubility models, a multitude of amphibole-bearing calc-alkaline products (whole-rocks and glasses, representing 38 volcanoes worldwide), crustal and high-P (1–3 GPa) mantle amphibole compositions have been used. Calcic amphiboles of basalt-rhyolite volcanic products display tschermakitic pargasite (37%), magnesiohastingsite (32%) and magnesiohornblende (31%) compositions with aluminium number (i.e. Al# = ^[6]Al/Al_T) ≤ 0.21. A few volcanic amphiboles (~1%) show high Al# (>0.21) and are inferred to represent xenocrysts of crustal or mantle materials. Most experimental results on calc-alkaline suites have been found to be unsuitable for using in thermobarometric calibrations due to the high Al# (>0.21) of amphiboles and high Al₂O₃/SiO₂ ratios of the coexisting melts. The pre-eruptive crystallization of consistent amphiboles is confined to relatively narrow physical–chemical ranges, next to their dehydration curves. The widespread occurrence of amphiboles with dehydration (breakdown) rims made of anhydrous phases and/or glass, related to sub-volcanic processes such as magma mixing and/or slow ascent during extrusion, confirms that crystal destabilization occurs with relatively low T–P shifts. At the stability curves, the variance of the system decreases so that amphibole composition and physical–chemical conditions are strictly linked to each other. This allowed us to retrieve some empirical thermobarometric formulations which work independently with different compositional components (i.e. Si^*, Al_T, Mg^*, ^[6]Al^*) of a single phase (amphibole), and are therefore easily applicable to all types of calc-alkaline volcanic products (including hybrid andesites). The Si^*-sensitive thermometer and the fO₂–Mg^* equation account for accuracies of ±22°C (σ_est) and 0.4 log units (maximum error), respectively. The uncertainties of the Al_T-sensitive barometer increase with pressure and decrease with temperature. Near the P–T stability curve, the error is <11% whereas for crystal-rich (porphyritic index i.e. PI > 35%) and lower-T magmas, the uncertainty increases up to 24%, consistent with depth uncertainties of 0.4 km, at 90 MPa (~3.4 km), and 7.9 km, at 800 MPa (~30 km), respectively. For magnesiohornblendes, the ^[6]Al^*-sensitive hygrometer has an accuracy of 0.4 wt% (σ_est) whereas for magnesiohastingsite and tschermakitic pargasite species, H₂O_melt uncertainties can be as high as 15% relative. The thermobarometric results obtained with the application of these equations to calc-alkaline amphibole-bearing products were finally, and successfully, crosschecked on several subduction-related volcanoes, through complementary methodologies such as pre-eruptive seismicity (volcano-tectonic earthquake locations and frequency), seismic tomography, Fe–Ti oxides, amphibole–plagioclase, plagioclase–liquid equilibria thermobarometry and melt inclusion studies. A user-friendly spreadsheet (i.e. AMP-TB.xls) to calculate the physical–chemical conditions of amphibole crystallization is also provided.  相似文献   

Shaking and splashing—A case study of far-field effects of the Mjølnir asteroid impact on depositional environments in the Barents Sea     

Rikke Bruhn  Jenő Nagy  Morten Smelror  Henning Dypvik  Sylfest Glimsdal  Richard Pegrum  Carlo Cavalli 《Basin Research》2023,35(2):620-641

The Mjølnir impact crater in the Norwegian Barents Sea features among the 20 largest impact craters listed in the Earth Impact Database. The impact is dated to 142 ± 2.6 Ma, corresponding closely to the Jurassic/Cretaceous boundary in the Boreal stratigraphy. Multidisciplinary studies carried out over the last three decades have suggested that the up to 40 km wide crater was created by a 1–3 km diameter impactor colliding with a shallow epicontinental sea, causing regional havoc and a regional ecological crisis that followed in its wake. Only minor evidence for the consequences of the impact for the surrounding depositional basins has been documented so far. This study describes a large submarine slump penetrated by hydrocarbon exploration well 7121/9-1, located in the southern Hammerfest Basin and approximately 350 km away from the impact site. The slump is dated by a black shale drape, which contains characteristic impact-related biotic assemblages and potential ejecta material. This precise dating enables us to associate the slump with large-scale fault movements and footwall collapse along the basin-bounding Troms-Finnmark Fault Complex, which we conclude were caused by shock waves from the Mjølnir impact and the passage of associated tsunami trains. The draping black shale is interpreted to represent significant reworking of material from the contemporary seabed by tsunamis and currents set up by the impact.  相似文献   

A new insight into land use classification based on aggregated mobile phone data   总被引：6，自引：0，他引：6  

Tao Pei  Carlo Ratti  Shih-Lung Shaw  Ting Li  Chenghu Zhou 《International journal of geographical information science》2014,28(9):1988-2007

Land-use classification is essential for urban planning. Urban land-use types can be differentiated either by their physical characteristics (such as reflectivity and texture) or social functions. Remote sensing techniques have been recognized as a vital method for urban land-use classification because of their ability to capture the physical characteristics of land use. Although significant progress has been achieved in remote sensing methods designed for urban land-use classification, most techniques focus on physical characteristics, whereas knowledge of social functions is not adequately used. Owing to the wide usage of mobile phones, the activities of residents, which can be retrieved from the mobile phone data, can be determined in order to indicate the social function of land use. This could bring about the opportunity to derive land-use information from mobile phone data. To verify the application of this new data source to urban land-use classification, we first construct a vector of aggregated mobile phone data to characterize land-use types. This vector is composed of two aspects: the normalized hourly call volume and the total call volume. A semi-supervised fuzzy c-means clustering approach is then applied to infer the land-use types. The method is validated using mobile phone data collected in Singapore. Land use is determined with a detection rate of 58.03%. An analysis of the land-use classification results shows that the detection rate decreases as the heterogeneity of land use increases, and increases as the density of cell phone towers increases.  相似文献   

Assessment of RegCM4 simulated inter-annual variability and daily-scale statistics of temperature and precipitation over Mexico     

Ramón Fuentes-Franco  Erika Coppola  Filippo Giorgi  Federico Graef  Edgar G. Pavia 《Climate Dynamics》2014,42(3-4):629-647

The skill of a regional climate model (RegCM4) in capturing the mean patterns, interannual variability and extreme statistics of daily-scale temperature and precipitation events over Mexico is assessed through a comparison of observations and a 27-year long simulation driven by reanalyses of observations covering the Central America CORDEX domain. The analysis also includes the simulation of tropical cyclones. It is found that RegCM4 reproduces adequately the mean spatial patterns of seasonal precipitation and temperature, along with the associated interannual variability characteristics. The main model bias is an overestimation of precipitation in mountainous regions. The 5 and 95 percentiles of daily temperature, as well as the maximum dry spell length are realistically simulated. The simulated distribution of precipitation events as well as the 95 percentile of precipitation shows a wet bias in topographically complex regions. Based on a simple detection method, the model produces realistic tropical cyclone distributions even at its relatively coarse resolution (dx = 50 km), although the number of cyclone days is underestimated over the Pacific and somewhat overestimated over the Atlantic and Caribbean basins. Overall, it is assessed that the performance of RegCM4 over Mexico is of sufficient quality to study not only mean precipitation and temperature patterns, but also higher order climate statistics.  相似文献   

Changes in extremes and hydroclimatic regimes in the CREMA ensemble projections   总被引：2，自引：0，他引：2  

Filippo Giorgi  Erika Coppola  Francesca Raffaele  Gulilat Tefera Diro  Ramon Fuentes-Franco  Graziano Giuliani  Ashu Mamgain  Marta Pereira Llopart  Laura Mariotti  Csaba Torma 《Climatic change》2014,125(1):39-51

We analyze changes of four extreme hydroclimatic indices in the RCP8.5 projections of the Phase I CREMA experiment, which includes 21st century projections over 5 CORDEX domains (Africa, Central America, South America, South Asia, Mediterranean) with the ICTP regional model RegCM4 driven by three CMIP5 global models. The indices are: Heat Wave Day Index (HWD), Maximum Consecutive Dry Day index (CDD), fraction of precipitation above the 95th intensity percentile (R95) and Hydroclimatic Intensity index (HY-INT). Comparison with coarse (GPCP) and high (TRMM) resolution daily precipitation data for the present day conditions shows that the precipitation intensity distributions from the GCMs are close to the GPCP data, while the RegCM4 ones are closer to TRMM, illustrating the added value of the increased resolution of the regional model. All global and regional model simulations project predominant increases in HWD, CDD, R95 and HY-INT, implying a regime shift towards more intense, less frequent rain events and increasing risk of heat wave, drought and flood with global warming. However, the magnitudes of the changes are generally larger in the global than the regional models, likely because of the relatively low “climate sensitivity” of the RegCM4, especially when using the CLM land surface scheme. In addition, pronounced regional differences in the change signals are found. The data from these simulations are available for use in impact assessment studies.  相似文献   

Sensitivity of the regional climate model RegCM4.2 to planetary boundary layer parameterisation     

Ivan Güttler  Čedo Branković  Travis A. O’Brien  Erika Coppola  Branko Grisogono  Filippo Giorgi 《Climate Dynamics》2014,43(7-8):1753-1772

This study investigates the performance of two planetary boundary layer (PBL) parameterisations in the regional climate model RegCM4.2 with specific focus on the recently implemented prognostic turbulent kinetic energy parameterisation scheme: the University of Washington (UW) scheme. When compared with the default Holtslag scheme, the UW scheme, in the 10-year experiments over the European domain, shows a substantial cooling. It reduces winter warm bias over the north-eastern Europe by 2 °C and reduces summer warm bias over central Europe by 3 °C. A part of the detected cooling is ascribed to a general reduction in lower tropospheric eddy heat diffusivity with the UW scheme. While differences in temperature tendency due to PBL schemes are mostly localized to the lower troposphere, the schemes show a much higher diversity in how vertical turbulent mixing of the water vapour mixing ratio is governed. Differences in the water vapour mixing ratio tendency due to the PBL scheme are present almost throughout the troposphere. However, they alone cannot explain the overall water vapour mixing ratio profiles, suggesting strong interaction between the PBL and other model parameterisations. An additional 18-member ensemble with the UW scheme is made, where two formulations of the master turbulent length scale in unstable conditions are tested and unconstrained parameters associated with (a) the evaporative enhancement of the cloud-top entrainment and (b) the formulation of the master turbulent length scale in stable conditions are systematically perturbed. These experiments suggest that the master turbulent length scale in the UW scheme could be further refined in the current implementation in the RegCM model. It was also found that the UW scheme is less sensitive to the variations of the other two selected unconstrained parameters, supporting the choice of these parameters in the default formulation of the UW scheme.  相似文献   

Distribution and Abundance of Arsenic in the Soils and Sediments of O‘ahu,Hawai‘i     

Eric Heinen De Carlo  Michael S. Tomlinson  Laura E. deGelleke  Sara Thomas 《Aquatic Geochemistry》2014,20(2-3):87-113

Lack of high-spatial-resolution soil and sediment arsenic data for Hawai‘i has generated substantial disagreement between researchers and regulators regarding the magnitude of natural levels of arsenic in Hawai‘i and rendered difficult the defining of areas of anthropogenically elevated arsenic. Our earlier research into the occurrence of arsenic in terrestrial and marine environments revealed widely disparate concentrations of arsenic with no apparent spatial pattern. To better understand the distribution and abundance of arsenic in soils and sediments of O‘ahu, we collected an additional 64 samples at locations chosen to represent different environments with varying degrees of human impact. We found surface arsenic values that ranged from 0.28 to 740 ppm with a median concentration of 8.1 ppm, which is above the global median of 5 ppm and US soil median of 5.2 ppm. Higher concentrations of arsenic (up to 913 ppm) were encountered at depth in soil cores. The median arsenic in streambed sediments from one of our earlier studies of 6.1 ppm was comparable to the conterminous US median of 6.3 ppm; however, we encountered arsenic concentrations as high as 43.9 ppm (median = 8.60 ppm, n = 75) in marine sediments in recent work off the leeward coast of O‘ahu. Overall, arsenic in the soils and sediments of O‘ahu is elevated relative to world and national values, but there still is no readily discernible pattern in the distribution of arsenic to explain these elevated values.  相似文献   

Quantitative hazard and risk assessment for slow-moving landslides from Persistent Scatterer Interferometry   总被引：6，自引：4，他引：2  

Ping Lu  Filippo Catani  Veronica Tofani  Nicola Casagli 《Landslides》2014,11(4):685-696

Preparation of reliable landslide hazard and risk maps is crucial for hazard mitigation and risk management. In recent years, various approaches have been developed for quantitative assessment of landslide hazard and risk. However, possibly due to the lack of new data, very few of these hazard and risk maps were updated after their first generation. In this study, aiming at an ongoing assessment, a novel approach for updating landslide hazard and risk maps based on Persistent Scatterer Interferometry (PSI) is introduced. The study was performed in the Arno River basin (central Italy) where most mass movements are slow-moving landslides which are properly within the detection precision of PSI point targets. In the Arno River basin, the preliminary hazard and risk assessment was performed by Catani et al. (Landslides 2:329–342, 2005) using datasets prior to 2002. In this study, the previous hazard and risk maps were updated using PSI point targets processed from 4 years (2003–2006) of RADARSAT images. Landslide hazard and risk maps for five temporal predictions of 2, 5, 10, 20 and 30 years were updated with the exposure of losses estimated in Euro (€). In particular, the result shows that in 30 years a potential loss of approximate €3.22 billion is expected due to these slow-moving landslides detected by PSI point targets.  相似文献   

Lessons learned from two case histories of seismic microzonation in Italy     

Filippo Santucci de Magistris  Anna d’Onofrio  Augusto Penna  Rodolfo Puglia  Francesco Silvestri 《Natural Hazards》2014,74(3):2005-2035

The prediction of the variability of the seismic ground motion in a given built-up area is considered an effective tool to plan appropriate urban development, to undertake actions on seismic risk mitigation and to understand the damage pattern caused by a strong-motion event. The procedures for studying the seismic response and the seismic microzonation of an urban area are well established; nevertheless, some controversial points still exists and are discussed here. In this paper, the selection of a reference input motion, the construction of a subsoil model and the seismic response analysis procedures are discussed in detail, based on the authors’ experience in two Italian case histories: the seismic microzonation of the city of Benevento, which was a predictive study, and the simulation of seismic response and damage distribution in the village of San Giuliano di Puglia, which was a retrospective analysis.  相似文献   

A peak acceleration threshold for soil liquefaction: lessons learned from the 2012 Emilia earthquake (Italy)     

Filippo Santucci de Magistris  Giovanni Lanzano  Giovanni Forte  Giovanni Fabbrocino 《Natural Hazards》2014,74(2):1069-1094

National and international seismic codes and recommendations provide criteria for liquefaction exclusion based on a peak ground acceleration (PGA) threshold value. In this paper, after a brief review of the procedures and the values suggested in those documents, a database of liquefaction case histories was created, exploiting the background data used in the most relevant verification charts, currently employed in research and professional practice. This dataset was used to identify, on the basis of simple statistical analyses, a PGA threshold on the free ground surface below which liquefaction is unlikely to occur, regardless of the geological site conditions. The calculated value, which is on the order of 0.07–0.1 g, based on the model employed to fit the data, was analyzed in light of information collected during the 2012 Emilia seismic sequence in Italy, which produced many liquefaction events triggered by low acceleration values. The case history of the Emilia earthquake advises setting a PGA threshold for code and recommendations at the lower probability level of occurrence, in the order of 1 %.  相似文献