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21.
Field capacity is a commonly used soil parameter in surface water hydrological models, loosely defined as the moisture content of a soil after drainage. The most commonly applied expression for field capacity is defined as the remaining water in a vertical soil column subject to 1/3 atm. of pressure head. While this quantification is sufficient in some cases, the definition is not consistent with the use of bulk field capacity in calculations of lateral drainage from hillslopes, as required by some surface soil parameterizations, nor does it address additional complications arising from differences in soil texture or sample size. Here, a simple alternative expression for bulk field capacity in a sloping or vertical soil is derived directly from Richards equation with the use of the Brooks‐Corey characteristics. It is demonstrated that this expression is consistent with data acquired from vertical soil columns, but may be extended to additional situations commonly found in surface water models and land surface schemes. The calculation of bulk field capacity requires only the Brooks‐Corey pore size distribution index, soil air‐entry pressure, and hillslope length and slope, and may be considered a physically based alternative to pedotransfer function or lookup table approaches. Copyright © 2010 John Wiley & Sons Ltd and Crown in the right of Canada.  相似文献   
22.
Water draining from a large agricultural catchment of 1 110 km2 in southwest France was sampled over an 18‐month period to determine the temporal variability in suspended sediment (SS) and dissolved (DOC) and particulate organic carbon (POC) transport during flood events, with quantification of fluxes and controlling factors, and to analyze the relationships between discharge and SS, DOC and POC. A total of 15 flood events were analyzed, providing extensive data on SS, POC and DOC during floods. There was high variability in SS, POC and DOC transport during different seasonal floods, with SS varying by event from 513 to 41 750 t; POC from 12 to 748 t and DOC from 9 to 218 t. Overall, 76 and 62% of total fluxes of POC and DOC occurred within 22% of the study period. POC and DOC export from the Save catchment amounted to 3090 t and 1240 t, equivalent to 1·8 t km?2 y?1 and 0·7 t km?2 y?1, respectively. Statistical analyses showed that total precipitation, flood discharge and total water yield were the major factors controlling SS, POC and DOC transport from the catchment. The relationships between SS, POC and DOC and discharge over temporal flood events resulted in different hysteresis patterns, which were used to deduce dissolved and particulate origins. In both clockwise and anticlockwise hysteresis, POC mainly followed the same patterns as discharge and SS. The DOC‐discharge relationship was mainly characterized by alternating clockwise and anticlockwise hysteresis due to dilution effects of water originating from different sources in the whole catchment. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
23.
Glass composition-based correlations of volcanic ash (tephra) traditionally rely on extensive manual plotting. Many previous statistical methods for testing correlations are limited by using geochemical means, masking diagnostic variability. We suggest that machine learning classifiers can expedite correlation, quickly narrowing the list of likely candidates using well-trained models. Eruptives from Alaska's Aleutian Arc-Alaska Peninsula and Wrangell volcanic field were used as a test environment for 11 supervised classification algorithms, trained on nearly 2000 electron probe microanalysis measurements of glass major oxides, representing 10 volcanic sources. Artificial neural networks and random forests were consistently among the top-performing learners (accuracy and kappa > 0.96). Their combination as an average ensemble effectively improves their performance. Using this combined model on tephras from Eklutna Lake, south-central Alaska, showed that predictions match traditional methods and can speed correlation. Although classifiers are useful tools, they should aid expert analysis, not replace it. The Eklutna Lake tephras are mostly from Redoubt Volcano. Besides tephras from known Holocene-active sources, Holocene tephra geochemically consistent with Pleistocene Emmons Lake Volcanic Center (Dawson tephra), but from a yet unknown source, is evident. These tephras are mostly anchored by a highly resolved varved chronology and represent new important regional stratigraphic markers.  相似文献   
24.
The performance of the Canadian Land Surface Scheme (CLASS 3.5) was assessed using turbulent fluxes derived from data recorded at two micrometeorological stations located in a potato field in Quebec, Canada. The minimum stomatal resistance, the maximum leaf area index, and the initial water content of the third soil layer were optimized using the Non-Dominated Sorting Genetic Algorithm-II and the mean square error of the latent heat flux. With respect to benchmark solutions, the optimization improved the sensible and latent heat fluxes by 31 and 23%, respectively. The use of a pedotransfer rule in adjustment of the water content of mineral soils having small percentages of organic matter provided better estimates of the evapotranspiration during the growing stage. However, like the original version of the model (without the pedotransfer rule), it underestimated evapotranspiration throughout the maturity stage. It is noteworthy that the original version produced a good estimate of cumulative evapotranspiration over the entire season as a result of over- and underestimates at the beginning and maturity stage of the growing season, respectively.  相似文献   
25.
In the present paper, we describe the genetic mechanism that causes the precipitation of raft cones in caves. These speleothems usually form in a hydrothermal and epiphreatic environment where dripwater, dripping repeatedly over the same spot, sinks calcite rafts that were floating on the water surface of a cave pool. In particular, the paper describes a new variety of raft cones that were recently discovered in the Paradise Chamber of the Sima de la Higuera Cave (Murcia, south‐eastern Spain) based on their morphological and morphometric characteristics. These speleothems, dubbed ‘double‐tower cones’, have a notch in the middle and look like two cones, one superimposed over the other. The genetic mechanism that gave rise to the double‐tower cones must include an intermediate stage of rapid calcite raft precipitation, caused by a drop in the water table and by changes in cave ventilation leading to greater carbon dioxide (CO2) degassing and evaporation over the surface of the thermal lake where these speleothems formed. Calcite rafts were deposited in Paradise Chamber, completely covering many of the cones. Later, conditions for slower calcite raft precipitation were restored and some of the cones continued to grow at the same points. When the water table finally fell below the level of Paradise Chamber, the tower cones became exposed, as the incongruent deposits of calcite rafts were dissolved and mobilized to lower cave levels. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
26.
A 4.3 m‐long peat sequence from the shore of Lake Tiriara, Mangaia, Cook Islands, was analyzed using an ITRAX core scanner equipped with a magnetic susceptibility meter. Variations in the elemental profiles, providing insights into long‐ and short‐term environmental changes over the last 3500 years, are supported by grain size data and diatom assemblages. The scattering ratio (Mo Inc/Mo Coh) was evaluated and found to represent a good proxy for organic matter in peat. X‐Ray Fluorescence (XRF) data were processed by principal component analysis that confirmed the distinction of biogenic and detrital phases, organic matter and elements of marine origin. The record preserved in the peat sequence includes a peatland infilling stage followed by alternating drier and wetter periods. A notable steady increase in clay associated with high counts of detrital elements from 2000–1700 cal yr BP is attributed to increased erosion, which is most probably linked with human colonization and/or more intense chemical weathering linked with a wetter climate. Freshwater gastropods (Melanoides sp.), which were possibly introduced by humans, or are native, occupied the wetland during a period of lower water level about 1000–1100 cal yr BP. Short‐term changes in the elemental profiles are often linked with slight coarsening of the inorganic fraction that is, however, only revealed after grain size analysis. Peaks in marine indicators (Br, Cl, S, and/or Ca) associated with marine‐dominated diatom assemblages most probably represent marine incursions through the underground tunnel in the makatea, a fossilized, uplifted coral limestone rim. While none of the marine event units present characteristics typical of cyclone or tsunami deposits, the concurrent or absent peak of detrital elements (Fe, Si, Rb, Ti, K) attributed to increased erosion of the volcanic cone associated with a cyclone is used to distinguish both types of events, as also suggested by principal component analysis.  相似文献   
27.
In coastal marshes, fish larvae may be exposed simultaneously to extreme salinities and to atrazine, a widely used herbicide. To assess the effects of salinity on the toxicity of atrazine, newly-hatched mummichog (Fundulus heteroclitus) were exposed to atrazine (0, 5, 50 and 500 microg/L) at three salinities (3, 15 and 35PSU). Whole body cortisol was measured after 24 h. Body length, condition factor, whole body proteins, lipids, residual masses and water contents were assessed after 96 h. Significants effects were found for both condition factor and water content. Condition factors were lower at salinity 3 and 35 compared to near isoosmotic salinity, 15PSU. In addition, atrazine decreased condition factor at 500 microg/L. Reduction in condition was likely due to retardation in axial growth since body length, percentages of proteins or lipids were not affected. In the absence of atrazine, salinity had no effect on the prevalence of dehydrated (81% water) or hyperhydrated (85% water) larvae. In larvae exposed to atrazine, the prevalence of hyperhydrated larvae increased at 3PSU and 5 microg/L atrazine and that of dehydrated larvae increased at 15 and 35PSU and 5 microg/L atrazine. Severity of dehydratation increased with atrazine concentration at salinity 35PSU. Thus, a short-term exposure to environmentally realistic concentrations of atrazine affects osmotic control in mummichog larvae with possible effects on buoyancy, survival and recruitment.  相似文献   
28.
A sensitive method for iron determination in seawater has been adapted on a submersible chemical analyser for in situ measurements. The technique is based on flow injection analysis (FIA) coupled with spectrophotometric detection. When direct injection of seawater was used, the detection limit was 1.6 nM, and the precision 7%, for a triplicate injection of a 4 nM standard. At low iron concentrations, on line preconcentration using a column filled with 8-hydroxyquinoline (8HQ) resin was used. The detection limit was 0.15 nM (time of preconcentration = 240 s), and the precision 6%, for a triplicate determination of a 1 nM standard, allowing the determination of Fe in most of the oceanic regimes, except the most depleted surface waters. The effect of temperature, pressure, salinity, copper, manganese, and iron speciation on the response of the analyser was investigated. The slope of the calibration curves followed a linear relation as a function of pressure (Cp = 2.8 × 10− 5P + 3.4 × 10− 2 s nmol− 1, R2 = 0.997, for Θ = 13 °C) and an exponential relation as a function of temperature (CΘ = 0.009e0.103Θ, R2 = 0.832, for P = 3 bar). No statistical difference at 95% confidence level was observed for samples of different salinities (S = 0, 20, 35). Only very high concentration of copper (1000 × [Fe]) produced a detectable interference. The chemical analyser was deployed in the coastal environment of the Bay of Brest to investigate the effect of iron speciation on the response of the analyser. Direct injection was used and seawater samples were acidified on line for 80 s. Dissolved iron (DFe, filtered seawater (0.4 μm), acidified and stored at pH 1.8) corresponded to 29 ± 4% of Fea (unfiltered seawater, acidified in line at pH 1.8 for 80 s). Most of Fea (71 ± 4%) was probably a fraction of total dissolvable iron (TDFe, unfiltered seawater, acidified and stored at pH 1.8).  相似文献   
29.
This paper evaluates the quality of the ensemble hydrological reforecasts obtained using the 18-year ensemble meteorological reforecast dataset available from the Canadian Centre for Meteorological and Environmental Prediction (CCMEP). This study focuses on four large watersheds in the province of Quebec. A distribution-based scaling (DBS) post-processing method is used to correct the 18-year ensemble precipitation reforecasts. An Ensemble Kalman Filter (EnKF) assimilation technique is also assessed to improve the initial conditions of the hydrologic model. There is a slight improvement in performance and reliability after applying the DBS approach to precipitation reforecasts, but this technique induces a reduction in the spread. The impact of the integration of the post-processed precipitation into the hydrologic model is also quite marginal. However, the addition of an EnKF provides better ensemble hydrological reforecasts with high performance, reliability, and skill, especially in the first reforecast horizons. The best results are, however, generally obtained when using DBS and an EnKF together. Combining DBS and an EnKF, hydrological forecasts for the next two weeks are obtained using the CCMEP reforecast and also the second generation Global Ensemble Forecast System (GEFS v2) reforecast, which is considered a reference. Forecasts of comparable skill and spread are obtained, with CCMEP-based forecasts showing better spread during the first week, and GEFS v2–based reforecasts showing better skill and spread during the second week. Finally, it is shown that the two meteorological reforecast products assessed in this study have similar economic value for hydrological forecasting applications based on the cost–loss model.  相似文献   
30.
Food tourism is a means to connect agriculture produce and tourism activity. Food tourism allows destinations to convey the authenticity that comes from their food heritage, which is closely linked to natural and cultural landscapes. Food and landscapes in New Zealand are strongly related to dairy production, cheese production being one of the main features. This study showcases cheesescapes in Canterbury, the largest region in the South Island of New Zealand in terms of milk production. On one hand, thanks to food tourism, the producers can explore ways to diversify their production. On the other hand, visitors are able to identify with the inhabitants of a country and ‘taste’ a portion of its landscape through gastronomy.  相似文献   
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