Activity-composition relations of the magnesiowüstite solid solution series in equilibrium with metallic iron in the temperature range 1050–1400 K     

I. Srečec  A. Ender  E. Woermann  W. Gans  E. Jacobsson  G. Eriksson  E. Rosén 《Physics and Chemistry of Minerals》1987,14(6):492-498

The equilibrium $${\text{(1}} - y{\text{)Fe}}_{(s)} + \tfrac{{\text{1}}}{{\text{2}}}{\text{O}}_{{\text{2(g)}}} \rightleftarrows {\text{Fe}}_{{\text{1}} - y} {\text{O}}_{{\text{(}}s,{\text{ in MW)}}} $$ was studied by measuring oxygen potentials for a range of different magnesiowüstite compositions relative to those of the iron-wüstite system in an oxygen concentration cell involving yttria stabilized zirconia as the solid electrolyte. The temperature range covered was 1050 to 1400 K. Separate measurements of the mole fraction of trivalent iron in magnesiowüstite (x(Fe³⁺)) were made and the composition dependence ofx(Fe³⁺) was taken into account in calculations of the activity-composition relations of FeO, Fe_2/3O and MgO.  相似文献   

Late Quaternary western Mediterranean pollen records and African winds     

D. Magri  I. Parra   《Earth and Planetary Science Letters》2002,200(3-4):401-408

Late Quaternary vegetation changes of regional and global significance in the Mediterranean region are generally interpreted as being controlled by changes in the circulation patterns of North Atlantic air masses. However, the possibility cannot be excluded that they may also be related to winds blowing from Africa. Long pollen records from southwest Europe show that Cedrus pollen of northwest African provenance is found during the glacial periods, and occasionally during abrupt deforestation events in the forest-dominated periods of the interglacials. A pollen concentration record from central Italy shows that during the Holocene the presence of Cedrus pollen coincides with two abrupt deforestation events, around 8.1 and 4.2 cal kyr BP. These observations raise the question of a possible influence of eolian activity on arboreal vegetation during phases of climatic stress towards aridity, and suggest the use of modern pollen monitoring as a strategy for revealing tendencies towards aridification in southwestern Europe.  相似文献   

Assessing the geochemical reactivity of inorganic phosphorus along estuaries by means of laboratory simulation experiments     

Enrique García‐Luque  Jesús M. Forja Pajares  Abelardo Gmez‐Parra 《水文研究》2006,20(16):3555-3566

Phosphate behaviour in natural estuarine systems can be studied by performing field measurements and by undertaking laboratory simulation experiments. Thus, in this paper we describe the use of a dynamic automated estuarine simulator to characterize the geochemical reactivity of phosphate in varying salinity gradients in order to study possible mechanisms of phosphate removal from the dissolved phase (e.g. formation of some kind of apatite) and how changes in pH and salinity values influence this removal. Six laboratory assays, representing various salinity and pH gradients (average pH values between 7 and 8), were carried out. The geochemical equilibrium model MINTEQA2 was employed to characterize removal of phosphate. Among the minerals from which dissolved phosphate can originate, it seems that hydroxyapatite is by far the mineral that shows the greatest saturation indexes in the experiments. Thus, there is evidence that a type of calcium phosphate (hydroxyapatite) is involved in phosphate removal in the assays. Phosphate removal by Ca²⁺ occurs sharply at salinity values of 1–2, whereas by Fe³⁺ it is relatively gradual, at least until a salinity value of 7. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

The La Luna formation: chemostratigraphy and organic facies in the Middle Magdalena Basin     

A. Rangel  P. Parra  C. Nio 《Organic Geochemistry》2000,31(12):2694

A detailed geochemical study and a sequence stratigraphic interpretation have been conducted on a sedimentary sequence of the Upper Cretaceous La Luna Formation, in a section outcropping in the eastern flank of the Middle Magdalena Basin (MMB), Colombia. The goals were to evaluate geochemical variability related to lithofacies and organic facies changes, characterize depositional environment and investigate the possible relationship between geochemical data and sequence stratigraphic cycles. The La Luna Formation is composed of organic-rich sediments of monotonous appearance, with good to excellent potential for oil generation. Most of the bulk, petrographic and biomarker parameters display a relatively narrow range of variation. However, the geochemical variations are sufficient to differentiate organic facies types B, BC and C in the Salada Member, B and D in the Pujamana Member and B in the Galembo Member. Certain biomarker ratios are consistent within the La Luna Formation and are characteristic of its depositional environment, for example, average ratios of diasterane/sterane are lower than 1, Ts/Tm averages are less than 0.33, the C₃₅/C₃₄ hopane ratio is more than 0.92, and oleanane/C₃₀ hopane ratios range from 0.02 to 0.19. Regarding depositional condition indicators, the C₃₅/C₃₄ hopane ratio shows a good positive correlation with HI. This suggests that in carbonate environment changes in this parameter are more strongly related to redox condition than to changes in carbonate content. Regarding the possible relationship between organic matter characteristics and sea level changes, in regressive carbonate shelves during shallow stages, HI tends to increase and TOC tends to decrease, while in regressive siliciclastic shelves, both TOC and HI decrease continuously. Some biomarker ratios (oleanane/C₃₀ hopane, C₂₀/C₂₃ tricyclic, Ts/Tm) increase during base level falls. Regarding δ ¹³C/¹²C isotope composition, the aromatic fraction and whole bitumen display an isotopic shift associated to the main deepening event in the section.  相似文献   

Neotethyan Evolution of the Ankara Mélange,Turkey: An Intraoceanic Subduction-Accretion System     

Ender Sar?fak?o?lu  Y?ld?r?m Dilek  Mustafa Sevin 《《地质学报》英文版》2015,89(Z2):9-9

<正>We report here new geochemical and geochronological data from mafic-ultramafic rock suites in the Ankara Mélange in north-central Turkey,and present a new tectonic model for its origin.Considered as one of most important relics of the Neotethyan realm in the region,the Ankara Mélange occurs between the Sakarya Continent  相似文献   

Mesozoic–Cenozoic multistage tectonic evolution of the Pamir: Detrital fission-track constraints from the Tajik Basin     

Lin Li  Yani Najman  Guillaume Dupont-Nivet  Mauricio Parra  Pierrick Roperch  Mustafa Kaya  Niels Meijer  Paul O'Sullivan  Gilby Jepson  Jovid Aminov 《Basin Research》2023,35(2):530-550

Knowledge of the tectonic history of the Pamir contributes to our understanding of both the evolution of collisional orogenic belts as well as factors controlling Central Asian aridification. It is, however, not easy to decipher the Mesozoic–Cenozoic tectonics of the Pamir due to extensive Neogene deformation in an orogen that remains largely understudied. This study reports detrital apatite and zircon fission-track (FT) ages from both the eastern Tajik Basin sedimentary rocks and Pamir modern river sands. These FT data, supported by vitrinite reflectance and zircon and apatite U–Pb double dating, suggest that the majority of the FT ages are unreset and record exhumation stages of the Pamir, which has served as the source terrane of the Tajik Basin since the Cretaceous. Furthermore, we combine the new data with a compilation of published detrital apatite and zircon FT data from both the Tajik Basin sedimentary rocks and Pamir modern river sands, to explore the Mesozoic–Cenozoic tectonic history of Pamir. Deconvolved FT Peak Ages document two major Mesozoic exhumation events associated with the Late Triassic–Early Jurassic Cimmerian orogeny that reflects accretion of the Pamir terranes, as well as the Early–early Late Cretaceous deformation associated with the northward subduction of the Neo-Tethys Ocean beneath Pamir. The compiled data also show significant Late Eocene–Neogene exhumation associated with the ongoing formation of the Pamir, which peaks at ca. 36, 25, 14 and 7 Ma.  相似文献   

SIDRA instrument for measurements of particle fluxes at satellite altitudes. Laboratory prototype     

O. V. Dudnik  M. Prieto  E. V. Kurbatov  S. Sanchez  T. G. Timakova  A. V. Spassky  V. N. Dubina  P. Parra 《Solar System Research》2013,47(1):58-65

The design concept and first set of results are presented for electronic modules of a laboratory prototype of the small-size satellite instrument SIDRA intended for measurements of charged particle fluxes in outer space. The working prototype consists of a detector assembly based on high-purity silicon and fast scintillation detectors, modules of analogue and digital processing, and a secondary power supply module. The first results are discussed of a Monte-Carlo simulation of the instrument with the use of the GEANT4 toolkit and of measurements of the main parameters of charge-sensitive pre-amplifiers, shapers, and peak detectors. Results of calibration measurements with the use of radioactive sources and beams of accelerated charged particles are presented.  相似文献   

Seismic hazard assessment in continental Ecuador     

H. Parra  M. B. Benito  J. M. Gaspar-Escribano 《Bulletin of Earthquake Engineering》2016,14(8):2129-2159

A seismic hazard assessment study of continental Ecuador is presented in this paper. The study begins with a revision of the available information on seismic events and the elaboration of a seismic catalog homogenized to magnitude Mw. Different seismic source definitions are revised and a new area-source model, based on geological and seismic data, is proposed. The available ground motion prediction equations for crustal and subduction sources are analyzed and selected for the tectonic environments observed in Ecuador. A probabilistic seismic hazard assessment approach is carried out to evaluate the exceedance probability of several levels of peak ground acceleration PGA and spectral accelerations SA (T) for periods (T) of 0.1, 0.2, 0.5, 1 and 2s. The resulting hazard maps for continental Ecuador are presented, together with the uniform hazard spectra of four province capital cities. Hazard disaggregation is carried out for target motions defined by the PGA values and SA (1s) expected for return periods of 475 and 2475 years, providing estimates for short-period and long-period controlling earthquakes.  相似文献   

Soil moisture dynamics at high temporal resolution in a semiarid Mediterranean watershed with scattered tree cover   总被引：1，自引：0，他引：1       下载免费PDF全文

Javier Lozano‐Parra  N. L. M. B. van Schaik  Susanne Schnabel  Álvaro Gómez‐Gutiérrez 《水文研究》2016,30(8):1155-1170

Subsurface water flows play a key role in the distribution of water and solutes and thereby in the water availability for plants. However, the characterization of different flow processes (i.e. matrix and preferential flow), the frequency and factors that cause them, is relatively rare. This characterization enables a better understanding of spatio‐temporal variability of water resources and allows for the design of models to be improved. Using a method based on the time derivative of soil moisture variation known as maximum wetting slope, types of soil wetting processes were classified and quantified. For this, capacitance sensors, which registered the volumetric water content at high temporal resolution (30 min) for more than two hydrological years, were installed at different depths and placed in soil moisture stations with different vegetation covers, lithology and topographic position. Results indicated that there is a general behaviour or pattern of soil moisture dynamics in the catchment with a dominant occurrence of slower soil wetting processes (>50%), caused by matrix flows, and a low occurrence of those faster processes (<30%), originated by preferential flows. Nevertheless, when the total volume of water is considered, preferential flow becomes the dominant process, so that the ecological role of both flow types becomes prominent in water‐limited environments. Statistical multivariate analyses based on data‐mining techniques proved that although both flow types depend on variables associated with precipitation and antecedent soil moisture conditions, faster soil wetting processes are mainly related to variables such as rainfall intensity and topography, while slower soil wetting processes are related to flow velocity, soils or vegetation. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Reactive geochemical transport modeling of hydrothermal dolomite fronts: The case of Marjaba dolomite front (Jurassic,Lebanon)     

F.H. Nader  D. Garcia  T. Parra  R. Swennen  R.M. Ellam  S.A. Gleeson 《Journal of Geochemical Exploration》2009

  相似文献