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31.
Increasing physical oceanographic evidence suggests that a regime shift, which featured increased equatoward surface winds and upwelling in the Eastern Pacific Boundary Current region, occurred following the 1997–1998 El Niño. We expect the signal of this change in biota to be stronger in euphausiids than in pelagic fishes such as Pacific hake (Merluccius productus) because lower trophic levels are more responsive to changes in upwelling and primary production. We used acoustic backscatter data from acoustic surveys in summer 1995, 1998, and 2001 to explore whether significant changes in abundance and distribution of euphausiids and fishes have occurred between 1995 and 2001. Graphical and statistical results show that the density of fish schools and euphausiid patches increased significantly south of Cape Blanco between 1995 and both 1998 and 2001. North of Cape Blanco there was no consistent change in euphausiid abundance, although both fish and euphausiid distributions in 2001 appear to be significantly higher nearshore than in the other years. Pelagic fish abundance distributions appeared more closely linked to El Niño than to regime shifts, with abundance shifted much farther north in 1998, an El Niño year, than in the other years, while 1995 and 2001 fish abundance distributions are similar to each other. The regime shift appears so far to have had a stronger effect on euphausiids than on pelagic fishes. The change in euphausiid abundance and distribution between the survey years was linked, through a conceptual model, to the relative strength of the poleward flowing California undercurrent and equatorward flowing California current and to the distribution and abundance of hake.  相似文献   
32.
Effects of Land Use on the Climate of the United States   总被引:14,自引:0,他引:14  
Land use practices have replaced much of the natural needleleaf evergreen, broadleaf deciduous, and mixed forests of the Eastern United States with crops. To a lesser extent, the natural grasslands in the Central United States have also been replaced with crops. Simulations with a land surface process model coupled to an atmospheric general circulation model show that the climate of the United States with modern vegetation is significantly different from that with natural vegetation. Three important climate signals caused by modern vegetation are: (1) 1 °C cooling over the Eastern United States and 1 °C warming over the Western United States in spring; (2) summer cooling of up to 2 °C over a wide region of the Central United States; and (3) moistening of the near-surface atmosphere by 0.5 to 1.5 g kg-1over much of the United States in spring and summer. Although individual months show large, statistically significant differences in precipitation due to land-use practices, these differences average out over the course of the 3-month seasons. These changes in surface temperature and moisture extend well into the atmosphere, up to 500 mb, and affect the boundary layer and atmospheric circulation. The altered climate is due to reduced surface roughness, reduced leaf and stem area index, reduced stomatal resistance, and increased surface albedo with modern vegetation compared to natural vegetation. The climate change caused by land use practices is comparable to other well known anthropogenic climate forcings. For example, it would take 100 to 175 years at the current, observed rate of summer warming over the United States to offset the cooling from deforestation. The summer sulfate aerosol forcing completely offsets the greenhouse forcing over the Eastern United States. Similarly, the climatic effect of North American deforestation, with extensive summer cooling, further offsets the greenhouse forcing.  相似文献   
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We report here our experiences from using easily acquired web-cam components for collaborative ventures in the Earth sciences. We have used a variety of hardware and different software. We demonstrate from various locations in the U.S.A. the feasibility of using web-cam in multitudinous activities, relevant for conducting research and knowledge dissemination. We summarize the quality of the connections from the various combinations of communicating parties. Today, web-cams can be utilized as an economical and viable means of point-to-point communication in the Earth science community. Greater bandwidth is sorely needed for activities such as multi-party conferencing on the present internet network. We propose that web-cam can be readily deployed as a web-service for facilitating collaborative research over the GRID infrastructure, using the middleware Narada-Brokering. Web-cam will play an important role in the emerging field of geoinformatics.  相似文献   
35.
We have used synchrotron-based soft X-ray core-level photoemission and adsorption spectroscopies to study the reaction of aqueous sodium chromate solutions with freshly fractured pyrite surfaces. Pyrite surfaces were reacted with 50 μM sodium chromate solution at pH 7 for reaction times between 1 min and 37 hr. Additional experiments were performed at pH 2 and pH 4 with 50 μM sodium chromate solutions and at pH 7 with 5 mM solutions. At chromate concentrations of 50 μM, all chromium present on the pyrite surface was in the form of Cr(III), while at 5 mM, both Cr(III) and Cr(VI) were present at the pyrite surface. Minor quantities of oxidized sulfur species (sulfate, sulfite, and zero-valent sulfur) were identified as reaction products on the pyrite surface. The amount of oxidized sulfur species observed on the surface was greater when pyrite was reacted with 5 mM Cr(VI) solutions because the rate of chromium deposition exceeded the rate of dissolution of pyrite oxidation products, effectively trapping Cr(VI) and oxidized sulfur species in an overlayer of iron(III)-containing Cr(III)-hydroxide. This work shows that pyrite, an extremely cheap and readily available waste material, may be suitable for the removal of hexavalent chromium from acidic to circumneutral waste streams. The reduced chromium ultimately forms a coating on the pyrite surface, which passivates the pyrite surface towards further oxidation.  相似文献   
36.
Structuring subjectivities? Using Q methodology in human geography   总被引:3,自引:0,他引:3  
This paper presents a critical and reflexive account of using Q methodology in human geography. Q methodology has a long pedigree in psychological, political and sociological research, but is only recently beginning to be used by human geographers. We discuss, in particular, the parts of the process(es) of Q methodology that are often glossed over in the literature, through reflecting on our learning in using Q within a project examining the use and production of environmental science by NGOs. We conclude that Q may be a useful supplement to existing methods in human geography, as long as it is used creatively and reflexively and with full awareness of its interpretative dimensions.  相似文献   
37.
We measured monthly soil surface elevation change and determined its relationship to groundwater changes at a mangrove forest site along Shark River, Everglades National Park, Florida. We combined the use of an original design, surface elevation table with new rod-surface elevation tables to separately track changes in the mid zone (0–4 m), the shallow root zone (0–0.35 m), and the full sediment profile (0–6 m) in response to site hydrology (daily river stage and daily groundwater piezometric pressure). We calculated expansion and contraction for each of the four constituent soil zones (surface [accretion and erosion; above 0 m], shallow zone [0–0.35 m], middle zone [0.35–4 m], and bottom zone [4–6]) that comprise the entire soil column. Changes in groundwater pressure correlated strongly, with changes in soil elevation for the entire profile (Adjusted R2 = 0.90); this relationship was not proportional to the depth of the soil profile sampled. The change in thickness of the bottom soil zone accounted for the majority (R2 = 0.63) of the entire soil profile expansion and contraction. The influence of hydrology on specific soil zones and absolute elevation change must be considered when evaluating the effect of disturbances, sea level rise, and water management decisions on coastal wetland systems.  相似文献   
38.
The fate and transport of uranium in contaminated soils and sediments may be affected by adsorption onto the surface of minerals such as montmorillonite. Extended X-ray absorption fine structure (EXAFS) spectroscopy has been used to investigate the adsorption of uranyl (UO22+) onto Wyoming montmorillonite. At low pH (∼4) and low ionic strength (10−3 M), uranyl has an EXAFS spectrum indistinguishable from the aqueous uranyl cation, indicating binding via cation exchange. At near-neutral pH (∼7) and high ionic strength (1 M), the equatorial oxygen shell of uranyl is split, indicating inner-sphere binding to edge sites. Linear-combination fitting of the spectra of samples reacted under conditions where both types of binding are possible reveals that cation exchange at low ionic strengths on SWy-2 may be more important than predicted by past surface complexation models of U(VI) adsorption on related montmorillonites. Analysis of the binding site on the edges of montmorillonite suggests that U(VI) sorbs preferentially to [Fe(O,OH)6] octahedral sites over [Al(O,OH)6] sites. When bound to edge sites, U(VI) occurs as uranyl-carbonato ternary surface complexes in systems equilibrated with atmospheric CO2. Polymeric surface complexes were not observed under any of the conditions studied. Current surface complexation models of uranyl sorption on clay minerals may need to be reevaluated to account for the possible increased importance of cation exchange reactions at low ionic strengths, the presence of reactive octahedral iron surface sites, and the formation of uranyl-carbonato ternary surface complexes. Considering the adsorption mechanisms observed in this study, future studies of U(VI) transport in the environment should consider how uranium retardation will be affected by changes in key solution parameters, such as pH, ionic strength, exchangeable cation composition, and the presence or absence of CO2.  相似文献   
39.
Oil sands mining in Alberta transforms the boreal landscape of forests and wetlands into open pits, tailings ponds and overburden piles. Whereas reclamation efforts have primarily focused on upland forests, rebuilding wetland systems has recently become a motivation for research. Wetland creation and sustainability in this region is complicated by the sub‐humid climate and salinity of underlying mining material. In 2012, Syncrude Canada Ltd. completed the construction of the Sandhill Fen Watershed (SFW), a 52‐ha upland‐wetland system to evaluate wetland reclamation strategies on soft tailings. SFW includes an active pumping system, upland hummocks, a fen wetland and underdrains. To evaluate the influence of management practices on the hydrology of the system, this study reports the water balance from January 2013 to December 2014, the first 2 years after commissioning. A semi‐distributed approach was taken to examine the fluxes and stores of water in uplands and lowlands. Natural and artificial inputs and outputs were measured using a series of precipitation gauges and pumps, and evapotranspiration was quantified using three eddy covariance towers. A series of near surface wells recorded water table position. Both 2013 and 2014 were normal rainfall years, with 2013 having more and 2014 less snow than normal. In 2013, inflow/outflow from pumping was the predominant hydrological fluxes, resulting in considerable variability in water table position and storage changes throughout the summer. In 2014, the artificial addition of water was negligible, yet the water table remained near the surface in lowland locations, suggesting that wetland conditions could be maintained under current conditions. Evapotranspiration rates between uplands and lowlands were similar between years and sites, ranging from 2.2 ± 1.8 to 2.5 ± 1.2 mm/day and were largely controlled by climate. These rates were less than nearby older upland systems, suggesting that water balance partitioning will change as vegetation develops. Comparison between years and with natural systems provides insight on how management practices influence hydrologic dynamics and the overall water balance of the SFW. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
40.
In arctic and sub‐arctic environments, mercury (Hg), more specifically toxic methylmercury (MeHg), is of growing concern to local communities because of its accumulation in fish. In these regions, there is particular interest in the potential mobilization of atmospherically deposited Hg sequestered in permafrost that is thawing at unprecedented rates. Permafrost thaw and the resulting ground surface subsidence transforms forested peat plateaus into treeless and permafrost‐free thermokarst wetlands where inorganic Hg released from the thawed permafrost and draining from the surrounding peat plateaus may be transformed to MeHg. This study begins to characterize the spatial distribution of MeHg in a peat plateau–thermokarst wetland complex, a feature that prevails throughout the wetland‐dominated southern margin of thawing discontinuous permafrost in Canada's Northwest Territories. We measured pore water total Hg, MeHg, dissolved organic matter characteristics and general water chemistry parameters to evaluate the role of permafrost thaw on the pattern of water chemistry. A gradient in vegetation composition, water chemistry and dissolved organic matter characteristics followed a toposequence from the ombrotrophic bogs near the crest of the complex to poor fens at its downslope margins. We found that pore waters in poor fens contained elevated levels of MeHg, and the water draining from these features had dissolved MeHg concentrations 4.5 to 14.5 times higher than the water draining from the bogs. It was determined through analysis of historical aerial images that the poor fens in the toposequence had formed relatively recently (early 1970s) as a result of permafrost thaw. Differences between the fens and bogs are likely to be a result of their differences in groundwater function, and this suggests that permafrost thaw in this landscape can result in hotspots for Hg methylation that are hydrologically connected to downstream ecosystems. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   
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