Ferric/ferrous ratio in silicate melts: a new model for 1 atm data with special emphasis on the effects of melt composition     

Alexander?BorisovEmail authorView author&#;s OrcID profile  Harald?Behrens  Francois?Holtz 《Contributions to Mineralogy and Petrology》2018,173(12):98

The effect of MgO and total FeO on ferric/ferrous ratio in model multicomponent silicate melts was investigated experimentally in the temperature range 1300–1500 °C at 1 atm total pressure in air. We demonstrate that the addition of these weak network modifier cations results in an increase of Fe³⁺/Fe²⁺ ratio in both mafic and silicic melts. Based on present and published experimental data, a new empirical equation is proposed to predict the ferric/ferrous ratio as a function of oxygen fugacity, temperature and melt composition. In contrast to previous equations, the compositional effect of melts on the Fe³⁺/Fe²⁺ ratio is not only modeled by the sum of the molar fraction of the individual oxide components. Additional interactions terms have also been incorporated. The main advantage of the proposed model is its applicability for a wide compositional range. However, its application to felsic melts (>?68 wt% SiO₂) is not recommended. Other advantages of this equation and differences when compared with previous models are discussed.  相似文献   

Simulations of an isolated two-dimensional thunderstorm: Sensitivity to cloud droplet size and the presence of graupel     

Mary-Jane Morongwa Bopape  Francois Alwyn Engelbrecht  David A. Randall  Willem Adolf Landman 《Asia-Pacific Journal of Atmospheric Sciences》2014,50(2):139-151

Cloud Resolving Models (CRMs) which are used increasingly to make operational forecasts, employ Bulk Microphysics Schemes (BMSs) to describe cloud microphysical processes. In this study two BMSs are employed in a new Nonhydrostatic σ-coordinate Model to perform two hour simulations of convection initiated by a warm bubble, using a horizontal grid resolution of 500 m. Different configurations of the two BMSs are applied, to test the effects of the presence of graupel with one scheme (2-configurations) and of changing the cloud droplet sizes in the second scheme (4-configurations), on the simulation of idealised thunderstorms. Maximum updrafts in all the simulations are similar over the first 40 minutes, but start to differ beyond this point. The first scheme simulates the development of a second convective cell that is triggered by the cold pool that develops from the outflow of the first storm. The cold pool is more intense in the simulation with graupel because of melting of graupel particles, which results in relatively large raindrops, decreases the temperature through latent heat absorption, causing stronger downdrafts, which all contribute to the formation of a more intense cold pool. The second scheme simulates the development of a second cell in two of its configurations, while two other configurations do not simulate the redevelopment. Two configurations that simulate the secondary redevelopment produce a slightly stronger cold pool just before redevelopment. Our results show that small differences in the microphysics formulations result in simulations of storm dynamics that diverge, possibly due nonlinearities in the model.  相似文献   

The bi-decadal rainfall cycle,Southern Annular Mode and tropical cyclones over the Limpopo River Basin,southern Africa     

Johan Malherbe  Willem A. Landman  Francois A. Engelbrecht 《Climate Dynamics》2014,42(11-12):3121-3138

The association between bi-decadal rainfall variability over southern Africa and the rainfall contributed by tropical cyclonic systems from the Southwest Indian Ocean (SWIO) provides a potential means towards understanding decadal-scale variability over parts of the region. A multi-decadal period is considered, focusing on the anomalous tropospheric patterns that induced a particularly wet 8-year long sub-period over the Limpopo River Basin. The wet sub-period was also characterized by a larger contribution to rainfall by tropical cyclones and depressions. The findings suggest that a broadening of the Hadley circulation underpinned by an anomalous anticyclonic pattern to the east of southern Africa altered tropospheric steering flow, relative vorticity and moisture contents spatially during the sub-period of 8 years. These circulation modulations induced enhanced potential for tropical systems from the SWIO to cause precipitation over the Limpopo River Basin. The same patterns are also conducive to increasing rainfall over the larger subcontinent, therefore explaining the positive association in the bi-decadal rainfall cycle and rainfall contributed by tropical cyclonic systems from the SWIO. An overview of regional circulation anomlies during alternating near-decadal wet and dry epochs is given. The regional circulation anomalies are also explained in hemispheric context, specifically in relation to the Southern Annular Mode, towards understanding variation over other parts of the Southern Hemisphere at this time scale.  相似文献   

Magnetic tracers,a probe of the solar convective layers     

Elizabeth Ribes  Francois Bonnefond 《地球物理与天体物理流体动力学》2013,107(3-4):241-261

Abstract

A meridional circulation of sunspots has been measured through the digital analysis of the Meudon spectroheliograms from 1978 to 1983. Old and young sunspots follow a zonal meridional circulation, in several bands of latitude, in which two adjacent bands have opposite motions. This meridional circulation pattern is time-dependent. Using the H _α filaments as magnetic field tracers, a large-scale magnetic pattern has been found that was also obtained independently by direct measurement of the magnetic field (Hoeksema, 1988).

The coincidence of a large-scale magnetic pattern with a zonal meridional circulation suggests the existence of azimuthal rolls below the surface, and these azimuthal rolls can explain a number of properties of the solar cycle. New rolls occur with increasing proximity to the Equator, thereby indicating the direction of propagation of the dynamo wave. The occurrence of rolls is very favorable to the emergence of the magnetic regions. The rolls also influence the magnetic complexity of the active regions. They modulate the surface rotation through the Coriolis force, which accelerates or decelerates the fluid particles. They therefore offer a plausible explanation of the torsional oscillation pattern.

There are a number of problems raised by such an unexpected circulation pattern: for example, the coexistence of axisymmeric rolls with hypothetical giant cells, the location of the dynamo source below or within the convective zone, and the coupling of the radiative interior and the convective layers. To resolve these important issues, continuous observational studies are needed of the manifestation of solar activity, as well as of radius and luminosity variations. So, we have aimed our paper at an audience of theoreticians in the hope that they take up the challenges we describe.  相似文献   

Iron Distribution in Size‐Resolved Aerosols Generated by UV‐Femtosecond Laser Ablation: Influence of Cell Geometry and Implications for In Situ Isotopic Determination by LA‐MC‐ICP‐MS     

Francois‐Xavier d'Abzac  Andrew D. Czaja  Brian L. Beard  James J. Schauer  Clark M. Johnson 《Geostandards and Geoanalytical Research》2014,38(3):293-309

The influence of ablation cell geometry (Frames single‐ and HelEx two‐volume cells) and laser wavelength (198 and 266 nm) on aerosols produced by femtosecond laser ablation (fs‐LA) were evaluated. Morphologies, iron mass distribution (IMD) and ⁵⁶Fe/⁵⁴Fe ratios of particles generated from magnetite, pyrite, haematite and siderite were studied. The following two morphologies were identified: spherules (10–200 nm) and agglomerates (5–10 nm). Similarity in IMD and ablation rate at 198 and 266 nm indicates similar ablation mechanisms. ⁵⁶Fe/⁵⁴Fe ratios increased with aerodynamic particle size as a result of kinetic fractionation during laser plasma plume expansion, cooling and aerosol condensation. The HelEx cell produces smaller particles with a larger range of ⁵⁶Fe/⁵⁴Fe ratios (1.85‰) than particles from the Frames cell (1.16‰), but the bulk aerosol matches the bulk substrate for both cells, demonstrating stoichiometric fs‐LA sampling. IMD differences are the result of faster wash out of the HelEx cell allowing less time for agglomeration of small, low‐δ ⁵⁶Fe particles with larger, high‐δ ⁵⁶Fe particles in the cell. Even with a shorter ablation time, half the total Fe ion intensity, and half the ablation volume, the HelEx cell produced Fe isotope determinations for magnetite that were as precise as the Frames cell, even when the latter included an aerosol‐homogenising mixing chamber. The HelEx cell delivered a more constant stream of small particles to the ICP, producing a more stable Fe ion signal (0.7% vs. 1.5% RSE for ⁵⁶Fe in a forty‐cycle single analysis), constant instrumental mass bias and thus a more precise measurement.  相似文献   

Summary of the Mars recent climate change workshop NASA/Ames Research Center,May 15–17, 2012     

Robert M. Haberle  Francois Forget  James Head  Melinda A. Kahre  Mikhail Kreslavsky  Sandra J. Owen 《Icarus》2013,222(1):415-418

This note summarizes the results from the Mars recent climate change workshop at NASA/Ames Research Center, May 15–17, 2012.  相似文献   

Mercury exosphere: II. The sodium/potassium ratio     

Francois Leblanc  Alain Doressoundiram 《Icarus》2011,211(1):10-20

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Evidence for Amazonian northern mid-latitude regional glacial landsystems on Mars: Glacial flow models using GCM-driven climate results and comparisons to geological observations     

James L. Fastook  James W. Head  Francois Forget  Jean-Baptiste Madeleine  David R. Marchant 《Icarus》2011,216(1):23-39

A fretted valley system on Mars located at the northern mid-latitude dichotomy boundary contains lineated valley fill (LVF) with extensive flow-like features interpreted to be glacial in origin. We have modeled this deposit using glacial flow models linked to atmospheric general circulation models (GCM) for conditions consistent with the deposition of snow and ice in amounts sufficient to explain the interpreted glaciation. In the first glacial flow model simulation, sources were modeled in the alcoves only and were found to be consistent with the alpine valley glaciation interpretation for various environments of flow in the system. These results supported the interpretation of the observed LVF deposits as resulting from initial ice accumulation in the alcoves, accompanied by debris cover that led to advancing alpine glacial landsystems to the extent observed today, with preservation of their flow texture and the underlying ice during downwasting in the waning stages of glaciation. In the second glacial flow model simulation, the regional accumulation patterns predicted by a GCM linked to simulation of a glacial period were used. This glacial flow model simulation produced a much wider region of thick ice accumulation, and significant glaciation on the plateaus and in the regional plains surrounding the dichotomy boundary. Deglaciation produced decreasing ice thicknesses, with flow centered on the fretted valleys. As plateaus lost ice, scarps and cliffs of the valley and dichotomy boundary walls were exposed, providing considerable potential for the production of a rock debris cover that could preserve the underlying ice and the surface flow patterns seen today. In this model, the lineated valley fill and lobate debris aprons were the product of final retreat and downwasting of a much larger, regional glacial landsystem, rather than representing the maximum extent of an alpine valley glacial landsystem. These results favor the interpretation that periods of mid-latitude glaciation were characterized by extensive plateau and plains ice cover, rather than being restricted to alcoves and adjacent valleys, and that the observed lineated valley fill and lobate debris aprons represent debris-covered residual remnants of a once more extensive glaciation.  相似文献   

Early Mars climate near the Noachian–Hesperian boundary: Independent evidence for cold conditions from basal melting of the south polar ice sheet (Dorsa Argentea Formation) and implications for valley network formation     

James L. Fastook  James W. Head  David R. Marchant  Francois Forget  Jean-Baptiste Madeleine 《Icarus》2012,219(1):25-40

Currently, and throughout much of the Amazonian, the mean annual surface temperatures of Mars are so cold that basal melting does not occur in ice sheets and glaciers and they are cold-based. The documented evidence for extensive and well-developed eskers (sediment-filled former sub-glacial meltwater channels) in the south circumpolar Dorsa Argentea Formation is an indication that basal melting and wet-based glaciation occurred at the South Pole near the Noachian–Hesperian boundary. We employ glacial accumulation and ice-flow models to distinguish between basal melting from bottom-up heat sources (elevated geothermal fluxes) and top-down induced basal melting (elevated atmospheric temperatures warming the ice). We show that under mean annual south polar atmospheric temperatures (?100 °C) simulated in typical Amazonian climate experiments and typical Noachian–Hesperian geothermal heat fluxes (45–65 mW/m²), south polar ice accumulations remain cold-based. In order to produce significant basal melting with these typical geothermal heat fluxes, the mean annual south polar atmospheric temperatures must be raised from today’s temperature at the surface (?100 °C) to the range of ?50 to ?75 °C. This mean annual polar surface atmospheric temperature range implies lower latitude mean annual temperatures that are likely to be below the melting point of water, and thus does not favor a “warm and wet” early Mars. Seasonal temperatures at lower latitudes, however, could range above the melting point of water, perhaps explaining the concurrent development of valley networks and open basin lakes in these areas. This treatment provides an independent estimate of the polar (and non-polar) surface temperatures near the Noachian–Hesperian boundary of Mars history and implies a cold and relatively dry Mars climate, similar to the Antarctic Dry Valleys, where seasonal melting forms transient streams and permanent ice-covered lakes in an otherwise hyperarid, hypothermal climate.  相似文献