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31.
In this paper, a multiple‐input multiple‐output (MIMO) model‐based robust control scheme is proposed for the indirect control of both total alkalinity and the ratio (intermediate alkalinity)/(total alkalinity) by regulating volatile fatty acid concentrations and strong ions concentration, while guaranteeing the so‐called operational stability in anaerobic digestion (AD) processes. The proposed MIMO regulator is an adaptive controller derived from an AD model which incorporates the physicochemical equilibrium of the system as well as the use of a robust interval observer to estimate key process bounds that are used in the computation of the control efforts. Numerical simulations were carried out for a number of operating conditions under the most uncertain scenarios. Results showed that the proposed multivariable control law is able to recover the system stability around a pre‐determined set point in the face of parameter uncertainty and load disturbances.  相似文献   
32.
The Península Valdés, in northeastern Patagonia, Argentina, is characterised by its arid climate and the lack of perennial watercourses; thus, all economic activities depend on the groundwater resources. Water demand is mainly associated with tourism, which is centralised in Puerto Pirámides and supplied by a water desalination plant, and to sheep farming, supplied by the local aquifer. Due to the exponential growth of tourism, the government is planning to exploit groundwater and convey it by aqueduct to the abovementioned locality. The objectives of this study were to corroborate the conceptual geohydrological model, to develop a mathematical model to simulate the response of the aquifer to different scenarios, and to assess the incidence of water input into the system as a variable—a function that poses difficulties in the models for arid regions. The Visual Modflow 4.1 code was used, calibrating it in trial-and-error mode, changing the recharge and hydraulic conductivity parameters with different variants in the recharge zone and in the inclusion or exclusion of the evapotranspiration module. Results indicate the importance of the recharge analysis by treating rainfall at daily time steps. The adjusted model was exposed to four scenarios with variations in water input and in output by pumping. It can be concluded that under different input conditions, but with a controlled extraction, the system responds in a sustainable manner.  相似文献   
33.
Two closely related scleractinian coral species, Porites cylindrica and Porites rus, were transplanted to two different locations: the natural environment on the reef flat, and culture tanks on land. The use of tanks enabled the regulation of certain environmental factors, and, hence, the evaluation of specific responses of the corals to these factors. For both species, growth and survival were much better in the field than in the land-based tanks most probably due to unrestricted water circulation. Since the two species were subjected to identical experimental treatments, it was possible to distinguish inherent differences between them in terms of responses to external variables. Porites cylindrica was more susceptible than P. rus to predation by corallivores. Predators, as well as grazers, occurred in significant numbers in the field, but not in the land-based tanks. Porites rus, on the other hand, succumbed more readily to overgrowth by macroalgae which thrived in the culture tanks presumably because of significantly higher nutrient levels and the conspicuous absence of grazers. These results have broader ecological implications because of accelerated environmental changes taking place in present-day reefs due to human impact. Major examples are eutrophication and alterations in water circulation which frequently result in sub-optimal conditions for coral survival and growth.  相似文献   
34.
The ESEOO Project, launched after the Prestige crisis, has boosted operational oceanography capacities in Spain, creating new operational oceanographic services and increasing synergies between these new operational tools and already existing systems. In consequence, the present preparedness to face an oil-spill crisis is enhanced, significantly improving the operational response regarding ocean, meteorological and oil-spill monitoring and forecasting. A key aspect of this progress has been the agreement between the scientific community and the Spanish Search and Rescue Institution (SASEMAR), significantly favoured within the ESEOO framework. Important achievements of this collaboration are: (1) the design of protocols that at the crisis time provide operational state-of-the-art information, derived from both forecasting and observing systems; (2) the establishment, in case of oil-spill crisis, of a new specialized unit, named USyP, to monitor and forecast the marine oceanographic situation, providing the required met-ocean and oil-spill information for the crisis managers. The oil-spill crisis scenario simulated during the international search and rescue Exercise "Gijón-2006", organized by SASEMAR, represented an excellent opportunity to test the capabilities and the effectiveness of this USyP unit, as well as the protocols established to analyze and transfer information. The results presented in this work illustrate the effectiveness of the operational approach, and constitute an encouraging and improved base to face oil-spill crisis.  相似文献   
35.
Neat ethanol (75.7 L) was released into the upper capillary zone in a continuous-flow, sand-packed aquifer tank (8.2 m3) with an average seepage velocity of 0.75 m/day. This model aquifer system contained a residual nonaqueous phase liquid (NAPL) that extended from the capillary zone to 10 cm below the water table. Maximum aqueous concentrations of ethanol were 20% v/v in the capillary zone and 0.08% in the saturated zone at 25 and 30 cm downgradient from the emplaced NAPL source, respectively. A bench-scale release experiment was also conducted for a similar size spill (scaled to the plan area). The concentrations of ethanol in ground water for both the bench- and pilot-scale experiments were consistent with advective–dispersive limited mass transfer from the capillary to the saturated zone. Concentrations of monoaromatic hydrocarbons and isooctane increased in the pore water of the capillary zone as a result of both redistribution of residual NAPL (confirmed by visualization) and enhanced hydrocarbon dissolution due to the cosolvent effect exerted by ethanol. In the tank experiment, higher hydrocarbon concentrations in ground water were also attributed to decreased hydrocarbon biodegradation activity caused by preferential microbial utilization of ethanol and the resulting depletion of oxygen. These results infer that spills of highly concentrated ethanol will be largely confined to the capillary zone due to its buoyancy, and ethanol concentrations in near-source zone ground water will be controlled by mass transfer limitations and hydrologic conditions. Furthermore, highly concentrated ethanol releases onto pre-existing NAPL will likely exacerbate impacts to ground water, due to NAPL mobilization and dissolution, and decreased bioattenuation of hydrocarbons.  相似文献   
36.
The sea level of Northeast Atlantic Ocean is calculated for the period between 1958 and 2001 using a state-of-the-art barotropic model with a grid size of 10′ × 15′ (long × lat). The model includes astronomic effects, considering seven components of the tide, and the meteorological effects of wind and atmospheric pressure, allowing obtaining the astronomic tide, the atmospheric residuals and the non-linear addition of both components of sea level.  相似文献   
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38.
Experimental studies on the retention of metals (Cu, Co, Ni, and Zn) in bentonite samples from the Grau Region (Northern Peru) have been accomplished using monometallic, bimetallic, trimetallic, and tetrametallic solutions. Parameters such as pH and concentration of dissolved metals and organic compounds have been evaluated by means of batch adsorption experiments. Adsorption rates indicate the suitability of these bentonites in the environmental industry for heavy metals retention purposes. In addition to its quality as physical barrier to avoid the dispersion through the environment of polluted leachates, bentonite, due to its high cation exchange capacity, can act also as a chemical barrier, protecting the quality of surface and groundwater systems, while limiting the migration of heavy metals in solid residues or sludge stocked in security landfills. Adsorption rates of tested bentonites were proved to decrease when concentrations of both metal and organic compounds, as well as the number of ionic species, increase in solution; additionally, lower metal removal rates from solution were obtained when extremely acidic conditions were achieved.  相似文献   
39.
40.
A computational fluid dynamics (CFD)‐based methodology is proposed to derive convective mass‐transfer coefficients (wind functions) that are required for estimating evaporation of water bodies with the mass‐transfer method. Three‐dimensional CFD was applied to model heat transfer in two water bodies: a Class‐A tank evaporimeter and an on‐farm artificial pond. The standard k–? model assuming isotropic turbulence was adopted to describe turbulent heat transport, whereas the heat and mass transfer analogy was assumed to derive the wind functions. The CFD‐derived wind functions were very similar to those empirically derived from the experimental water bodies. The evaporation rates calculated with the synthetic wind functions were in good agreement with hourly and daily evaporation measurements for the tank and pond, respectively. The proposed CFD‐approach is generalisable and cost effective, because it has low input data requirements. Besides, it provides additional capability of modelling the spatial distribution of the evaporation rate over the water surface. Although the application of CFD to water bodies evaporation modelling is still in development, it looks very promising. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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