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Livers of catfish (Ariopsis assimilis) from the Bay of Chetumal were analyzed for organochlorine compounds and hydrocarbons as part of a study to diagnose the environmental health of the Bay after a catfish mass mortality that occurred in 1996. The presence of histological lesions in several organs of the fish as result of chemical exposure was also evaluated. The concentrations of organic pollutants found in the Bay may be considered high if compared to the levels reported for sites affected by chemical pollution. High prevalences of cellular alteration histopathologies were found in liver, including hepatic tumors. The presence of some lesions may be related statistically to environmental pollution in the Bay, specially with chlorinated compounds.  相似文献   
2.
Lake sediments in Eklutna Lake, Alaska, reveal the presence of turbidites within varved sequences. These turbidites, which result from flood events and earthquakes, show a similar macroscopic appearance. In order to use turbidites to reconstruct flood variability and/or seismic history in the lake basin, it is crucial to determine the trigger of the turbidity currents. This study examined the turbidite caused by the ad 1964 Great Alaska earthquake as well as turbidites linked to historical flood events in order to differentiate between these earthquake-triggered and flood-triggered turbidites. In a suite of samples from throughout the lake, distinctive proxies are identified that can be associated with event-specific flow characteristics. The study presents straightforward discrimination methods related to the sedimentology and geochemical components of the turbidites. These methods are also applicable to other lakes, particularly proglacial lakes where the sediment composition of onshore and offshore sources is similar. Finally, the discrimination of the turbidite trigger can be used to reconstruct the palaeoflood and seismic history.  相似文献   
3.
Glass composition-based correlations of volcanic ash (tephra) traditionally rely on extensive manual plotting. Many previous statistical methods for testing correlations are limited by using geochemical means, masking diagnostic variability. We suggest that machine learning classifiers can expedite correlation, quickly narrowing the list of likely candidates using well-trained models. Eruptives from Alaska's Aleutian Arc-Alaska Peninsula and Wrangell volcanic field were used as a test environment for 11 supervised classification algorithms, trained on nearly 2000 electron probe microanalysis measurements of glass major oxides, representing 10 volcanic sources. Artificial neural networks and random forests were consistently among the top-performing learners (accuracy and kappa > 0.96). Their combination as an average ensemble effectively improves their performance. Using this combined model on tephras from Eklutna Lake, south-central Alaska, showed that predictions match traditional methods and can speed correlation. Although classifiers are useful tools, they should aid expert analysis, not replace it. The Eklutna Lake tephras are mostly from Redoubt Volcano. Besides tephras from known Holocene-active sources, Holocene tephra geochemically consistent with Pleistocene Emmons Lake Volcanic Center (Dawson tephra), but from a yet unknown source, is evident. These tephras are mostly anchored by a highly resolved varved chronology and represent new important regional stratigraphic markers.  相似文献   
4.
The dissolved load of the Amazon River is generally considered to be lowly impacted by anthropogenic activities. In this work, based on the chemical and hydrological database of the Environmental Research Observatory—HYBAM (http://www.ore-hybam.org), we explore the importance of the Peruvian Foreland petroleum activity on the dissolved Na and Cl fluxes of the Amazon River. The main result of this study allows us suggesting that oil extraction activity, concentrated in the El Tigre River basin, a small foreland watershed in the Peruvian Amazon, influenced drastically the Na and Cl exportation of the Amazon River during the 2006–2007 period. During these years,  the dissolved exportations of this basin represented almost 20 % of the annual dissolved Cl Amazon flux and almost 12 % of the annual dissolved Na Amazon flux for a mean annual discharge <1 % of the Amazon River discharge. Since the last decades, the anthropogenic activities are increasing over the whole Amazon basin, especially in Andean countries. In this context, our results demonstrate that extractive activity cannot be considered as negligible on the hydro-chemistry of the Amazonian Rivers especially for the weathering budget estimation based on river-dissolved loads. Moreover, Cl and Na can be used to trace the formation waters derived from oil extraction at a large spatial scale. The environmental impacts of contaminants associated with deep water released to the hydrosystem (polycyclic aromatics hydrocarbons, metallic trace elements, etc.) at local and regional scales are still underestimated and should be monitored to map their local and regional influence and to prevent their risks on human health.  相似文献   
5.
The primary objective of the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS‐REx) mission is to return to Earth a pristine sample of carbonaceous material from the primitive asteroid (101955) Bennu. To support compositional mapping of Bennu as part of sample site selection and characterization, we tested 95 spectral indices on visible to near infrared laboratory reflectance data from minerals and carbonaceous meteorites. Our aim was to determine which indices reliably identify spectral features of interest. Most spectral indices had high positive detection rates when applied to spectra of pure, single‐component materials. The meteorite spectra have fewer and weaker absorption features and, as a result, fewer detections with the spectral indices. Indices targeting absorptions at 0.7 and 2.7–3 μm, which are attributable to hydrated minerals, were most successful for the meteorites. Based on these results, we identified a set of 17 indices that are most likely to be useful at Bennu. These indices detect olivines, pyroxenes, carbonates, water/OH‐bearing minerals, serpentines, ferric minerals, and organics. Particle size and albedo are known to affect band depth but had a negligible impact on interpretive success with spectral indices. Preliminary analysis of the disk‐integrated Bennu spectrum with these indices is consistent with expectations given the observed absorption near 3 μm. Our study prioritizes spectral indices to be used for OSIRIS‐REx spectral analysis and mapping and informs the reliability of all index‐derived data products, including a science value map for sample site selection.  相似文献   
6.
Turbidites embedded in lacustrine sediment sequences are commonly used to reconstruct regional flood or earthquake histories. A critical step for this method to be successful is that turbidites and their trigger mechanisms are determined unambiguously. The latter is particularly challenging for prehistoric proglacial lake records in high-seismicity settings where both earthquake-generated and flood-generated turbidites interrupt the background varved sedimentation. This calls for a new method to allow efficient and objective identification and classification of turbidites. This study examined turbidites in five long (9 to 17 m) sediment cores from Eklutna Lake, a proglacial lake in south-central Alaska, using standard core logging and grain-size data. A novel statistical approach is presented, in which varve-thickness distributions were first analyzed to objectively identify the thickest turbidites and distinguish them from background sedimentation. For each turbidite, a selection of variables were then measured, including: basal grain-size, thickness, magnetic susceptibility and spectrophotometric variables. Triggering mechanisms were discriminated by a combination of principal component analysis and clustering, and by calibration with historical events. Using this approach, a 2250 year long lake-wide event stratigraphy was constructed, with 94 prehistoric events, including 24 earthquake and 70 flood events. Basal grain-size and thickness variables turn out to be the most effective proxies for discrimination. This statistical approach is a powerful and new method to identify turbidites and their triggering mechanisms in long prehistoric sediment records. It opens up new prospects for palaeoseismological, palaeohydrological and palaeoclimate studies in proglacial lakes worldwide.  相似文献   
7.
Suspended sediment delivery and deposition in proglacial lakes is generally sensitive to a wide range of hydrometeorologic and geomorphic controls. High discharge conditions are of particular importance in many glaciolacustrine records, with individual floods potentially recorded as distinctive turbidites. We used an extensive network of surface sediment cores and hydroclimatic monitoring data to analyse recent flood turbidites and associated sediment transfer controls over instrumental periods at Eklutna Lake, western Chugach Mountains, Alaska. Close to a decade of fluvial data from primary catchment tributaries show a dominating influence of discharge on sediment delivery, with various interconnections with other related hydroclimatic controls. Multivariate fluvial models highlight and help quantify some complexities in sediment transfer, including intra-annual variations, meteorological controls, and the influence of subcatchment glacierization. Sediments deposited in Eklutna Lake during the last half century are discontinuously varved and contain multiple distinctive turbidites. Over a 30-year period of stratigraphic calibration, we correlate the four thickest flood turbidites (1989, 1995, 2006, and 2012) to specific regional storms. The studied turbidites correlate with late-summer and early-autumn rainstorms with a magnitude of relatively instantaneous sedimentation 3–15 times greater than annual background accumulation. Our network of sediment core data captured the broad extent and sediment variability among the study turbidites and background sediment yield. Within-lake spatial modelling of deposition quantifies variable rates of downlake thinning and sediment focusing effects, and highlights especially large differences between the thickest flood turbidites and background sedimentation. This we primarily relate to strongly contrasting dispersion processes controlled by inflow current strength and turbidity. Sediment delivery is of interest for this catchment because of reservoir and water supply operations. Furthermore, although smaller floods may not be consistently represented, the lake likely contains a valuable proxy record of regional flooding proximal to major population centers of south-central Alaska including Anchorage.  相似文献   
8.
A subdomain approach for dynamic soil–structure interaction is proposed for the linear elastic seismic analysis of an anchored sheet pile, retaining a horizontally layered soil on rigid bedrock. A hybrid solution technique is used, employing a finite element formulation for the generalized sheet pile, a thin layer formulation for the soil and a direct stiffness formulation for the tieback; the displacement vectors of the sheet pile and the soil are decomposed, using the eigenmodes of the sheet pile and the propagating or decaying modes in the soil. The discretization can be limited to the interface(s), where pointwise continuity of the displacements is enforced, whereas a weak variational formulation is used for the stress equilibrium. The solution technique is illustrated by means of a numerical example, where the harmonic response of a flexible anchored sheet pile is considered and compared to the case where no tieback is present. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
9.
The effect of environmental pollutants present in sediments obtained from Bahía de Chetumal, a bay on the border between Mexico and Belize, was studied in nile tilapia (Oreochromis niloticus) intraperitoneally injected with sediment extracts from six different sites of the Bay. Sediment samples used for the study contained a variety of organic chemicals such as organochlorine pesticides, polychlorinated biphenyls (PCBs) and polynuclear aromatic hydrocarbons (PAHs). Total cytochrome P-450 and EROD activity were measured in fish liver. Haematological and histological analyses were also carried out. Hepatic P-450 content in treated fish increased from 43 to 240%, and EROD activity from 85 to 160% compared to controls. Extracts from two sampling sites inhibited EROD activity. There were positive significant correlations between P-450 content and the levels of PCBs 44 and 128. EROD activity correlated to HCB, op'-DDE, pp'-DDE, pp'-DDD, mirex and PCB 18 concentrations. Blood examination showed cell degeneration and binucleated leukocytes with abnormal chromatin. Extract treatment also resulted in foci of hyperplasia on the basement of gill lamellae, hypertrophy and oedema in gills and liver necrosis. Control fish showed no abnormalities. The results demonstrate that sediments from Bahía of Chetumal have the potential to cause histopathological, haematological and biochemical alterations in fish. The administration of sediment extracts to fish may serve as a useful test to screen the toxicity of sediments from different areas.  相似文献   
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