Boundedness of Turbulent Temperature Probability Distributions,and their Relation to the Vertical Profile in the Convective Boundary Layer   总被引：3，自引：3，他引：0  

Alexander Graf  Dirk Schüttemeyer  Heiner Geiß  Axel Knaps  Michael Möllmann-Coers  Jan H. Schween  Stefan Kollet  Bruno Neininger  Michael Herbst  Harry Vereecken 《Boundary-Layer Meteorology》2010,134(3):459-486

Higher-order moments, minima and maxima of turbulent temperature and water vapour mixing ratio probability density functions measured with an eddy-covariance system near the ground were related to each other and to vertical boundary-layer profiles of the same scalars obtained through airborne soundings. The dependence of kurtosis on squared skewness showed a kurtosis intercept below the Gaussian expectation, suggesting a compression of the probability density function by the presence of natural boundaries. This hypothesis was corroborated by comparing actual minima and maxima of turbulent fluctuations to estimates obtained from the first four sample moments by fitting a four-parameter beta distribution. The most sharply defined boundaries were found for the minima of temperature datasets during the day, indicating that negative temperature fluctuations at the sensor are limited by the availability of lower temperatures in the boundary layer. By comparison to vertical profiles, it could be verified that the turbulent minimum of temperature near the ground is close to the minimum of potential temperature in the boundary layer. The turbulent minimum of water vapour mixing ratio was found to be equal to the mixing ratio at a height above the minimum of the temperature profile. This height roughly agrees with the top of the non-local unstable domain according to bulk Richardson number profiles. We conclude that turbulence statistics measured near the surface cannot be solely explained by local effects, but contain information about the whole boundary layer including the entrainment zone.  相似文献   

Diurnal and Seasonal Trends in Convective Mixed-Layer Heights Estimated from Two Years of Continuous Ceilometer Observations in Vancouver,BC     

Derek van der Kamp  Ian McKendry 《Boundary-Layer Meteorology》2010,137(3):459-475

Twenty-six months of continuous ceilometer data are used to estimate the convective mixed-layer height for 710 days by identifying backscatter gradients associated with the entrainment zone. To accomplish this, a semi-automatic procedure is developed that removes all non-applicable data before applying a mixed-layer height algorithm to the backscatter profiles. Two different algorithms for estimating the mixed-layer height are assessed: the minimum-gradient method and the ideal-profile method. The latter of these two algorithms is found to be more robust. Comparisons of mixed-layer height values estimated from the ceilometer agree with previous observations with slightly higher estimates in the mornings and evenings. For clear days with no cumulus cloud formation, the seasonal cycle in mixed-layer heights peaks in late June to early July. Daily maximum values are suppressed by the site’s coastal location, remaining below 800 m for all but a few days. The mean daily maximum mixed-layer height increases by 384 m for days with boundary-layer clouds. The mean summer diurnal trend is found not to differ greatly from that in spring on clear days, while days with boundary-layer clouds have higher spring values than in summer. Net surface heat flux and synoptic stability likely have the largest influence on the mixed-layer heights. Additionally, large intra-monthly variability suggests a strong influence from regional dynamics.  相似文献   

Study of the total lightning activity in a hailstorm   总被引：1，自引：0，他引：1  

Joan Montany  Serge Soula  Nicolau Pineda  Oscar van der Velde  Pere Clapers  Glria Sol  Joan Bech  D. Romero 《Atmospheric Research》2009,91(2-4):430-437

A thunderstorm that developed over northeastern Spain on 16 June 2006 is analyzed. This severe thunderstorm produced hailstones as large as 40 mm and had a lifetime of 3 h and 30 min. Radar cross-sections show strong vertical development with cloud echo tops reaching an altitude of 13 km. The specific characteristics of the lightning activity of this storm were: (i) a large amount (81%) of negative cloud-to-ground (−CG) flashes with very low peak currents (< 10 kA in absolute value), (ii) a very large proportion of intra-cloud (IC) flashes with an IC/CG ratio reaching about 400, (iii) a large number of “short” IC flashes (with only 1-VHF source according to SAFIR detection), (iv) a large increase of the −CG flash rate and of the CG proportion near the end of the storm. The rate of −CG flashes with a low peak current were observed to evolve similarly to the rates of IC flashes. Most of them have been assumed to be IC flashes misclassified by the Spanish Lightning Detection Network (SLDN). They have been filtered as it is usually done for misclassified +CG flashes. After this filtering, CG flash rates remained very low (< 1 min^− 1) with +CG flashes sometimes dominant. All the particular lightning activity characteristics similar to those observed in the Severe Thunderstorm Electrification and Precipitation Study (STEPS) campaigns support the hypothesis that this thunderstorm could have had an inverted-polarity or complex charge structure. The maximum IC flash rate (67 min^− 1) peaked 24 min before the presence of reflectivity higher than 60 dBZ. The IC activity abruptly decreased during the period when reflectivity was dramatically increasing. The time of maximum reflectivity observed by radar was consistent with the times of reported hail at the ground.  相似文献   

Identification, definition and quantification of goods and services provided by marine biodiversity: implications for the ecosystem approach     

Beaumont NJ  Austen MC  Atkins JP  Burdon D  Degraer S  Dentinho TP  Derous S  Holm P  Horton T  van Ierland E  Marboe AH  Starkey DJ  Townsend M  Zarzycki T 《Marine pollution bulletin》2007,54(3):253-265

This paper identifies and defines ecosystem goods and services provided by marine biodiversity. Case studies have been used to provide an insight into the practical issues associated with the assessment of marine ecosystem goods and services at specific locations. The aim of this research was to validate the definitions of goods and services, and to identify knowledge gaps and likely difficulties of quantifying the goods and services. A validated theoretical framework for the assessment of goods and services is detailed, and examples of the goods and services at a variety of case study areas are documented. These results will enable future assessments of marine ecosystem goods and services. It is concluded that the utilisation of this goods and services approach has the capacity to play a fundamental role in the Ecosystem Approach, by enabling the pressures and demands of society, the economy and the environment to be integrated into environmental management.  相似文献   

Dating bedrock gorge incision in the French Western Alps (Ecrins-Pelvoux massif) using cosmogenic ¹⁰Be     

Pierre G. Valla  Peter A. van der Beek  Julien Carcaillet 《地学学报》2010,22(1):18-25

We report in-situ produced ¹⁰Be data from the Gorge du Diable (French Western Alps) to date and quantify bedrock gorge incision into a glacial hanging valley. We sampled gorge sidewalls and the active channel bed to derive both long-term and present-day incision rates. ¹⁰Be ages of sidewall profiles reveal rapid incision through the late Holocene (ca 5 ka) at rates ranging from 6.5 to 13 mm yr⁻¹. Present-day incision rates are significantly lower and vary from 0.5 to 3 mm yr⁻¹ within the gorge. Our data imply either delayed initiation of gorge incision after final ice retreat from internal Alpine valleys at ca 12 ka, or post-glacial surface reburial of the gorge. Our results suggest that fluvial incision rates >1 cm yr⁻¹ into crystalline bedrock may be encountered in transient landscape features induced by glacial-interglacial transitions.  相似文献   

Titanium in subduction zone fluids: First insights from abinitio molecular metadynamics simulations     

Jelle van Sijl  Neil L. Allan  Wim van Westrenen 《Geochimica et cosmochimica acta》2010,74(9):2797-7377

The preferential incorporation of High-Field-Strength Elements (HFSE) in rutile (TiO₂), combined with its supposed stability in subduction zone settings, make it an ideal candidate to explain the low HFSE concentrations in subduction-derived magmas. The solubility behaviour of rutile is key to these arguments, but at present experimental and field-based evidence are contradictory.We have used abinitio molecular (meta)dynamics to investigate the coordination environment of Ti(IV) in pure water at 300 and 1000 K and densities ranging from 900-1260 kg m⁻³ (approximate pressures 0.9-3.6 GPa). In all high temperature simulations, the long-range structure of the solvent indicates a breakdown of the hydrogen bonding network as expected for supercritical water. The five-fold coordination of titanium to water is energetically most favourable in aqueous fluids at room temperature and pressure, separated from four and six-fold configurations by ∼175 and ∼200 kJ mol⁻¹, respectively. The average first shell Ti-O distance is 2.00 Å, in excellent agreement with bond lengths obtained from experiments. At similar densities and 1000 K, titanium is on average six-fold coordinate with water, and shows some degree of water dissociation in the first hydration shell. This coordination environment is remarkably persistent with increasing density from 1021 to 1260 kg m⁻³ at constant temperature (1000 K). At lower densities, however, (900 kg m⁻³ at 1000 K), the coordination with first shell water molecules is less than five. The observed coordination changes could promote association of titanium with peralkaline or peraluminous domains in the aqueous fluid, and thereby explain field-and laboratory based evidence of enhanced HFSE concentrations.This study demonstrates that abinitio molecular dynamics has considerable potential to access details of element behaviour in aqueous fluids at geologically relevant conditions that are impossible to examine otherwise. Changes in the solvent structure due to density variations lead to differences in solvent behaviour allowing access to new domains for fluid-solid interaction. Moreover, changes in the solvent structure are strongly linked to the effectiveness of element solvation.  相似文献   

New indices and calibrations derived from the distribution of crenarchaeal isoprenoid tetraether lipids: Implications for past sea surface temperature reconstructions   总被引：3，自引：0，他引：3  

Jung-Hyun Kim  Jaap van der Meer  Peer Helmke  Francesca Sangiorgi  Ellen C. Hopmans 《Geochimica et cosmochimica acta》2010,74(16):4639-4654

Several studies have shown that there is a strong relationship between the distribution of crenarchaeotal isoprenoid glycerol dibiphytanyl glycerol tetraethers (GDGTs) and sea surface temperature (SST). Based on this, a ratio of certain GDGTs, called TEX₈₆ (TetraEther indeX of tetraethers consisting of 86 carbon atoms), was developed as a SST proxy. In this study, we determined the distribution of crenarchaeotal isoprenoid GDGTs in 116 core-top sediments mostly from (sub)polar oceans and combined these data with previously published core-top data. Using this extended global core-top dataset (n = 426), we re-assessed the relationship of crenarchaeal isoprenoid GDGTs with SST. We excluded data from the Red Sea from the global core-top dataset to define new indices and calibration models, as the Red Sea with its elevated salinity appeared to behave differently compared to other parts of the oceans. We tested our new indices and calibration models on three different paleo datasets, representing different temperature ranges. Our results indicate that the crenarchaeol regio-isomer plays a more important role for temperature adaptation in (sub)tropical oceans than in (sub)polar oceans, suggesting that there may be differences in membrane adaptation of the resident crenarchaeotal communities at different temperatures. We, therefore, suggest to apply two different calibration models. For the whole calibration temperature range (−3 to 30 °C), a modified version of TEX₈₆ with a logarithmic function which does not include the crenarchaeol regio-isomer, called , is shown to correlate best with SST: (r² = 0.86, n=396, p <0.0001). Application of on sediments from the subpolar Southern Ocean results in realistic absolute SST estimates and a similar SST trend compared to a diatom SST record from the same core. , which is defined as the logarithmic function of TEX₈₆, yields the best correlation with SST, when the data from the (sub)polar oceans are removed: (r² = 00.87, n = 255, p < 0.0001). Furthermore, gives the best correlation for mescosm data with temperatures ranging between 10 and 46 °C. For Quaternary sediments from the tropical Arabian Sea, both and yield similar trends and SST estimates. However, the extrapolation of calibration on a sediment record from a greenhouse world ocean predicts more reliable absolute SST estimates and relative SST changes in agreement with estimates based on the δ¹⁸O of planktonic foraminifera. Based on the comparison of and derived SSTs using the core top data, we recommend applying above 15 °C and below 15 °C. In cases where paleorecords encompass temperatures both below and above 15 °C, we suggest to use .  相似文献   

Social networks in spatial data infrastructures     

P. A. J. van Oort  G. W. Hazeu  H. Kramer  A. K. Bregt  F. I. Rip 《GeoJournal》2010,75(1):105-118

Data sharing over the internet is increasingly efficient and increasingly anonymous. This growing anonymity makes it difficult for data users to exchange feedback: interesting ideas, innovations, ancillary data, concerns about data quality, etcetera. For data producers not knowing the end-users makes it more difficult to collect end-user feedback and tailor the production process to users needs. Feedback can be exchanged through social networks, in other words contacts with other users. Very little is known about such social networks in the case of data sharing. In this paper we present an analysis of the social networks associated with two land cover datasets. We found that most users have zero to two links to other users and virtually no links to users in other her organisations. Without these links, it seems almost impossible to identify users of a particular dataset. Internet technology can help but is currently not used to enhance exchange of feedback within the user community.  相似文献   

Clay smear processes in mechanically layered sequences — Results of water-saturated model experiments with free top surface     

Joyce Schmatz  Marc Holland  Steffen Giese  Wouter van der Zee  Janos. L. Urai 《Journal of the Geological Society of India》2010,75(1):74-88

The aim of this study is to improve our knowledge of the processes that lead to clay smear during faulting of a layered sand-clay sequence in an analogue sandbox model. We carefully characterized mechanical properties of the materials used by a series of geotechnical tests. Displacement field was quantified using PIV (Particle Image Velocimetry). The model is water-saturated to allow the deformation of wet clay and sand in one experiment comprising a sand package with a horizontal layer of clay above a predefined rigid basement fault. The thickness and rigidity of the clay layer are the parameters varied in this study. The model shows a range of structures that are related to competence contrast between sand and different clay types. Results show ductile shearing of soft clay with a transition to brittle fracturing of stiff clay accompanied by the formation of rotating clay blocks in the fault zone. Localized deformation is observed through time showing (i) the propagation of one active fault migrating laterally through the sediment package, and (ii) the formation of a stable prism between two or more active faults that gets progressively smaller with minor rotation of the hanging wall fault. Continuous clay smear is observed resulting from the lateral injection of clay as well as from a reworked mixture of sand and clay.  相似文献   

Experimental and computational study of trace element distribution between orthopyroxene and anhydrous silicate melt: substitution mechanisms and the effect of iron     

Mirjam van Kan Parker  Axel Liebscher  Dirk Frei  Jelle van Sijl  Wim van Westrenen  Jon Blundy  Gerhard Franz 《Contributions to Mineralogy and Petrology》2010,159(4):459-473

Although orthopyroxene (Opx) is present during a wide range of magmatic differentiation processes in the terrestrial and lunar mantle, its effect on melt trace element contents is not well quantified. We present results of a combined experimental and computational study of trace element partitioning between Opx and anhydrous silicate melts. Experiments were performed in air at atmospheric pressure and temperatures ranging from 1,326 to 1,420°C in the system CaO–MgO–Al₂O₃–SiO₂ and subsystem CaO–MgO–SiO₂. We provide experimental partition coefficients for a wide range of trace elements (large ion lithophile: Li, Be, B, K, Rb, Sr, Cs, Ba, Th, U; rare earth elements, REE: La, Ce, Nd, Sm, Y, Yb, Lu; high field strength: Zr, Nb, Hf, Ta, Ti; transition metals: Sc, V, Cr, Co) for use in petrogenetic modelling. REE partition coefficients increase from $ D_{\text{La}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.0005 Although orthopyroxene (Opx) is present during a wide range of magmatic differentiation processes in the terrestrial and lunar mantle, its effect on melt trace element contents is not well quantified. We present results of a combined experimental and computational study of trace element partitioning between Opx and anhydrous silicate melts. Experiments were performed in air at atmospheric pressure and temperatures ranging from 1,326 to 1,420°C in the system CaO–MgO–Al₂O₃–SiO₂ and subsystem CaO–MgO–SiO₂. We provide experimental partition coefficients for a wide range of trace elements (large ion lithophile: Li, Be, B, K, Rb, Sr, Cs, Ba, Th, U; rare earth elements, REE: La, Ce, Nd, Sm, Y, Yb, Lu; high field strength: Zr, Nb, Hf, Ta, Ti; transition metals: Sc, V, Cr, Co) for use in petrogenetic modelling. REE partition coefficients increase from $ D_{\text{La}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.0005 $ D_{\text{La}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.0005 to $ D_{\text{Lu}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.109 $ D_{\text{Lu}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.109 , D values for highly charged elements vary from $ D_{\text{Th}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0026 $ D_{\text{Th}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0026 through $ D_{\text{Nb}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0033 $ D_{\text{Nb}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0033 and $ D_{\text{U}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0066 $ D_{\text{U}}^{{{\text{Opx}} {\hbox{-}} {\text{melt}}}} \sim 0.0066 to $ D_{\text{Ti}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.058 $ D_{\text{Ti}}^{{\text{Opx}} {\hbox{-}} {\text{melt}}} \sim 0.058 , and are all virtually independent of temperature. Cr and Co are the only compatible trace elements at the studied conditions. To elucidate charge-balancing mechanisms for incorporation of REE into Opx and to assess the possible influence of Fe on Opx-melt partitioning, we compare our experimental results with computer simulations. In these simulations, we examine major and minor trace element incorporation into the end-members enstatite (Mg₂Si₂O₆) and ferrosilite (Fe₂Si₂O₆). Calculated solution energies show that R²⁺ cations are more soluble in Opx than R³⁺ cations of similar size, consistent with experimental partitioning data. In addition, simulations show charge balancing of R³⁺ cations by coupled substitution with Li⁺ on the M1 site that is energetically favoured over coupled substitution involving Al–Si exchange on the tetrahedrally coordinated site. We derived best-fit values for ideal ionic radii r ₀, maximum partition coefficients D ₀, and apparent Young’s moduli E for substitutions onto the Opx M1 and M2 sites. Experimental r ₀ values for R³⁺ substitutions are 0.66–0.67 ? for M1 and 0.82–0.87 ? for M2. Simulations for enstatite result in r ₀ = 0.71–0.73 ? for M1 and ~0.79–0.87 ? for M2. Ferrosilite r ₀ values are systematically larger by ~0.05 ? for both M1 and M2. The latter is opposite to experimental literature data, which appear to show a slight decrease in $ r_{0}^{{{\text{M}}2}} $ r_{0}^{{{\text{M}}2}} in the presence of Fe. Additional systematic studies in Fe-bearing systems are required to resolve this inconsistency and to develop predictive Opx-melt partitioning models for use in terrestrial and lunar magmatic differentiation models.  相似文献