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101.
Bulletin of Volcanology - Correlations on the eruptive behaviour of the volcano of Capelinhos (Fayal island) in 1957–58, with (a) solar activity, and (b) earth-tide amplitudes, by way of a... 相似文献
102.
Bulletin of Volcanology - In another paper of the author, a picture of the tectonics of the Azores was presented. The morphological analysis showed evidence of a folded and faulted structure and... 相似文献
103.
Jean-Fran?ois?DeconinckEmail author Stephen?P.?Hesselbo Nicolas?Debuisser Olivier?Averbuch Fran?ois?Baudin Julian?Bessa 《International Journal of Earth Sciences》2003,92(2):255-266
We present a dataset including clay mineralogy, gamma-ray spectrometry, organic matter content and magnetic susceptibility of the Hettangian to lowest Sinemurian successions of Dorset and Somerset, southern UK (Blue Lias Formation, Bristol Channel and Wessex basins). In both areas, the clay assemblages comprise predominantly detrital illite, kaolinite and illite/smectite mixed layers. Clays probably originated from the erosion of the Hercynian massifs, the relative proportions of kaolinite and illite being modulated by arid-humid climatic fluctuations. The organic matter (OM) content (types II to IV) ranges up to 12% in both areas. A clear stratigraphical trend in clay mineral assemblages is apparent in Somerset, whereas in Dorset sharp contrasts between adjacent horizons and a greater dilution by carbonate mask the long-term evolution. Correlations between both areas based on similar vertical trends in clay mineral abundance support the suggestion of a hiatus within the angulata Zone of the Dorset succession. As expected, the kaolinite/illite ratio correlates with the Th/K ratio deduced from gamma-ray spectrometry. However, significant departures from the correlation occur in OM-rich intervals, suggesting that Th may be partly adsorbed on to OM particles. Surprisingly, high magnetic susceptibility correlates with abundant kaolinite, not with Fe-rich clays, indicating either that kaolinite is accompanied by a soil-inherited magnetisable phase (possibly iron oxide) or that illite-rich rocks are more strongly diluted by carbonate than are kaolinite-rich strata. 相似文献
104.
105.
The LMDZ4 general circulation model: climate performance and sensitivity to parametrized physics with emphasis on tropical convection 总被引:3,自引:11,他引:3
Frédéric Hourdin Ionela Musat Sandrine Bony Pascale Braconnot Francis Codron Jean-Louis Dufresne Laurent Fairhead Marie-Angèle Filiberti Pierre Friedlingstein Jean-Yves Grandpeix Gerhard Krinner Phu LeVan Zhao-Xin Li François Lott 《Climate Dynamics》2006,27(7-8):787-813
The LMDZ4 general circulation model is the atmospheric component of the IPSL–CM4 coupled model which has been used to perform climate change simulations for the 4th IPCC assessment report. The main aspects of the model climatology (forced by observed sea surface temperature) are documented here, as well as the major improvements with respect to the previous versions, which mainly come form the parametrization of tropical convection. A methodology is proposed to help analyse the sensitivity of the tropical Hadley–Walker circulation to the parametrization of cumulus convection and clouds. The tropical circulation is characterized using scalar potentials associated with the horizontal wind and horizontal transport of geopotential (the Laplacian of which is proportional to the total vertical momentum in the atmospheric column). The effect of parametrized physics is analysed in a regime sorted framework using the vertical velocity at 500 hPa as a proxy for large scale vertical motion. Compared to Tiedtke’s convection scheme, used in previous versions, the Emanuel’s scheme improves the representation of the Hadley–Walker circulation, with a relatively stronger and deeper large scale vertical ascent over tropical continents, and suppresses the marked patterns of concentrated rainfall over oceans. Thanks to the regime sorted analyses, these differences are attributed to intrinsic differences in the vertical distribution of convective heating, and to the lack of self-inhibition by precipitating downdraughts in Tiedtke’s parametrization. Both the convection and cloud schemes are shown to control the relative importance of large scale convection over land and ocean, an important point for the behaviour of the coupled model. 相似文献
106.
Trace Metal Solid State Speciation in Aerosols of the Northern Levantine Basin,East Mediterranean 总被引:3,自引:0,他引:3
Mustafa Koçak Nilgun Kubilay Barak Herut Malcolm Nimmo 《Journal of Atmospheric Chemistry》2007,56(3):239-257
An established three stage sequential leach scheme was applied to a series of selected high volume aerosol samples (n = 35) collected from the Turkish Eastern Mediterranean coastline (Erdemli). Samples were selected according to their air
mass back trajectory history to reflect the contrasting mixtures of aerosol material present in the Eastern Mediterranean
marine aerosol. Two populations were adopted, those samples which were classed as “anthropogenic” and those which were “Saharan”
dominated aerosol populations. Applying the three stage leach it was possible to define the proportion for each of the considered
metals (Al, Fe, Cu, Pb, Cd, Zn and Mn) present in the (a) “exchangeable” (b) “carbonate / oxide” and (c) “refractory” phases,
representing novel solid state aerosol speciation data for this marine system. Clear trends were established, conforming with
data from previous studies with mainly crustal derived metals (Al and Fe) being present in the refractory phases (Al > 88%;
Fe > 84%) and those influenced by anthropogenic sources being dominating in the exchangeable phase, although for these metals
the variability was comparatively high (12–64%; 19–85%; 40–100% for Zn, Pb and Cd, respectively). For the majority, greater
exchangeable fractions were present the lower the crustal source contribution to the aerosol population, whereas the “refractory”
fraction exhibited contrasting behaviour. This was illustrated by the novel application of the mixing diagram, presenting
each of the three speciation stages against the corresponding percent anthropogenic contribution to each collected sample.
Zn, Pb and Cd all illustrated progressive decrease in the percent exchangeable with increasing crustal contribution to the
aerosol population. The percent exchangeable was discussed in terms of its use to represent the upper limit of the bioavailable
fraction of metal associated with the aerosol, post deposition. The mixing diagram approach enabled the prediction of the
residual fractions for Cd, Pb and Zn (41 ± 4%; 62 ± 4% and 82 ± 5%, respectively,) in Saharan end-member material. 相似文献
107.
P. van Beek R. François M. Conte J.-L. Reyss M. Charette 《Geochimica et cosmochimica acta》2007,71(1):71-86
We measured 228Raex/226Raex and 226Raex/Baex ratios in suspended and sinking particles collected at the Oceanic Flux Program (OFP) time-series site in the western Sargasso Sea and compared them to seawater ratios to provide information on the origin and transport of barite (BaSO4) in the water column. The 228Raex/226Raex ratios of the suspended particles down to 2000 m are nearly identical to those of seawater at the same water depth. These ratios are much lower than expected if suspended barite was produced in surface waters and indicate that barite is produced throughout the mesopelagic layer. The 228Raex/226Raex activity ratios of sinking particles collected at 1500 and 3200 m varied mostly between 0.1 and 0.2, which is intermediate between the seawater ratio at these depths (<0.03) and the seawater ratios found in the upper 250 m (0.31-0.42). This suggests that excess Ba (i.e., Baex = Batotal − Balithogenic), considered to be mainly barite, present in the sinking flux is a mixture of crystals formed recently in the upper water column, formed several years earlier in the upper water column, or formed recently in deeper waters. We observe a sizeable temporal variability in the 228Raex/226Raex ratios of sinking particles, which indicates temporal variability in the relative proportion of barite crystals originating from surface (with a high 228Raex/226Raex ratio) and mesopelagic (with a low 228Raex/226Raex ratio) sources. However, we could not discern a clear pattern that would elucidate the factors that control this variability. The 226Ra/Ba ratios measured in seawater are consistent with the value reported from the GEOSECS expeditions (2.3 dpm μmol−1) below 500 m depth, but are significantly lower in the upper 500 m. High 226Raex/Baex ratios and elevated Sr concentrations in suspended particles from the upper water column suggest preferential uptake of 226Ra over Ba during formation of SrSO4 skeletons by acantharians, which must contribute to barite formation in shallow waters. Deeper in the water column the 226Raex/Baex ratios of suspended particles are lower than those of seawater. Since 228Raex/226Raex ratios demonstrate that suspended barite at these depths has been produced recently and in situ, their low 226Raex/Baex ratios indicate preferential uptake of Ba over Ra in barite formed in mesopelagic water. 相似文献
108.
André Burnol Francis Garrido Philippe Baranger Catherine Joulian Marie-Christine Dictor Françoise Bodénan Guillaume Morin Laurent Charlet 《Geochemical transactions》2007,8(1):12
High levels of arsenic in groundwater and drinking water are a major health problem. Although the processes controlling the
release of As are still not well known, the reductive dissolution of As-rich Fe oxyhydroxides has so far been a favorite hypothesis.
Decoupling between arsenic and iron redox transformations has been experimentally demonstrated, but not quantitatively interpreted.
Here, we report on incubation batch experiments run with As(V) sorbed on, or co-precipitated with, 2-line ferrihydrite. The
biotic and abiotic processes of As release were investigated by using wet chemistry, X-ray diffraction, X-ray absorption and
genomic techniques. The incubation experiments were carried out with a phosphate-rich growth medium and a community of Fe(III)-reducing
bacteria under strict anoxic conditions for two months. During the first month, the release of Fe(II) in the aqueous phase
amounted to only 3% to 10% of the total initial solid Fe concentration, whilst the total aqueous As remained almost constant
after an initial exchange with phosphate ions. During the second month, the aqueous Fe(II) concentration remained constant,
or even decreased, whereas the total quantity of As released to the solution accounted for 14% to 45% of the total initial
solid As concentration. At the end of the incubation, the aqueous-phase arsenic was present predominately as As(III) whilst
X-ray absorption spectroscopy indicated that more than 70% of the solid-phase arsenic was present as As(V). X-ray diffraction
revealed vivianite Fe(II)3(PO4)2.8H2O in some of the experiments. A biogeochemical model was then developed to simulate these aqueous- and solid-phase results.
The two main conclusions drawn from the model are that (1) As(V) is not reduced during the first incubation month with high
Eh values, but rather re-adsorbed onto the ferrihydrite surface, and this state remains until arsenic reduction is energetically
more favorable than iron reduction, and (2) the release of As during the second month is due to its reduction to the more
weakly adsorbed As(III) which cannot compete against carbonate ions for sorption onto ferrihydrite. The model was also successfully
applied to recent experimental results on the release of arsenic from Bengal delta sediments. 相似文献
109.
Sébastien Joannin Frédéric Quillévéré Christophe Lécuyer François Martineau 《Quaternary Research》2007,67(2):264-274
Vegetation inherited from a Pliocene subtropical climate evolved through obliquity oscillations and global cooling leading to modern conditions. An integrated, highly time-resolved record of pollen and stable isotopes (δ18O and δ13C of Globigerina bulloides) was obtained to understand vegetation responses to Early Pleistocene climate changes. Continental and marine responses are compared in the Central Mediterranean region with a particular consideration of environmental changes during anoxic events.Pollen data illustrate vegetation dynamics as follows: [1] development of mesothermic elements (warm and humid conditions); [2] expansion of mid- and high-altitude elements (cooler but still humid conditions); and [3] strengthening of steppe and herb elements (cooler and dry conditions). These successions correlate with precession. δ18O variations recorded by Globigerina bulloides define two cycles (MIS 43-40) related to obliquity. At northern low- to mid-latitudes, the pollen signal records temperature and wetness changes related to precession even during global climate changes induced by obliquity. This may result in unexpected increasing wetness during glacial periods, which has to be considered specific to the Central and Eastern Mediterranean region. Lastly, an analysis of anoxic events reveals that enhanced runoff is indicated by increasing frequency of the riparian trees Liquidambar and Zelkova. 相似文献
110.
Jean-Franois Pastre Agns Gauthier Sbastien Nomade Paul Orth Ana Andrieu Franck Goupille Herv Guillou Stphane Kunesch Stphane Scaillet Paul Randall Renne 《Comptes Rendus Geoscience》2007,339(16):987-997
The Alleret maar (Massif Central, France) provides a long lacustrine sequence (40.6 m) attributed to the early Middle Pleistocene. Sediment, pollen and diatoms analysis of its upper part (AL2 core, 14.6 m) indicates two temperate phases marked by high lake levels, forest development and vegetation expansion. They are separated by a cold period during which lake level drops, coarse sediment input increases and steppic and xerophilous plants develop. Pollen data suggests that this sequence belongs to the upper part of the Cromerian complex. These results are in agreement with the 557 ± 3 ka (±12 ka, including all errors) 40Ar/39Ar age obtained from an interbedded tephra layer emitted by the Mont-Dore/Sancy strato-volcano and establish that this sequence probably covers the MIS 15 substages. 相似文献