In Situ Multi-Element Analysis of the Mount Pinatubo Quartz-Hosted Melt Inclusions by NIR Femtosecond Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry     

Anastassia Yu. Borisova  Rémi Freydier  Mireille Polvé  Stefano Salvi  Frederic Candaudap  Thierry Aigouy 《Geostandards and Geoanalytical Research》2008,32(2):209-229

Microscopic melt inclusions found in magmatic minerals are undoubtedly one of the most important sources of information on the chemical composition of melts. This paper reports on the successful application of near-infrared (NIR) femtosecond laser ablation (LA) - inductively coupled plasma-mass spectrometry to in situ determination of incompatible trace elements (Li, Rb, Sr, Y, Zr, Nb, Cs, Ba, REE, Ta, Th, U) and ore metals (As, Mo, Pb) in individual melt inclusions hosted in quartz from the Mount Pinatubo dacites, Philippines. The determined elements cover a concentration range of five orders of magnitude. Femtosecond LA-ICP-MS analyses of twenty-eight individual melt inclusions demonstrate the efficiency of the microanalytical technique and suggests a spectacular homogeneity of the entrapped melt, at least with respect to the following incompatible trace elements: Rb, Sr, Nb, Cs, Ba, La, Ce, Pr, Nd, Pb, Th. The analytical precision (1s) for Na, Ca, Rb, Sr, Y, Nb, Ba and LREE ranged from 3 to 20%. Comparison of trace element concentrations in Mt. Pinatubo melt inclusions determined by femtosecond LA-ICP-MS with those of melt inclusions previously analysed by secondary ion mass spectrometry analysis (SIMS) and those of matrix glasses previously determined by nanosecond LA-ICP-MS showed an agreement typically within 30–40%. The homogeneity of trace element concentrations of the Mt. Pinatubo melt inclusions and the matrix glasses is consistent with the melt inclusion origin as homogeneous rhyolitic melt that was trapped in quartz phenocrysts at the final crystallisation stages of the host adakite (dacite) magma.  相似文献   

A note on 10Be‐derived mean erosion rates in catchments with heterogeneous lithology: examples from the western Central Andes          下载免费PDF全文

Sebastien Carretier  Vincent Regard  Riccardo Vassallo  Joseph Martinod  Frederic Christophoul  Eric Gayer  Laurence Audin  Christelle Lagane 《地球表面变化过程与地形》2015,40(13):1719-1729

Millennial catchment–mean erosion rates derived from terrestrial cosmogenic nuclides are generally based on the assumption that the lithologies of the parent rock each contain the same proportion of quartz. This is not always true for large catchments, in particular at the edge of mountainous plateaus where quartz‐rich basement rocks may adjoin sedimentary or volcano‐sedimentary rocks with low quartz content. The western Central Andes is an example of this type of situation. Different quartz contents may be taken into account by weighting the TCN production rates in the catchment. We recall the underlying theory and show that weighting the TCN production rate may also lead to bias in the case of a spatial correlation between erosion rate and lithology. We illustrate the difference between weighted and unweighted erosion rates for seven catchments (16 samples) in southern Peru and northern Chile and show variations up to a factor of 2 between both approaches. In this dataset, calculated erosion rates considering only granitoid outcrops are better correlated with catchment mean slopes than those obtained without taking into account the geological heterogeneity of the drained watershed. This dataset analysis demonstrates that weighting erosion rates by relative proportions of quartz is necessary to evaluate the uncertainties for calculated catchment–mean erosion rates and may reveal the correlation with geomorphic parameters. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   

Numerical evidence of site effects contributing to triggering the Las Colinas landslide during the 2001 <Emphasis Type="Italic">M</Emphasis><Subscript>w</Subscript> = 7.7 El Salvador earthquake     

Zezhong Zhang  Jean-Alain Fleurisson  Frederic L. Pellet 《Landslides》2018,15(12):2373-2384

The Las Colinas landslide, which was triggered by the 13 January 2001, M_w?=?7.7 El Salvador earthquake, was highly destructive. The local site is composed of pyroclastic flows, brown cinders, soft pyroclastic fall deposits and a thin palaeosol and is characterised by steep slopes. The extremely high ground motions recorded near the landslide location are assumed to be both produced by site effects and responsible for the landslide. To characterise the ground motion amplifications due to site effects in terms of the variation in geometrical and geological settings, parametric studies were conducted with a linear elastic slope model, which was vertically subjected to the scattering SV wave of the Gabor wavelet. The results show that a maximum amplification is obtained when the model slope angle is approximately 30° (similar to the actual slope angle), and the maximum amplification is located approximately 20 m behind the crest, where the actual movement was initiated. Additionally, a slope with a height of approximately 160 m enhances ground motion amplification. The subsurface geology is found to induce a greater effect on amplification than that of the slope topography. In particular, a soft pyroclastic fall deposit is observed to contribute most of the ground motion amplification. According to the numerical results, it can be concluded that the local site conditions induced extremely high ground motions that then contributed to the slope movement. Although the thin, buried layer of palaeosol did not cause any significant amplification, its weak cohesion enhanced movement.  相似文献   

Gradual diversions of the Rio Pastaza in the Ecuadorian piedmont of the Andes from 1906 to 2008: role of tectonics, alluvial fan aggradation, and ENSO events     

Carolina Bernal  Frédéric Christophoul  Jean-Claude Soula  José Darrozes  Luc Bourrel  Alain Laraque  José Burgos  Séverine Bès de Berc  Patrice Baby 《International Journal of Earth Sciences》2012,101(7):1913-1928

The successive courses of the Rio Pastaza in the upper Amazonian Puyo plateau (Ecuador) during the past century have been followed using historical maps, aerial photographs, satellite imagery, topographic and river long profiles, and field studies. The abrupt change in direction of the Rio Pastaza from transverse to longitudinal was a result of two avulsions occurred between 1906 and 1976 at the braided-meandering transition of the former alluvial plain. These avulsions are related to aggradation at the toe of a braided piedmont fan prograding on to a hinterland-dipping topographic slope formed by ongoing tectonic backtilting. The main avulsion proceeded by annexation of a south-dipping depression created in front of the cordillera by backtilting of the plateau. A partial and gradual avulsion having occurred upstream of the former site between 1976 and 2008 is marked by the progressive predominance of a newly formed inner branch. Tectonic backtilting enhanced aggradation upstream of the initial site while it offered the newly avulsed channel a still more favorable way along the cordillera by creating a westward lateral slope. The correlation between ENSO events and the occurrence of the 1976–2008 avulsions strongly suggests that the triggers of the avulsions were the floods caused by the high water and sediment discharges associated with ENSO (La Ni?a) events contrasting with the regular monthly discharge and the lack of actual ‘normal’ floods during the inter-ENSO periods.  相似文献   

ISRM Suggested Method for Step-Rate Injection Method for Fracture In-Situ Properties (SIMFIP): Using a 3-Components Borehole Deformation Sensor     

Yves Guglielmi  Frederic Cappa  Hervé Lançon  Jean Bernard Janowczyk  Jonny Rutqvist  C. F. Tsang  J. S. Y. Wang 《Rock Mechanics and Rock Engineering》2014,47(1):303-311

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Estimating water fluxes in the critical zone using water stable isotope approaches in the Groundnut and Ferlo basins of Senegal     

Djim M. L. Diongue  Christine Stumpp  Olivier Roupsard  Didier Orange  Frederic C. Do  Serigne Faye 《水文研究》2023,37(1):e14787

Sustainable water management in semi-arid agriculture practices requires quantitative knowledge of water fluxes within the soil-vegetation-atmosphere system. Therefore, we used stable-isotope approaches to evaluate evaporation (E_a), transpiration (T_a), and groundwater recharge (R) at sites in Senegal's Groundnut basin and Ferlo Valley pasture region during the pre-monsoon, monsoon, and post-monsoon seasons of 2021. The approaches were based upon (i) the isothermal evaporation model (for quantifying E_a); (ii) water and isotope mass balances (to partition E_a and T_a for groundnut and pasture); and (iii) the piston displacement method (for estimating R). E_a losses derived from the isothermal evaporation model corresponded primarily to Stage II evaporation, and ranged from 0.02 to 0.09 mm d⁻¹ in the Groundnut basin, versus 0.02–0.11 mm d⁻¹ in Ferlo. At the groundnut site, E_a rates ranged from 0.01 to 0.69 mm d⁻¹; T_a was in the range 0.55–2.29 mm d⁻¹; and the T_a/ET_a ratio was 74%–90%. At the pasture site, the ranges were 0.02–0.39 mm d⁻¹ for E_a; 0.9–1.69 mm d⁻¹ for T_a; and 62–90% for T_a/ET_a. The ET_a value derived for the groundnut site via the isotope approach was similar to those from eddy covariance measurements, and also to the results from the previous validated HYDRUS-1D model. However, the HYDRUS-1D model gave a lower T_a/ET_a ratio (23.2%). The computed groundwater recharge for the groundnut site amounted to less than 2% of the local annual precipitation. Recommendations are made regarding protocols for preventing changes to isotopic compositions of water in samples that are collected in remote arid regions, but must be analysed days later. The article ends with suggestions for studies to follow up on evidence that local aquifers are being recharged via preferential pathways.  相似文献