Layered mantle structure beneath the western Guyana Shield, Venezuela: Evidence from diamonds and xenocrysts in Guaniamo kimberlites     

Daniel J. Schulze  Dante Canil  Felix V. Kaminsky 《Geochimica et cosmochimica acta》2006,70(1):192-205

Mantle xenoliths and xenocrysts from Guaniamo, Venezuela kimberlites record equilibration conditions corresponding to a limited range of sampling in the lithosphere (100-150 km). Within this small range, however, compositions vary considerably, but regularly, defining a strongly layered mantle sequence. Major and trace element compositions suggest the following lithologic sequence: highly depleted lherzolite from 100 to 115 km, mixed ultra-depleted harzburgite and lherzolite from 115 to 120 km, relatively fertile lherzolite from 120 to 135 km, and mixed depleted harzburgite and relatively fertile lherzolite from 135 to 150 km. Based on comparison with well-documented mantle peridotites and xenocrysts from elsewhere, we conclude that the Meso-proterozoic Cuchivero Province (host to the Guaniamo kimberlites) is underlain by depleted and ultra-depleted shallow Archean mantle that was underplated, and uplifted, by Proterozoic subduction, perhaps more than once. These Proterozoic subduction events introduced less-depleted oceanic lithosphere beneath the Archean section, which remains there and is the source of the abundant Guaniamo eclogite-suite diamonds that have ocean-floor geochemical signatures. Although diamond-indicative low-Ca Cr-pyrope garnets are abundant, they are derived primarily from the shallow depleted layer within the field of graphite stability, and the rare peridotite-suite diamonds are either metastably preserved at these shallow depths, or were derived from the small amount of depleted lithosphere sampled by these kimberlites that remains within the diamond stability field (the mixture of Archean and Proterozoic mantle in the depth range 135-150 km).  相似文献   

Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

Source(s) and cycling of the nonhydrolyzable organic fraction of oceanic particles     

Jeomshik Hwang  Ellen R.M. Druffel  Daniel J. Repeta 《Geochimica et cosmochimica acta》2006,70(20):5162-5168

A major fraction of particulate organic carbon (POC) in the deep ocean remains molecularly uncharacterized. In an effort to determine the chemical characteristics and source(s) of sinking POC, we studied a nonhydrolyzable fraction of sinking POC using ¹³C NMR (nuclear magnetic resonance) spectroscopy and analytical pyrolysis. ¹³C NMR spectra and products from analytical pyrolysis of the nonhydrolyzable fraction exhibit a strongly aliphatic character that is distinct from that of bulk POC. The aliphatic nature of this fraction is consistent with its low stable carbon isotope values. We hypothesize that the nonhydrolyzable fraction derives to a significant extent from a refractory component of organisms that selectively accumulates, resulting in its manifestation as a major part of POC sinking to the deep ocean and in underlying sediments.  相似文献   

Variability in Early Amazonian Tharsis stress state based on wrinkle ridges and strike-slip faulting     

Chris H. Okubo  Richard A. Schultz   《Journal of Structural Geology》2006,28(12):2169

We present evidence for a decrease in the magnitude of Tharsis-circumferential compressive stress during the Late Hesperian to the Middle Amazonian based on chronologic changes in the predominant style of faulting in southern Amazonis Planitia. Using high-resolution MOLA topography, we identify a population of strike-slip faults that exhibit Middle Amazonian-aged displacements of regional chrono-stratigraphic units. These strike-slip faults are adjacent to an older population of previously documented Late Hesperian-aged thrust faults (wrinkle ridges). Along-strike orientations of these thrust and strike-slip faults reveal the Tharsis-radial stress to be the area's most compressive remote principal stress and that this stress orientation and magnitude persisted throughout the Late Hesperian to the Middle Amazonian. We show that the change in the predominant style of faulting from thrust faulting to strike-slip faulting during this time requires a decrease of the Tharsis-circumferential compressive stress to a magnitude less than lithostatic load, with negligible change in stress orientation.  相似文献   

Displacement-length scaling relations for faults on the terrestrial planets     

Richard A. Schultz  Chris H. Okubo  Scott J. Wilkins   《Journal of Structural Geology》2006,28(12):2182

Displacement-length (D/L)scaling relations for normal and thrust faults from Mars, and thrust faults from Mercury, for which sufficiently accurate measurements are available, are consistently smaller than terrestrial D/L ratios by a factor of about 5, regardless of fault type (i.e. normal or thrust). We demonstrate that D/L ratios for faults scale, to first order, with planetary gravity. In particular, confining pressure modulates: (1) the magnitude of shear driving stress on the fault; (2) the shear yield strength of near-tip rock; and (3) the Young's (or shear) modulus of crustal rock. In general, all three factors decrease with gravity for the same rock type and pore-pressure state (e.g. wet conditions). Faults on planets with lower surface gravities, such as Mars and Mercury, demonstrate systematically smaller D/L ratios than faults on larger planets, such as Earth. Smaller D/L ratios of faults on Venus and the Moon are predicted by this approach, and we infer still smaller values of D/L ratio for faults on icy satellites in the outer solar system. Collection of additional displacement-length and down-dip height data from terrestrial normal, strike-slip, and thrust faults, located within fold-and-thrust belts, plate margins, and continental interiors, is required to evaluate the influence of fault shape and progressive deformation on the scaling relations for faults from Earth and elsewhere.  相似文献   

Review: Microbial biocenoses in pristine aquifers and an assessment of investigative methods   总被引：2，自引：6，他引：2  

Nico Goldscheider  Daniel Hunkeler  Pierre Rossi 《Hydrogeology Journal》2006,14(6):926-941

The current knowledge of microbial biocenoses (communities) in pristine aquifers is presented in a review, which also discusses their relevance for questions of groundwater protection. Aquifers are heterogeneous on all scales and structured in a variety of habitats. The void spaces in many aquifers are small. The biocenoses are thus predominantly composed of microorganisms and, often, microinvertebrates. Larger voids and macroorganisms occur in karst cavities. Due to the absence of light, the biocenoses depend on chemical energy resources, which are, however, scarce in non-contaminated groundwater. The microorganisms thus show small cell sizes, low population densities and reduced activity; they developed specific strategies to survive oligotrophic conditions. The review also discusses the impact of contamination on the biocenoses, and the potential use of the biocenoses or specific organisms as indicators for groundwater quality, and the limits of this approach. Bacteria are either planktonic or attached to aquifer material, which requires both fluid and solid phase sampling. Most groundwater bacteria are viable but non-culturable. Consequently, cultivation techniques give an incomplete picture of the biocenoses, while methods from molecular microbiology provide genetic fingerprints of the entire community. Different analytical methods are available to count microorganisms, identify species, characterise microbial diversity, and measure activity.  相似文献   

Study of geothermal water intrusion due to groundwater exploitation in the Puebla Valley aquifer system, Mexico   总被引：1，自引：1，他引：1  

E. Leticia Flores-Márquez  Gabriel Jiménez-Suárez  Raymundo G. Martínez-Serrano  René E. Chávez  Daniel Silva Pérez 《Hydrogeology Journal》2006,14(7):1216-1230

Significant intrusion of geothermal water into fresh groundwater takes place in the Puebla Valley aquifer system, Mexico. The decline in the potentiometric surface due to the overexploitation of the groundwater induces this intrusion. This hydrological system comprises three aquifers located in Plio-Quaternary volcanic sediments and Mesozoic calcareous rocks. The hydraulic balance of the aquifer shows that the annual output exceeds the natural inputs by 12 million m³. Between 1973 and 2002, a drop in the potentiometric surface, with an 80 m cone of depression, was identified in a 5-km-wide area located southwest of the city of Puebla. Chemical analyses performed on water samples since 1990 have shown an increase in total dissolved solids (TDS) of more than 500 mg/L, coinciding with the region showing a cone of depression in the potentiometric surface. A three-dimensional flow and transport model, based on the hydrogeological and geophysical studies, was computed by using the MODFLOW and MT3D software. This model reproduces the evolution of the aquifer system during the last 30 years and predicts for 2010 an additional drawdown in the potentiometric surface of 15 m, and an increase in the geothermal water intrusion.  相似文献   

Monte Carlo simulation of mixing in Ca3Fe2Ge3O12–Ca4Ge4O12 garnets and implications for the thermodynamic stability of pyrope–majorite solid solution     

Victor L. Vinograd  Bjoern Winkler  Daniel J. Wilson  Andrew Putnis  Julian D. Gale 《Physics and Chemistry of Minerals》2006,33(8-9):533-544

Static lattice energy calculations, based on empirical pair potentials, were performed for a large set of structures differing in the arrangement of octahedral cations within the garnet 2 × 2 × 2 supercell. The compositions of these structures varied between Ca₃Fe₂Ge₃O₁₂ and Ca₄Ge₄O₁₂. The energies were cluster expanded using pair and quaternary terms. The derived ordering constants were used to constrain Monte Carlo simulations of temperature-dependent mixing properties in the ranges of 1,073–3,673 K and 0–10 GPa. The free energies of mixing were calculated using the method of thermodynamic integration. The calculations predict a wide miscibility gap between Fe-rich (cubic) and Fe-pure (tetragonal) garnets consistent with recent experimental observations of Iezzi et al. (Phys Chem Miner 32:197–207, 2005). It is shown that the miscibility gap arises due to a very strong cation ordering at the Fe-pure composition, driven by the charge difference between Ca²⁺ and Ge⁴⁺ cations. The structural and thermodynamic analogies between Ca–Ge and Mg–Si systems suggest that a similar miscibility gap should exist between pyrope and Mg–Si-majorite.  相似文献   

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献   

Blessed with Tourists: The Borderlands of Religion and Tourism in San Antonio by Thomas S. Bremer     

Daniel H. Olsen 《The Professional geographer》2006,58(4):503-504

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