High-temperature emplacement of the Cerro Galán and Toconquis Group ignimbrites (Puna plateau,NW Argentina) determined by TRM analyses     

Chiara Lesti  Massimiliano Porreca  Guido Giordano  Massimo Mattei  Raymond A. F. Cas  Heather M. N. Wright  Chris B. Folkes  Josè Viramonte 《Bulletin of Volcanology》2011,73(10):1535-1565

Estimates of pyroclastic flow emplacement temperatures in the Cerro Galán ignimbrite and Toconquis Group ignimbrites were determined using thermal remanent magnetization of lithic clasts embedded within the deposits. These ignimbrites belong to the Cerro Galán volcanic system, one of the largest calderas in the world, in the Puna plateau, NW Argentina. Temperature estimates for the 2.08-Ma Cerro Galán ignimbrite are retrieved from 40 sites in 14 localities (176 measured clasts), distributed at different distances from the caldera and different stratigraphic heights. Additionally, temperature estimates were obtained from 27 sample sites (125 measured clasts) from seven ignimbrite units forming the older Toconquis Group (5.60–4.51 Ma), mainly outcropping along a type section at Rio Las Pitas, Vega Real Grande. The paleomagnetic data obtained by progressive thermal demagnetization show that the clasts of the Cerro Galán ignimbrite have one single magnetic component, oriented close to the expected geomagnetic field at the time of emplacement. Results show therefore that most of the clasts acquired a new magnetization oriented parallel to the magnetic field at the moment of the ignimbrite deposition, suggesting that the clasts were heated up to or above the highest blocking temperature (T _b) of the magnetic minerals (T _b = 580°C for magnetite; T _b = 600–630°C for hematite). We obtained similar emplacement temperature estimations for six out of the seven volcanic units belonging to the Toconquis Group, with the exception of one unit (Lower Merihuaca), where we found two distinct magnetic components. The estimation of emplacement temperatures in this latter case is constrained at 580–610°C, which are lower than the other ignimbrites. These estimations are also in agreement with the lowest pre-eruptive magma temperatures calculated for the same unit (i.e., 790°C; hornblende–plagioclase thermometer; Folkes et al. 2011b). We conclude that the Cerro Galán ignimbrite and Toconquis Group ignimbrites were emplaced at temperatures equal to or higher than 620°C, except for Lower Merihuaca unit emplaced at lower temperatures. The homogeneity of high temperatures from proximal to distal facies in the Cerro Galán ignimbrite provides constraints for the emplacement model, marked by a relatively low eruption column, low levels of turbulence, air entrainment, surface–water interaction, and a high level of topographic confinement, all ensuring minimal heat loss.  相似文献   

Magnetic properties and cation ordering of nanopowders of the synthetic analogue of kuramite, Cu3SnS4     

Francesco Di Benedetto  Daniele Borrini  Andrea Caneschi  Gabriele Fornaciai  Massimo Innocenti  Alessandro Lavacchi  Carlo Andrea Massa  Giordano Montegrossi  Werner Oberhauser  Luca A. Pardi  Maurizio Romanelli 《Physics and Chemistry of Minerals》2011,38(6):483-490

An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu₃SnS₄, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu₃SnS₄ crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)₂Cu(II)SnS₄ and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites.  相似文献   

Global mass wasting during the Middle Ordovician: Meteoritic trigger or plate-tectonic environment?     

Guido Meinhold  Arzu Arslan  Oliver Lehnert  Gérard M. Stampfli 《Gondwana Research》2011,19(2):535-541

Mass wasting at continental margins on a global scale during the Middle Ordovician has recently been related to high meteorite influx. Although a high meteorite influx during the Ordovician should not be neglected, we challenge the idea that mass wasting was mainly produced by meteorite impacts over a period of almost 10 Ma. Having strong arguments against the impact-related hypothesis, we propose an alternative explanation, which is based on a re-evaluation of the mass wasting sites, considering their plate-tectonic distribution and the global sea level curve. A striking and important feature is the distribution of most of the mass wasting sites along continental margins characterised by periods of magmatism, terrane accretion and continental or back-arc rifting, respectively, related to subduction of oceanic lithosphere. Such processes are commonly connected with seismic activity causing earthquakes, which can cause downslope movement of sediment and rock. Considering all that, it seems more likely that most of this mass wasting was triggered by earthquakes related to plate-tectonic processes, which caused destabilisation of continental margins resulting in megabreccias and debris flows. Moreover, the period of mass wasting coincides with sea level drops during global sea level lowstand. In some cases, sea level drops can release pore-water overpressure reducing sediment strength and hence promoting instability of sediment at continental margins. Reduced pore-water overpressure can also destabilise gas hydrate-bearing sediment, causing slope failure, and thus resulting in submarine mass wasting. Overall, the global mass wasting during the Middle Ordovician does not need meteoritic trigger.  相似文献   

Impact of single inclined faults on the fluid flow and heat transport: results from 3-D finite element simulations   总被引：1，自引：1，他引：0  

Yvonne Cherubini  Mauro Cacace  Guido Blöcher  Magdalena Scheck-Wenderoth 《Environmental Earth Sciences》2013,70(8):3603-3618

The impact of inclined faults on the hydrothermal field is assessed by adding simplified structural settings to synthetic models. This study is innovative in carrying out numerical simulations because it integrates the real 3-D nature of flow influenced by a fault in a porous medium, thereby providing a useful tool for complex geothermal modelling. The 3-D simulations for the coupled fluid flow and heat transport processes are based on the finite element method. In the model, one geological layer is dissected by a dipping fault. Sensitivity analyses are conducted to quantify the effects of the fault’s transmissivity on the fluid flow and thermal field. Different fault models are compared with a model where no fault is present to evaluate the effect of varying fault transmissivity. The results show that faults have a significant impact on the hydrothermal field. Varying either the fault zone width or the fault permeability will result in relevant differences in the pressure, velocity and temperature field. A linear relationship between fault zone width and fluid velocity is found, indicating that velocities increase with decreasing widths. The faults act as preferential pathways for advective heat transport in case of highly transmissive faults, whereas almost no fluid may be transported through poorly transmissive faults.  相似文献   

Levels and spatial distribution of polychlorinated biphenyls (PCBs) in superficial sediment from 15 Italian Marine Protected Areas (MPA)     

Karla Pozo  Denise Lazzerini  Guido Perra  Valerio Volpi  Simonetta Corsolini  Silvano Focardi 《Marine pollution bulletin》2009,58(5):773-776

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Impact of Poroelastic Response of Sandstones on Geothermal Power Production     

Guido Blöcher  Günter Zimmermann  Harald Milsch 《Pure and Applied Geophysics》2009,166(5-7):1107-1123

During geothermal power production using a borehole doublet consisting of a production and injection well, the reservoir conditions such as permeability k, porosity φ and Skempton coefficient B at the geothermal research site Gross Schoenebeck/Germany will change. Besides a temperature decrease at the injection well and a change of the chemical equilibrium, also the pore pressure p _p will vary in a range of approximately 44 MPa ± 10 MPa in our reservoir at ?3850 to ?4258 m depth. This leads to a poroelastic response of the reservoir rocks depending on effective pressure p _eff (difference between mean stress and pore pressure), resulting in a change in permeability k, porosity φ and the poroelastic parameter Skempton coefficient B. Hence, we investigated the effective pressure dependency of Flechtinger sandstone, an outcropping equivalent of the reservoir rock via laboratory experiments. The permeability decreased by 21% at an effective pressure range from 3 to 30 MPa, the porosity decreased by 11% (p _eff = 6 to 65 MPa) and the Skempton coefficient decreased by 24% (p _eff = 4 to 25 MPa). We will show which mechanisms lead to the change of the mentioned hydraulic and poroelastic parameters and the influence of these changes on the productivity of the reservoir. The most significant changes occur at low effective pressures until 15 to 20 MPa. For our in situ reservoir conditions p _eff = 43 MPa a change of 10 MPa effective pressure will result in a change in matrix permeability of less than 4% and in matrix porosity of less than 2%. Besides natural fracture systems, fault zones and induced hydraulic fractures, the rock matrix its only one part of geothermal systems. All components can be influenced by pressure, temperature and chemical reactions. Therefore, the determined small poroelastic response of rock matrix does not significantly influence the sustainability of the geothermal reservoir.  相似文献   

The Holocene Secche di Lazzaro phreatomagmatic succession (Stromboli,Italy): evidence of pyroclastic density current origin deduced by facies analysis and AMS flow directions     

Guido Giordano  Massimiliano Porreca  Pietro Musacchio  Massimo Mattei 《Bulletin of Volcanology》2008,70(10):1221-1236

The edifice of Stromboli volcano gravitationally collapsed several times during its volcanic history (>100 ka–present). The largest Holocene event occurred during the final stage of the Neostromboli activity (∼13–5 ka), and was accompanied by the emplacement of phreatomagmatic and lahar deposits, known as the Secche di Lazzaro succession. A stratigraphic and paleomagnetic study of the Secche di Lazzaro deposits allows the interpretation of the emplacement and the eruptive processes. We identify three main units within the succession that correspond to changing eruption conditions. The lower unit (UA) consists of accretionary lapilli-rich, thinly bedded, parallel- to cross-stratified ash deposits, interpreted to indicate the early stages of the eruption and emplacement of dilute pyroclastic density currents. Upward, the second unit (UB) of the deposit is more massive and the beds thicker, indicating an increase in the sedimentation rate from pyroclastic density currents. The upper unit (UC) caps the succession with thick, immediately post-eruptive lahars, which reworked ash deposited on the volcano’s slope. Flow directions obtained by Anisotropy of Magnetic Susceptibility (AMS) analysis of the basal bed of UA at the type locality suggest a provenance of pyroclastic currents from the sea. This is interpreted to be related to the initial base-surges associated with water–magma interaction that occurred immediately after the lateral collapse, which wrapped around the shoulder of the sector collapse scar. Upward in the stratigraphy (upper beds of UA and UB) paleoflow directions change and show a provenance from the summit vent, probably related to the multiple collapses of a vertical, pulsatory eruptive column.  相似文献   

Volcanology,history and myths of the Lake Albano maar (Colli Albani volcano,Italy)     

A.A. De Benedetti  R. Funiciello  G. Giordano  G. Diano  E. Caprilli  M. Paterne 《Journal of Volcanology and Geothermal Research》2008

The polygenetic Albano maar is the most recent centre of the Colli Albani volcano, located just few kilometres to the south-east of Roma. Presently the maar hosts a 167.5 m deep crater lake, the deepest in Europe. The maar is to be considered quiescent, as phreatic activity is documented throughout the Holocene. This paper illustrates the close relationships between the activity of the maar and the history of settlement in the Roman region as recorded in the geology, archaeology, history and legends of the area. Severe fluctuations of the groundwater table and catastrophic overflows of the Lake Albano from the maar rim had occurred prior to and after the early prehistoric settlements dated in the maar area at the Eneolithic times (ca. III millennium B.C.). Repeated lahars occurred along the northwestern slope of the maar filling in the paleodrainage network and forming a vast plain. Paleohydraulic analyses on fluvial and lahar deposits originated from the Holocene phreatic activity of the Albano maar indicate sediment–water flows in excess of hundreds of cubic metres per second. Absolute age determinations of the paleosoil underlying one of the most recent deposits of the lahar succession at 5800 ± 100 yr B.P. (¹⁴C CAL) are in perfect agreement with the age of the overlying Eneolithic age settlements. The last catastrophic overflow is described in the Roman literature as a consequence of the anger of Poseidon against the Romans in 398 B.C. for their war against the Etruscans. In 394 B.C. the Romans decided to prevent the repetition of such events by the excavation through the maar crater wall of a 1.5 km long drain tunnel, which is still operational, keeping the lake 70 m below the lowest point of the maar rim. This tunnel drain may be regarded as the first prevention device for volcanic hazard in history and shows an unprecedented development of the engineering technology under the pressure of hazard perception. The surprising and still largely unknown results of this study are very important to redefine the hazard of the Roman region.  相似文献   

Volcanoes and human history     

K.V. Cashman  G. Giordano 《Journal of Volcanology and Geothermal Research》2008

The study of volcanic hazards leads inevitably to questions of how past cultures have lived in volcanically active regions of the world. Here we summarize linkages between volcanological, archaeological and anthropological studies of historic and prehistoric volcanic eruptions, with the goal of evaluating the impact of past eruptions on human populations to better prepare for future events. We use examples from papers collected in this volume to illustrate ways in which volcanological studies aid archaeological investigations by providing basic stratigraphic markers and information about the nature and timing of specific volcanic events. We then turn to archaeological perspectives, which provide physical evidence of the direct impacts of volcanic eruptions, such as site abandonment and human migration, as well as indirect impacts on local cultures as reflected in human artifacts. Finally we review anthropological studies of societal responses to past and recent volcanic eruptions. We pay particular attention to both the psychological impact of catastrophic events and records of these impacts encoded within oral traditions. Taken together these studies record drastic short-term eruption impacts but adaptation to volcanic activity over the longer term, largely through strategies of adaptive land use.  相似文献   

Places of the Holocaust: Towards a model of GIS of place     

Alberto Giordano  Tim Cole 《Transactions in GIS》2020,24(4):842-857

Progress toward developing a GIS of place can only follow from an understanding of what place is, and this understanding draws on geographical theory. Here—following Agnew, Tuan, and others—we consider place as being made up of three components—location, locale, and sense of place—which are recognizable at multiple scales and vary historically as a product of social and political processes. Using the testimonies of two survivors of the Holocaust, we sketch the components of a model for a GIS of place that allows for this theory of place to be visualized and analyzed. The model is, crucially, both multi‐scalar and sensitive to uncertainty, as a GIS of place needs to be able to zoom in and out of the different scales at which place is experienced, as well as capture both uncertain data and uncertainty as data. We see potential in the representations proposed for scaling up from the anecdotal to the general in the sense that any narrative can be grouped and classified according to places and scales as shown here. The challenge in developing a GIS of place along the lines we propose here is to design a new set of functionalities that can do so.  相似文献