Are peatlands in different states with respect to their thermodynamic behaviour? A simple test of peatland energy and entropy budgets     

Fred Worrall  Ross Morrison  Chris Evans  Joerg Kaduk  Susan Page  Alex Cumming  Mark Rayment  Nicholas Kettridge 《水文研究》2021,35(12):e14431

Whilst all ecosystems must obey the second law of thermodynamics, these physical bounds and controls on ecosystem evolution and development are largely ignored across the ecohydrological literature. To unravel the importance of these underlying restraints on ecosystem form and function, and their power to inform our scientific understanding, we have calculated the entropy budget of a range of peat ecosystems. We hypothesize that less disturbed peatlands are ‘near equilibrium’ with respect to the second law of thermodynamics and thus respond to change by minimizing entropy production. This ‘near equilibrium’ state is best achieved by limiting evaporative losses. Alternatively, peatlands ‘far-from-equilibrium’ respond to a change in energy inputs by maximizing entropy production which is best achieved by increasing evapotranspiration. To test these alternatives this study examined the energy balance time series from seven peatlands across a disturbance gradient. We estimate the entropy budgets for each and determine how a change in net radiation (ΔR_n) was transferred to a change in latent heat flux (ΔλE). The study showed that: (i) The transfer of net radiation to latent heat differed significantly between peatlands. One group transferred up to 64% of the change in net radiation to a change in latent heat flux, while the second transferred as little as 27%. (ii) Sites that transferred the most energy to latent heat flux were those that produced the greatest entropy. The study shows that an ecosystem could be ‘near equilibrium’ rather than ‘far from equilibrium’.  相似文献   

Development of large‐scale seismites in Upper Cretaceous fluvial sandstones in a fault‐proximal setting          下载免费PDF全文

Michael C. Wizevich  Edward L. Simpson  Hannah L. Hilbert‐Wolf  Sarah E. Tindall 《Sedimentology》2016,63(6):1719-1738

Large‐scale soft‐sediment deformation structures occur within fluvial sandstone bodies of the Upper Cretaceous Wahweap Formation in the Kaiparowits basin, southern Utah, USA. These structures represent an exceptional example of metre‐scale fault‐proximal, seismogenic load structures in nearly homogenous sandstones. The load structures consist of two types: large‐scale load casts and wedge‐shaped load structures. Large‐scale load casts penetrate up to 4·5 m into the underlying sandstone bed. Wedge‐shaped load structures include metre‐scale, parallel, sub‐vertical features and decimetre‐scale features along the periphery of the large‐scale load casts or other wedge‐shaped load structures. Wedge‐shaped load structures contain well‐developed, medial cataclastic shear deformation bands. All load structures contain pervasive well‐defined millimetre‐thick to centimetre‐thick internal laminae, oriented parallel to the outside form of the load structures and asymptotic to deformation bands. Both types of load structures formed because of an inverted density profile, earthquake‐triggered liquefaction and growth of irregularities (a Rayleigh–Taylor instability) on the sandstone–sandstone erosional contact. The internal laminae and deformation bands formed during deformation and clearly demonstrate polyphase deformation, recording a transition from liquefied to hydroplastic to brittle modes of deformation. Decimetre‐scale wedge‐shaped load structures on the edge of the large‐scale load casts probably formed towards the end of a seismic event after the sediment dewatered and increased the frictional contact of grains enough to impart strength to the sands. Metre‐scale wedge‐shaped load structures were created as the tips of downward foundering sediments were driven into fractures, which widened incrementally with seismic pulsation. With each widening of the fracture, gravity and a suction effect would draw additional sediment into the fracture. Superimposed laminae indicate a secondary syndeformational origin for internal laminae, probably by flow‐generated shearing and vibrofluidization mechanisms. Large‐scale and wedge‐shaped load structures, polyphase deformation and secondary laminae may characterize soft‐sediment deformation in certain fault‐proximal settings.  相似文献   

The hydrogeology of the Sacramento Mountains and Roswell and Salt basins of New Mexico,USA: overview of investigations on dryland groundwater systems using environmental tracers and geochemical approaches     

Brent D. Newman  Lewis Land  Fred M. Phillips  Geoffrey C. Rawling 《Hydrogeology Journal》2016,24(4):753-756

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Soil-water dynamics and tree water uptake in the Sacramento Mountains of New Mexico (USA): a stable isotope study     

Casey?Gierke  B.?Talon?NewtonEmail author  Fred?M.?Phillips 《Hydrogeology Journal》2016,24(4):805-818

In the southwestern United States, precipitation in the high mountains is a primary source of groundwater recharge. Precipitation patterns, soil properties and vegetation largely control the rate and timing of groundwater recharge. The interactions between climate, soil and mountain vegetation thus have important implications for the groundwater supply. This study took place in the Sacramento Mountains, which is the recharge area for multiple regional aquifers in southern New Mexico. The stable isotopes of oxygen and hydrogen were used to determine whether infiltration of precipitation is homogeneously distributed in the soil or whether it is partitioned among soil-water ‘compartments’, from which trees extract water for transpiration as a function of the season. The results indicate that “immobile” or “slow” soil water, which is derived primarily from snowmelt, infiltrates soils in a relatively uniform fashion, filling small pores in the shallow soils. “Mobile” or “fast” soil water, which is mostly associated with summer thunderstorms, infiltrates very quickly through macropores and along preferential flow paths, evading evaporative loss. It was found that throughout the entire year, trees principally use immobile water derived from snowmelt mixed to differing degrees with seasonally available mobile-water sources. The replenishment of these different water pools in soils appears to depend on initial soil-water content, the manner in which the water was introduced to the soil (snowmelt versus intense thunderstorms), and the seasonal variability of the precipitation and evapotranspiration. These results have important implications for the effect of climate change on recharge mechanisms in the Sacramento Mountains.  相似文献   

Social capital,individual responses to heat waves and climate change adaptation: An empirical study of two UK cities     

Johanna Wolf  W. Neil Adger  Irene Lorenzoni  Vanessa Abrahamson  Rosalind Raine 《Global Environmental Change》2010,20(1):44-52

It has been claimed that high social capital contributes to both positive public health outcomes and to climate change adaptation. Strong social networks have been said to support individuals and collective initiatives of adaptation and enhance resilience. As a result, there is an expectation that social capital could reduce vulnerability to risks from the impacts of climate change in the health sector. This paper examines evidence on the role social networks play in individuals’ responses to heat wave risk in a case study in the UK. Based on interviews with independently living elderly people and their primary social contacts in London and Norwich, we suggest that strong bonding networks could potentially exacerbate rather than reduce the vulnerability of elderly people to the effects of heat waves. Most respondents interviewed did not feel that heat waves posed a significant risk to them personally, and most said that they would be able to cope with hot weather. Bonding networks could perpetuate rather than challenge these narratives and therefore contribute to vulnerability rather than ameliorating it. These results suggest a complex rather than uniformly positive relationship between social capital, health and adaptation to climate change.  相似文献   

Wolfsburg fifty years on —and the future?     

Wolf Tietze 《GeoJournal》1988,17(1):75-83

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Variational stabilization of the ionic charge densities in the electron-gas theory of crystals: Applications to MgO and CaO     

George H. Wolf  Mark S. T. Bukowinski 《Physics and Chemistry of Minerals》1988,15(3):209-220

The electron-gas theory of crystals is extended to include the effects of many-body forces that arise from both electrostatic and overlap interactions. These effects are incorporated through a self-consistent spherical relaxation of the ionic charge distributions such that the crystal binding energy is minimized. This variational model is used to compute the elastic constants and equations of state of MgO and CaO, and we compare its results to those derived from earlier electron-gas models. In the variational model, the anion charge distributions are markedly more sensitive to the local crystal environment than they are in the PIB or other electron-gas models. We find that for these oxides the variational model gives the best overall agreement with experiment for lattice constants, equations of state, dissociation energies, and elastic moduli.  相似文献   

Iron porphyrins in the Permian Kupferschiefer of the lower Rhine Basin, N.W. Germany     

C. B. Eckardt  M. Wolf  J. R. Maxwell 《Organic Geochemistry》1989,14(6)

Immature samples of the Permian Kupferschiefer from the Lower Rhine Basin in N.W. Germany were analysed for tetrapyrrole pigment type and abundance. The sediment, thought to have been deposited in a marine regime with enhanced salinity, was found to contain high concentrations of metalloporphyrins. The porphyrins are complexed to nickel (Ni) and oxovanadium (V=0), but high abundances of iron (Fe) porphyrins were also detected using UV/visible spectroscopy and mass spectrometry. The presence in the latter of series of aetioporphyrins, cycloalkanoporphyrins, di-cycloalkanoporphyrins and benz-cycloalkanoporphyrins was confirmed by accurate mass measurements; HPLC co-injection of deoxophylloerythroetioporphyrin (C₃₂ DPEP) with the demetallated iron porphyrins indicated its presence in the sediment as an iron complex. The study provides the first evidence for the occurrence of Fe porphyrins in geological samples other than coals and lignites, and reports the highest concentrations in sedimentary organic matter to date.  相似文献   

Criterion of stability and implementation issues of hybrid frequency-time-domain procedure for non-linear dynamic analysis     

Georges R. Darbre  John P. Wolf 《地震工程与结构动力学》1988,16(4):569-581

A criterion of stability pertaining to the hybrid frequency-time-domain procedure is derived. It stems from the initial-value theorem on one side and from the condition of convergence which applies to the harmonic counterpart of the procedure on the other side. The criterion depends on the dynamic stiffnesses of both the original non-linear system and the pseudo-linear system evaluated at the Nyquist frequency. Since at this frequency both stiffnesses are usually controlle by the mass, the criterion of stability is satisfied for most structural systems. The procedure must, however, be applie sequentially to individual time segments. The validity of this criterion is confirmed by a numerical investigation performe for a SDOF system. The solution of non-linear dynamic problems requires consideration of implementation issues which are also discusse in the paper. The analysis of a non-linear soil-structure-interaction system in which the soil's stiffness coefficients an directly defined in the frequency domain also demonstrates the accuracy of the hybrid frequency-time-domain procedure.  相似文献   

Deglacial land emergence and lateral upper-mantle heterogeneity in the Svalbard Archipelago—I. First results for simple load models     

Doris Breuer  Detlef Wolf 《Geophysical Journal International》1995,121(3):775-788

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