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排序方式: 共有418条查询结果,搜索用时 46 毫秒
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Daniela Comelli Massimo D'orazio Luigi Folco Mahmud El‐Halwagy Tommaso Frizzi Roberto Alberti Valentina Capogrosso Abdelrazek Elnaggar Hala Hassan Austin Nevin Franco Porcelli Mohamed G. Rashed Gianluca Valentini 《Meteoritics & planetary science》2016,51(7):1301-1309
Scholars have long discussed the introduction and spread of iron metallurgy in different civilizations. The sporadic use of iron has been reported in the Eastern Mediterranean area from the late Neolithic period to the Bronze Age. Despite the rare existence of smelted iron, it is generally assumed that early iron objects were produced from meteoritic iron. Nevertheless, the methods of working the metal, its use, and diffusion are contentious issues compromised by lack of detailed analysis. Since its discovery in 1925, the meteoritic origin of the iron dagger blade from the sarcophagus of the ancient Egyptian King Tutankhamun (14th C. BCE) has been the subject of debate and previous analyses yielded controversial results. We show that the composition of the blade (Fe plus 10.8 wt% Ni and 0.58 wt% Co), accurately determined through portable x‐ray fluorescence spectrometry, strongly supports its meteoritic origin. In agreement with recent results of metallographic analysis of ancient iron artifacts from Gerzeh, our study confirms that ancient Egyptians attributed great value to meteoritic iron for the production of precious objects. Moreover, the high manufacturing quality of Tutankhamun's dagger blade, in comparison with other simple‐shaped meteoritic iron artifacts, suggests a significant mastery of ironworking in Tutankhamun's time. 相似文献
3.
Gazzola Laura Ferronato Massimiliano Frigo Matteo Janna Carlo Teatini Pietro Zoccarato Claudia Antonelli Massimo Corradi Anna Dacome Maria Carolina Mantica Stefano 《Computational Geosciences》2021,25(5):1731-1750
Computational Geosciences - Anthropogenic land subsidence can be evaluated and predicted by numerical models, which are often built over deterministic analyses. However, uncertainties and... 相似文献
4.
Maurizio Gemelli Massimo D'Orazio Luigi Folco 《Geostandards and Geoanalytical Research》2015,39(1):55-69
We evaluate the performance of a hand‐held XRF (HHXRF) spectrometer for the bulk analysis of iron meteorites. Analytical precision and accuracy were tested on metal alloy certified reference materials and iron meteorites of known chemical composition. With minimal sample preparation (i.e., flat or roughly polished surfaces) HHXRF allowed the precise and accurate determination of most elements heavier than Mg, with concentrations > 0.01% m/m in metal alloy CRMs, and of major elements Fe and Ni and minor elements Co, P and S (generally ranging from 0.1 to 1% m/m) in iron meteorites. In addition, multiple HHXRF spot analyses could be used to determine the bulk chemical composition of iron meteorites, which are often characterised by sulfide and phosphide accessory minerals. In particular, it was possible to estimate the P and S bulk contents, which are of critical importance for the petrogenesis and evolution of Fe‐Ni‐rich liquids and iron meteorites. This study thus validates HHXRF as a valuable tool for use in meteoritics, allowing the rapid, non‐destructive (a) identification of the extraterrestrial origin of metallic objects (i.e., archaeological artefacts); (b) preliminary chemical classification of iron meteorites; (c) identification of mislabelled/unlabelled specimens in museums and private collections and (d) bulk analysis of iron meteorites. 相似文献
5.
Francesco Di Benedetto Daniele Borrini Andrea Caneschi Gabriele Fornaciai Massimo Innocenti Alessandro Lavacchi Carlo Andrea Massa Giordano Montegrossi Werner Oberhauser Luca A. Pardi Maurizio Romanelli 《Physics and Chemistry of Minerals》2011,38(6):483-490
An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu3SnS4, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu3SnS4 crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)2Cu(II)SnS4 and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites. 相似文献
6.
Chiara Lesti Massimiliano Porreca Guido Giordano Massimo Mattei Raymond A. F. Cas Heather M. N. Wright Chris B. Folkes Josè Viramonte 《Bulletin of Volcanology》2011,73(10):1535-1565
Estimates of pyroclastic flow emplacement temperatures in the Cerro Galán ignimbrite and Toconquis Group ignimbrites were
determined using thermal remanent magnetization of lithic clasts embedded within the deposits. These ignimbrites belong to
the Cerro Galán volcanic system, one of the largest calderas in the world, in the Puna plateau, NW Argentina. Temperature
estimates for the 2.08-Ma Cerro Galán ignimbrite are retrieved from 40 sites in 14 localities (176 measured clasts), distributed
at different distances from the caldera and different stratigraphic heights. Additionally, temperature estimates were obtained
from 27 sample sites (125 measured clasts) from seven ignimbrite units forming the older Toconquis Group (5.60–4.51 Ma), mainly
outcropping along a type section at Rio Las Pitas, Vega Real Grande. The paleomagnetic data obtained by progressive thermal
demagnetization show that the clasts of the Cerro Galán ignimbrite have one single magnetic component, oriented close to the
expected geomagnetic field at the time of emplacement. Results show therefore that most of the clasts acquired a new magnetization
oriented parallel to the magnetic field at the moment of the ignimbrite deposition, suggesting that the clasts were heated
up to or above the highest blocking temperature (T
b) of the magnetic minerals (T
b = 580°C for magnetite; T
b = 600–630°C for hematite). We obtained similar emplacement temperature estimations for six out of the seven volcanic units
belonging to the Toconquis Group, with the exception of one unit (Lower Merihuaca), where we found two distinct magnetic components.
The estimation of emplacement temperatures in this latter case is constrained at 580–610°C, which are lower than the other
ignimbrites. These estimations are also in agreement with the lowest pre-eruptive magma temperatures calculated for the same
unit (i.e., 790°C; hornblende–plagioclase thermometer; Folkes et al. 2011b). We conclude that the Cerro Galán ignimbrite and Toconquis Group ignimbrites were emplaced at temperatures equal to or higher
than 620°C, except for Lower Merihuaca unit emplaced at lower temperatures. The homogeneity of high temperatures from proximal
to distal facies in the Cerro Galán ignimbrite provides constraints for the emplacement model, marked by a relatively low
eruption column, low levels of turbulence, air entrainment, surface–water interaction, and a high level of topographic confinement,
all ensuring minimal heat loss. 相似文献
7.
Turbulent Transfer Between Street Canyons and the Overlying Atmospheric Boundary Layer 总被引:1,自引:1,他引:0
Pietro Salizzoni Massimo Marro Lionel Soulhac Nathalie Grosjean Richard J. Perkins 《Boundary-Layer Meteorology》2011,141(3):393-414
The turbulent exchange of momentum between a two-dimensional cavity and the overlying boundary layer has been studied experimentally,
using hot-wire anemometry and particle image velocimetry (PIV). Conditions within the boundary layer were varied by changing
the width of the canyons upstream of the test canyon, whilst maintaining the square geometry of the test canyon. The results
show that turbulent transfer is due to the coupling between the instabilities generated in the shear layer above the canyons
and the turbulent structures in the oncoming boundary layer. As a result, there is no single, unique velocity scale that correctly
characterizes all the processes involved in the turbulent exchange of momentum across the boundary layer. Similarly, there
is no single velocity scale that can characterize the different properties of the turbulent flow within the canyon, which
depends strongly on the way in which turbulence from the outer flow is entrained into the cavity and carried round by the
mean flow. The results from this study will be useful in developing simple parametrizations for momentum exchange in the urban
canopy, in situations where the street geometry consists principally of relatively long, uniform streets arranged in grid-like
patterns; they are unlikely to be applicable to sparse geometries composed of isolated three-dimensional obstacles. 相似文献
8.
9.
On the dependence of the saturated hydraulic conductivity upon the effective porosity through a power law model at different scales 下载免费PDF全文
We study the scale dependence of the saturated hydraulic conductivity Ks through the effective porosity ne by means of a newly developed power‐law model (PLM) which allows to use simultaneously measurements at different scales. The model is expressed as product between a single PLM (capturing the impact of the dominating scale) and a characteristic function κ? accounting for the correction because of the other scale(s). The simple (closed form) expression of the κ?‐function enables one to easily identify the scales which are relevant for Ks. The proposed model is then applied to a set of real data taken at the experimental site of Montalto Uffugo (Italy), and we show that in this case two (i.e. laboratory and field) scales appear to be the main ones. The implications toward an important application (solute transport) in Hydrology are finally discussed. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
10.