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61.
Vapor intrusion (VI) occurs when volatile contaminants in the subsurface migrate through the vadose zone into overlying buildings. The 2015 U.S. EPA petroleum VI guidance recommends that additional investigation of the VI risk from gasoline hydrocarbons at the underground storage tank (UST) sites is not necessary where the vertical distance between a building and a vapor source exceeds a recommended vertical screening distance. However, due to the lack of soil-gas data on the attenuation of ethylene dibromide (EDB), additional VI investigations to evaluate VI risk from EDB are recommended at UST sites with leaded gasoline releases containing EDB. We analyzed soil-gas and groundwater concentrations of EDB from eight petroleum UST sites using a new analytical method with soil-gas detection limit <0.16 μg/m3 EDB (VI screening level at the 10−6 risk level). The analysis included (1) assessing the frequency of EDB detections ≤0.16 μg/m3 at various vertical separation distances and (2) predicting vertical screening distances for EDB using the U.S. EPA PVIScreen model for different soil types in the vadose zone above dissolved-phase and LNAPL sources. Ranges of estimated aerobic biodegradation rate constants for EDB, air exchange rates for residential buildings, and source vapor concentrations for other constituents were combined with conservative estimates of EDB source concentrations as model inputs. Concentrations of EDB in soil-gas indicated that the U.S. EPA recommended vertical screening distances are protective of VI risk from EDB. Conversely, vertical screening distances predicted by modeling were >6 ft (1.8 m) for sites with sand and loam soil above dissolved phase sources and >15 ft (4.6 m) for sites with sand soil above LNAPL sources. This predicted dependence on the vapor source type and soil type in the vadose zone highlights the importance of soil characterization for VI screening at sites with EDB sources.  相似文献   
62.
Australian farmers navigate their contemporary circumstances through the use of different business and legal arrangements that are shaped by the commercial realities of farming and the aspirations of farm-owning households. In posing the question ‘Family or Enterprise?’, this paper examines the extent to which various household and farm business indicators are associated with different forms of farm ownership, namely sole proprietorships, partnerships, trusts and companies. Results from a postal survey of farm enterprises in Victoria, Australia suggest that both household and enterprise factors contribute to the business structure used, although the strongest determinants appear to be those factors that are less well understood in the rural geographical and sociological literature: household composition, farmer age and farm size. Greater scrutiny of the business instruments deployed by farmers to manage family and enterprise pressures should inform expectations of the fate of family farming in advanced financialised economies.  相似文献   
63.
The Pantanal is the world's largest tropical wetland and a biodiversity hotspot, yet its response to Quaternary environmental change is unclear. To address this problem, sediment cores from shallow lakes connected to the Upper Paraguay River (PR) were analyzed and radiocarbon dated to track changes in sedimentary environments. Stratal relations, detrital particle size, multiple biogeochemical indicators, and sponge spicules suggest fluctuating lake-level lowstand conditions between ~ 11,000 and 5300 cal yr BP, punctuated by sporadic and in some cases erosive flood flows. A hiatus has been recorded from ~ 5300 to 2600 cal yr BP, spurred by confinement of the PR within its channel during an episode of profound regional drought. Sustained PR flooding caused a transgression after ~ 2600 cal yr BP, with lake-level highstand conditions appearing during the Little Ice Age. Holocene PR flood pulse dynamics are best explained by variability in effective precipitation, likely driven by insolation and tropical sea-surface temperature gradients. Our results provide novel support for hypotheses on: (1) stratigraphic discontinuity of floodplain sedimentary archives; (2) late Holocene methane flux from Southern Hemisphere wetlands; and (3) pre-colonial indigenous ceramics traditions in western Brazil.  相似文献   
64.
While extensive Pleistocene loess deposits have been identified across Eurasia, Holocene age loess (typically nonglaciogenic) is rarely recognized. We explore possible loess deposits in the Mureş River Valley of western Romania, providing a regional signal of increased aridity during the mid‐late Holocene. This proposed aridity may be responsible for the abandonment of Middle Bronze Age tell settlements along the major drainages of the eastern Carpathian Basin (Pannonian plain). This hypothesis centers on a proposed aeolian deposit (the “Pecica deposit”), a ca. 50–80 cm thick, relatively homogeneous, gray layer blanketing the top of the Bronze Age tell of Pecica—Şanţul Mare. Comparing the morphological, geochemical, and physical characteristics of this specific tell deposit with two representative profiles near the site containing glaciogenic calcareous loess and potential Holocene loess deposits developed in Chernozems, we find significant similarities to support this hypothesis. We then review various forms of proxy data published from elsewhere in Central and Eastern Europe suggesting a warming trend during this period. The temporal placement of the Pecica deposit is bracketed using diagnostic artifacts, radiocarbon dates, and the degree of soil development, suggesting a period of increased aridity likely occurring soon after the 17th century B.C.  相似文献   
65.
The interest in fishing‐induced life‐history evolution has been growing in the last decade, in part because of the increasing number of studies suggesting evolutionary changes in life‐history traits, and the potential ecological and economic consequences these changes may have. Among the traits that could evolve in response to fishing, growth has lately received attention. However, critical reading of the literature on growth evolution in fish reveals conceptual confusion about the nature of ‘growth’ itself as an evolving trait, and about the different ways fishing can affect growth and size‐at‐age of fish, both on ecological and on evolutionary time‐scales. It is important to separate the advantages of being big and the costs of growing to a large size, particularly when studying life‐history evolution. In this review, we explore the selection pressures on growth and the resultant evolution of growth from a mechanistic viewpoint. We define important concepts and outline the processes that must be accounted for before observed phenotypic changes can be ascribed to growth evolution. When listing traits that could be traded‐off with growth rate, we group the mechanisms into those affecting resource acquisition and those governing resource allocation. We summarize potential effects of fishing on traits related to growth and discuss methods for detecting evolution of growth. We also challenge the prevailing expectation that fishing‐induced evolution should always lead to slower growth.  相似文献   
66.
67.
Radiometric analysis indicates that a granular variety of glauconite, widespread on the Chatham Rise, is derived from late Tertiary sediments. Other forms of glauconite, associated with pumice, phosphorite nodules, and glacially‐transported erratic blocks, are of Quaternary age. These are quantitatively unimportant, and may have originated as a result of redistribution of components from the older glauconite.  相似文献   
68.
The metamorphic core of the Himalaya is composed of Indian cratonic rocks with two distinct crustal affinities that are defined by radiogenic isotopic geochemistry and detrital zircon age spectra. One is derived predominantly from the Paleoproterozoic and Archean rocks of the Indian cratonic interior and is either represented as metamorphosed sedimentary rocks of the Lesser Himalayan Sequence(LHS) or as slices of the distal cratonic margin. The other is the Greater Himalayan Sequence(GHS) whose provenance is less clear and has an enigmatic affinity. Here we present new detrital zircon Hf analyses from LHS and GHS samples spanning over 1000 km along the orogen that respectively show a striking similarity in age spectra and Hf isotope ratios. Within the GHS, the zircon age populations at 2800-2500 Ma,1800 Ma, 1000 Ma and 500 Ma can be ascribed to various Gondwanan source regions; however, a pervasive and dominant Tonianage population(~860-800 Ma) with a variably enriched radiogenic Hf isotope signature(eHf = 10 to-20) has not been identified from Gondwana or peripheral accreted terranes. We suggest this detrital zircon age population was derived from a crustal province that was subsequently removed by tectonic erosion. Substantial geologic evidence exists from previous studies across the Himalaya supporting the Cambro-Ordovician Kurgiakh Orogeny. We propose the tectonic removal of Tonian lithosphere occurred prior to or during this Cambro-Ordovician episode of orogenesis in a similar scenario as is seen in the modern Andean and Indonesian orogenies, wherein tectonic processes have removed significant portions of the continental lithosphere in a relatively short amount of time. This model described herein of the pre-Himalayan northern margin of Greater India highlights the paucity of the geologic record associated with the growth of continental crust. Although the continental crust is the archive of Earth history, it is vital to recognize the ways in which preservation bias and destruction of continental crust informs geologic models.  相似文献   
69.
We studied the population ecology of the snail Melampus bidentatus in relation to patch composition and landscape structure across several salt marsh systems in Connecticut, USA. These marshes have changed significantly over the past 40–50 years including loss of total area, increased areas of short Spartina alterniflora, and decreased areas and fragmentation of Spartina patens. These changes are consistent with tidal inundation patterns that indicate frequent flooding of high marsh areas. Melampus bidentatus densities were highly variable, both among different salt marsh systems and locations within specific marshes, but were generally similar among short Sp. alterniflora and Sp. patens patches within locations. Densities were lowest where the marsh was regularly inundated at high tide and only remnant Sp. patens patches remained. Almost no snails were found in bare patches. Areas that had large Sp. patens patches adjacent to short Sp. alterniflora supported the highest M. bidentatus densities. Population size‐structure varied significantly among patch types, with higher proportions of large individuals in short Sp. alterniflora and hummocked Sp. patens patches than in large and remnant Sp. patens patches. This was likely due to size‐selective predation and/or higher snail growth rates due to better food resource conditions in short Sp. alterniflora patches. Egg mass densities and the number of eggs per egg mass were highest in short Sp. alterniflora. Our results indicate that M. bidentatus is resilient to the level and patterns of salt marsh change evident at our study sites. Indeed, snail densities were significantly higher than reported in other field studies, suggesting that increased patch areas of short Sp. alterniflora and associated environmental conditions at our study sites may provide more favorable habitats than previously when marshes were dominated by extensive Sp. patens meadows. However, there may be threshold conditions that could overwhelm the ability of M. bidentatus to maintain itself within salt marsh systems where changes in hydrology, sedimentation and other factors lead to increased numbers of bare patches and ponds and loss of short Sp. alterniflora and Sp. patens. Studies of the responses of resident and transient fauna to salt marsh change are critically needed in order to better understand the implications for salt marsh ecosystem dynamics and services.  相似文献   
70.
We present a numerical, catchment-scale model that solves flow equations of surface and subsurface flow in a three-dimensional domain. Surface flow is described by the two-dimensional parabolic approximation of the St. Venant equation, using Manning’s equation of motion; subsurface flow is described by the three-dimensional Richards’ equation for the unsaturated zone and by three-dimensional Darcy’s law for the saturated zone, using an integrated finite difference formulation. The hydrological component is a dynamic link library implemented within a comprehensive model which simulates surface energy, radiation budget, snow melt, potential evapotranspiration, plant development and plant water uptake. We tested the model by comparing distributed and integrated three-dimensional simulated and observed perched water depth (PWD), stream flow data, and soil water contents for a small catchment. Additional tests were performed for the snow melting algorithm as well as the different hydrological processes involved. The model successfully described the water balance and its components as evidenced by good agreement between measured and modelled data.  相似文献   
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