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61.
Large laboratory columns (15.2 cm diameter, 183 cm long) were fed with groundwater containing trichloroethylene (TCE), were biostimulated and bioaugmented, and were monitored for over 7.5 years. The objective of the study was to observe how the selection of the carbon and energy source, i.e., whey, Newman Zone® standard surfactant emulsified oil and Newman Zone nonionic surfactant emulsified oil, affected the rate and extent of dechlorination. Column effluent was monitored for TCE and its degradation products, redox indicators (nitrate‐N, Fe(II), sulfate), and changes in iron mineralogy. Total bacteria and Dehalococcoides mccartyi strains were quantified using q‐PCR. Complete dechlorination was only observed in the whey treated columns, occurring 1 year after bioaugmentation with addition of a culture known to dechlorinate TCE to ethene, and 3 years later in the non‐bioaugmented column. The addition of the emulsified oils with or without bioaugmentation resulted in dechlorination only through cis‐DCE and vinyl chloride. While Dehalococcoides mccartyi strains are the only known bacteria that can fully dechlorinate TCE, their presence, either natural or augmented, was not the sole determiner of complete dechlorination. The establishment of a supporting microbial community and biogeochemistry that developed with continuous feeding of whey, in addition to the presence of D. mccartyi, were necessary to support complete reductive dechlorination. Results confirm that careful selection of a biostimulant is critical to the success of TCE dechlorination in complex soil environments.  相似文献   
62.
Environmental data sets are often multidimensional and consequently display complex structure. This article shows the limitations of principal component analysis (PCA) for the study of such three-dimensional (3D) data sets. These limitations can be resolved by the use of the statistical tool STATIS. The inlet (a swallow hole) and the outlet (a spring) of a karst system of the Western Paris basin were sampled during three rain events of various intensities. These 3D geochemical data sets (variables × sites × dates) for a karst system were analyzed by STATIS method to identify hydrological processes. STATIS proceeds in three steps (interstructure, compromise, and intrastructure), which allows us to focus the analysis of hydrologic systems at different temporal and spatial scales. Compromise plane shows that suspended matter and flood are not simultaneous and highlights a rapid flow, characterized by turbidity and phosphate, which represents a point source contamination, and a ground water flow contaminated by nitrate. Intrastructure plane allows us to compare hydrochemical variations between the swallow hole and the spring lead. By this way, hydrological processes such as direct transfer and resuspension of intrakarstic sediments before and after the flood were identified what cannot be realized by comparison of inlet and outlet breakthrough curves. Finally, results obtained from the same data set by STATIS and a coupled study using PCA and normalized hysteresis curves were compared. This comparison shows the efficiency of STATIS at the identification of transport processes and vulnerability of karst system and its potential for hydrological applications.  相似文献   
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64.
Forested landscapes often exhibit large spatial variability in vertical and horizontal foliage distributions. This variability may affect canopy-atmosphere exchanges through its action on the development of turbulent structures. Here we investigate in neutral stratification the turbulent structures encountered in a maritime pine forest characterized by a high, dense foliated layer associated with a deep and sparse trunk space. Both stand and edge regions are considered. In situ measurements and the results of large-eddy simulations are used and analyzed together. In stand conditions, far from the edge, canopy-top structures appear strongly damped by the dense crown layer. Turbulent wind fluctuations within the trunk space, where the momentum flux vanishes, are closely related to these canopy-top structures through pressure diffusion. Consequently, autocorrelation and spectral analyses are not quite appropriate to characterize the vertical scale of coherent structures in this type of canopy, as pressure diffusion enhances the actual scale of structures. At frequencies higher than those associated with canopy-top structures, wind fluctuations related to wake structures developing behind tree stems are observed within the trunk space. They manifest themselves in wind velocity spectra as secondary peaks in the inertial subrange region, confirming the hypothesis of spectral short-cuts in vegetation canopies. In the edge region specific turbulent structures develop just below the crown layer, in addition to canopy-top structures. They are generated by the wind shear induced by the sub-canopy wind jet that forms at the edge. These structures provide a momentum exchange mechanism similar to that observed at the canopy top but in the opposite direction and with a lower magnitude. They may develop as in plane mixing-layer flows, with some perturbations induced by canopy-top structures. Wake structures are also observed within the trunk space in the edge region.  相似文献   
65.
The temporal variability of water-level fluctuations in the chalk aquifer of Upper Normandy, France is constrained by natural climate fluctuations and is closely linked to the regional geological patterns. The chalk plateaus are covered with 5–50 m thick semi-permeable surficial formations; the thickness of the underlying chalk aquifer varies from 50 to 300 m. The relationship among climate oscillations, piezometric levels, and geologic structure were investigated by correlation, Fourier spectral, and continuous wavelet analyses of selected piezometric time-series data. Analysis focused on two piezometers located on the uplifted side of a major fault and two piezometers on the downthrown side. After generalization to other piezometers in the region, it was deduced that, in the downthrown compartments, a substantial aquifer and surficial formations thickness would imply a strong attenuation of annual variability, while multi-year variability is clearly expressed. Conversely, in the uplifted compartments, a thin layer of surficial formations and small thickness of the chalk authorizes strong variations on the annual mode with respect to the contribution of long-term climatic oscillations (multi-year variability). The results then demonstrated—and proposed a spatial determination of—the differential influence of geological patterns on the filtering of climate-induced oscillations in piezometric variability.  相似文献   
66.
This paper analyses the meteorological numerical simulation in Paris during two days (March 10 and 13, 1995) observed during ECLAP (Etude de la Couche Limite en Agglomération Parisienne– the boundary-layer study of the Paris area), a recent measurement campaign over the Paris area, in which both in-situ and remote-sensing devices at urban and rural locations have been deployed in addition to the operational meteorological network. The chosen days are well documented and correspond to different meteorological situations leading to pollution events (regarding wind direction, cloud cover, surface and synoptic inversion strength).Comparisons of three-dimensional mesoscale model results with the ECLAP observation data are presented, focusing on the temperature field and turbulent fluxes along with the urban heat island and the evolution of the mixing height. It is shown that the model correctly reproduces the main characteristics of the temperature field, its diurnal evolution (near the ground and higher up) especially the gradient between Paris and the surrounding countryside. The mixing-height evolutions are in a good agreement with the observations and the model is also able to reproduce the turbulent features of the atmosphere. The small difference observed between the urban and rural mixing-height evolution is also well reproduced.  相似文献   
67.
The general aim of this paper is to evaluate the influence of panning on the map user’s (attentive) behaviour, using a mixed methods approach. A user study was conducted in which participants – with an expertise in cartography – had to execute four tasks in Google Maps, using only a panning operation. During the first two tasks, participants had to follow a predefined route; during the latter two tasks they had to locate Belgium on a less detailed scale level. A strong task-related interactive behaviour was revealed by the participants’ mouse action and eye movements. Furthermore, the attentive behaviour was influenced by the type of view (map or satellite) and whether it occurs while performing the panning operation. The georeferenced eye movements were imported in a GIS for spatial analysis. Based on these spatial queries, we discovered that the duration of the fixations was associated by their location on the map.  相似文献   
68.
Landscape discontinuities such as forest edges play an important role in determining the characteristics of the atmospheric flow by generating increased turbulence and triggering the formation of coherent tree-scale structures. In a fragmented landscape, consisting of surfaces of different heights and roughness, the multiplicity of edges may lead to complex patterns of flow and turbulence that are potentially difficult to predict. Here, we investigate the effects of different levels of forest fragmentation on the airflow. Five gap spacings (of length approximately 5h, 10h, 15h, 20h, 30h, where h is the canopy height) between forest blocks of length 8.7h, as well as a reference case consisting of a continuous forest after a single edge, were investigated in a wind tunnel. The results reveal a consistent pattern downstream from the first edge of each simulated case, with the streamwise velocity component at tree top increasing and turbulent kinetic energy decreasing as gap size increases, but with overshoots in shear stress and turbulent kinetic energy observed at the forest edges. As the gap spacing increases, the flow appears to change monotonically from a flow over a single edge to a flow over isolated forest blocks. The apparent roughness of the different fragmented configurations also decreases with increasing gap size. No overall enhancement of turbulence is observed at any particular level of fragmentation.  相似文献   
69.
The tectonic evolution of the Tian Shan, as for most ranges in continental Asia is dominated by north‐south compression since the Cenozoic India‐Asia collision. However, precollision governing tectonic processes remain enigmatic. An excellent record is provided by thick Palaeozoic – Cenozoic lacustrine to fluvial depositional sequences that are well preserved in the southern margin of the Junggar Basin and exposed along a foreland basin associated to the Late Cenozoic rejuvenation of the Tian Shan ranges. U/Pb (LA‐ICP‐MS) dating of detrital zircons from 14 sandstone samples from a continuous series ranging in age from latest Palaeozoic to Quaternary is used to investigate changes in sediment provenance through time and to correlate them with major tectonic phases in the range. Samples were systematically collected along two nearby sections in the foreland basin. The results show that the detrital zircons are mostly magmatic in origin, with some minor input from metamorphic zircons. The U‐Pb detrital zircon ages range widely from 127 to 2856 Ma and can be divided into four main groups: 127–197 (sub‐peak at 159 Ma), 250–379 (sub‐peak at 318 Ma), 381–538 (sub‐peak at 406 Ma) and 543–2856 Ma (sub‐peak at 912 Ma). These groups indicate that the zircons were largely derived from the Tian Shan area to the south since a Late Carboniferous basin initiation. The provenance and basin‐range pattern evolution of the southern margin of Junggar Basin can be generally divided into four stages: (1) Late Carboniferous – Early Triassic basin evolution in a half‐graben or post‐orogenic extensional context; (2) From Middle Triassic to Upper Jurassic times, the southern Junggar became a passively subsiding basin until (3) being inverted during Lower Cretaceous – Palaeogene; (4) During the Neogene, a piedmont developed along the northern margin of the North Tian Shan block and Junggar Basin became a true foreland basin.  相似文献   
70.
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