The origin of chromitites and related PGE mineralization in the Bushveld Complex: new mineralogical and petrological constraints   总被引：2，自引：0，他引：2  

Naldrett  A. J.  Wilson  Allan  Kinnaird  Judith  Yudovskaya  Marina  Chunnett  Gordon 《Mineralium Deposita》2012,47(3):209-232

This article reports a study of chromitites from the LG-1 to the UG-2/3 from the Bushveld Complex. Chromite from massive chromitite follows two compositional trends on the basis of cation ratios: trend A—decreasing Mg/(Mg + Fe) with increasing Cr/(Cr + Al); trend B—decreasing Mg/(Mg + Fe) with decreasing Cr/(Cr + Al). The chromitites are divided into five stages on the basis of which trend they follow and the data of Eales et al. (Chemical Geology 88:261–278, 1990) on the behaviour of the Mg/Fe ratio of the pyroxene and whole rock Sr isotope composition of the environment in which they occur. Following Eales et al. (Chemical Geology 88:261–278, 1990), the different characteristics of the stages are attributed to the rate at which new magma entered the chamber and the effect of this on aAl₂O₃ and, in the case of stage 5, the appearance of cumulus plagioclase buffering the aAl₂O₃. The similarity of PGE profiles across the MG-3 and MG-4 chromitites that are separated laterally by up to 300 km and the variation in V in the UG-2 argue that the chromitites have largely developed in situ. Modelling using the programme MELTS shows that increase in pressure, mixing of primitive and fractionated magma, felsic contamination of primitive magma or addition of H₂O do not promote crystallization of spinel before orthopyroxene (in general they hinder it) and that the Cr₂O₃ content of the magma was of the order of 0.25 wt.%. Less than 20% of the chromite in the magma is removed before orthopyroxene joins chromite, which implies a >13-km thickness of magma for the Critical Zone. It is suggested that the large excess of magma has escaped up marginal structures such as the Platreef. The PGE profile of chromitites depends on whether sulphide accumulated or not along with chromite. Modelling shows that contamination of Critical Zone magma with a felsic melt will induce sulphide immiscibility, although not chromite precipitation. The LG-1 to LG-4 chromitites developed without sulphide, whilst those from the LG-5 upwards had associated liquid sulphide. Much of the sulphide originally in the LG-5 and above has been destroyed as a result of reaction with the chromite.  相似文献   

A Hydrological Budget (2002–2008) for a Large Subtropical Wetland Ecosystem Indicates Marine Groundwater Discharge Accompanies Diminished Freshwater Flow     

Amartya K. Saha  Christopher S. Moses  René M. Price  Victor Engel  Thomas J. SmithIII  Gordon Anderson 《Estuaries and Coasts》2012,35(2):459-474

Water budget parameters are estimated for Shark River Slough (SRS), the main drainage within Everglades National Park (ENP) from 2002 to 2008. Inputs to the water budget include surface water inflows and precipitation while outputs consist of evapotranspiration, discharge to the Gulf of Mexico and seepage losses due to municipal wellfield extraction. The daily change in volume of SRS is equated to the difference between input and outputs yielding a residual term consisting of component errors and net groundwater exchange. Results predict significant net groundwater discharge to the SRS peaking in June and positively correlated with surface water salinity at the mangrove ecotone, lagging by 1 month. Precipitation, the largest input to the SRS, is offset by ET (the largest output); thereby highlighting the importance of increasing fresh water inflows into ENP for maintaining conditions in terrestrial, estuarine, and marine ecosystems of South Florida.  相似文献   

Iron speciation in minerals and glasses probed by $$\hbox{M}_{2/3}$$-edge X-ray Raman scattering spectroscopy     

A.?NyrowEmail author  C.?Sternemann  M.?Wilke  R.?A.?Gordon  K.?Mende  H.?Yava?  L.?Simonelli  N.?Hiraoka  Ch.?J.?Sahle  S.?Huotari  G.?B.?Andreozzi  A.?B.?Woodland  M.?Tolan  J.?S.?Tse 《Contributions to Mineralogy and Petrology》2014,167(5):1012

We present a spectroscopic study of the iron \(\hbox{M}_{2/3}\)-edge for several minerals and compounds to reveal information about the oxidation state and the local coordination of iron. We describe a novel approach to probe the iron \(\hbox{M}_{2/3}\)-edge bulk sensitively using X-ray Raman scattering. Significant changes in the onset and shape of the Fe \(\hbox{M}_{2/3}\)-edge were observed on ferrous and ferric model compounds with Fe in octahedral and tetrahedral coordination. Simulation of the spectra is possible using an atomic multiplet code, which potentially allows determination of, e.g., crystal-field parameters in a quantitative manner. A protocol is discussed for determination of the Fe oxidation state in compounds by linear combination of spectra of ferric and ferrous end members. The presented results demonstrate the capabilities of Fe \(\hbox{M}_{2/3}\)-edge spectroscopy by X-ray Raman scattering to extract information on the ratio of trivalent to total iron \(\hbox{Fe}^{3+}/\sum \hbox{Fe}\) and local coordination. As X-ray Raman scattering is performed with hard X-rays, this approach is suitable for in situ experiments at high pressure and temperature. It thus may provide indispensable information on oxidation state, electronic structure and local structure of materials that are important for physical and chemical processes of the deep Earth.  相似文献   

Oxygen fugacity control in piston-cylinder experiments: a re-evaluation     

Sigurdur Jakobsson  Jon Blundy  Gordon Moore 《Contributions to Mineralogy and Petrology》2014,167(6):1-4

Jakobsson (Contrib Miner Petrol 164(3):397–407, 2012) investigated a double capsule assembly for use in piston-cylinder experiments that would allow hydrous, high-temperature, and high-pressure experiments to be conducted under controlled oxygen fugacity conditions. Using a platinum outer capsule containing a metal oxide oxygen buffer (Ni–NiO or Co–CoO) and H₂O, with an inner gold–palladium capsule containing hydrous melt, this study was able to compare the oxygen fugacity imposed by the outer capsule oxygen buffer with an oxygen fugacity estimated by the AuPdFe ternary system calibrated by Barr and Grove (Contrib Miner Petrol 160(5):631–643, 2010). H₂O loss or gain, as well as iron loss to the capsule walls and carbon contamination, is often observed in piston-cylinder experiments and often go unexplained. Only a few have attempted to actually quantify various aspects of these changes (Brooker et al. in Am Miner 83(9–10):985–994, 1998; Truckenbrodt and Johannes in Am Miner 84:1333–1335, 1999). It was one of the goals of Jakobsson (Contrib Miner Petrol 164(3):397–407, 2012) to address these issues by using and testing the AuPdFe solution model of Barr and Grove (Contrib Miner Petrol 160(5):631–643, 2010), as well as to constrain the oxygen fugacity of the inner capsule. The oxygen fugacities of the analyzed melts were assumed to be equal to those of the solid Ni–NiO and Co–CoO buffers, which is incorrect since the melts are all undersaturated in H₂O and the oxygen fugacities should therefore be lower than that of the buffer by 2 log $a_{{{\text{H}}_{ 2} {\text{O}}}}$ .  相似文献   

Adventive occurrence of the fouling serpulid Ficopomatus enigmaticus (Polychaeta) in New Zealand   总被引：1，自引：1，他引：0  

Geoffrey B. Read  Dennis P. Gordon 《新西兰海洋与淡水研究杂志》2013,47(3):269-273

The exotic marine‐fouling polychaete Ficopomatus enigmaticus (Fauvel) is recorded and described from New Zealand. Its sudden occurrence in New Zealand around 1967 was marked by its ecological prominence in estuaries of Whangarei and Auckland Harbours, as a nuisance species on submerged artificial structures including pleasure craft and power station intake pipes.  相似文献   

Zooidal budding in the cheilostomatous bryozoan Fenestrulina malusii var. thyreophora     

D. P. Gordon 《新西兰海洋与淡水研究杂志》2013,47(3-4):453-460

Zooidal budding in Fenestrulina malusii var. thyreophora is described and notes on the budding of Micropora mortenscni are included for comparison. In both, an autozooidal bud arises from a membranous window in the exterior wall of a dietella. Dietellae themselves arise by being delimited as dichotomies of the developing lateral walls of autozooids. Because of the structural discreteness of dietellae of Fenestrulina and Micropora, and Hastings’ (1963) observation that some dietellae of Microporella occur as avicularia, dietellae in the Microporellidae and Micropora are regarded as fully formed heterozooids and not merely as incipient zooid buds, as lateral septulae are. The formation of dietellae in Fenestrulina and Micropora is a continuous process, and comparable with the con‐strictive budding of distal autozooids of Membranipora and Metrarabdotos.  相似文献   

Intra-crater glacial processes in central Utopia Planitia, Mars     

Geoffrey Pearce  Gordon R. Osinski  Richard J. Soare 《Icarus》2011,212(1):86-95

We describe and interpret a series of previously unidentified glacial-like lobes (34-43°N; 107-125°E) that were discovered as part of a survey of large (D > 5 km) impact craters in Utopia Planitia, one of the great northern plains of Mars. The lobes have characteristics that are consistent with a glacial origin. Evidence includes curvilinearity of form, lineations and ridges, and surface textures that are thought to form by the sublimation of near-surface volatiles. The lobes display morphologies that range from wedge-shaped to near-circular to elongate. The flow directions are towards the northern walls in the case of craters with large single lobes, and in all directions in the case of the largest (D > 30 km) craters. Concentric crater fill is also interspersed within craters of our study region, with such craters having much higher filling rates than those with flow lobes. We suggest that the impact crater population in south-west Utopia Planitia demonstrates a spectrum of glacial modifications, from low levels of filling in the case of craters with elongate lobes at one extreme, to concentric crater fill in highly-filled craters at the other.  相似文献   

Seismic anisotropy in granite at the Underground Research Laboratory, Manitoba   总被引：2，自引：0，他引：2  

Gordon M. Holmes  Stuart Crampin  & R. Paul Young 《Geophysical Prospecting》2000,48(3):415-435

The Shear-Wave Experiment at Atomic Energy of Canada Limited's Underground Research Laboratory was probably the first controlled-source shear-wave survey in a mine environment. Taking place in conjunction with the excavation of the Mine-by test tunnel at 420 m depth, the shear-wave experiment was designed to measure the in situ anisotropy of the rockmass and to use shear waves to observe excavation effects using the greatest variety of raypath directions of any in situ shear-wave survey to date. Inversion of the shear-wave polarizations shows that the anisotropy of the in situ rockmass is consistent with hexagonal symmetry with an approximate fabric orientation of strike 023° and dip 35°. The in situ anisotropy is probably due to microcracks with orientations governed by the in situ stress field and to mineral alignment within the weak gneissic layering. However, there is no unique interpretation as to the cause of the in situ anisotropy as the fabric orientation agrees approximately with both the orientation expected from extensive-dilatancy anisotropy and that of the gneissic layering. Eight raypaths with shear waves propagating wholly or almost wholly through granodiorite, rather than granite, do not show the expected shear-wave splitting and indicate a lower in situ anisotropy, which may be due to the finer grain size and/or the absence of gneissic layering within the granodiorite. These results suggest that shear waves may be used to determine crack and mineral orientations and for remote monitoring of a rockmass. This has potential applications in mining and waste monitoring.  相似文献   

Improved structural interpretation of legacy 3D seismic data from Karee platinum mine (South Africa) through the application of novel seismic attributes     

Musa S.D. Manzi  Gordon R.J. Cooper  Alireza Malehmir  Raymond J. Durrheim 《Geophysical Prospecting》2020,68(1):145-163

Seismic detection of faults, dykes, potholes and iron-rich ultramafic pegmatitic bodies is of great importance to the platinum mining industry, as these structures affect safety and efficiency. The application of conventional seismic attributes (such as instantaneous amplitude, phase and frequency) in the hard-rock environment is more challenging than in soft-rock settings because the geology is often complex, reflections disrupted and the seismic energy strongly scattered. We have developed new seismic attributes that sharpen seismic reflections, enabling additional structural information to be extracted from hard-rock seismic data. The symmetry attribute is based on the invariance of an object with respect to transformations such as rotation and reflection; it is independent of the trace reflection amplitude, and hence a better indicator of the lateral continuity of thin and weak reflections. The reflection-continuity detector attribute is based on the Hilbert transform; it enhances the visibility of the peaks and troughs of the seismic traces, and hence the continuity of weak reflections. We demonstrate the effectiveness of these new seismic attributes by applying them to a legacy 3D seismic data set from the Bushveld Complex in South Africa. These seismic attributes show good detection of deep-seated thin (∼1.5 m thick) platinum ore bodies and their associated complex geological structures (faults, dykes, potholes and iron-rich ultramafic pegmatites). They provide a fast, cost-effective and efficient interpretation tool that, when coupled with horizon-based seismic attributes, can reveal structures not seen in conventional interpretations.  相似文献   

DMSP and DMS dynamics and microzooplankton grazing in the Labrador Sea: application of the dilution technique     

Gordon V. Wolfe  Maurice Levasseur  Guy Cantin  Sonia Michaud 《Deep Sea Research Part I: Oceanographic Research Papers》2000,47(12):687

We adapted the dilution technique to study microzooplankton grazing of algal dimethylsulfoniopropionate (DMSP) vs. Chl a, and to estimate the impact of microzooplankton grazing on dimethyl sulfide (DMS) production in the Labrador Sea. Phytoplankton numbers were dominated by autotrophic nanoflagellates in the Labrador basin, but diatoms and colonial Phaeocystis pouchetii contributed significantly to phytomass at several high chlorophyll stations and on the Newfoundland and Greenland shelfs. Throughout the region, growth of algal Chl a and DMSP was generally high (0.2–1 d⁻¹), but grazing rates were lower and more variable, characteristic of the early spring bloom period. Production and consumption of Chl a vs. DMSP followed no clear pattern, and sometimes diverged greatly, likely because of their differing distributions among algal prey taxa and size class. In several experiments where Phaeocystis was abundant, we observed DMS production proportional to grazing rate, and we found clear evidence of DMS production by this haptophyte following physical stress such as sparging or filtration. It is possible that grazing-activated DMSP cleavage by Phaeocystis contributes to grazer deterrence: protozoa and copepods apparently avoided healthy colonies (as judged by relative growth and grazing rates of Chl a and DMSP), and grazing of Phaeocystis was significant only at one station where cells were in poor condition. Although we hoped to examine selective grazing on or against DMSP-containing algal prey, the dilution technique cannot differentiate selective ingestion and varying digestion rates of Chl a and DMSP. We also found that the dilution method alone was poorly suited for assessing the impact of grazing on dissolved sulfur pools, because of rapid microbial consumption and the artifactual release of DMSP and DMS during filtration. Measuring and understanding the many processes affecting organosulfur cycling by the microbial food web in natural populations remain a technical challenge that will likely require a combination of techniques to address.  相似文献