Metal speciation and toxicity of Tamar Estuary water to larvae of the Pacific oyster, Crassostrea gigas     

Money C  Braungardt CB  Jha AN  Worsfold PJ  Achterberg EP 《Marine environmental research》2011,72(1-2):3-12

As part of the PREDICT Tamar Workshop, the toxicity of estuarine waters in the Tamar Estuary (southwest England) was assessed by integration of metal speciation determination with bioassays. High temporal resolution metal speciation analysis was undertaken in situ by deployment of a Voltammetric In situ Profiling (VIP) system. The VIP detects Cd (cadmium), Pb (lead) and Cu (copper) species smaller than 4?nm in size and this fraction is termed 'dynamic' and considered biologically available. Cadmium was mainly present in the dynamic form and constituted between 56% and 100% of the total dissolved concentration, which was determined subsequently in the laboratory in filtered discrete samples. In contrast, the dynamic Pb and Cu fractions were less important, with a much larger proportion of these metals associated with organic ligands and/or colloids (45-90% Pb and 46-85% Cu), which probably reduced the toxicological impact of these elements in this system. Static toxicity tests, based on the response of Crassostrea gigas larva exposed to discrete water samples showed a high level of toxicity (up to 100% abnormal development) at two stations in the Tamar, particularly during periods of the tidal cycle when the influence of more pristine coastal water was at its lowest. Competitive ligand-exchange Cu titrations showed that natural organic ligands reduced the free cupric ion concentration to levels that were unlikely to have been the sole cause of the observed toxicity. Nonetheless, it is probable that the combined effect of the metals determined in this work contributed significantly to the bioassay response.  相似文献   

Rapid extensive erosion of the North Alpine foreland basin at 5–4 Ma     

Charlotte E. Cederbom  Peter van der Beek  Fritz Schlunegger  Hugh D. Sinclair  Onno Oncken 《Basin Research》2011,23(5):528-550

An extensive low‐temperature thermochronology study of the Swiss part of the North Alpine Foreland Basin has been conducted with the aim of deciphering the late Neogene basin development. Apatite fission‐track (AFT) ages from wells located in the distal and weakly deformed Plateau Molasse reveal rapid, km‐scale erosion with an onset in early Pliocene times. The distribution of erosion implies that there was a strong gradient in late Miocene deposition rates along the strike of the basin, with an increase towards the northeast. Additionally, renewed tectonic activity and km‐scale out‐of‐sequence thrusting during Plio‐Pleistocene times is indicated by AFT data from wells within the thrusted, proximal Subalpine Molasse. Several different mechanisms driving late Neogene basin erosion and accelerated erosional discharge from the European Alps have been considered in the literature. Based on our AFT results, we reevaluate previously published hypotheses, and suggest that a change in climate and/or drainage reorganisation coincided and possibly interacted with preexisting tectonic and geodynamic forces in the Alpine region.  相似文献   

http://www.sciencedirect.com/science/article/pii/S1674987113000315   总被引：2，自引：0，他引：2  

Clement Ganino  Nicholas T.Arndt  Catherine Chauvel  Alexandre Jean  Charlotte Athurion 《地学前缘(英文版)》2013,4(5):535-546

The Panzhihua gabbroic intrusion,part of the plumbing system of the Emeishan large igneous province, intruded late-Proterozoic dolomites and marls about～263 Ma ago.The dolomites in the contact aureole were converted to brucite marbles and a diverse suite of forsterite,diopside and garnet skarns.The variation in mineralogy is explained in part by differences in the composition of the protolith,particularly the proportion of silica minerals and clay,and in part by transfer of elements from intruding magmas.The trace element compositions of most marbles and skarns are very similar to those of unmetamorphosed dolomites and marls,but some contain high Si,Ti,and Fe contents that are interpreted to have come from a magmatic source.Three brucite marbles sampled～10 m from the contact of the intrusion and named "enriched brucite marble" have trace element compositions very different from their dolomitic protolith:their rare earth elements are strongly enriched whereas levels of Nb-Ta,Zr-Hf and Ti are very low.These characteristics resemble those of carbonate liquid in equilibrium with silicate liquid or more probably with silicate minerals in the case of Panzhihua,a similarity we take to indicate that the sample underwent partial melting.Samples taken up to 300 m from the contact contain brucite indicating that high temperatures persisted well into the country rocks.However,other samples collected only tens of metres from the contact are only slightly recrystallized indicating that conditions in the aureole were highly variable.We suggest that temperatures within the aureole were controlled by conduction of heat from the main intrusion and by supply of additional heat from abundant small dykes within the aureole.Circulation of fluids derived from deeper levels in the aureole flushed the carbon dioxide from the dolomite,lowering temperature needed to partially melt carbonate to the temperatures attained near the intrusion.Irregular but extensive heating destabilized the carbonates of the aureole and decarbonation reactions associated with carbonate breakdown and melting emitted a large volume of CO₂,with potential impact on global climate.  相似文献   

Erratum: Breit–Pauli energy levels, transition probabilities and lifetimes for 3d⁵ levels in Fe iv of astrophysical interest     

Charlotte Froese Fischer  Robert H. Rubin 《Monthly notices of the Royal Astronomical Society》2004,355(4):1400-1400

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Impacts of rising air temperatures and emissions mitigation on electricity demand and supply in the United States: a multi-model comparison   总被引：2，自引：2，他引：0  

James McFarland  Yuyu Zhou  Leon Clarke  Patrick Sullivan  Jesse Colman  Wendy S. Jaglom  Michelle Colley  Pralit Patel  Jiyon Eom  Son H. Kim  G. Page Kyle  Peter Schultz  Boddu Venkatesh  Juanita Haydel  Charlotte Mack  Jared Creason 《Climatic change》2015,132(1):111-125

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Potentially mobile pools of phosphorus and silicon in sediment from the Bay of Brest: Interactions and implications for phosphorus dynamics     

Petra Tallberg  Paul Tréguer  Charlotte Beucher  Rudolph Corvaisier 《Estuarine, Coastal and Shelf Science》2008

Competitive interactions between silicate and phosphate at ligand exchange sites in the sediment surface layer may increase the release of phosphorus (P) from the sediment into the water column. In this study, the role of silicon (Si) in the release of P from the sediment surface layer was studied in a marine estuarine environment, the Bay of Brest, with the aid of a sequential sediment fractionation procedure developed for P, and the addition of inorganic or diatom-bound Si to surface sediment samples in vitro. The potentially mobile pools of P in the surface sediment (loosely bound P + Fe/Al-bound-P) amounted to 5.0 μmol g⁻¹ dry sed., 42% of the total extractable and 33% of the total amount of P in the sediment, while the similarly extracted pools of Si were bigger (ca. 20 μmol g⁻¹ dry sed., 50% of the total extractable Si). Additions of inorganic Si increased the concentration of dissolved P in the sediment interstitial water in a bottle experiment, and the addition of both inorganic Si and cultivated diatoms to intact sediment cores increased the outward flux of dissolved P. Model calculations based on the regression equation from the bottle experiment and Si and P water column data showed that the sedimentation of spring diatoms could cause Si pulses to the sediment which would produce a P flux to the water column of ca. 44 μmol m⁻² d⁻¹. Field data from the bay show that in spring, decreases in P and Si and an increase in chl a due to diatom production are often followed by a small separate P peak which may be caused by Si-induced P fluxes from the sediment surface.  相似文献   

A volcanological and geochemical investigation of Boa Vista,Cape Verde Islands; 40Ar/39Ar geochronology and field constraints     

Charlotte T. Dyhr  Paul M. Holm 《Journal of Volcanology and Geothermal Research》2010,189(1-2):19-32

Boa Vista, the easternmost island in the Cape Verde archipelago, consists of volcanic products, minor intrusions and a thin partial sedimentary cover. The first 15 age results from ⁴⁰Ar/³⁹Ar incremental heating analysis of groundmass separates from volcanic and plutonic rocks from Boa Vista are presented. The combination of age results and field observations demonstrates that the volcanic activity that formed the island occurred in three main stages: (1) > 16 Ma, (2) 15–12.5 Ma and (3) 9.5–4.5 Ma. The first stage, restricted to the north eastern part of the island, is dominated by ankaramitic lavas. The second stage, consisting of evolved lavas of phonolitic–trachytic compositions and nepheline syenites, makes up large central parts of the island. The large volume of evolved rocks and the extended eruption period of several Ma make stage 2 in Boa Vista unique to Cape Verde. Mainly basanites and nephelinites were erupted during the third stage, initially dominated by eruption of subaerial mafic lavas around 9 Ma. Pillow lavas are erupted around 7 Ma whereupon dominantly subaerial mafic lavas were erupted. Stage 3 saw volcanism in many centres distributed mainly along the present coastline and with activity partly overlapping in time. The volcanic evolution of Boa Vista constrains the initiation of volcanic activity in the Cape Verde archipelago to the eastern islands. Major and trace element geochemistry of 160 volcanic and plutonic rocks representing the entire exposed chronological sequence on Boa Vista is presented, revealing an extremely well developed Daly Gap. Only a little was modified from the mafic magmas that rose in small batches from the mantle. Compositional variation distinguishes each volcanic complex and was to a large extent present in the mantle melts. The highly evolved stage 2 phonolites and trachytes are related through the fractional crystallization of three compositionally distinct magmas. Two of these may have been derived by crystal fractionation of primitive Boa Vista melts, whereas the third was not.  相似文献   

Catchment instability and Asian summer monsoon variability during the early Holocene in southwestern China     

Charlotte G. Cook  Richard T. Jones  Chris S. M. Turney 《Boreas: An International Journal of Quaternary Research》2013,42(1):224-235

A high‐resolution palaeorecord (06SD) from Lake Shudu, Yunnan Province, southwestern China indicates a broad trend towards catchment stability, enhanced organic productivity and regional forest‐cover expansion during the early to mid Holocene. These changes are congruent with a shift to warm, wet climatic conditions, probably driven by orbitally forced Asian summer monsoon strengthening. Intriguingly, however, during the very early Holocene (c. 10.7 to 10.1 cal. ka BP), there is a prominent reversal in this trend, suggesting a weakening Asian summer monsoon. The precise cause and extent of this event remain unclear but demonstrate the urgent need for more comprehensive dating of records from across the region to test for synchroneity and examine climatic forcing mechanisms.  相似文献   

Contaminant fluxes from point and diffuse sources from abandoned mines in the River Tamar catchment, UK     

Krongkaew Mighanetara  Charlotte B. Braungardt  John S. Rieuwerts  Fethi Azizi   《Journal of Geochemical Exploration》2009,100(2-3):116-124

Acid mine waters have the potential to seriously impair the environmental quality of aquatic systems long after mining activities have ceased. This detailed study of dissolved and particulate metal fluxes from adits, drains and streams in the River Tamar catchment, southwest England, showed that seven specific sources, of the 25 adits and streams surveyed, accounted for more than 75% each of the 13 t a^− 1 Fe, 4.3 t a^− 1 Mn, 4.2 t a^− 1 Cu, 3.6 t a^− 1 Zn and 1.4 t a^− 1 As that we estimated to be discharged annually from the abandoned metalliferous mining area centred around Calstock and Gunnislake. Upstream of this study area, widespread multi-metallic mineralisation contributed to the flux of Fe, Mn, As, Co, Cu and Zn within the River Tamar. Simple mass balance calculations indicated that a large proportion (≥ 50% for most dissolved and particulate metals) of the metal flux in the River Tamar was unaccounted for by our survey, and therefore is likely to have an important diffuse component, which is subject to ongoing investigations. Potential impacts of mine contamination on the estuarine environment are discussed. The study provided information necessary to prioritise monitoring and remediation efforts in the context of sustainable catchment management.  相似文献   

Impact of earthquakes on agriculture during the Roman-Byzantine period from pollen records of the Dead Sea laminated sediment     

Suzanne A.G. Leroy  Shmuel Marco  Charlotte S. Miller 《Quaternary Research》2010,73(2):191-5248

The Dead Sea region holds the archives of a complex relationship between an ever-changing nature and ancient civilisations. Regional pollen diagrams show a Roman-Byzantine period standing out in the recent millennia by its wetter climate that allowed intensive arboriculture. During that period, the Dead Sea formed laminites that display mostly a seasonal character. A multidisciplinary study focused on two earthquakes, 31 BC and AD 363, recorded as seismites in the Ze’elim gully A unit III which has been well dated by radiocarbon in a previous study. The sampling of the sediment was done at an annual resolution starting from a few years before and finishing a decade after each earthquake. A clear drop in agricultural indicators (especially Olea and cereals) is shown. These pollen indicators mostly reflect human activities in the Judean Hills and coastal oases. Agriculture was disturbed in large part of the rift valley where earthquake damage affected irrigation and access to the fields. It took 4 to 5 yr to resume agriculture to previous conditions. Earthquakes must be seen as contributors to factors damaging societies. If combined with other factors such as climatic aridification, disease epidemics and political upheaval, they may lead to civilisation collapse.  相似文献