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61.
62.
Perfluorinated chemicals including PFOA and PFOS have been widely used in consumer products and have become ubiquitous pollutants widely distributed in the aqueous environment. Following a major flood event in 2011, water samples were collected along a spatial gradient of the Brisbane River system to provide an initial estimate of the release of PFASs from flooded urban areas. PFOA (mean concentrations 0.13–6.1 ng L−1) and PFOS (mean concentrations 0.18–15 ng L−1) were the most frequently detected and abundant PFASs. Mean total PFASs concentrations increased from 0.83 ng L−1 at the upstream Wivenhoe Dam to 40 ng L−1 at Oxley Creek, representing an urban catchment. Total masses of PFOA and PFOS delivered into Moreton Bay from January to March were estimated to be 5.6 kg and 12 kg respectively. From this study, urban floodwaters appear to be a previously overlooked source of PFASs into the surrounding environment.  相似文献   
63.
The critical role of ecological preferences and opportunity in determining contaminant uptake and adaptive responses of sexes in the wild is still poorly understood. This ecological relationship was investigated by measuring metal bioaccumulation and antioxidant activity in male and female blue crab populations from open water habitat and the littoral/inter‐tidal zone of the Lagos Lagoon. A total of 741 samples of blue crab (littoral zone: 263 females, 137 males; open water zone, 230 females, 111 males) was collected monthly over 24 months (January 2010–January 2012) from each site and the measurements of morphometric features (wet weight, carapace length, carapace width) were recorded; condition index, metal (redox active: Cu, Zn, redox inactive: Pb, Cd) concentration in tissues (gills, hepatopancreas, gonads and muscle) and antioxidant activity (superoxide dismutase, reduced glutathione, glutathione peroxidase, catalase and malondialdehyde) were measured for each sex. Monthly sediment samples for both habitats were also analysed for metals using standard methods. Female crabs were significantly larger (p < .05) with a better condition index than the male crabs across sites and seasons, while higher oxidative damage was recorded in male crabs in the littoral zone compared to the open water zone. The results show that there was a negative association between antioxidant activity and lipid peroxidation; a negative relationship between concentrations of redox‐inactive metals (Pb and Cd) and antioxidant activity in male crab tissues; and a positive relationship between uptake of a redox‐active metal (Cu) and antioxidant activity in female crab tissues. Although these trends suggest sex‐specific toxicity, they also associate redox‐inactive metals with the downregulation of antioxidant activity and oxidative stress. Furthermore, the higher condition index of females corroborates the possibility of sex‐specific toxicity, while the larger‐sized females compared to males suggests size‐sexual dimorphism in the blue crab populations. The site‐specific oxidative damage between sexes may be attributed to the different complexity of both habitats, which affords different ecological opportunities for the sexes.  相似文献   
64.
Different interpretation of sedimentary environments lead to “scenario uncertainty” where the prior reservoir model has a high level of discrete uncertainty. In a real field application, the scenario uncertainty has a considerable effect on flow response uncertainty and makes the uncertainty quantification problem highly nonlinear. We use clustering methods to address the scenario uncertainty. Our approach to cluster analysis is based on the posterior probabilities of models, known as “Bayesian model selection.” Accordingly, we integrate overall possible parameters in each scenario with respect to their corresponding priors to give the measure of how well a model is supported by observations. We propose a cluster-based reduced terms polynomial chaos proxy to efficiently estimate the posterior probability density function under each cluster and calculate the posterior probability of each model. We demonstrate that the convergence rate of the reduced terms polynomial chaos proxy is significantly improved under each cluster comparing to the non-clustered case. We apply the proposed cluster-based polynomial chaos proxy framework to study the plausibility of three training images based on different geological interpretation of the second layer of synthetic Stanford VI reservoir. We demonstrate that the proposed workflow can be efficiently used to calculate the posterior probability of each scenario and also sample from the posterior facies models within each scenario.  相似文献   
65.
Detailed reservoir models routinely contain 106–108 grid blocks. These models often cannot be used directly in a reservoir simulation because of the time and memory required for solving the pressure grid on the fine grid. We propose a nested gridding technique that efficiently obtains an approximate solution for the pressure field. The domain is divided into a series of coarse blocks, each containing several fine cells. Effective mobilities are computed for each coarse grid block and the pressure is then found on the coarse scale. The pressure field within each coarse block is computed using flux boundary conditions obtained from the coarse pressure solution. Streamline-based simulation is used to move saturations forward in time. We test the method for a series of example waterflood problems and demonstrate that the method can give accurate estimates of oil production for large 3D models significantly faster than direct simulation using streamlines on the fine grid, making the method overall approximately up to 1,000 times faster than direct conventional simulation.  相似文献   
66.
This paper presents an analysis of an asteroid deflection method based on multiple solar concentrators. A model of the deflection through the sublimation of the surface material of an asteroid is presented, with simulation results showing the achievable impact parameter with, and without, accounting for the effects of mirror contamination due to the ejected debris plume. A second model with simulation results is presented analyzing an enhancement of the Yarkovsky effect, which provides a significant deflection even when the surface temperature is not high enough to sublimate. Finally the dynamical model of solar concentrators in the proximity of an irregular celestial body are discussed, together with a Lyapunov-based controller to maintain the spacecraft concentrators at a required distance from the asteroid.  相似文献   
67.
We numerically follow the nonlinear evolution of the Parker instability in the presence of phase transitions from a warm to a cold H  i interstellar medium in two spatial dimensions. The nonlinear evolution of the system favours modes that allow the magnetic field lines to cross the galactic plane. Cold H  i clouds form with typical masses  ≃105 M  , mean densities  ≃20 cm−3  , mean magnetic-field strengths  ≃4.3 μG  (rms field strengths  ≃6.4 μG  ), mass-to-flux ratios  ≃0.1–0.3  relative to critical, temperatures  ≃50 K  , (two-dimensional) turbulent velocity dispersions  ≃1.6 km s−1  and separations  ≃500 pc  , in agreement with observations. The maximum density and magnetic-field strength are  ≃103 cm−3  and  ≃20 μG  , respectively. Approximately 60 per cent of all H  i mass is in the warm neutral medium. The cold neutral medium is arranged into sheet-like structures both perpendicular and parallel to the galactic plane, but it is also found almost everywhere in the galactic plane, with the density being highest in valleys of the magnetic field lines. 'Cloudlets' also form whose physical properties are in quantitative agreement with those observed for such objects by Heiles. The nonlinear phase of the evolution takes ≲30 Myr, so that, if the instability is triggered by a nonlinear perturbation such as a spiral density shock wave, interstellar clouds can form within a time suggested by observations.  相似文献   
68.
A blind faith in the ability of MPAs to counteract loss of biodiversity is fraught with risk, especially when MPAs are poorly planned and when the consequences of establishing MPAs are not adequately thought out. MPA shortcomings are categorized as one of five main types: (1) MPAs that by virtue of their small size or poor design are ecologically insufficient; (2) inappropriately planned or managed MPAs; (3) MPAs that fail due to the degradation of the unprotected surrounding ecosystems; (4) MPAs that do more harm than good due to displacement and unintended consequences of management; and (5) MPAs that create a dangerous illusion of protection when in fact no protection is occurring. A strategic alternative, which fully utilizes the strengths of the MPA tool while avoiding the pitfalls, can overcome these shortcomings: integrating marine protected area planning in broader marine spatial planning and ocean zoning efforts.  相似文献   
69.
The clays and other minerals in a succession of Late Permian coals of high-volatile bituminous to semi-anthracite rank have been identified, using low-temperature oxygen plasma ashing and X-ray diffraction, and evaluated to identify the relative roles in mineral matter formation of detrital input, early diagenesis in the peat swamp and late diagenesis associated with rank advance. Although well-ordered kaolinite of probable early diagenetic origin is abundant throughout the succession, the uppermost and lowermost seams of the sequence, regardless of rank, contain relatively abundant illite and/or interstratified illite/smectite, along with a small but significant proportion of chlorite. These clays are thought to be essentially of detrital origin, washed or blown into the peat deposit in relative abundance during the establishment and subsequent overwhelming of an extensive and long-lived swampy environment. Quartz is also abundant in the lower seams of the sequence, especially close to the regional sediment source area. Illite is unusually abundant in the topmost seam in both high- and low-rank parts of the succession, and thus appears to represent detrital input from a particular source material. Although significant changes are reported in the clays of the associated strata due to rank advance, the principal effect of rank advance on the minerals in the coal itself appears to be the development of an ammonium illite, and possibly some additional fine-grained chlorite, in the semi-anthracite material. Isolation within the organic matter of the coal is thought to have inhibited access for ions such as K+, which might otherwise have become involved in metamorphic reactions and given rise to mineralogical changes commonly found in non-coal sedimentary successions.  相似文献   
70.
Scientists often turn to farmers to understand soil management. This process reveals differences and overlaps between local and scientific soil knowledge but rarely considers women and gender issues. This paper examines men's and women's local knowledge of soils in upland, smallholder farms in two villages in Mindanao, the Philippines, using focus group discussions, semi‐structured household interviews, field visits, GIS and soil testing. Farmers' field areas were calculated and delineated based on their perceptions of the different types of soils on their land. Men and women chose the same plots for what they considered their best soil but differed on what they felt were their worst. The fertility of the soils that women considered to be the best and worst was not significantly different from that of the men's respective choices. There was a difference in fertility, however, between the best and worst soils regardless of gender. Although soil fertility analyses showed that the women's chosen soils were similar to men's, analyses of qualitative data showed that their knowledge of soils was different and was based in part on a gendered division of labour. A multidisciplinary approach helped bridge the gap between sociocultural and physical research.  相似文献   
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