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52.
A rapid sample preparation procedure is described to determine trace element compositions of peridotites using LA‐ICP‐MS. Peridotite powders were fused with albite in a molybdenum–graphite assembly to obtain homogeneous glasses. Best conditions for the fusion procedure (heating at 1500–1550 °C for 10–15 min with a sample‐to‐flux ratio of 1:2) were constrained with melting experiments on two USGS reference materials, PCC‐1 and DTS‐2B. Mass fractions of first series transition elements, Ba and Pb, in quenched glasses of PCC‐1 and DTS‐2B are consistent with published data within 10% RSD. Three spinel peridotite xenoliths from eastern China were analysed following both our method and conventional solution ICP‐MS. Compared with solution ICP‐MS, the relative deviations of our method for most elements were within 10%, while for the REE, Ta, Pb, Th and U, the relative deviations were within 20%. In particular, volatile elements (e.g., Pb and Zn) are retained in the glass. Compared with conventional wet chemistry digestion, our method is faster. Additional advantages are complete sample fusion, especially useful for samples with acid‐resistant minerals (spinel and rutile), and long‐term conservation of glasses allowing unlimited repeated measurements with microbeam techniques. The same approach can be used for analyses of other mantle rocks, such as eclogites and pyroxenites.  相似文献   
53.
The ring laser gyroscope ??G-Pisa?? has been taking data inside the Virgo interferometer central area with the aim of performing high sensitivity measurements of rotations in the vertical as well as in the horizontal orientation. We discuss the main characteristics of the instrument, describing its mechanical design and presenting the measured sensitivity limit. By applying a simple effective model for the laser gyroscope, we show that the stability of the sensor above 10?s of integration time is mainly limited by backscattering effects. The horizontal rotation rate signal is also compared with the signals recorded by the Virgo environmental monitoring system and by a biaxial mechanical tiltmeter rigidly fixed on top of the gyrolaser mounting frame.  相似文献   
54.
Sea surface height anomalies observed by satellites in 1992–2010 are combined with monthly climatologies of temperature and salinity to estimate circulation in the southern Bering Sea. The estimated surface and deep currents are consistent with independent velocity observations by surface drifters and Argo floats parked at 1,000?m. Analysis reveals 1–3-Sv interannual transport variations of the major currents with typical intra-annual variability of 3–7?Sv. On the seasonal scale, the Alaskan Stream transport is well correlated with the Kamchatka (0.81), Near Strait (0.53) and the Bering Slope (0.37) currents. Lagged correlations reveal a gradual increase of the time the lags between the transports of the Alaskan Stream, the Bering Slope Current and the Kamchatka Current, supporting the concept that the Bering Sea basin is ventilated by the waters carried by the Alaskan Stream south of the Aleutian Arc and by the flow through the Near Strait. Correlations of the Bering Sea currents with the Bering Strait transport are dominated by the seasonal cycle. On the interannual time scale, significant negative correlations are diagnosed between the Near Strait transport and the Bering Slope and Alaskan Stream currents. Substantial correlations are also diagnosed between the eddy kinetic energy and Pacific Decadal Oscillation.  相似文献   
55.
Partial melting and reactive melt transport may change the composition, microstructures, and physical properties of mantle rocks. Here we explore the relations between deformation and reactive melt transport through detailed microstructural analysis and crystallographic orientation measurements in spinel peridotite xenoliths that sample the shallow lithospheric mantle beneath the southeastern rim of the Siberian craton. These xenoliths have coarse-grained, annealed microstructures and show petrographic and chemical evidence for variable degrees of reaction with silicate melts and fluids, notably Fe-enrichment and crystallization of metasomatic clinopyroxene (cpx). Olivine crystal preferred orientations (CPO) range from strong to weak. [010]-fiber patterns, characterized by a point concentration of [010] normal to the foliation and by dispersion of [100] in the foliation plane with a weak maximum parallel to the lineation, predominate relative to the [100]-fiber patterns usually observed in lithospheric mantle xenoliths and peridotite massifs. Variations in olivine CPO patterns or intensity are not correlated with modal and chemical compositions. This, together with the analysis of microstructures, suggests that reactive melt percolation postdated both deformation and static recrystallization. Preferential crystallization of metasomatic cpx along (010) olivine grain boundaries points to an influence of the preexisting deformation fabrics on melt transport, with higher permeability along the foliation. Similarity between orthopyroxene (opx) and cpx CPO suggests that cpx orientations may be inherited from those of opx during melt-rock reaction. As observed in previous studies, reactive melt transport does not weaken olivine CPO and seismic anisotropy in the upper mantle, except in melt accumulation domains. In contrast, recovery and selective grain growth during static recrystallization may lead to development of [010]-fiber olivine CPO and, if foliations are horizontal, result in apparent isotropy for vertically propagating SKS waves, but strong anisotropy for horizontally propagating surface waves.  相似文献   
56.
We report new textural and chemical data for 10 garnet peridotite xenoliths from the Udachnaya kimberlite and examine them together with recent data on another 21 xenoliths from the 80–220 km depth range. The samples are very fresh (LOI near zero), modally homogeneous and large (>100 g). Some coarse-grained peridotites show incipient stages of deformation with <10 % neoblasts at grain boundaries of coarse olivine. Such microstructures can only be recognized in very fresh rocks, because fine-grained interstitial olivine is strongly affected by alteration, and may have been overlooked in previous studies of altered peridotite xenoliths in the Siberian and other cratons. Some of the garnet peridotites are similar in composition to low-opx Udachnaya spinel harzburgites (previously interpreted as pristine melt extraction residues), but the majority show post-melting enrichments in Fe and Ti. The least metasomatized coarse peridotites were formed by 30–38 % of polybaric fractional melting between 7 and 4 GPa and ≤1–3 GPa. Our data together with experimental results suggest that garnet in these rocks, as well as in some other cratonic peridotites elsewhere, may be a residual mineral, which has survived partial melting together with olivine and opx. Many coarse and all deformed garnet peridotites from Udachnaya underwent modal metasomatism through interaction of the melting residues with Fe-, Al-, Si-, Ti-, REE-rich melts, which precipitated cpx, less commonly additional garnet. The xenoliths define a complex geotherm probably affected by thermal perturbations shortly before the intrusion of the host kimberlite magmas. The deformation in the lower lithosphere may be linked to metasomatism.  相似文献   
57.
The current generation of hydrological models has been widely criticized for their inability to adequately simulate hydrological processes. In this study, we evaluate competing model representations of hydrological processes with respect to their capability to simulate observed processes in the Mahurangi River basin in Northland, New Zealand. In the first part of this two‐part series, the precipitation, soil moisture, and flow data in the Mahurangi were used to estimate the dominant hydrological processes and explore several options for their suitable mathematical representation. In this paper, diagnostic tests are applied to gain several insights for model selection. The analysis highlights dominant hydrological processes (e.g. the importance of vertical drainage and baseflow compared to sub‐surface stormflow), provides guidance for the choice of modelling approaches (e.g. implicitly representing sub‐grid heterogeneity in soils), and helps infer appropriate values for model parameters. The approach used in this paper demonstrates the benefits of flexible model structures in the context of hypothesis testing, in particular, supporting a more systematic exploration of current ambiguities in hydrological process representation. The challenge for the hydrological community is to make better use of the available data, not only to estimate parameter values but also to diagnostically identify more scientifically defensible model structures. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
58.
This paper deals with the integration of electrical resistivity tomography and geochemical methods for studying four different fire-prone landfills. Landfill gas composition (CH4, H2S, O2, CO, CO2) and subsurface temperature were measured with the constant net 50 × 50 m from the depth 10–60 cm. 28 electrical resistivity tomography lines were surveyed, while Wenner and Sclumberger electrode arrays were employed for all measurements. At the studied sites the landfill gas and temperature measurements mapped gas and temperature anomalies over underground fire sources. 2D electrical resistivity tomography lines, performed over these anomalies, showed these fire sources as high-resistivity zones. The joint employment of the electrical imaging and geochemical survey seems to be a useful tool in carrying out diagnostic investigations at fire-prone landfills.  相似文献   
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60.
Two 14C accelerator mass spectrometry (AMS) wiggle‐match dated peat sequences from Denmark and northern England record changes in mire surface wetness reconstructed using plant macrofossil and testate amoebae analyses. A number of significant mid–late Holocene climatic deteriorations (wet shifts) associated with declines in solar activity were recorded (at ca. 2150 cal. yr BC, 740 cal. yr BC, cal. yr AD 930, cal. yr AD 1020, cal. yr AD 1280–1300, cal. yr AD 1640 and cal. yr AD 1790–1830). The wet shifts identified from ca. cal. yr AD 930 are concurrent with or lag decreases in solar activity by 10–50 years. These changes are replicated by previous records from these and other sites in the region and the new records provide improved precision for the ages of these changes. The rapidly accumulating (up to 2–3 yr cm?1, ~1310 yr old, 34 14C dates) Danish profile offers an unprecedented high‐resolution record of climate change from a peat bog, and has effectively recorded a number of significant but short‐lived climate change events since ca. cal. yr AD 690. The longer time intervals between samples and the greater length of time resolved by each sample in the British site due to slower peat accumulation rates (up to 11 yr cm?1, ~5250 yr old, 42 14C dates) acted as a natural smoothing filter preventing the clear registration of some of the rapid climate change events. Not all the significant rises in water table registered in the peat bog archives of the British and Danish sites have been caused by solar forcing, and may be the result of other processes such as changes in other external forcing factors, the internal variability of the climate system or raised bog ecosystem. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
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