Summary ?Mong Hsu rubies of the “trapiche” type are sporadically seen in the gem market. However, they have never been described in
the field. The study of the nature of solid inclusions, the variation of trace-element contents, as well as the cathodoluminescence
behaviour of six “trapiche” rubies permit the conclusion that these rubies crystallised in the same geological environment
(marble-type deposit) as the normal rubies from Mong Hsu: (1) Cr and V are the main chromophorous elements in both ruby types;
they act, together with Ti, as activators or quenchers for cathodoluminescence; (2) calcite, dolomite, rutile, mica, diaspore,
apatite, chlorite, and feldspar are solid inclusions found in both ruby types; (3) the presence of bastn?site in trapiche
ruby and fluorite in non-trapiche ruby indicates the circulation of F-bearing fluids during ruby deposition; (4) the distribution
of trace-element contents in the crystal is similar for both ruby types. In the Cr2O3 vs. Fe2O3 and Cr2O3 vs. Fe2O3/TiO2 diagrams, the population fields of Mong Hsu “trapiche” and non-“trapiche” rubies overlap. They are distinct from those of
rubies and sapphires hosted in basalts from South-east Asia.
Received October 30, 2001; revised version accepted March 25, 2002 相似文献
Emerald deposits of Colombia are confined to lower Cretaceous shales of the Eastern Cordillera. The tectonic pattern of the deposits is related to deep reverse and large regional fault systems. Hydrofracturing is the main factor controlling emerald mineralization. It permitted to the hydrothermal solutions to permeate through fractures but also along stratification planes forming in this case stratabound mineralizations. Emerald occurs in calcite veins, veinlets, pockets and brecciated zones associated mainly with pyrite, quartz, parisite, codazzite and fluorite. Emerald mineralization belongs to an epigenetic hydrothermal process. The alternance of arenite-shale formations in the Cretaceous probably played an important role in the accumulation of solutions and in the propagation of the hydrothermal channels. The origin of emerald involves chemical elements mobilized by the fluids in the Cr-V-Fe-Al-Si-bearing black shales. The source of beryllium remains a problem and is discussed in the paper. 相似文献
Robust decision-making is being increasingly used to support environmental resources decisions and policy analysis under changing climate and society. In this context, a robust decision is a decision that is as much as possible insensitive to a large degree of uncertainty and ensures certain performance across multiple plausible futures. Yet, the concept of robustness is neither unique nor static. Multiple robustness metrics, such as maximin, optimism-pessimism, max regret, have been proposed in the literature, reflecting diverse optimistic/pessimistic attitudes by the decision maker. Further, these attitudes can evolve in time as a response to sequences of favorable (or adverse) events, inducing possible dynamic changes in the robustness metrics. In this paper, we explore the impact of alternative definitions of robustness and their evolution in time for a case of water resources system management under changing climate. We study the decisions of the Lake Como operator, who is called to regulate the lake by balancing irrigation supply and flood control, under an ensemble of climate change scenarios. Results show a considerable variability in the system performance across multiple robustness metrics. In fact, the mis-definition of the actual decision maker’s attitude biases the simulation of its future decisions and produces a general underestimation of the system performance. The analysis of the dynamic evolution of the decision maker’s preferences further confirms the potentially strong impact of changing robustness definition on the decision-making outcomes. Climate change impact assessment studies should therefore include the definition of robustness among the uncertain parameters of the problem in order to analyze future human decisions under uncertainty. 相似文献
Olivine in kimberlites can provide unique insights into magma petrogenesis, because it is the most abundant xenocrystic phase and a stable magmatic product over most of the liquid line of descent. In this study we examined the petrography and chemistry of olivine in kimberlites from different tectonic settings, including the Slave craton, Canada (Ekati: Grizzly, Koala), the Brasilia mobile belt (Limpeza-18, Tres Ranchos-04), and the Kaapvaal craton, South Africa (Kaalvallei: Samada, New Robinson). Olivine cores display a wide range of compositions (e.g., Mg# = 78–95). The similarity in olivine composition, resorption of core zones and inclusions of mantle-derived phases, indicates that most olivine cores originated from the disaggregation of mantle peridotites, including kimberlite-metasomatised lithologies (i.e. sheared lherzolites and megacrysts). Olivine rims typically show a restricted range of Mg#, with decreasing Ni and increasing Mn and Ca contents, a characteristic of kimberlitic olivine worldwide. The rims host inclusions of groundmass minerals, which implies crystallisation just before and/or during emplacement. There is a direct correlation between olivine rim composition and groundmass mineralogy, whereby high Mg/Fe rims are associated with carbonate-rich kimberlites, and lower Mg/Fe rims are correlated with increased phlogopite and Fe-bearing oxide mineral abundances. There are no differences in olivine composition between explosive (Grizzly) and hypabyssal (Koala) kimberlites. Olivine in kimberlites also displays transitional zones and less common internal zones, between cores and rims. The diffuse transitional zones exhibit intermediate compositions between cores and rims, attributed to partial re-equilibration of xenocrystic cores with the ascending kimberlite melt. In contrast, internal zones form discrete layers with resorbed margins and restricted Mg# values, but variable Ni, Mn and Ca concentrations, which indicates a discrete crystallization event from precursor kimberlite melts at mantle depths. Overall, olivine exhibits broadly analogous zoning in kimberlites worldwide. Variable compositions for individual zones relate to different parental melt compositions rather than variations in tectonic setting or emplacement mechanism.
Carbonates in fresh hypabyssal kimberlites worldwide have been studied to understand their origin [i.e. primary magmatic (high T) versus deuteric (‘low T’) versus hydrothermal/alteration (‘low T’)] and identify optimal strategies for petrogenetic studies of kimberlitic carbonates. The approach presented here integrates detailed textural characterisation, cathodoluminescence (CL) imaging, in situ major- and trace-element analysis, as well as in situ Sr-isotope analysis. The results reveal a wide textural diversity. Calcite occurs as fine-grained groundmass, larger laths, segregations, veins or as a late crystallising phase, replacing olivine or early carbonates. Different generations of carbonates commonly coexist in the same kimberlite, each one defined by a characteristic texture, CL response and composition (e.g., variable Sr and Ba concentrations). In situ Sr isotope analysis revealed a magmatic signature for most of the carbonates, based on comparable 87Sr/86Sr values between these carbonates and the coexisting perovskite, a robust magmatic phase. However, this study also shows that in situ Sr isotope analysis not always allow distinction between primary (i.e., magmatic) and texturally secondary carbonates within the same sample. Carbonates with a clear secondary origin (e.g., late-stage veins) occasionally show the same moderately depleted 87Sr/86Sr ratios of primary carbonates and coexisting perovskite (e.g., calcite laths-shaped crystals with 87Sr/86Sr values identical within uncertainty to those of vein calcite in the De Beers kimberlite). This complexity emphasises the necessity of integrating detailed petrography, geochemical and in situ Sr isotopic analyses for an accurate interpretation of carbonate petrogenesis in kimberlites. Therefore, the complex petrogenesis of carbonates demonstrated here not only highlights the compositional variability of kimberlites, but also raises concerns about the use of bulk-carbonate C-O isotope studies to characterise the parental melt compositions. Conversely, our integrated textural and in situ study successfully identifies the most appropriate (i.e. primary) carbonates for providing constraints on the isotopic parameters of parental kimberlite magmas.
Effects of global warming on animal distribution and performance become visible in many marine ecosystems. The present study was designed to develop a concept for a cause and effect understanding with respect to temperature changes and to explain ecological findings based on physiological processes. The concept is based on a wide comparison of invertebrate and fish species with a special focus on recent data obtained in two model species of fish. These fish species are both characterized by northern and southern distribution limits in the North Atlantic: eelpout (Zoarces viviparus), as a typical non-migrating inhabitant of the coastal zone and the cod (Gadus morhua), as a typical inhabitant of the continental shelf with a high importance for fisheries.Mathematical modelling demonstrates a clear significant correlation between climate induced temperature fluctuations and the recruitment of cod stocks. Growth performance in cod is optimal at temperatures close to 10°C, regardless of the population investigated in a latitudinal cline. However, temperature specific growth rates decrease at higher latitudes. Also, fecundity is less in White Sea than in North and Baltic Sea cod or eelpout populations. These findings suggest that a cold-induced shift in energy budget occurs which is unfavorable for growth performance and fecundity. Thermal tolerance limits shift depending on latitude and are characterized by oxygen limitation at both low or high temperatures. Oxygen supply to tissues is optimized at low temperature by a shift in hemoglobin isoforms and oxygen binding properties to lower affinities and higher unloading potential. Protective stimulation of heat shock protein synthesis was not observed.According to a recent model of thermal tolerance the downward shift of tolerance limits during cold adaptation is associated with rising mitochondrial densities and, thus, aerobic capacity and performance in the cold, especially in eurythermal species. At the same time the costs of mitochondrial maintenance reflected by mitochondrial proton leakage should rise leaving a lower energy fraction for growth and reproduction. The preliminary conclusion can be drawn that warming will cause a northern shift of distribution limits for both species with a rise in growth performance and fecundity larger than expected from the Q10 effect in the north and lower growth or even extinction of the species in the south. Such a shift may heavily affect fishing activities in the North Sea. 相似文献
Radiometric ages and chemical character of the Tertiary and Quaternary volcanics of the Aegean Sea indicate a gap between the Recent calc-alkaline volcanism and the Tertiary one. This latter reached its climax in the Oligocene—Late Miocene. The two calc-alkaline magmatisms are related to distinct subduction processes. 相似文献
Habitat Suitability (HS) models have been extensively used by conservation planners to estimate the spatial distribution of threatened species and of species of commercial interest. In this work we compare three HS models for the estimation of commercial yield potential and the identification of suitable sites for Tapes philippinarum rearing in the Sacca di Goro lagoon (Italy) on the basis of six environmental factors. The habitat suitability index (HSI) is based on expert opinion while the habitat suitability conditional (HSC) is calibrated on observational data. The habitat suitability mixed (HSM) model is a two-part model combining expert knowledge and regression analysis: the first component of the model uses logistic regression to identify the areas in which clams are likely to be present; the second part applies the same parameter-specific suitability functions of the HSI model only in the areas previously identified as productive by the logistic component. The HS models were validated on an independent data set and estimates of potential yield of the Goro lagoon were compared. The effectiveness of the three approaches is then discussed in terms of predicted yield and identification of suitable sites for farming. 相似文献
We analyze changes of four extreme hydroclimatic indices in the RCP8.5 projections of the Phase I CREMA experiment, which includes 21st century projections over 5 CORDEX domains (Africa, Central America, South America, South Asia, Mediterranean) with the ICTP regional model RegCM4 driven by three CMIP5 global models. The indices are: Heat Wave Day Index (HWD), Maximum Consecutive Dry Day index (CDD), fraction of precipitation above the 95th intensity percentile (R95) and Hydroclimatic Intensity index (HY-INT). Comparison with coarse (GPCP) and high (TRMM) resolution daily precipitation data for the present day conditions shows that the precipitation intensity distributions from the GCMs are close to the GPCP data, while the RegCM4 ones are closer to TRMM, illustrating the added value of the increased resolution of the regional model. All global and regional model simulations project predominant increases in HWD, CDD, R95 and HY-INT, implying a regime shift towards more intense, less frequent rain events and increasing risk of heat wave, drought and flood with global warming. However, the magnitudes of the changes are generally larger in the global than the regional models, likely because of the relatively low “climate sensitivity” of the RegCM4, especially when using the CLM land surface scheme. In addition, pronounced regional differences in the change signals are found. The data from these simulations are available for use in impact assessment studies. 相似文献
We present a validation analysis of a regional climate model coupled to a distributed one dimensional (1D) lake model for the Caspian Sea Basin. Two model grid spacings are tested, 50 and 20 km, the simulation period is 1989–2008 and the lateral boundary conditions are from the ERA-Interim reanalysis of observations. The model is validated against atmospheric as well as lake variables. The model performance in reproducing precipitation and temperature mean seasonal climatology, seasonal cycles and interannual variability is generally good, with the model results being mostly within the observational uncertainty range. The model appears to overestimate cloudiness and underestimate surface radiation, although a large observational uncertainty is found in these variables. The 1D distributed lake model (run at each grid point of the lake area) reproduces the observed lake-average sea surface temperature (SST), although differences compared to observations are found in the spatial structure of the SST, most likely as a result of the absence of 3 dimensional lake water circulations. The evolution of lake ice cover and near surface wind over the lake area is also reproduced by the model reasonably well. Improvements resulting from the increase of resolution from 50 to 20 km are most significant in the lake model. Overall the performance of the coupled regional climate—1D lake model system appears to be of sufficient quality for application to climate change scenario simulations over the Caspian Sea Basin. 相似文献
