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31.
Geochemical studies of long-lived volcanic complexes are crucial for the understanding of the nature and composition of the subduction component of arc magmatism. The Pichincha Volcanic Complex (Northern Andean Volcanic Zone) consists of: (1) an old, highly eroded edifice, the Rucu Pichincha, whose lavas are mostly andesites, erupted from 1,100 to 150 ka; and (2) a younger, essentially dacitic, Guagua Pichincha composite edifice, with three main construction phases (Basal Guagua Pichincha, Toaza, and Cristal) which developed over the last 60 ka. This structural evolution was accompanied by a progressive increase of most incompatible trace element abundances and ratios, as well as by a sharp decrease of fluid-mobile to fluid-immobile element ratios. Geochemical data indicate that fractional crystallization of an amphibole-rich cumulate may account for the evolution from the Guagua Pichincha andesites to dacites. However, in order to explain the transition between the Rucu Pichincha andesites and Guagua Pichincha dacites, the mineralogical and geochemical data indicate the predominance of magma mixing processes between a mafic, trace-element depleted, mantle-derived end-member, and a siliceous, trace-element enriched, adakitic end-member. The systematic variation of trace element abundances and ratios in primitive samples leads us to propose that the Rucu Pichincha magmas came from a hydrous-fluid metasomatized mantle wedge, whereas Guagua Pichincha magmas are related to partial melting of a siliceous-melt metasomatized mantle. This temporal evolution implies a change from dehydration to partial melting of the slab, which may be associated with an increase in the geothermal gradient along the slab due to the presence of the subducted Carnegie Ridge at the subduction system. This work emphasizes the importance of studying arc-magma systems over long periods of time (of at least 1 million of years), in order to evaluate the potential variations of the slab contribution into the mantle source of the arc magmatism.  相似文献   
32.
The Polochic and Motagua faults define the active plate boundary between the North American and Caribbean plates in central Guatemala. A splay of the Polochic Fault traverses the rapidly growing city of San Miguel Uspantán that is periodically affected by destructive earthquakes. This fault splay was located using a 2D electrical resistivity tomography (ERT) survey that also characterized the fault damage zone and evaluated the thickness and nature of recent deposits upon which most of the city is built. ERT images show the fault as a ~50 m wide, near-vertical low-resistivity anomaly, bounded within a few meters by high resistivity anomalies. Forward modeling reproduces the key aspects of the observed electrical resistivity data with remarkable fidelity thus defining the overall location, geometry, and internal structure of the fault zone as well as the affected lithologies. Our results indicate that the city is constructed on a ~20 m thick surficial layer consisting of poorly consolidated, highly porous, water-logged pumice. This soft layer is likely to amplify seismic waves and to liquefy upon moderate to strong ground shaking. The electrical conductivity as well as the major element chemistry of the groundwater provides evidence to suggest that the local aquifer might, at least in part, be fed by water rising along the fault. Therefore, the potential threat posed by this fault splay may not be limited to its seismic activity per se, but could be compounded its potential propensity to enhance seismic site effects by injecting water into the soft surficial sediments. The results of this study provide the basis for a rigorous analysis of seismic hazard and sustainable development of San Miguel Uspantán and illustrate the potential of ERT surveying for paleoseismic studies.  相似文献   
33.
Laguna Chichój (Lake Chichój) is the only deep permanent lake in the central highlands of Guatemala. The lake is located in the boundary zone between the North American and Caribbean plates. The lake has been struck by devastating earthquakes and tropical cyclones in historical times. We investigated the imprint of twentieth century extreme events on the sedimentary record of this tropical lake using a bathymetric survey of the lake, coring the lake floor, and providing a chronology of sediment accumulation. The lake occupies a series of circular depressions likely formed by the rapid dissolution of a buried body of gypsum. 210Pb and 137Cs inventories and varve counting indicate high rates of sedimentation (1–2 cm year?1). The annually layered sediment is interrupted by turbidites of two types: a darker-colored turbidite, enriched in lake-derived biogenic constituents, and interpreted as a seismite, and a lighter-colored type, enriched in catchment-derived constituents, interpreted as a flood layer. Comparison of our 137Cs-determined layer ages with a catalog of twentieth century earthquakes shows that an earthquake on the Motagua fault in 1976 generated a conspicuous darker-colored turbidite and slumped deposits in separate parts of the lake. The entire earthquake inventory further reveals that mass movements in the lake are triggered at Modified Mercalli Intensities higher than V. Tropical cyclonic depressions known to have affected the lake area had limited effect on the lake, including Hurricane Mitch in 1998. One storm however produced a significantly thicker flood layer in the 1940s. This storm is reportedly the only event to have generated widespread slope failures in the lake catchment. It is thus inferred that abundant landsliding provided large amounts of concentrated sediment to the lake, through hyperpycnal flows.  相似文献   
34.
High-frequency variability of the ionosphere, or irregularities, constitutes the main threat for real-time precise positioning techniques based on Global Navigation Satellite Systems (GNSS) measurements. Indeed, during periods of enhanced ionospheric variability, GNSS users in the field—who cannot verify the integrity of their measurements—will experience positioning errors that can reach several decimeters, while the nominal accuracy of the technique is cm-level. In the frame of this paper, a climatological analysis of irregularities over the European mid-latitude region is presented. Based on a 10 years GPS dataset over Belgium, the work analyzes the occurrence rate (as a function of the solar cycle, season and local time) as well as the amplitude of ionospheric irregularities observed at a single GPS station. The study covers irregularities either due to space weather events (solar origin) or of terrestrial origin. If space weather irregularities are responsible for the largest effects in terms of ionospheric error, their occurrence rate highly depends on solar activity. Indeed, the occurrence rate of ionospheric irregularities is about 9 % during solar maximum, whereas it drops to about 0 % during medium or low solar activity periods. Medium-scale ionospheric disturbances (MSTIDs) occurring during daytime in autumn/winter are the most recurrent pattern of the time series, with yearly proportions slightly varying with the solar cycle and an amplitude of about 10 % of the TEC background. Another recurrent irregularity type, though less frequent than MSTIDs, is the noise-like variability in TEC observed during summer nighttime, under quiet geomagnetic conditions. These summer nighttime irregularities exhibit amplitudes ranging between 8 and 15 % of the TEC background.  相似文献   
35.
Determining how the global mean sea level (GMSL) evolves with time is of primary importance to understand one of the main consequences of global warming and its potential impact on populations living near coasts or in low-lying islands. Five groups are routinely providing satellite altimetry-based estimates of the GMSL over the altimetry era (since late 1992). Because each group developed its own approach to compute the GMSL time series, this leads to some differences in the GMSL interannual variability and linear trend. While over the whole high-precision altimetry time span (1993–2012), good agreement is noticed for the computed GMSL linear trend (of $3.1\pm 0.4$  mm/year), on shorter time spans (e.g., ${<}10~\hbox {years}$ ), trend differences are significantly larger than the 0.4 mm/year uncertainty. Here we investigate the sources of the trend differences, focusing on the averaging methods used to generate the GMSL. For that purpose, we consider outputs from two different groups: the Colorado University (CU) and Archiving, Validation and Interpretation of Satellite Oceanographic Data (AVISO) because associated processing of each group is largely representative of all other groups. For this investigation, we use the high-resolution MERCATOR ocean circulation model with data assimilation (version Glorys2-v1) and compute synthetic sea surface height (SSH) data by interpolating the model grids at the time and location of “true” along-track satellite altimetry measurements, focusing on the Jason-1 operating period (i.e., 2002–2009). These synthetic SSH data are then treated as “real” altimetry measurements, allowing us to test the different averaging methods used by the two processing groups for computing the GMSL: (1) averaging along-track altimetry data (as done by CU) or (2) gridding the along-track data into $2^{\circ }\times 2^{\circ }$ meshes and then geographical averaging of the gridded data (as done by AVISO). We also investigate the effect of considering or not SSH data at shallow depths $({<}120~\hbox {m})$ as well as the editing procedure. We find that the main difference comes from the averaging method with significant differences depending on latitude. In the tropics, the $2^{\circ }\times 2^{\circ }$ gridding method used by AVISO overestimates by 11 % the GMSL trend. At high latitudes (above $60^{\circ }\hbox {N}/\hbox {S}$ ), both methods underestimate the GMSL trend. Our calculation shows that the CU method (along-track averaging) and AVISO gridding process underestimate the trend in high latitudes of the northern hemisphere by 0.9 and 1.2 mm/year, respectively. While we were able to attribute the AVISO trend overestimation in the tropics to grid cells with too few data, the cause of underestimation at high latitudes remains unclear and needs further investigation.  相似文献   
36.
We report a measurement procedure to determine simultaneously the major cation concentrations (Na, Ca, K and Mg) of seawater‐derived solutions by inductively coupled plasma‐atomic emission spectrometry. The best results were obtained when the IAPSO (‘standard’) seawater reference material was diluted by thirty times with Milli‐Q® water. We obtained an average reference value rK (the ratio of the mass fraction of potassium to that of chlorine, i.e., (g kg?1)/(g kg?1)) for IAPSO seawater of 0.0205 ± 0.0006 (2.9% RSD), not significantly different from 0.0206 ± 0.0005 (2.4% RSD) for seawater composition reported in the literature. The measured Na, Ca and Mg concentrations correspond to rNa, rCa and rMg values of 0.5406 ± 0.0026 (0.5% RSD), 0.02192 ± 0.00048 (2.2% RSD) and 0.06830 ± 0.00047 (0.7% RSD), respectively, in line with previous values measured by wet‐chemistry and atomic absorption spectrophotometry or wet‐chemical titration. Our measurement procedure was used successfully on synthetic seawater solutions and high‐temperature hydrothermal fluids.  相似文献   
37.
In this paper, we compare the elemental and isotopic (C, N, Pb) geochemistry of lake sediments from two contrasted environments in south‐central Chile. The first lake, Laguna Chica de San Pedro (LCSP), is situated in the urbanised area of the Biobio Region (36°S). The second lake, Lago Puyehue (40° S), is located 400 km to the southeast of LCSP and within an Andean national park. Our aim is to identify environmental impacts associated with increasing industrial activities and land degradation during the last 150 a. In LCSP, shifts in C/N atomic ratios, δ13C and δ15N from 1915–1937 to the late 1980s are attributed to successive land degradation episodes in the lake watershed. Based on a Pb isotopic mixing model, we estimate that up to 20% of lead in LCSP sediments is supplied from urban atmospheric pollution. By contrast, human impact in the watershed of Lago Puyehue is very limited. We observe no change in organic geochemistry during the last 150 a and lead contamination remains lower than 5%, even during the last decades. Although contamination levels are much higher in LCSP than in Lago Puyehue, a peak in anthropogenic Pb is recorded during the same period (1974–1976) at both sites. This maximum contamination level is consistent with increased industrial activity in the vicinity of Concepción. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
38.
39.
A significant increase of the permeability of concrete upon micro‐cracking and a good correlation between the evolution of damage (material stiffness) and permeability are observed experimentally. The present contribution investigates this correlation theoretically, with the help of lattice analyses. Scaling analysis of lattices which contain elastic brittle bonds has shown that the material degradation should be described by the evolution of the material stiffness, or compliance, in a continuum setting (damage models). This result is reviewed and further documented in the first part of the paper. In the second part, hydro‐mechanical problems are considered with the construction of a hydraulic lattice, dual to the mechanical one. We observe that the average permeability upon micro‐cracking is the lattice scale‐independent controlling variable in the hydraulic problem. Additionally, results show that in a continuum poro‐mechanical approach, the evolution of the material permeability ought to be related to the elastic unloading stiffness, described e.g. with the help of continuum damage variables. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
40.
Recent studies of the Baltic clam Macoma balthica (L.) from the southern Baltic (the Gulf of Gdansk) have revealed striking morphological, histological and cytogenetic features. Strong deformation of the shell, including elongation of the posterior end and the appearance of an easily visible flexure in this part, has been recorded. The population contribution of the deformed blunt shelled ("irregular") clams ranged from 0% to 65% and tended to increase with depth. The morphologically "irregular" clams had higher accumulated tissue concentrations of trace metals (As, Ag, Cd, Pb, Cu and Zn), indicating a different metal handling ability. Adverse conditions in deeper water regions of the Gulf (e.g. hypoxia, hydrogen sulphide, elevated bioavailability of contaminants) have been suggested as inducers of the phenotypical changes (morphological deformation) in part of the population and, in parallel, of the specific physiological adaptations that result in higher metal accumulation in the "irregular" clams. Cytogenetic and histological analyses showed the presence of tumours in gill cells and digestive system of the affected clams, the prevalence of disseminated neoplasia ranging from 0% to 94% depending on the site. The disease was manifested by a modified karyotype (i.e. an abnormal number and morphology of chromosomes), a higher activity of nucleolar organizer regions (AgNORs), and tissue lesions (enlarged cells, actively proliferative with pleomorphic nuclei). Bottom sediments showed acute toxicity and have been proposed as a source of an initialising carcinogenic factor. However, none of the ecotoxicological studies provided was successful in the clear demonstration of a single (or multifactorial) agent that can account for the disseminated neoplasia.  相似文献   
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