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31.
Natural Hazards - Analysis of long-term land use and land cover (LULC) changes requires up-to-date remotely sensed data to assess their effects on erosion. This is a particularly important...  相似文献   
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Geotechnical and Geological Engineering - Soil erosion is one of the major environmental problems in the Middle East and North Africa (MENA) region. Favoured by the harmful effects of climate...  相似文献   
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The fall and recovery of the Tissint meteorite in 2011 created a rare opportunity to examine a Martian sample with a known, short residence time on Earth. Tissint is an olivine‐phyric shergottite that accumulated olivine antecrysts within a single magmatic system. Coarse olivine grains with nearly homogeneous cores of Mg# >80 suggest slow re‐equilibration. Many macroscopic features of this sample resemble those of LAR 06319, including the olivine crystal size distribution and the presence of evolved oxide and olivine compositions. Unlike LAR 06319, however, no magmatic hydrous phases were found in the analyzed samples of Tissint. Minor and trace element compositions indicate that the meteorite is the product of closed‐system crystallization from a parent melt derived from a depleted source, with no obvious addition of a LREE‐rich (crustal?) component prior to or during crystallization. The whole‐rock REE pattern is similar to that of intermediate olivine‐phyric shergottite EETA 79001 lithology A, and could also be approximated by a more olivine‐rich version of depleted basaltic shergottite QUE 94201. Magmatic oxygen fugacities are at the low end of the shergottite range, with log fO2 of QFM‐3.5 to ‐4.0 estimated based on early‐crystallized minerals and QFM‐2.4 estimated based on the Eu in pyroxene oxybarometer. These values are similarly comparable to other depleted shergottites, including SaU 005 and QUE 94201. Tissint occupies a previously unsampled niche in shergottite chemistry: containing olivines with Mg# >80, resembling the enriched olivine‐phyric shergottite LAR 06319 in its crystallization path, and comparable to intermediate olivine‐phyric shergottite EETA 79001A, depleted olivine‐phyric shergottite DaG 476, and depleted basaltic shergottite QUE 94201 in its trace element abundances and oxygen fugacity. The apparent absence of evidence for terrestrial alteration in Tissint (particularly in trace element abundances in the whole‐rock and individual minerals) confirms that exposure to the arid desert environment results in only minimal weathering of samples, provided the exposure times are brief.  相似文献   
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We investigated the chemical evolution in IC 63 nebula, a photo-dominated region (PDR). The chemical structure and the ionization state depend directly on the intensity of the incident UV radiation. The electron density is also affected by the incident UV radiation. It decreases gradually with the increase of the depth in the cloud varying from 5.9×10-5 at the surface to 9.6×10-9 in the core. Ionic carbon(C+) dominates the electron density in the outer region while ionic metals and other ions (H+, CH2D+, and HCO+) are the most dominant in the deepest region. Our results at A V = 6.7 mag are in good agreement with observations except in the case of H2S, where the calculated value is lower than the observed value by about two orders of magnitude.  相似文献   
37.
In order to better understand the long-term speciation and fractionation of Zn in soils, we investigated three soils naturally enriched in Zn (237–864 mg/kg Zn) from the weathering of Zn-rich limestones (40–207 mg/kg Zn) using extended X-ray absorption fine structure (EXAFS) spectroscopy and sequential extractions. The analysis of bulk EXAFS spectra by linear combination fitting (LCF) indicated that Zn in the oolitic limestones was mainly present as Zn-containing calcite (at site Dornach), Zn-containing goethite (Gurnigel) and Zn-containing goethite and sphalerite (Liestal). Correspondingly, extraction of the powdered rocks with 1 M NH4-acetate at pH 6.0 mobilized only minor fractions of Zn from the Gurnigel and Liestal limestones (<30%), but most Zn from the Dornach rock (81%). In the Dornach soil, part of the Zn released from the dissolving limestone was subsequently incorporated into pedogenic hydroxy-interlayered vermiculite (Zn-HIV, 30%) and Zn-containing kaolinite (30%) and adsorbed or complexed by soil organic and inorganic components (40%). The Gurnigel and Liestal soils contained substantial amounts of Zn-containing goethite (50%) stemming from the parent rock, smaller amounts (20%) of Zn-containing kaolinite (and possibly Zn-HIV), as well as adsorbed or complexed Zn-species (30%). In the soil from Liestal, sphalerite was only found in trace amounts, indicating its dissolution during soil formation. In sequential extractions, large percentages of Zn (55–85%) were extracted in recalcitrant extraction steps, confirming that Zn-HIV, Zn-containing kaolinite and Zn-containing goethite are highly resistant to weathering. These Zn-bearing phases thus represent long-term hosts for Zn in soils over thousands of years. The capability of these phases to immobilize Zn in heavily contaminated soils may however be limited by their uptake capacity (especially HIV and kaolinite) or their abundance in soil.  相似文献   
38.
X-ray Absorption Fine Structure (XAFS) spectroscopy was used in combination with high resolution transmission electron microscopy (HRTEM), electron energy loss spectroscopy (EELS), X-ray energy dispersive spectroscopy (XEDS), X-ray powder diffraction, and Mössbauer spectroscopy to obtain detailed information on arsenic and iron speciation in the products of anaerobic reduction of pure and As(V)- or As(III)-adsorbed lepidocrocite (γ-FeOOH) by Shewanella putrefaciens ATCC 12099. We found that this strain of S. putrefaciens is capable of using Fe(III) in lepidocrocite and As(V) in solution or adsorbed on lepidocrocite surfaces as electron acceptors. Bioreduction of lepidocrocite in the absence of arsenic resulted in the formation of hydroxycarbonate green rust 1 [FeII4FeIII2(OH)12CO3: GR1(CO3)], which completely converted into ferrous-carbonate hydroxide (FeII2(OH)2CO3: FCH) over nine months. This study thus provides the first evidence of bacterial reduction of stoichiometric GR1(CO3) into FCH. Bioreduction of As(III)-adsorbed lepidocrocite also led to the formation of GR1(CO3) prior to formation of FCH, but the presence of As(III) slows down this transformation, leading to the co-occurrence of both phases after 22-month of aging. At the end of this experiment, As(III) was found to be adsorbed on the surfaces of GR1(CO3) and FCH. After five months, bioreduction of As(V)-bearing lepidocrocite led directly to the formation of FCH in association with nanometer-sized particles of a minor As-rich Fe(OH)2 phase, with no evidence for green rust formation. In this five-month experiment, As(V) was fully converted to As(III), which was dominantly sorbed at the surface of the Fe(OH)2 nanoparticles as oligomers binding to the edges of Fe(OH)6 octahedra at the edges of the octahedral layers of Fe(OH)2. These multinuclear As(III) surface complexes are characterized by As-As pairs at a distance of 3.32 ± 0.02 Å and by As-Fe pairs at a distance of 3.50 ± 0.02 Å and represent a new type of As(III) surface complex. Chemical analyses show that the majority of As(III) produced in the experiments with As present is associated with iron-bearing hydroxycarbonate or hydroxide solids, reinforcing the idea that, at least under some circumstances, bacterial reduction can promote As(III) sequestration instead of mobilizing it into solution.  相似文献   
39.
Channel bifurcations can be found in river network systems from high gradient gravel-bed rivers to fine-grained low gradient deltas. In these systems, bifurcations often evolve asymmetrically such that one downstream channel silts up and the other deepens and, in most cases, they eventually avulse. Past analytical and numerical studies showed that symmetric bifurcations are unstable in high and low Shields stress conditions resulting in asymmetric bifurcations and avulsion, while they can be stable in the mid-Shields range, but this range is smaller for larger width-to-depth ratio. Here, using a one-dimensional (1D) numerical model, we show that effects of sediment grain size and of channel slope are much larger than expected for low-gradient systems when a sediment transport relation is used that separates between bedload and suspended load transport. We found that the range of Shields stress conditions with unstable symmetric bifurcations expanded for lower channel slopes and for finer sediment. In high sediment mobility, suspended load increasingly dominates the sediment transport, which increases the sediment transport nonlinearity and lowers the relative influence of the stabilizing transverse bedslope-driven flux. Contrary to previous works, we found another stable symmetric solution in high Shields stress, but this only occurs in the systems with small width-to-depth ratio. This indicates that suspended load-dominated bifurcations of lowland rivers are more likely to develop into highly asymmetric channels than previously thought. This explains the tendency of channel avulsion observed in many systems.  相似文献   
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Abstract: Geology and genesis of the sediment-hosted barite deposits in the Lasbela and Khuzdar districts of Balochistan, Pakistan have been studied and described. Hot solutions generated in rifting environments during the initial stage of separation of the continental crustal block related to the Gondwanaland fragmentation subsequently reposed in Jurassic rocks, most probably played an important role on barite formation.
Paragenetic relationships indicate that the period of barite mineralization was distinctly later than that of zinc-lead sulphide mineralization in the Lasbela and Khuzdar districts. The barite deposits occur on top and in peripheral to the zinc-lead sulphides. The earliest barite mineralization took place in the clastic rock sequence of the lower Spingwar Formation as cross cutting veins. Younger mineralization as stratabound-replacement type occurred within the platform limestones of Loralai Formation, just above the Spingwar Formation. The youngest mineralization as stratiform is hosted within black shales, mudstones and argillaceous limestones of Anjira Formation at the top of Loralai Formation. In the light of the evidences gathered from field and laboratory investigations a genetic model has been deduced.  相似文献   
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