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41.
The influence of salinity on growth and Cu uptake in the green macroalga Ulva reticulata collected from the intertidal area in the Western Indian Ocean was studied under controlled laboratory conditions. Exposure concentrations ranged from 5 to 500 μg Cu l−1 at five salinities (ranging 20–40). The accumulation of Cu increased with decreasing salinity, so that the uptake at 500 μg Cu l−1 was approximately 2.7, 2.4 and 2.0 times higher at salinities of 20, 25, and 30 respectively, than uptake at salinity of 35, and with uptake being lowest at salinity of 40. Ulva maintained a positive growth rate over the whole salinity range (20–40), with highest rates at salinity of 35. When exposing to Cu at low salinities (20 and 25), the growth rate of Ulva was strongly inhibited suggesting an increase in toxicity of Cu with decreasing salinity. EC50 and NOEC increased with increase in salinity, implying a reduced Cu toxicity at high salinities. It was concluded that salinity needs to be considered when using macroalgae, such as U. reticulata, as a bioindicator of heavy metals in areas with heavy rainfall, underground fresh water intrusion or in estuaries, as they might accumulate more metals and be more negatively affected.  相似文献   
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43.
CO was observed on March 11, 1997 in comet Hale–Bopp with theIRAM Plateau de Bure interferometer. The maps show evidence for asymmetrical patterns, due to the Existence of CO jets. Analysis of the spectra and their velocity shifts shows that there is a spiral CO jet rotating in a plane almost perpendicular to the sky plane.This is the first time that rotating jets are observed for parent molecules.We have developed a 3-D model simulating rotating spiral jets of CO gas.We present here the comparison between the observations and our model.  相似文献   
44.
A radiotracer technique using 210Pb was applied to quantify the transfer and distribution of lead in the asteroid Asterias rubens following a single ingestion of radio-labelled mussels under controlled laboratory conditions. Approximately 50% of the 210Pb accumulated by mussels in their soft tissues from seawater was transferred to the asteroid through the food pathway resulting in a transfer factor less than unity. Loss kinetics of 210Pb in the asteroid were best described by a two-component exponential model. A. rubens eliminated 56% +/- 5% of the ingested 210Pb in a few days while the remaining fraction (42% +/- 5%), was absorbed and eliminated very slowly. Following ingestion, 210Pb was accumulated in the pyloric caeca and the body wall with little radioisotope found in the coelomic fluid. Lead-210 was then transferred to the organic matrix of the body wall through the general body cavity via the coelomic fluid, and then to the skeleton. In this way, lead appears to be progressively eliminated from the organic matrix of the body wall while it is efficiently trapped in the calcite skeleton. The sequestration and retention of lead in the skeleton is considered as a detoxification process, but it also prevents lead transfer to higher trophic levels of the marine food chain since the skeleton is not digested by higher consumers. In addition, the skeleton of asteroids can be regarded as a bioindicator of long-term dietary lead contamination.  相似文献   
45.
The Paraná-Plata basin is the second largest hydrological basin in South America and is of great importance for the countries of the region (Argentina, Bolivia, Brazil, Paraguay and Uruguay). The present study focuses on the long-term trends in basin-scale precipitation with special emphasis on the role of distribution changes in extreme large-scale precipitation events and on the characteristics and evolution of ENSO teleconnections over the last 50 years. First, we defined a Paraná-Plata basin total precipitation index (PTPI) as the precipitations spatially averaged over the hydrological basin. On interannual time scales, such an index is mainly representative of anomalous monsoon precipitations in the northern part of the basin and large convective precipitation anomalies in the center of the basin (Paraguay-southern Brazil-Uruguay-northern Argentina) typical of the canonical ENSO teleconnection pattern. Our major findings clearly highlight a positive trend in yearly averaged PTPI mainly from the late 1960s to the early 1980s with a strong dependence from month-to-month. The largest precipitation increase is observed from November to May in southern Brazil and Argentina. A close examination of PTPI distributions during the two halves of the period 1950–2001 shows that the changes in the mean state from 1950–1975 to 1976–2001 result from significant changes in each calendar month mean state and in the tails of the PTPI anomaly distributions in May with lesser and weaker large-scale dry events and stronger large-scale wet events. Further studies will be needed to assess whether the observed trend in large-scale extreme precipitation conditions can be related to natural climate variability or anthropogenic activities and whether it is associated to changes in local/regional extreme events. The stronger wet conditions in different months seem to be associated to changes in ENSO characteristics (amplitude, propagation, spatial structure, ...) since the 1982–1983 El Niño. Indeed, spatial ENSO teleconnections (stronger in November and April–May) have greatly evolved from 1950–1975 to 1976–2001. Moreover, we demonstrate that there is a strong modulation and displacement of the teleconnection patterns from one event to another, impeding the definition of robust statistical relationship between ENSO and precipitation in the Paraná-Plata basin (except maybe over a very limited area near the common border between Paraguay, Argentina and Brazil). Finally, the non-antisymmetrical patterns of precipitation between El Niño and La Niña conditions and the non-linear relationship between precipitation and either Niño3.4 or Niño1+2 sea surface temperature indices show that linear statistical forecast systems are actually of very limited use for impact predictions on society on a local or regional scale.  相似文献   
46.
Significant offshore asphaltic deposits with active seepage occur in the Santa Barbara Channel offshore southern California. The composition and isotopic signatures of gases sampled from the oil and gas seeps reveal that the coexisting oil in the shallow subsurface is anaerobically biodegraded, generating CO2 with secondary CH4 production. Biomineralization can result in the consumption of as much as 60% by weight of the original oil, with 13C enrichment of CO2. Analyses of gas emitted from asphaltic accumulations or seeps on the seafloor indicate up to 11% CO2 with 13C enrichment reaching +24.8‰. Methane concentrations range from less than 30% up to 98% with isotopic compositions of –34.9 to –66.1‰. Higher molecular weight hydrocarbon gases are present in strongly varying concentrations reflecting both oil-associated gas and biodegradation; propane is preferentially biodegraded, resulting in an enriched 13C isotopic composition as enriched as –19.5‰. Assuming the 132 million barrels of asphaltic residues on the seafloor represent ~40% of the original oil volume and mass, the estimated gas generated is 5.0×1010 kg (~76×109 m3) CH4 and/or 1.4×1011 kg CO2 over the lifetime of seepage needed to produce the volume of these deposits. Geologic relationships and oil weathering inferences suggest the deposits are of early Holocene age or even younger. Assuming an age of ~1,000 years, annual fluxes are on the order of 5.0×107 kg (~76×106 m3) and/or 1.4×108 kg for CH4 and CO2, respectively. The daily volumetric emission rate (2.1×105 m3) is comparable to current CH4 emission from Coal Oil Point seeps (1.5×105 m3/day), and may be a significant source of both CH4 and CO2 to the atmosphere provided that the gas can be transported through the water column.  相似文献   
47.
Several techniques have been introduced in the last decades for the dehydration and release of O2 from biogenic silica (opal-A) for oxygen-isotope analysis. However, only one silica standard is universally available: a quartz standard (NBS28) distributed by the IAEA, Vienna. Hence, there is a need for biogenic silica working standards. This paper compares the existing methods of oxygen-isotope analyses of opal-A and aims to characterize additional possible working standards to calibrate the δ18O values of biogenic silica. For this purpose, an inter-laboratory comparison was organized. Six potential working standard materials were analysed repeatedly against NBS28 by eight participating laboratories using their specific analytical methods. The materials cover a wide range of δ18O values (+23 to +43‰) and include diatoms (marine, lacustrine), phytoliths and synthetically-produced hydrous silica. To characterize the proposed standards, chemical analyses and imaging by scanning electron microscopy (SEM) were also performed. Despite procedural differences at each laboratory, all methods are in reasonable agreement with a standard deviation (SD) for δ18O values between 0.3‰ and 0.9‰ (1σ). Based on the results, we propose four additional biogenic silica working standards (PS1772-8: 42.8‰; BFC: 29.0‰; MSG60: 37.0‰; G95-25-CL leaves: 36.6‰) for δ18O analyses, available on request through the relevant laboratories.  相似文献   
48.
For the first time a simulation of blowing snow events was validated in detail using one-month long observations (January 2010) made in Adélie Land, Antarctica. A regional climate model featuring a coupled atmosphere/blowing snow/snowpack model is forced laterally by meteorological re-analyses. The vertical grid spacing was 2 m from 2 to 20 m above the surface and the horizontal grid spacing was 5?km. The simulation was validated by comparing the occurrence of blowing snow events and other meteorological parameters at two automatic weather stations. The Nash test allowed us to compute efficiencies of the simulation. The regional climate model simulated the observed wind speed with a positive efficiency (0.69). Wind speeds higher than 12 m s ?1 were underestimated. Positive efficiency of the simulated wind speed was a prerequisite for validating the blowing snow model. Temperatures were simulated with a slightly negative efficiency (?0.16) due to overestimation of the amplitude of the diurnal cycle during one week, probably because the cloud cover was underestimated at that location during the period concerned. Snowfall events were correctly simulated by our model, as confirmed by field reports. Because observations suggested that our instrument (an acoustic sounder) tends to overestimate the blowing snow flux, data were not sufficiently accurate to allow the complete validation of snow drift values. However, the simulation of blowing snow occurrence was in good agreement with the observations made during the first 20 days of January 2010, despite the fact that the blowing snow flux may be underestimated by the regional climate model during pure blowing snow events. We found that blowing snow occurs in Adélie Land only when the 30-min wind speed value at 2 m a.g.l. is >10 m s ?1. The validation for the last 10 days of January 2010 was less satisfactory because of complications introduced by surface melting and refreezing.  相似文献   
49.
A hindcast experiment of the Mediterranean present-day climate is performed using a fully-coupled Atmosphere–Ocean Regional Climate Model (AORCM) for the Mediterranean basin. The new model, called LMDz-NEMO-Med, is composed of LMDz4-regional as atmospheric component and of NEMOMED8 as oceanic component. This AORCM equilibrates freely, without any flux adjustment, neither in fresh water nor in heat. At its atmospheric lateral boundary conditions, it is driven by ERA-40 data from 1958 to 2001, after a spin-up of 40 years in coupled configuration. The model performance is assessed and compared with available observational datasets. The model skill in reproducing mean state and inter-annual variability of main atmospheric and oceanic surface fields is in line with that of state-of-the-art AORCMs. Considering the ocean behaviour, the inter-annual variations of the basin-scale heat content are in very good agreement with the observations. The model results concerning salt content could not be adequately validated. High inter-annual variability of deep convection in the Gulf of Lion is simulated, with 53 % of convective winters, representative of the present climate state. The role of different factors influencing the deep convection and its inter-annual variability is examined, including dynamic and hydrostatic ocean preconditioning and atmospheric surface forcing. A conceptual framework is outlined and validated in linking the occurrence of deep convection to the efficiency of the integrated surface buoyancy fluxes along the winter season to mix the initially stratified averaged water column down to the convective threshold depth. This simple framework (based only on 2 independent variables) is able to explain 60 % (resp. 69 %) of inter-annual variability of the deep water formation rate (resp. maximum mixed layer depth) for the West Mediterranean Deep Water (WMDW) formation process.  相似文献   
50.
We present radio observations of HCO+, H3O+ and CO+ in Hale-Bopp. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
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