Laboratory sulfurisation of the marine microalga Nannochloropsis salina     

Francois Gelin  Marika D. Kok  Jan W. de Leeuw  Jaap S. Sinninghe Damst 《Organic Geochemistry》1998,29(8):1837-1848

To understand more fully the mode of preservation of organic matter in marine sediments, laboratory sulfurisation of intact cells of the cultured microalga Nannochloropsis salina was performed using inorganic polysulfides in seawater at 50°C. Solvent extractable and non-extractable materials were analysed by GC–MS and Py–GC–MS, respectively, to study the incorporation of sulfur into the microalgal organic matter. No GC-amenable sulfur-containing compounds were found in the extracts apart from some minor thiophenes with a phytanyl carbon skeleton. The residue after extraction and hydrolysis contained abundant macromolecular sulfur-containing moieties as revealed by the presence of dominant C₂₈–C₃₂ thiols, thiophenes, thianes and thiolanes in the flash pyrolysates. These products are thought to be formed from moieties derived from sulfurisation of C₂₈–C₃₂ diols and alkenols, characteristic lipids of N. salina. C₁–C₂ alkylated thiophenes were also found in the pyrolysates and probably result from moieties formed upon sulfurisation of carbohydrates. The highly resistant biomacromolecule (algaenan) synthesised by N. salina remains unaffected by sulfurisation. The non-hydrolysable residue isolated from the sulfurised N. salina thus comprises algaenan and (poly)sulfide-bound long alkyl chains. The sulfurisation experiments show that both selective preservation of algaenans and lipid and carbohydrate “vulcanisation” can be involved in the preservation of algal organic matter in marine environments.  相似文献   

Scale effects in the determination of rock mass strength and deformability   总被引：1，自引：0，他引：1  

Francois E. Heuze 《Rock Mechanics and Rock Engineering》1980,12(3-4):167-192

SummaryScale Effects in the Determination of Rock Mass Strength and Deformability An extensive literature search was conducted, to investigate the effect of the scale of testing on the measurement of strength and stiffness of rock masses. The results are presented for bearing capacity tests, compression tests, and several types of deformability tests.Field strength values are generally several times smaller than laboratory values. Field moduli generally appear to be between 20 per cent to 60 per cent of laboratory measured moduli.All strength and deformability results reviewed point to the great need for more field tests. Specific suggestions are given.

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ZusammenfassungMastabeffekte bei der Bestimmung mechanischer Eigenschaften von Fels Ein eingehendes Literaturstudium wurde durchgeführt, um den Maßstabeffekt auf die Festigkeits- und Verformbarkeitsmessungen im Fels zu untersuchen. Es werden Resultate von Plattendruckversuchen, Druckversuchen und mehreren Verformungsversuchen aufgeführt. Die in-situ gemessene Festigkeit ist im allgemeinen ein Bruchteil derjenigen, die bei Laborversuchen festgestellt wird. Die Verformbarkeiten in-situ betragen meistens 20 bis 60 Prozent der im Labor erhaltenen Werte. Alle Resultate zeigen, daß mehr In-situ-Versuche notwendig sind. Der Autor macht dazu einige Vorschläge.

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RésuméL'effet d'échelle dans les mesures de propriétés mécaniques des massifs rocheux. On a fait une recherche bibliographique détaillée, pour étudier l'effet d'échelle sur les mesures de résistance et de déformabilité des masses rocheuses. On présente des résultats concernant les essais de résistance à la plaque, les essais de compression, et plusieurs types d'essais de déformabilité en place.Les résistances mesurées in-situ sont généralement une fraction de celles mesurées au laboratoire. Les déformabilités mesurées en place sont généralement entre 20 et 60 pour cent des valeurs au laboratoire.Tous les résultats que l'on a examiné indiquent la nécessité d'effectuer plus d'essais en place. L'auteur offre un certain nombre de suggestions.

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With 22 Figures  相似文献   

Annual survey of water vapor behavior from the OMEGA mapping spectrometer onboard Mars Express     

Luca Maltagliati  Dmitrij V. Titov  Thérèse Encrenaz  Francois Forget  Jean-Pierre Bibring 《Icarus》2011,213(2):480-1871

We present here the annual behavior of atmospheric water vapor on Mars, as observed by the OMEGA spectrometer on board Mars Express during its first martian year. We consider all the different features of the cycle of water vapor: temporal evolution, both at a seasonal and at a diurnal scale; longitudinal distribution; and the vertical profile, through the variations in the saturation height. We put our results into the context of the current knowledge on the water cycle through a systematic comparison with the already published datasets. The seasonal behavior is in very good agreement with past and simultaneous retrievals both qualitatively and quantitatively, within the uncertainties. The average water vapor abundance during the year is ∼10 pr. μm, with an imbalance between northern and southern hemisphere, in favor of the first. The maximum of activity, up to 60 pr. μm, occurs at high northern latitudes during local summer and shows the dominance of the northern polar cap within the driving processes of the water cycle. A corresponding maximum at southern polar latitudes during the local summer is present, but less structured and intense. It reaches ∼25 pr. μm at its peak. Global circulation has some influence in shaping the water cycle, but it is less prominent than the results from previous instruments suggest. No significant correlation between water vapor column density and local hour is detected. We can constrain the amount of water vapor exchanged between the surface and the atmosphere to few pr. μm. This is consistent with recent results by OMEGA and PFS-LW. The action of the regolith layer on the global water cycle seems to be minor, but it cannot be precisely constrained. The distribution of water vapor on the planet, after removing the topography, shows the already known two-maxima system, over Tharsis and Arabia Terra. However, the Arabia Terra increase is quite fragmented compared with previous observations. A deep zone of minimum separates the two regions. The saturation height of water vapor is mainly governed by the variations of insolation during the year. It is confined within 5-15 km from the surface at aphelion, while in the perihelion season it stretches up to 55 km of altitude.  相似文献   

Solubility of manganotantalite, zircon and hafnon in highly fluxed peralkaline to peraluminous pegmatitic melts   总被引：2，自引：0，他引：2  

Marieke Van Lichtervelde  Francois Holtz  John M. Hanchar 《Contributions to Mineralogy and Petrology》2010,160(1):17-32

The behavior of tantalum and zirconium in pegmatitic systems has been investigated through the determination of Ta and Zr solubilities at manganotantalite and zircon saturation from dissolution and crystallization experiments in hydrous, Li-, F-, P- and B-bearing pegmatitic melts. The pegmatitic melts are synthetic and enriched in flux elements: 0.7–1.3 wt% Li₂O, 2–5.5 wt% F, 2.8–4 wt% P₂O₅ and 0–2.8 wt% B₂O₃, and their aluminum saturation index ranges from peralkaline to peraluminous (ASI_Li = Al/[Na + K + Li] = 0.8 to 1.3) with various K/Na ratios. Dissolution and crystallization experiments were conducted at temperatures varying between 700 and 1,150°C, at 200 MPa and nearly water-saturated conditions. For dissolution experiments, pure synthetic, end member manganotantalite and zircon were used in order to avoid problems with slow solid-state kinetics, but additional experiments using natural manganotantalite and zircon of relatively pure composition (i.e., close to end member composition) displayed similar solubility results. Zircon and manganotantalite solubilities considerably increase from peraluminous to peralkaline compositions, and are more sensitive to changes in temperature or ASI of the melt than to flux content. A model relating the enthalpy of dissolution of manganotantalite to the ASI_Li of the melt is proposed: ∆H _diss (kJ/mol) = 304 × ASI_Li − 176 in the peralkaline field, and ∆H _diss (kJ/mol) = −111 × ASI_Li + 245 in the peraluminous field. The solubility data reveal a small but detectable competitivity between Zr and Ta in the melt, i.e., lower amounts of Zr are incorporated in a Ta-bearing melt compared to a Ta-free melt under the same conditions. A similar behavior is observed for Hf and Ta. The competitivity between Zr (or Hf) and Ta increases from peraluminous to peralkaline compositions, and suggests that Ta is preferentially bonded to non-bridging oxygens (NBOs) with Al as first-neighbors, whereas Zr is preferentially bonded to NBOs formed by excess alkalies. As a consequence Zr/Ta ratios, when buffered by zircon and manganotantalite simultaneously, are higher in peralkaline melts than in peraluminous melts.  相似文献   

Effects of melt composition on Fe3+/Fe2+ in silicate melts: a step to model ferric/ferrous ratio in multicomponent systems     

Alexander Borisov  Harald Behrens  Francois Holtz 《Contributions to Mineralogy and Petrology》2015,169(2):1-12

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小型激光天文动力学空间计划概念   总被引：1，自引：0，他引：1  

倪维斗  朱进  武向平  褚桂柏  杨彬  高健  关敏  汤健仁  周翊  张中豪  黄天衣  曲钦岳  易照华  李广宇  陶金河  吴岸明  罗俊  叶贤基  周泽兵  熊耀恒  毕少兰  须重明  吴雪君  唐孟希  包芸  李芳昱  黄珹  杨福民  叶叔华  张书练  张元仲  聂玉昕  陈光  Joergen Christensen-Dalsgaard  Hansjoerg Dittus  Yasunori Fujii  Claus Laemmerzahl  Jean Francois Mangin  Achim Peters  Albrecht Ruediger  Etienne Samain  Stephan Schiller 《天文研究与技术》2002,(3):123-136

小型激光天文动力学空间计划是 :使用在太阳轨道上无拖曳航天器和地面站以激光干涉和脉冲测距的方法 ,精确地探讨天文动力学 ,检测相对论与时空基本定律 ,改进探测引力波的灵敏度以及更准确地测定太阳、行星和小行星的参数。 1 969年开始的月球激光 (反射 )测距 ,对地球物理、参考坐标的选定、相对论的检验均有重要的贡献。 3 0年来 ,激光技术的长足进步 ,使现在正是适合于开始进行研究空间有源 (主动 )测距和光波空间通讯的时候。激光天文动力学的兴起是必然的趋势 ,其精确度将比现在提高 3到 6个数量级 ,将是天文动力学革命性的发展。小型激光天文动力学空间计划可以起到带头作用。它的关键技术有三 ,即 :弱光锁相、极精确无拖曳航天和高衰减日冕仪。弱光锁相已有长足的进步。对高衰减日冕仪的研究 ,也有了初步的方案。LISA空间计划将于 2 0 0 6年 8月发射SMART -2 ,研究测试极精确无拖曳航天。小型激光天文动力学空间计划的关键技术已日趋成熟。在第一届国际激光天文动力学研讨会 ( 2 0 0 1 ,9.1 3 -2 3 )中介绍了各相关学科背景及前沿研究 ,讨论了激光天文动力学空间计划科学目标及相关技术 ,并召开了两次小型激光天文动力学空间计划预研究筹备会 ,建立了和欧洲的合作关系。会后着手进行此项对基础  相似文献   

Characteristics of VLF emissions manifested by their cross-spectral phase information     

Dyfrig Jones  Francois Lefeuvre  Michel Parrot 《Planetary and Space Science》1983,31(10):1083-1097

Natural VLF emissions received by a single antenna can be characterised at each point in the emissions' frequency-time domain by a power and a phase. Emissions received at a single point by two antennae with a fixed relative orientation in space can be similarly described by the cross-spectral power and relative phase. It is shown that the cross-spectral phase contains information on the propagation characteristics of the waves which is better utilised in wave analysis than the power. In fact, the phase information allows weak signals to be identified more readily than is possible from a power spectrogram. It also allows the recognition of waves propagating with different wave normal directions. Data from the Geos-1 electric and magnetic antennae, pre-processed by the on-board correlator, are used to study the cross-spectral characteristics of VLF hiss and chorus in the Earth's magnetosphere.  相似文献   

Distribution and petrogenetic behaviour of trace elements in granitic pegmatite quartz from South Norway   总被引：1，自引：0，他引：1  

Rune?B.?LarsenEmail author  Iain?Henderson  Peter?M.?Ihlen  Francois?Jacamon 《Contributions to Mineralogy and Petrology》2004,147(5):615-628

The present study documents that the trace-element distribution in granitic quartz is highly sensitive to CAFC processes in granitic melts. Igneous quartz efficiently records both the origin and the evolution of the granitic pegmatites. Aluminium, P, Li, Ti, Ge and Na in that order of abundance, comprises >95% of the trace elements. Most samples feature >1 ppm of any of these elements. The remnant 5% includes K, Fe, Be, B, Ba and Sr whereas the other elements are present at concentrations lower than the detection limit. Potassium, Fe, Be and Ti are relatively compatible hence obtain the highest concentrations in early formed quartz. Phosphorous, Ge, Li and Al are relatively incompatible and generally obtain the highest concentrations in quartz that formed at lower temperatures from more evolved granitic melts. The Ge/Ti, the Ge/Be, the P/Ge and the P/Be ratios of quartz are strongly sensitive to the origin and evolution of the granitic melts and similarly the Rb/Sr and the Rb/K ratios of K-feldspars may be utilised in petrogenetic interpretations. However, the quartz trace element ratios are better at distinguishing similarities and differences in the origin and evolution of granitic melts. After evaluating the different trace element ratios, the Ge/Ti ratio appears to be most robust during subsolidus processes in the igneous systems, hence probably should be the preferred ratio for analysing and understanding petrogenetic processes in granitic igneous rocks.Editorial responsibility: J. Hoefs  相似文献   

Stable isotopes and trace elements in modern ostracod shells: implications for reconstructing past environments on the Tibetan Plateau,China   总被引：1，自引：0，他引：1  

Nicole Börner  Bart De Baere  Lailah Gifty Akita  Roger Francois  Klaus Peter Jochum  Peter Frenzel  Liping Zhu  Antje Schwalb 《Journal of Paleolimnology》2017,58(2):191-211

Stable isotopes and trace elements in ostracod shells have been used widely in paleolimnological investigations of past lake hydrochemistry and climate because they provide insights into past water balance and solute evolution of lakes. Regional differences in lake characteristics and species-specific element fractionation, however, do not permit generalization of results from other regions or ostracod species to the southern Tibetan Plateau, in part because most common taxa from the southern Tibetan Plateau are endemic to the area. This study evaluated relations between present-day environmental conditions and the geochemical composition of modern ostracod shells from the southern Tibetan Plateau, to assess the suitability of using shell chemistry to infer hydrological conditions. We studied nine lakes and their catchments, located along a west–east transect in the south-central part of the Tibetan Plateau. Stable oxygen and carbon isotope values and trace element concentrations in recent shells from the four most abundant ostracod species (Leucocytherella sinensis, ?Leucocythere dorsotuberosa, Limnocythere inopinata, Tonnacypris gyirongensis) were measured, together with hydrochemical properties of host waters at the time of sampling. Results revealed significant between-species differences in stable isotope fractionation and trace element incorporation into shell calcite. Stable oxygen and carbon isotope values of ostracod shells were correlated significantly with the stable isotope composition of the respective water body \( \left( {\updelta^{18} {\text{O}}_{{{\text{H}}_{ 2} {\text{O}}}} \,{\text{and }}\updelta^{13} {\text{C}}_{{{\text{H}}_{ 2} {\text{O}}}} } \right) \), reflecting salinity and productivity, respectively. Offsets between δ¹⁸O_shell and δ¹³C_shell and inorganic calcite, the latter representing isotopic equilibrium, suggest shell formation of T. gyirongensis during spring melt. L. sinensis reproduces throughout the monsoon season until September and shows several consecutive generations, and L. inopinata molts to the adult stage after the monsoon season in August/September. The influence of pore water δ¹³C was displayed by L. inopinata, suggesting shell calcification within the sediment. Mg/Ca_shell is primarily influenced by water Mg/Ca ratios and salinity and confirms the use of this shell ratio as a proxy for precipitation-evaporation balance and lake level. In addition, Sr/Ca and Ba/Ca can be used to infer changes in salinity, at least in closed-basin lakes with calcite saturation. Observed effects of water Sr/Ca and salinity on Sr/Ca incorporation are biased by the presence of aragonite precipitation in the lakes, which removes bioavailable Sr from the host water, resulting in low Sr/Ca_shell values. Changes in carbonate mineralogy affect the bioavailability of trace elements, a process that should be considered in paleoclimate reconstructions. Oxygen isotopes and Mg/Ca_shell ratios were unaffected by water temperature. Positive correlations among Fe/Ca, Mn/Ca and U/Ca in ostracod shells, and their negative correlation with δ¹³C, which reflects organic matter decay, show the potential to infer changes in redox conditions that can be used to reconstruct past oxygen supply to bottom waters and thus past water-circulation changes within lakes. The intensity of microbial activity, associated with organic matter decomposition, can be inferred from U/Ca ratios in ostracod shells. These findings highlight the value of fossil ostracod records in lake deposits for inferring paleoenvironmental conditions on the southern Tibetan Plateau.  相似文献   

Effects of Late Mergers on Stellar Populations in E and S0 Galaxies     

Francois Schweizer 《Astrophysics and Space Science》1999,267(1-4):299-307

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