A high-resolution TEM-AEM, pH titration, and modeling study of Zn coprecipitation with ferrihydrite     

Stacin Martin  Chen Zhu  Joseph Rule  Robert Ford  Yee Soong 《Geochimica et cosmochimica acta》2005,69(6):1543-1553

Experiments of Zn²⁺ and Fe³⁺ coprecipitation as a function of pH were conducted in the laboratory at ambient temperature and pressure. X-ray diffraction patterns of the coprecipitates show two broad peaks at 0.149 and 0.258 nm, which is consistent with published patterns for pure 2-line ferrihydrite. Zn²⁺ uptake occurred at pH ≥5 while Fe³⁺ precipitation occurred between pH 3 and 4, although both Zn²⁺ and Fe³⁺ were present in the same solution during the entire range of pH titration. High-resolution transmission electron microscopy shows that the coprecipitates are 2 to 6 nm sized single crystalline particles but aggregated to 50 to 400 nm sized clusters. Analytical electron microscopy indicated that the 5% atomic Zn with respect to Fe was homogeneously distributed. No segregated phases were found in the clusters or at single crystal edges, which is consistent with published extended X-ray absorption fine structure (EXAFS) results at similar Zn/(Zn + Fe) ratios. Hence, occlusion and surface precipitation may be excluded as possible coprecipitation mechanisms. The bulk solution Zn²⁺ sorption edge was fitted to both solid solution and generalized diffuse layer surface complexation models. However, a solid solution model is inconsistent with published EXAFS results that show tetrahedral polydentate Zn²⁺ complexes sharing apices with Fe³⁺octahedra.  相似文献   

In situ feldspar dissolution rates in an aquifer   总被引：1，自引：0，他引：1  

Chen Zhu 《Geochimica et cosmochimica acta》2005,69(6):1435-1453

In situ silicate dissolution rates within the saturated Navajo sandstone, at Black Mesa, Arizona were determined from elemental fluxes in the aquifer. The mass transfer between groundwater and mineral matrix along flow paths was calculated from inverse mass balance modeling. The reaction time is bound by ¹⁴C-based travel time. BET surface areas were measured with N₂ gas adsorption. Dissolution rates for K-feldspar and plagioclase are 10⁻¹⁹ and 10⁻¹⁶ mol (feldspar) m⁻² s⁻¹, respectively, which are ∼10⁵ times slower than laboratory experiment-derived rates under similar pH and temperature but at far from equilibrium conditions. The rates obtained in this study are consistent with the slower field rates found in numerous watershed and soil profile studies. However, these rates are from saturated aquifers, overcoming some concerns on estimated rates from unsaturated systems. The Navajo sandstone is a quartz-sandstone with a relatively simple and well-studied hydrogeology, groundwater geochemistry, and lithology, a large number of groundwater analyses and ¹⁴C groundwater ages, groundwater residence times up to ∼37 ky, groundwater pH from ∼8 to 10, and temperature from ∼15 to 35°C.  相似文献   

Erratum to B. Chen and Y. Arakawa (2005) “Elemental and Nd-Sr isotopic geochemistry of granitoids from the West Junggar foldbelt (NW China), with implications for Phanerozoic continental growth”, Geochimica et Cosmochimica Acta 69, 1307-1320     

Bin Chen 《Geochimica et cosmochimica acta》2005,69(22):5387-5388

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午后多重极光弧观测研究          下载免费PDF全文

温艳波  杨惠根  韩德胜  T.Araki  艾勇  刘瑞源  刘勇华  胡泽骏  陈卓天  邓忠新  刘嵘  王晶 《极地研究》2005,17(4):255-263

本文利用2001-2003年南极中山站175天全天空摄像机观测,对午后多重极光弧的出现率及其与Kp指数的关系进行了统计分析,结果表明午后多重极光弧出现率呈一单峰分布,最大发生率出现在1445UT(1645MLT),其位置在1500MLT极光热点(1300-1700MLT)近夜侧的部分。与地磁活动指数Kp的相关统计分析表明,Kp值为2-3之间时多重极光弧有较大的出现率,这说明中等地磁活动情形下午后多重极光弧有较高的出现率。事件分析表明多重极光弧的强度变化与地磁Pc5脉动具有较高的相关性,并且有类似的频谱特征,这说明午后多重极光弧可能与同时出现的Pc5地磁脉动有关。  相似文献   

Ionospheric effects in uncalibrated phase delay estimation and ambiguity-fixed PPP based on raw observable model   总被引：7，自引：5，他引：2  

Shengfeng Gu  Chuang Shi  Yidong Lou  Jingnan Liu 《Journal of Geodesy》2015,89(5):447-457

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Semi-analytical and Numerical Studies on the Flattened Brazilian Splitting Test Used for Measuring the Indirect Tensile Strength of Rocks     

Y. G. Huang  L. G. Wang  Y. L. Lu  J. R. Chen  J. H. Zhang 《Rock Mechanics and Rock Engineering》2015,48(5):1849-1866

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Fracture mechanics analysis of multiple cracks in anisotropic media     

Chia‐Huei Tu  C.‐S. Chen  T.‐T. Yu 《国际地质力学数值与分析法杂志》2011,35(11):1226-1242

This paper presents a single‐domain boundary element method (BEM) for linear elastic fracture mechanics analysis in the two‐dimensional anisotropic material. In this formulation, the displacement integral equation is collocated on the un‐cracked boundary only, and the traction integral equation is collocated on one side of the crack surface only. A special crack‐tip element was introduced to capture exactly the crack‐tip behavior. A computer program with the FORTRAN language has been developed to effectively calculate the stress intensity factors of an anisotropic material. This BEM program has been verified having a good accuracy with the previous researches. Furthermore, by analyzing the different anisotropic degree cracks in a finite plate, we found that the stress intensity factors of crack tips had apparent influence by the geometry forms of cracks and media with different anisotropic degrees. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Chemical weathering and CO2 consumption in the glaciated Karuxung River catchment,Tibetan Plateau     

Fan Zhang  Xiong Xiao  Lijie Wang  Chen Zeng  Zhengliang Yu  Guanxing Wang  Xiaonan Shi 《水文研究》2021,35(8):e14330

Climate factors play critical roles in controlling chemical weathering, while chemically weathered surface material can regulate climate change. To estimate global chemical weathering fluxes and CO₂ balance, it is important to identify the characteristics and driving factors of chemical weathering and CO₂ consumption on the Tibetan Plateau, especially in glaciated catchments. The analysis of the hydro-geochemical data indicated that silicate weathering in this area was inhibited by low temperatures, while carbonate weathering was promoted by the abundant clastic rocks with fresh surfaces produced by glacial action. Carbonate weathering dominated the riverine solute generation (with a contribution of 58%, 51%, and 43% at the QiangYong Glacier (QYG), the WengGuo Hydrological Station (WGHS), and the lake estuary (LE), respectively). The oxidation of pyrite contributed to 35%, 42%, and 30% of the riverine solutes, while silicate weathering contributed to 5%, 6%, and 26% of the riverine solutes at the QYG, WGHS, and LE, respectively. The alluvial deposit of easily weathering fine silicate minerals, the higher air temperature, plant density, and soil thickness at the downstream LE in comparison to upstream and midstream may lead to longer contact time between pore water and mineral materials, thus enhancing the silicate weathering. Because of the involvement of sulfuric acid produced by the oxidation of pyrite, carbonate weathering in the upstream and midstream did not consume atmospheric CO₂, resulting in the high rate of carbonate weathering (73.9 and 75.6 t km⁻² yr⁻¹, respectively, in maximum) and potential net release of CO₂ (with an upper constraint of 35.6 and 35.2 t km⁻² yr⁻¹, respectively) at the QYG and WGHS. The above results indicate the potential of the glaciated area of the Tibetan Plateau with pyrite deposits being a substantial natural carbon source, which deserves further investigation.  相似文献   

Petrological evidence for shock‐induced high‐P metamorphism in a gabbro          下载免费PDF全文

J.‐J. Yang  H.‐R. Zhang  A.‐P. Chen  M.‐X. Huang 《Journal of Metamorphic Geology》2017,35(2):121-140

Microlites (minute spherulitic, dendritic, skeletal, acicular and poikilitic crystals) diagnostic of crystallization in quenched melt or glass in fault rocks have been used to infer fossil earthquakes. High‐P microlites and crystallites are described here in a variably eclogitized gabbro, the wallrock to the coesite‐bearing eclogite breccia at Yangkou in the Chinese Su‐Lu high‐P metamorphic belt. The studied hand specimens are free of discernible shear deformation, although microfractures are not uncommon under the microscope. In the least eclogitized gabbro, the metagabbro, stellate growths of high‐P minerals on the relict igneous minerals are common. Dendritic garnet crystals (<1?5 μm) grew around rutile and/or phengite replacing ilmenite and biotite, respectively. Skeletal garnet also rims broken flakes of igneous biotite and mechanically twinned augite. Radial intergrowths of omphacite and quartz developed around relict igneous orthopyroxene and are rimmed by skeletal or poikilitic garnet where a Ti‐bearing mineral relict is present. Acicular epidote, kyanite and phengite crystallites are randomly distributed in a matrix of Na‐rich plagioclase, forming the pseudomorphs after igneous plagioclase. In the more eclogitized gabbro, the coronitic eclogite located closer to the eclogite breccia, all the igneous minerals broke down into high‐P assemblages. Thick coronas of poikilitic garnet grew between the pseudomorphs after igneous plagioclase and ferromagnesian minerals. The igneous plagioclase is replaced by omphacite crystallites, with minor amounts of phengite and kyanite. Thermodynamic modelling of the plagioclase pseudomorphs shows an increase in P–T in the wallrock from the metagabbro to the coronitic eclogite, and the P–T variation is unrelated to H₂O content. The fluid‐poor pressure overstepping scenario is unsupported both by phase diagram modelling and by whole‐rock chemical data, which show that the various types of eclogitized gabbro are all fairly dry. A large pressure difference of >2 GPa between the metagabbro and the coesite‐bearing eclogites ~20 m apart cannot be explained by the subduction hypothesis because this would require a depth difference of >60 km. The microlites and crystallites are evidence for dynamic crystallization due to rapid cooling because constitutional supercooling was unlikely for the plagioclase pseudomorphs. The lack of annealing of the broken biotite and augite overgrown by strain free skeletal garnet is consistent with a transient high‐P–T event at a low ambient temperature (<300 °C), probably in the crust. Therefore, the eclogitization of the wallrock to the eclogite breccia was also coseismic, as proposed earlier for the eclogite facies fault rocks. The outcrop‐scale P–T variation and the transient nature of the high‐P–T event are inconsistent with the other existing tectonic models for high‐P metamorphism. The fact that the less refractory but denser biotite is largely preserved while the more refractory but less dense plagioclase broke down completely into high‐P microlite assemblages in the metagabbro indicates a significant rise in pressure rather than temperature. Given that the metamorphic temperatures are far below the melting temperatures of most of the gabbroic minerals under fluid‐absent conditions, stress‐induced amorphization appears to be the more likely mechanism of the coseismic high‐P metamorphism.  相似文献   

Using raw regional climate model outputs for quantifying climate change impacts on hydrology          下载免费PDF全文

Jie Chen  François P. Brissette  Pan Liu  Jun Xia 《水文研究》2017,31(24):4398-4413

General circulation model outputs are rarely used directly for quantifying climate change impacts on hydrology, due to their coarse resolution and inherent bias. Bias correction methods are usually applied to correct the statistical deviations of climate model outputs from the observed data. However, the use of bias correction methods for impact studies is often disputable, due to the lack of physical basis and the bias nonstationarity of climate model outputs. With the improvement in model resolution and reliability, it is now possible to investigate the direct use of regional climate model (RCM) outputs for impact studies. This study proposes an approach to use RCM simulations directly for quantifying the hydrological impacts of climate change over North America. With this method, a hydrological model (HSAMI) is specifically calibrated using the RCM simulations at the recent past period. The change in hydrological regimes for a future period (2041–2065) over the reference (1971–1995), simulated using bias‐corrected and nonbias‐corrected simulations, is compared using mean flow, spring high flow, and summer–autumn low flow as indicators. Three RCMs driven by three different general circulation models are used to investigate the uncertainty of hydrological simulations associated with the choice of a bias‐corrected or nonbias‐corrected RCM simulation. The results indicate that the uncertainty envelope is generally watershed and indicator dependent. It is difficult to draw a firm conclusion about whether one method is better than the other. In other words, the bias correction method could bring further uncertainty to future hydrological simulations, in addition to uncertainty related to the choice of a bias correction method. This implies that the nonbias‐corrected results should be provided to end users along with the bias‐corrected ones, along with a detailed explanation of the bias correction procedure. This information would be especially helpful to assist end users in making the most informed decisions.  相似文献