Natural attenuation of TCE, As, Hg linked to the heterogeneous oxidation of Fe(II): an AFM study   总被引：1，自引：0，他引：1  

Laurent Charlet  Dirk Bosbach  Tanya Peretyashko   《Chemical Geology》2002,190(1-4):303-319

Hydrous ferric oxide (HFO) colloids formed, in strictly anoxic conditions upon oxidation of Fe²⁺ ions adsorbed on mineral surface, were investigated under in situ conditions by contact mode atomic force microscopy (AFM). Freshly cleaved and acid-etched large single crystals of near endmember phlogopite were pre-equilibrated with dissolved Fe(II) and then reacted with Hg(II), As(V) and trichlorethene (TCE)-bearing solutions at 25 °C and 1 atm. HFO structures are found to be of nanometer scale. The As(V)–Fe(II) and Hg(II)–Fe(II) reaction products are round (25 nm) microcrystallites located predominantly on the layer edges and are indicative of an accelerated Fe(II) oxidation rate upon formation of Fe(II) inner sphere surface complexes with the phyllosilicate edge surface sites. On the other hand, TCE–Fe(II)–phlogopite reaction products are needle-shaped (45 nm long) particles located on the basal plane along the Periodic Bond Chains (PCBs) directions. Experiments with additions of sodium chloride confirm the importance of the Fe(II) adsorption step in the control of the overall heterogeneous Fe(II)–TCE electron transfer reaction.

Kinetic measurements at the nanomolar level of Hg° formed upon reduction of Hg(II) by Fe(II) in presence of phlogopite particles provide further convincing evidence for reduction of Hg(II)_aq coupled to the oxidation of Fe(II) adsorbed at the phlogopite–fluid interface, and indicate that sorption of Fe(II) to mineral surfaces enhances the reduction rate of Hg(II) species. The Hg(II) reduction reaction follows a first-order kinetic law. Under our experimental conditions, which were representative of many natural systems, 80% of the mercury is transferred to the atmosphere as Hg° in less than 2 h.

The reduction of a heavy metal (Hg), a toxic oxyanion (arsenate ion) and a chlorinated solvent (TCE) thus appear to be driven by the high reactivity of adsorbed Fe(II). This is of environmental relevance since these three priority pollutants are that way reductively transformed to a volatile, an immobilizable and a biodegradable species, respectively. Such kinetic data and reaction pathways are important in the evaluation of natural evaluation scenarios, in the optimization of Fe(II)/mineral mixtures as reductants in technical systems, and in general, in predicting the fate and transport of pollutants in natural systems.  相似文献   

The Elbe Fault System in North Central Europe—a basement controlled zone of crustal weakness     

Magdalena Scheck  Ulf Bayer  Volker Otto  Juliette Lamarche  Dirk Banka  Tim Pharaoh 《Tectonophysics》2002,360(1-4):281-299

The Elbe Fault System (EFS) is a WNW-striking zone extending from the southeastern North Sea to southwestern Poland along the present southern margin of the North German Basin and the northern margin of the Sudetes Mountains. Although details are still under debate, geological and geophysical data reveal that upper crustal deformation along the Elbe Fault System has taken place repeatedly since Late Carboniferous times with changing kinematic activity in response to variation in the stress regime. In Late Carboniferous to early Permian times, the Elbe Fault System was part of a post-Variscan wrench fault system and acted as the southern boundary fault during the formation of the Permian Basins along the Trans-European Suture Zone (sensu [Geol. Mag. 134 (5) (1997) 585]). The Teisseyre–Tornquist Zone (TTZ) most probably provided the northern counterpart in a pull-apart scenario at that time. Further strain localisation took place during late Mesozoic transtension, when local shear within the Elbe Fault System caused subsidence and basin formation along and parallel to the fault system. The most intense deformation took place along the system during late Cretaceous–early Cenozoic time, when the Elbe Fault System responded to regional compression with up to 4 km of uplift and formation of internal flexural highs. Compressional deformation continued during early Cenozoic time and actually may be ongoing. The upper crust of the Elbe Fault System, which itself reacted in a more or less ductile fashion, is underlain by a lower crust characterised by low P-wave velocities, low densities and a weak rheology. Structural, seismic and gravimetric data as well as rheology models support the assumption that a weak, stress-sensitive zone in the lower crust is the reason for the high mobility of the area and repeated strain localisation along the Elbe Fault System.  相似文献   

Effective precipitation in southern Spain ( 266 to 46 ka) based on a speleothem stable carbon isotope record     

Edward J. Hodge  David A. Richards  Peter L. Smart  Bartolom Andreo  Dirk L. Hoffmann  Dave P. Mattey  Antonio Gonzlez-Ramn 《Quaternary Research》2008,69(3):447-457

We present the longest-duration directly dated terrestrial palaeoclimate record from the western Mediterranean region: a flowstone speleothem from Gitana Cave, southeast Spain. The main phase of growth was 274 to 58 ka, dated by multi-collector inductively coupled plasma mass spectrometry (MC-ICPMS) U-series methods. Effective precipitation, which we consider primarily responsible for flowstone calcite δ¹³C variations, measured at 300 μm resolution, was higher during interglacials associated with marine oxygen isotope stages (MIS) 7 and 5, and lower during glacial MIS 6. There is a close correspondence between speleothem δ¹³C and sea surface temperature (SST) estimates from adjacent Atlantic Ocean cores during MIS 6, which implies that oceanic conditions are critical in controlling the western Mediterranean terrestrial moisture balance during glacial periods. Other features of our record, such as the sequence of termination II warming/moistening between approximately 133 and 127 ka, including a “pause” around 130–128 ka, and the lagged termination of MIS 5 warm intervals (5e, 5c and 5a) are similar to other terrestrial records within the Mediterranean basin, indicating climate synchroneity along the northern Mediterranean coast. The Gitana cave region also may have been a refugium for temperate species during short-lived cold/arid periods during MIS 5.  相似文献   

An Approach for the Classification of Urban Building Structures Based on Discriminant Analysis Techniques   总被引：4，自引：0，他引：4  

Stefan Steiniger  Tilman Lange  Dirk Burghardt  Robert Weibel 《Transactions in GIS》2008,12(1):31-59

Recognition of urban structures is of interest in cartography and urban modelling. While a broad range of typologies of urban patterns have been published in the last century, relatively little research on the automated recognition of such structures exists. This work presents a sample‐based approach for the recognition of five types of urban structures: (1) inner city areas, (2) industrial and commercial areas, (3) urban areas, (4) suburban areas and (5) rural areas. The classification approach is based only on the characterisation of building geometries with morphological measures derived from perceptual principles of Gestalt psychology. Thereby, size, shape and density of buildings are evaluated. After defining the research questions we develop the classification methodology and evaluate the approach with respect to several aspects. The experiments focus on the impact of different classification algorithms, correlations and contributions of measures, parameterisation of buffer‐based indices, and mode filtering. In addition to that, we investigate the influence of scale and regional factors. The results show that the chosen approach is generally successful. It turns out that scale, algorithm parameterisation, and regional heterogeneity of building structures substantially influence the classification performance.  相似文献   

Field instrumentation for high‐resolution parallel monitoring of bedrock erosion and bedload transport          下载免费PDF全文

Alexander R. Beer  Jens M. Turowski  Bruno Fritschi  Dirk H. Rieke‐Zapp 《地球表面变化过程与地形》2015,40(4):530-541

River incision is fundamental in shaping the Earth's surface. In mountainous regions with steep river beds, fluvial bedrock erosion by bedload transport is an important mechanism forming channels. However, there are only a few complete field datasets that can be used to improve process understanding and evaluate erosion models, especially at the process scale. To provide a simultaneous dataset of hydraulics, bedload transport and bedrock erosion at high temporal and spatial resolution, a new measuring device has been installed in the Erlenbach, a gauged stream in the Swiss Pre‐Alps. In this stream, bedload transport rates can be calculated from surveying deposits and from geophone plate sensors and bedload transport samples can be taken directly by an automated moving basket system. To measure bedrock erosion rates simultaneously, two natural stone slabs were mounted flush with the channel bed in a steel frame hosting various measurement devices. Force sensors below the slabs record normal stress and shear stress. At‐a‐point erosion rates on the slab surfaces are continuously measured at sub‐millimetre precision at three locations on each slab. In addition, the slab topography is monitored following erosive flood events. In this article (i) the ‘erosion scale’ device is described, (ii) data resolution and data quality is assessed by means of tests and event data, and (iii) the first transport event is discussed. The erosion scales are confirmed to provide data at high spatio‐temporal resolution for process analysis. The preliminary data show evidence for the tools effect in bedrock erosion. The bedrock slabs can be exchanged to obtain measurements for catchments with different lithologies for comparison. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Fidelity and repeatability of wave fields reconstructed from multicomponent streamer data     

Kurt Eggenberger  Philip Christie  Massimiliano Vassallo  Ali Özbek  Everhard Muyzert  Dirk‐Jan van Manen  Ed Kragh 《Geophysical Prospecting》2014,62(5):994-1008

Wave field reconstruction – the estimation of a three‐dimensional (3D) wave field representing upgoing, downgoing or the combined total pressure at an arbitrary point within a marine streamer array – is enabled by simultaneous measurements of the crossline and vertical components of particle acceleration in addition to pressure in a multicomponent marine streamer. We examine a repeated sail line of North Sea data acquired by a prototype multicomponent towed‐streamer array for both wave field reconstruction fidelity (or accuracy) and reconstruction repeatability. Data from six cables, finely sampled in‐line but spaced at 75 m crossline, are reconstructed and placed on a rectangular data grid uniformly spaced at 6.25 m in‐line and crossline. Benchmarks are generated using recorded pressure data and compared with wave fields reconstructed from pressure alone, and from combinations of pressure, crossline acceleration and vertical acceleration. We find that reconstruction using pressure and both crossline and vertical acceleration has excellent fidelity, recapturing highly aliased diffractions that are lost by interpolation of pressure‐only data. We model wave field reconstruction error as a linear function of distance from the nearest physical sensor and find, for this data set with some mismatched shot positions, that the reconstructed wave field error sensitivity to sensor mispositioning is one‐third that of the recorded wave field sensitivity. Multicomponent reconstruction is also more repeatable, outperforming single‐component reconstruction in which wave field mismatch correlates with geometry mismatch. We find that adequate repeatability may mask poor reconstruction fidelity and that aliased reconstructions will repeat if the survey geometry repeats. Although the multicomponent 3D data have only 500 m in‐line aperture, limiting the attenuation of non‐repeating multiples, the level of repeatability achieved is extremely encouraging compared to full‐aperture, pressure‐only, time‐lapse data sets at an equivalent stage of processing.  相似文献   

A new approach to overcome shortcomings with multiple testing of reproduction data in ecotoxicology   总被引：1，自引：1，他引：0  

René Lehmann  Jean Bachmann  Dirk Maletzki  Christian Polleichtner  Hans Toni Ratte  Monika Ratte 《Stochastic Environmental Research and Risk Assessment (SERRA)》2016,30(3):871-882

In ecotoxicology species reproduction tests and multiple testing of reproduction data are wide spread. While normal approximation of the data is a minor problem often the requirement of variance homogeneity is not fulfilled. Variance homogeneity is necessary to assure the proper application of statistical procedures like pairwise t tests, Dunnett t test, and Williams t test. A Poisson model can solve this issue preserving meaningful results and rendering statistical analysis more reliable. Moreover, sequential application of pairwise statistical “control vs. treatment” tests is a drawback concerning \(\alpha \)-inflation. The closure principle (CP) for hypothesis testing is used to generate a step-wise approach for detection of the No/Lowest Observed Effect Concentration using the computational approach test (CAT). The advantages and disadvantages of the combined CPCAT approach compared to the widely used t tests are pointed out and results of real data and fictitious data analysis are compared revealing the superiority of the Poisson model and CPCAT.  相似文献   

Passive seismic source localization via common-reflection-surface attributes     

Benjamin Schwarz  Alexander Bauer  Dirk Gajewski 《Studia Geophysica et Geodaetica》2016,60(3):531-546

The common-reflection-surface (CRS) stack can be viewed as a physically justified extension of the classical common-midpoint (CMP) stack, utilizing redundant information not only in a single, but in several neighboring CMP gathers. The zero-offset CRS moveout is parameterized in terms of kinematic attributes, which utilize reciprocity and raypath symmetries to describe the two-way process of the actual wave propagation in active seismic experiments by the propagation of auxiliary one-way wavefronts. For the diffraction case, only the attributes of a single one-way wavefront, originating from the diffractor are sufficient to explain the traveltime differences observed at the surface. While paraxial ray theory gives rise to a second-order approximation of the CRS traveltime, many higher-order approximations were subsequently introduced either by squaring the second-order expression or by employing principles of optics and geometry. It was recently discovered that all of these higher-order operators can be formulated either for the optical projection or in an auxiliary medium of a constant effective velocity. Utilizing this duality and the one-way nature of the CRS parameters, we present a simple data-driven stacking scheme that allows for the estimation of the a priori unknown excitation time of a passive seismic source. In addition, we demonstrate with a simple data example that the output of the suggested workflow can directly be used for subsequent focusing-based normal-incidence-point (NIP) tomography, leading to a reliable localization in depth.  相似文献   

A Possible Source Mechanism of the 1946 Unimak Alaska Far-Field Tsunami: Uplift of the Mid-Slope Terrace Above a Splay Fault Zone     

Roland von Huene  John J. Miller  Dirk Klaeschen  Peter Dartnell 《Pure and Applied Geophysics》2016,173(12):4189-4201

  相似文献   

Modeling multiple elementary waves in layered media using ray field maps     

Dirk Kraaijpoel  Tijmen Jan Moser 《Studia Geophysica et Geodaetica》2012,56(1):21-34

Seismic ray tracing in layered media becomes complicated and demanding when modeling for multiple ray codes (reflection/transmission sequences) and/or dense acquisition geometries. However, we observe some redundancies in current algorithms: (a) the same layers are crossed repeatedly by similar ray segments, and (b) the effort of tracing through a layer is determined by variations in the incoming wavefront rather than the medium. We deal with these redundancies by separating the modeling process in two stages: (Stage 1) compute ray field maps representing all ray segments between each pair of adjacent interfaces, then (Stage 2) for each desired ray code assemble the complete ray field from ray segments by iterative lookup in the ray field maps.  相似文献